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Programmable interfacial Nanofluids for high-heat-flux Chip cooling via heat networks 高热流通量芯片通过热网冷却的可编程界面纳米流体
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-04 DOI: 10.1016/j.applthermaleng.2026.130142
Chenghang Li , Zhumei Luo , Shan Qing , Xiaohui Zhang , Zichang Shi , Guili He , Shuai Feng , Haoming Huang , Xiaoyu Huang , Jing Zhang
To overcome thermal bottlenecks in high–heat-flux chip cooling, we develop a programmable interfacial nanofluid (CuO@APTES/L-cysteine/SSA) through surface molecular engineering integrated with a multiscale framework spanning material synthesis, density functional theory (DFT), molecular dynamics (MD), microchannel experiments, and computational fluid dynamics (CFD) validation. DFT calculations confirm robust interfacial stability enabled by Si–O–Cu anchoring, yielding a total binding energy of −33.48 eV. Spectroscopic and microscopic characterizations verify ordered multilayer functionalization, defining a grafting maximum load (GML) of 174.97% and excellent dispersion stability (zeta potential up to +59 mV).
At 358.15 K and 2.5 vol%, the nanofluid achieves a thermal conductivity of 1.517 W/m·K (138.5% enhancement over water), significantly exceeding Maxwell predictions, with the optimized S30.4 formulation reaching 1.79 W/m·K. Molecular-level analysis reveals a transition from passive to programmable interfacial heat transport, characterized by enhanced CuO radial distribution functions, increased coordination numbers, and strengthened SiO and OS heat-transfer pathways.
Microchannel experiments demonstrate a 14.7% reduction in junction temperature and a 17.3% improvement in temperature uniformity at 10 W/cm2, accompanied by reduced thermal resistance and improved convective heat transfer. CFD predictions agree well with experiments (deviation <1.5%) and confirm superior cooling performance up to 10,000 W/cm2 with only a modest pressure-drop penalty. Thereby establishing a validated multiscale framework that provides predictive insight into interfacial heat transport and guides the design of advanced nanofluids for high–heat-flux electronic cooling.
为了克服高热流通量芯片冷却的热瓶颈,我们通过表面分子工程与跨材料合成、密度泛函理论(DFT)、分子动力学(MD)、微通道实验和计算流体动力学(CFD)验证的多尺度框架相结合,开发了可编程界面纳米流体(CuO@APTES/ l -半胱氨酸/SSA)。DFT计算证实了Si-O-Cu锚定的界面稳定性,总结合能为−33.48 eV。光谱和微观表征验证了有序的多层功能化,确定了接枝最大负载(GML)为174.97%和出色的色散稳定性(zeta电位高达+59 mV)。在358.15 K和2.5 vol%的条件下,纳米流体的导热系数达到1.517 W/m·K(比水提高138.5%),显著超过Maxwell预测,优化后的S30.4配方达到1.79 W/m·K。分子水平分析揭示了从被动到可编程界面热传递的转变,其特征是CuO径向分布函数增强,配位数增加,SiO和OS传热途径增强。微通道实验表明,在10w /cm2下,结温降低14.7%,温度均匀性提高17.3%,同时热阻降低,对流换热改善。CFD预测与实验结果吻合良好(偏差<;1.5%),并证实了高达10,000 W/cm2的卓越冷却性能,而压降损失较小。因此,建立了一个有效的多尺度框架,为界面热传递提供了预测性的见解,并指导设计用于高热流密度电子冷却的先进纳米流体。
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引用次数: 0
Efficient thermal management of lithium-ion battery modules using a simplified two-phase immersion cooling system 采用简化的两相浸入式冷却系统实现锂离子电池模块的高效热管理
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-04 DOI: 10.1016/j.applthermaleng.2026.129993
He Bai , Xiutao Li , Zhenyang Zhou , Yue Zhang , Zhaoyu Jin , Haoyu Wang , Penglun Zheng , Xiaomeng Zhou
With the increasing energy density and fast-charging requirements of lithium-ion batteries (LIBs), effective thermal management has become critical for ensuring safety, performance, and longevity. This study proposes a simplified two-phase immersion cooling (TLIC) system that eliminates the conventional condensation reflux apparatus, thereby reducing system complexity. Using fluorinated liquid coolants and an optimized battery housing, the system's thermal management performance was evaluated under high-rate charge-discharge conditions. Experimental results demonstrate that TLIC significantly outperforms air cooling (AC) and single-phase immersion cooling (SLIC), reducing the maximum temperature by 56% and the maximum temperature difference by 88% relative to AC, maintaining the maximum battery temperature below 37.7 °C and temperature differences within 1.7 °C under 3C cycling at 25 °C. Even at elevated ambient temperatures up to 40 °C, TLIC maintains effective cooling with a heat dissipation efficiency exceeding 80%. Numerical simulations further validate the experimental findings and reveal the influence of ambient temperature on boiling behavior and heat transfer efficiency. The proposed TLIC system offers a promising solution for next-generation electric vehicles and energy storage systems by combining high cooling performance with structural simplicity.
随着锂离子电池(lib)的能量密度和快速充电要求的不断提高,有效的热管理对于确保锂离子电池的安全性、性能和寿命至关重要。本研究提出了一种简化的两相浸入式冷却(TLIC)系统,该系统消除了传统的冷凝回流装置,从而降低了系统的复杂性。使用含氟液体冷却剂和优化的电池外壳,在高倍率充放电条件下评估了系统的热管理性能。实验结果表明,TLIC明显优于空气冷却(AC)和单相浸没冷却(SLIC),相对于AC, TLIC最大温度降低56%,最大温差降低88%,在25℃下的3C循环下,电池最大温度保持在37.7℃以下,温差在1.7℃以内。即使环境温度高达40℃,TLIC仍能保持有效散热,散热效率超过80%。数值模拟进一步验证了实验结果,揭示了环境温度对沸腾行为和换热效率的影响。该TLIC系统结合了高冷却性能和结构简单性,为下一代电动汽车和储能系统提供了一个有前景的解决方案。
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引用次数: 0
Numerical investigation of phase change material (PCM) melting in a two-dimensional rotary kiln 二维回转窑相变材料(PCM)熔化的数值研究
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-04 DOI: 10.1016/j.applthermaleng.2026.130049
Athanasios Balachtsis, Yannis Dimakopoulos, John Tsamopoulos
This fundamental study investigates the coupled thermal and fluid dynamics including melting of a granular bed within a rotating kiln, a process critical to optimizing efficiency in various material processing applications, like clinker production. Unlike previous simpler models, the framework simultaneously resolves the deformable gas-bed interface via a phase-field method and the internal solid-liquid phase change using the enthalpy method. A temperature dependent viscosity technique is employed, assigning extremely high viscosity to the solid phase and low viscosity to the liquid. This allows the solid-liquid transition to be captured implicitly without mesh deformation. The simulations reveal that doubling the wall angular velocity from 1rpm to 2rpm reduces the total melting time by approximately 38%. Lower melt viscosity accelerates flow and heat transport, while higher viscosity limits recirculation and delays melting. Conversely, increasing the characteristic temperature difference intensifies heat transfer and leads to faster melting without altering the underlying mechanisms. Furthermore, the analysis identifies a distinct regime transition in heat transfer mechanisms at a critical value of Pr120, separating buoyancy-driven flows from forced convection regimes. The findings conclusively demonstrate that natural convection, as indicated by the Richardson number, plays an indispensable role in the melting rate. Higher filling degrees prolonged the melting duration due to increased thermal mass, whereas lower filling degrees intensified circulation and accelerated melting. Finally, a sensitivity analysis examines a more realistic scenario by prescribing distinct properties for the solid and liquid phases.
这项基础研究调查了热和流体动力学的耦合,包括旋转窑内颗粒床的熔化,这是优化各种材料处理应用(如熟料生产)效率的关键过程。与以往的简单模型不同,该框架同时通过相场法求解可变形气床界面,并使用焓法求解内部固液相变。采用温度依赖粘度技术,将极高的粘度分配给固相而将低粘度分配给液体。这允许在没有网格变形的情况下隐式捕获固-液过渡。模拟结果表明,将壁角速度从1rpm增加一倍至2rpm可使总熔化时间缩短约38%。较低的熔体粘度加速流动和热传输,而较高的粘度限制再循环和延迟熔化。相反,增加特征温差会加强传热,导致更快的熔化,而不会改变潜在的机制。此外,分析还发现,在Pr≈120的临界值处,传热机制中存在明显的模式转变,将浮力驱动的流动与强迫对流区分开。研究结果确凿地表明,理查德森数表明的自然对流在融化速度中起着不可缺少的作用。充填度越高,热质量越大,融化时间越长;充填度越低,循环加剧,融化速度加快。最后,灵敏度分析通过规定固相和液相的不同性质来检验更现实的情况。
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引用次数: 0
Leveraging band bending in SnS/SnSe type-I heterojunction for high thermoelectric performance and on-chip hotspot cooling 利用SnS/SnSe i型异质结的能带弯曲实现高热电性能和片上热点冷却
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-04 DOI: 10.1016/j.applthermaleng.2026.130042
Yixuan Liu , Lifu Yan , Shangchao Lin
Thermoelectric thin films are ideal for highly integrated on-chip cooling, especially for local hotspots. However, the thermoelectric figure of merit (ZT) of thin films is far below their bulk material counterparts. Environmentally friendly SnSe-based heterojunction thin films have been hypothesized as a promising solution for high performance thermoelectric films due to additional carrier transfer at the interface. However, a rational design of heterojunctions with experimentally relevant larger thickness has not been reported yet. Therefore, in this work we firstly design larger-thickness SnS/SnSe heterojunctions to leverage electronic band bending at the SnS-SnSe interface. The designed multilayer (SnS)6/(SnSe)6 heterojunction shows a remarkable power factor, up to 96.4 μW cm−1 K−2 at 500 K, across a wide range of charge carrier concentrations for easier doping. It shows significant improvement compared to other thin films, ∼8 times of the predicted SnSe monolayer here and ∼ 3.7 times of the highest experimental value in SnSe thin films. The SnS/SnSe heterojunctions not only have excited electrons from the SnS layer near the SnS/SnSe interface, but also have increased total carrier mobility because electron transfer caused by band bending provides a fast channel for hole transport along the b-axis (in-plane). Meanwhile, the SnS/SnSe heterojunctions exhibit double-peaked high PFs with respect to the carrier concentrations under compressive strains due to the reduced band gap and the band convergence effect. After thermal conductivity estimation, the in-plane ZT of the (SnS)6/(SnSe)6 heterojunction is estimated to range from 0.81 to 1.6 at temperatures from 300 to 500 K, which is very high among the thin film thermoelectric materials. Finally, we theoretically demonstrate that integrating the (SnS)6/(SnSe)6 heterojunction-based thermoelectric thin film onto a chip can achieve a maximum cooling power density of ∼13.5 W cm−2, showing great promises for local on-chip hotspot cooling in computing and power electronics.
热电薄膜是高度集成的片上冷却的理想选择,特别是对于局部热点。然而,薄膜的热电优值(ZT)远低于其块状材料。环境友好的snse基异质结薄膜被假设为高性能热电薄膜的有前途的解决方案,因为在界面处有额外的载流子转移。然而,合理设计具有实验相关的更大厚度的异质结尚未见报道。因此,在这项工作中,我们首先设计了更厚的SnS/SnSe异质结,以利用SnS-SnSe界面上的电子能带弯曲。所设计的多层(SnS)6/(SnSe)6异质结具有显著的功率因数,在500 K时功率因数高达96.4 μW cm−1 K−2,并且在较宽的载流子浓度范围内易于掺杂。与其他薄膜相比,它显示出显著的改善,是这里预测的SnSe单层的8倍,是SnSe薄膜中最高实验值的3.7倍。SnS/SnSe异质结不仅从SnS/SnSe界面附近的SnS层激发电子,而且由于能带弯曲引起的电子转移为沿b轴(平面内)的空穴传输提供了快速通道,从而增加了载流子的总迁移率。同时,由于带隙减小和带收敛效应,SnS/SnSe异质结在压缩应变下对载流子浓度表现出双峰高的PFs。经过导热系数估算,在300 ~ 500 K温度下,(SnS)6/(SnSe)6异质结的面内ZT在0.81 ~ 1.6之间,在薄膜热电材料中是非常高的。最后,我们从理论上证明,将(SnS)6/(SnSe)6异质结热电薄膜集成到芯片上可以实现约13.5 W cm−2的最大冷却功率密度,为计算和电力电子的局部片上热点冷却提供了巨大的希望。
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引用次数: 0
Comprehensive structural parameter for thermal optimization of PCM composites under constant heat flux: Experiments and simulations 恒热流密度下PCM复合材料热优化的综合结构参数:实验与仿真
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-03 DOI: 10.1016/j.applthermaleng.2026.130101
Yufeng Shuai , Chuan Zhang , Xusheng Hu , Siyuan He , Xiao-lu Gong
In this study, we focus on the comprehensive structural parameter A introduced and validated in our prior research. Five distinct metal foam samples using aluminum alloy AS7G through 3D printing were fabricated. The heating was maintained at a constant heat flux and positioned at various locations on the phase change material-metal foam composites (PCM composites). Our investigation encompasses both simulations and experiments, to explore the thermal behaviors of samples using parameter A under diverse heating conditions. The thermal performance of PCM composites is assessed with different indicators that we proposed. We examine the relation between the structural parameter A and the thermal performance and also the impact of gravity, sample size, heat flux, structural non-homogeneity and ambient temperature. This paper establishes the reliability of parameter A as a structural optimization criterion for metal foam. Furthermore, we find that if the heat transfer mode changes, the relation between the structural parameter and the thermal performance can be different. For conduction-dominated mode, lower parameter A structure shows better performance. For convection-dominated mode, higher parameter A structure improves performance. This may provide explanation for the existing debut regarding the influence of pore density. The study concludes with a comprehensive strategy for structural optimization of thermal performance of PCM composite based on all obtained results.
在本研究中,我们重点研究在我们之前的研究中引入并验证的综合结构参数A。采用铝合金AS7G,通过3D打印制作了5种不同的金属泡沫样品。在相变材料-金属泡沫复合材料(PCM)上,加热保持恒定的热流密度,并放置在不同的位置。我们的研究包括模拟和实验,以探索使用参数A的样品在不同加热条件下的热行为。采用我们提出的不同指标对PCM复合材料的热性能进行了评价。我们研究了结构参数A与热性能的关系,以及重力、样本量、热流密度、结构非均匀性和环境温度的影响。本文建立了参数A的可靠度作为泡沫金属结构优化准则。此外,我们发现,当换热方式改变时,结构参数与热性能之间的关系可能会有所不同。在电导主导模式下,A参数越低的结构性能越好。对于对流主导模式,更高的参数A结构可以提高性能。这可以解释目前关于孔隙密度影响的初步研究。在此基础上,提出了综合优化PCM复合材料热性能的结构策略。
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引用次数: 0
Study on thermophysical properties and performance enhancement of novel quaternary molten salt for thermal energy storage 新型储热用季铵盐热物性及增强性能研究
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-03 DOI: 10.1016/j.applthermaleng.2026.130122
Yuanyuan Wang, Yue Wang, Yuanwei Lu, Yuting Wu, Cancan Zhang
Molten salts are commonly used as heat transfer and thermal storage media in CSP systems. However, conventional molten salts may have drawbacks such as high melting points, narrow operating temperature ranges, and low thermal conductivity, which limit the overall system efficiency. In this work, a novel quaternary nitrate-nitrite molten salt is developed, featuring low melting point, wide operating temperature range, high thermal conductivity, and low cost. The melting point of the quaternary salt (composed of 41.4wt%KNO3–32.7wt%NaNO2–7.9wt%KNO2-18 wt% Ca(NO3)2·4H2O) is 96.6 °C, and the decomposition temperature is 622.3 °C. The quaternary salt shows an average specific heat capacity of 1.58 J∙g−1∙K−1 and an average thermal conductivity of 0.574 W∙m−1∙K−1 in the liquid state. The long-term thermal stability testing (including 1000 h of high-temperature aging and 500 thermal shock cycles) indicates that the thermal properties of this quaternary salt undergo certain changes, primarily attributed to the conversion of NO2 to NO3 within the molten salt. Using precursor decomposition method, MgO-molten salt nanocomposites and Al2O3-molten salt nanocomposites were synthesized in situ. In terms of both cost-effectiveness and performance enhancement, the Al2O3 additive underperforms compared to the MgO additive. Adding 0.5 wt% MgO to quaternary salt can increase its specific heat capacity by 20.4%, enhance its thermal conductivity by 55.5%, and simultaneously reduce its sensible heat storage cost by 18.3%. The novelty of this work is the design and systematic evaluation of novel molten salt, focusing on its long-term stability, performance enhancement mechanism, and economic viability, thereby offering the promising candidate materials for TES applications.
在CSP系统中,熔盐通常用作传热和储热介质。然而,传统的熔盐可能存在熔点高、工作温度范围窄、导热系数低等缺点,从而限制了系统的整体效率。本文研制了一种新型的季铵盐-亚硝酸盐熔盐,具有熔点低、工作温度范围宽、导热系数高、成本低等特点。季铵盐(41.4wt% KNO3-32.7wt % NaNO2-7.9wt %KNO2-18 wt% Ca(NO3)2·4H2O)的熔点为96.6℃,分解温度为622.3℃。季盐液相平均比热容为1.58 J∙g−1∙K−1,平均导热系数为0.574 W∙m−1∙K−1。长期热稳定性测试(包括1000 h高温老化和500次热冲击循环)表明,该季盐的热性能发生了一定的变化,主要原因是熔盐中NO2−向NO3−的转化。采用前驱体分解法,原位合成了mgo -熔盐纳米复合材料和al2o3 -熔盐纳米复合材料。在成本效益和性能增强方面,Al2O3添加剂不如MgO添加剂。在季盐中加入0.5 wt%的MgO,其比热容提高20.4%,导热系数提高55.5%,显热成本降低18.3%。本工作的新颖之处在于新型熔盐的设计和系统评估,重点关注其长期稳定性、性能增强机制和经济可行性,从而为TES应用提供有前途的候选材料。
{"title":"Study on thermophysical properties and performance enhancement of novel quaternary molten salt for thermal energy storage","authors":"Yuanyuan Wang,&nbsp;Yue Wang,&nbsp;Yuanwei Lu,&nbsp;Yuting Wu,&nbsp;Cancan Zhang","doi":"10.1016/j.applthermaleng.2026.130122","DOIUrl":"10.1016/j.applthermaleng.2026.130122","url":null,"abstract":"<div><div>Molten salts are commonly used as heat transfer and thermal storage media in CSP systems. However, conventional molten salts may have drawbacks such as high melting points, narrow operating temperature ranges, and low thermal conductivity, which limit the overall system efficiency. In this work, a novel quaternary nitrate-nitrite molten salt is developed, featuring low melting point, wide operating temperature range, high thermal conductivity, and low cost. The melting point of the quaternary salt (composed of 41.4wt%KNO<sub>3</sub>–32.7wt%NaNO<sub>2</sub>–7.9wt%KNO<sub>2</sub>-18 wt% Ca(NO<sub>3</sub>)<sub>2</sub>·4H<sub>2</sub>O) is 96.6 °C, and the decomposition temperature is 622.3 °C. The quaternary salt shows an average specific heat capacity of 1.58 J∙g<sup>−1</sup>∙K<sup>−1</sup> and an average thermal conductivity of 0.574 W∙m<sup>−1</sup>∙K<sup>−1</sup> in the liquid state. The long-term thermal stability testing (including 1000 h of high-temperature aging and 500 thermal shock cycles) indicates that the thermal properties of this quaternary salt undergo certain changes, primarily attributed to the conversion of NO<sub>2</sub><sup>−</sup> to NO<sub>3</sub><sup>−</sup> within the molten salt. Using precursor decomposition method, MgO-molten salt nanocomposites and Al<sub>2</sub>O<sub>3</sub>-molten salt nanocomposites were synthesized in situ. In terms of both cost-effectiveness and performance enhancement, the Al<sub>2</sub>O<sub>3</sub> additive underperforms compared to the MgO additive. Adding 0.5 wt% MgO to quaternary salt can increase its specific heat capacity by 20.4%, enhance its thermal conductivity by 55.5%, and simultaneously reduce its sensible heat storage cost by 18.3%. The novelty of this work is the design and systematic evaluation of novel molten salt, focusing on its long-term stability, performance enhancement mechanism, and economic viability, thereby offering the promising candidate materials for TES applications.</div></div>","PeriodicalId":8201,"journal":{"name":"Applied Thermal Engineering","volume":"290 ","pages":"Article 130122"},"PeriodicalIF":6.9,"publicationDate":"2026-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser Rayleigh scattering vs. pyrometer thermometry for DME-based fuels under flame and MILD combustion regimes in a semi-industrial furnace 半工业炉中基于二甲醚的燃料在火焰和轻度燃烧状态下的激光瑞利散射与高温计测温
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-03 DOI: 10.1016/j.applthermaleng.2026.130121
M. Mustafa Kamal , Marianna Cafiero , Alessandro Parente
Accurate in-furnace temperature measurements are essential for temperature-based CFD validation and NOx risk assessment, yet intrusive probes can under-read in regions with strong gradients and evidence for DME-based blends across flame and MILD operation remains limited. This study investigates the sensitivity and accuracy of intrusive (suction pyrometer probe) versus non-intrusive (planar laser Rayleigh scattering, LRS) thermometry in measuring temperature, using CFD simulations as a complementary benchmark for interpretation and model assessment, in a semi-industrial scale furnace. By comparing temperature data across three techniques, it is shown how fuel composition and burning regime (conventional flame vs. MILD combustion) affect measurement agreement and accuracy. The analysis covers pure DME, DME/CH4, and DME/H2 mixtures under both flame and MILD conditions, extending earlier work in this furnace to a broader fuel-regime matrix. LRS successfully captured the thermal field for all fuel compositions in both flame and MILD modes, generally aligning well with CFD-predicted temperature distributions. Intrusive probe measurement yielded similar overall trends but showed significant deviations in regions of steep temperature gradients, particularly near burner jets and in highly reactive, hydrogen rich flames. In these zones, the probe-measured temperatures were up to 200 K lower than LRS values, a discrepancy far exceeding experimental uncertainty and attributed to the probe's volumetric averaging and flow disturbance effects. The effect was most pronounced for the DME/H2 blend under flame-like conditions, reflecting the increased measurement sensitivity to fuel reactivity. The numerical simulations capture the overall combustion behaviour across fuel mixtures, though modelling of the mixtures with high H2 required adjusting turbulence-chemistry parameters to capture its mixing-controlled flame characteristics and NOx emissions. Overall, the results provide a semi-industrial benchmark comparison of LRS and suction-probe thermometry for DME-based blends across flame and MILD regimes, clarifying the fuel- and regime-dependence of diagnostic bias and its implications for temperature-based CFD validation and diagnostic selection in practical combustion systems.
准确的炉内温度测量对于基于温度的CFD验证和NOx风险评估至关重要,但在梯度强的地区,侵入式探头可能读取不足,并且基于二甲醚的火焰混合物和MILD操作的证据仍然有限。本研究在半工业规模的熔炉中,利用CFD模拟作为解释和模型评估的补充基准,研究了侵入式(吸力高温计探头)与非侵入式(平面激光瑞利散射,LRS)测温法在测量温度方面的灵敏度和准确性。通过比较三种技术的温度数据,显示了燃料成分和燃烧状态(传统火焰与轻度燃烧)如何影响测量的一致性和准确性。该分析涵盖了在火焰和MILD条件下的纯二甲醚、二甲醚/CH4和二甲醚/H2混合物,将该炉的早期工作扩展到更广泛的燃料状态矩阵。LRS成功地捕获了火焰和MILD模式下所有燃料成分的热场,与cfd预测的温度分布基本一致。侵入式探针测量得到了类似的总体趋势,但在陡峭的温度梯度区域,特别是在燃烧器射流附近和高活性富氢火焰中,显示出明显的偏差。在这些区域,探针测量的温度比LRS值低高达~ 200k,这一差异远远超过了实验的不确定性,并归因于探针的体积平均和流动干扰效应。在类火焰条件下,DME/H2混合物的效果最为明显,反映了对燃料反应性的测量灵敏度提高。数值模拟捕获了燃料混合物的整体燃烧行为,尽管高H2混合物的建模需要调整湍流化学参数以捕获其混合控制的火焰特性和氮氧化物排放。总体而言,研究结果为基于二甲醚的混合物在火焰和轻度燃烧状态下的LRS和吸力探针测温提供了半工业基准比较,阐明了诊断偏差对燃料和状态的依赖,及其对实际燃烧系统中基于温度的CFD验证和诊断选择的影响。
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引用次数: 0
Vortex-induced forced immersion of droplets levitating on liquid nitrogen 悬浮在液氮上的液滴的涡诱导强制浸没
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-03 DOI: 10.1016/j.applthermaleng.2026.130114
Jose H. Lizama , I-Ming Hsiao , Noel A. Sanchez, Chiu-Jen Chen, Yong-Ming Ye, Hsiu-Yang Tseng
When plunged onto liquid nitrogen (LN₂), droplets below a critical size or density remain levitated for several seconds due to the inverse Leidenfrost effect (LFE), where continuous vaporized nitrogen flow generated at the droplet–LN₂ interface establishes an upward pressure field that, together with LN₂ surface tension, counteracts the droplet weight. At sufficiently large droplet size or density, this balance is broken, leading to immediate immersion. To date, this levitation–immersion threshold has only been studied for static LN₂ baths, and the influence of how LN₂ flow imposed within the bath affects the stability of LFE-supported levitation remains unexplored. Here, the effects of a controlled free-surface vortex on droplet–LN₂ interactions are investigated. High-speed imaging across a range of droplet volumes, landing positions, and vortex angular speeds shows that the vortex can alter the levitation state and lead to immersion for droplets that would remain levitated on static LN₂. An approximate thermal/force-balance formulation is used to interpret these observations by assessing how centrifugal force competes with levitation supported by the vapor film. The results further show that, because the vortex immerses the larger droplets more readily than the smaller ones, those larger droplets (provided they are not so large that thermal inertia dominates) can achieve higher overall cooling rates. This overturns the usual trend on static LN₂, where smaller droplets cool faster than larger ones. A controlled LN₂ vortex therefore offers a means of reshaping levitation–immersion behavior in cryogenic droplet systems.
当液滴落入液氮(LN₂)时,由于反莱顿弗罗斯特效应(LFE),低于临界尺寸或密度的液滴会悬浮几秒钟,在液滴- LN₂界面处产生的连续汽化氮流建立了一个向上的压力场,与LN₂表面张力一起抵消了液滴的重量。当液滴的尺寸或密度足够大时,这种平衡就会被打破,导致立即浸没。迄今为止,这种悬浮-浸入阈值仅针对静态LN 2浴进行了研究,并且LN 2在浴内的流动如何影响lfe支撑悬浮的稳定性仍未被探索。本文研究了受控制的自由表面涡对液滴- ln 2相互作用的影响。在液滴体积、着陆位置和涡旋角速度范围内的高速成像表明,涡旋可以改变悬浮状态,并导致液滴浸入,而液滴在静态LN₂上保持悬浮状态。一个近似的热/力平衡公式被用来解释这些观察结果,通过评估离心力如何与气膜支持的悬浮竞争。结果进一步表明,由于涡流比小液滴更容易浸入较大的液滴,因此较大的液滴(如果它们没有大到热惯性占主导地位)可以实现更高的整体冷却速率。这颠覆了通常的静态LN 2的趋势,在静态LN 2中,较小的液滴比较大的液滴冷却得更快。因此,在低温液滴系统中,可控的ln2涡提供了一种重塑悬浮-浸泡行为的方法。
{"title":"Vortex-induced forced immersion of droplets levitating on liquid nitrogen","authors":"Jose H. Lizama ,&nbsp;I-Ming Hsiao ,&nbsp;Noel A. Sanchez,&nbsp;Chiu-Jen Chen,&nbsp;Yong-Ming Ye,&nbsp;Hsiu-Yang Tseng","doi":"10.1016/j.applthermaleng.2026.130114","DOIUrl":"10.1016/j.applthermaleng.2026.130114","url":null,"abstract":"<div><div>When plunged onto liquid nitrogen (LN₂), droplets below a critical size or density remain levitated for several seconds due to the inverse Leidenfrost effect (LFE), where continuous vaporized nitrogen flow generated at the droplet–LN₂ interface establishes an upward pressure field that, together with LN₂ surface tension, counteracts the droplet weight. At sufficiently large droplet size or density, this balance is broken, leading to immediate immersion. To date, this levitation–immersion threshold has only been studied for static LN₂ baths, and the influence of how LN₂ flow imposed within the bath affects the stability of LFE-supported levitation remains unexplored. Here, the effects of a controlled free-surface vortex on droplet–LN₂ interactions are investigated. High-speed imaging across a range of droplet volumes, landing positions, and vortex angular speeds shows that the vortex can alter the levitation state and lead to immersion for droplets that would remain levitated on static LN₂. An approximate thermal/force-balance formulation is used to interpret these observations by assessing how centrifugal force competes with levitation supported by the vapor film. The results further show that, because the vortex immerses the larger droplets more readily than the smaller ones, those larger droplets (provided they are not so large that thermal inertia dominates) can achieve higher overall cooling rates. This overturns the usual trend on static LN₂, where smaller droplets cool faster than larger ones. A controlled LN₂ vortex therefore offers a means of reshaping levitation–immersion behavior in cryogenic droplet systems.</div></div>","PeriodicalId":8201,"journal":{"name":"Applied Thermal Engineering","volume":"290 ","pages":"Article 130114"},"PeriodicalIF":6.9,"publicationDate":"2026-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Three-dimensional layer-level model of cylindrical lithium-ion batteries 圆柱形锂离子电池的三维层级模型
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-03 DOI: 10.1016/j.applthermaleng.2026.130124
Junghyun Nam, Seunghun Jung
The shift toward large-format cylindrical lithium-ion batteries necessitates precise modeling of electro-thermal non-uniformity. However, conventional distributed equivalent circuit models (Distributed ECMs) oversimplify the spiral-wound structure as a homogeneous layer, neglecting the critical coupling between through-plane ionic transport and in-plane electronic conduction. To address this, we propose a three-dimensional layer-level overlapped potential-pair network (OPPN) framework. This electro-thermal model, implemented using the finite volume method, physically reconstructs the bipolar connectivity through the jellyroll thickness. Validation against Panasonic NCR18650B experiments confirmed high predictive accuracy. Crucially, comparative analysis reveals that the Distributed ECM fundamentally miscalculates internal current distribution. Specifically, while the Distributed ECM predicted negligible variations across tab configurations (potential drop <0.001 V, temperature difference < 0.4 °C), the layer-level OPPN model captured significant structure-induced gradients, revealing potential drops and temperature deviations up to 0.04 V and 1.7 °C, respectively. This confirms that Distributed ECMs predict unrealistic uniformity in State-of-Charge (SOC) and temperature fields. Since overlooking these gradients poses severe risks for thermal design and lifetime estimation, this study establishes the OPPN framework as an essential engineering tool for the robust design of modern, scaling cylindrical batteries.
向大尺寸圆柱形锂离子电池的转变需要对电热不均匀性进行精确建模。然而,传统的分布式等效电路模型(distributed ecm)将螺旋缠绕结构过于简化为一个均匀层,忽略了平面内离子传输和面内电子传导之间的关键耦合。为了解决这个问题,我们提出了一个三维层级重叠电位对网络(OPPN)框架。该电热模型采用有限体积法实现,通过胶辊厚度物理重构双极连通性。针对松下NCR18650B实验验证了较高的预测精度。至关重要的是,对比分析表明,分布式ECM从根本上错误地计算了内部电流分布。具体来说,分布式ECM预测了标签配置之间可以忽略不计的变化(电位下降& 0.001 V,温差& 0.4°C),而层级OPPN模型捕获了显著的结构诱导梯度,显示电位下降和温度偏差分别高达0.04 V和1.7°C。这证实了分布式ecm在荷电状态(SOC)和温度场中预测了不切实际的均匀性。由于忽略这些梯度会给热设计和寿命估计带来严重风险,因此本研究将OPPN框架建立为现代圆柱形电池稳健设计的基本工程工具。
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引用次数: 0
Thermal analysis of a solar-assisted pyrolysis drop tube reactor with radiation heat transfer 太阳辅助热解落管反应器辐射传热的热分析
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-03 DOI: 10.1016/j.applthermaleng.2026.130033
Amir Hossein Bashiri , Shervin Karimkashi , Vignesvar Krish Subramani , Sylvain Rodat , Stéphane Abanades , Mika Järvinen , Ville Vuorinen
Fast pyrolysis of biomass is recognized as a promising method for bio-oil production which can be further utilized in the production of sustainable fuels. Numerical simulations are carried out in order to verify the discrete ordinate method (DOM) implementation in OpenFOAM open-source software. 1D and 3D test problems are investigated including conjugate and radiative heat transfer in addition to a 2D test case. The main application of interest is a 3D solar-assisted drop tube reactor, which is studied from the viewpoint of heat distribution within the reactor. The main results of the research are as follows: (1) 1D modeling indicates that the heat fluxes are correctly implemented for transient and steady state configurations. (2) 2D rectangular enclosure study indicate correct heat flux implementation in OpenFOAM for the viewFactor and fvDOM methods. (3) 3D reactor studies in OpenFOAM and STAR-CCM+ indicate that the heat distributions are highly similar within 2% deviation in peak temperature values. The final 3D results are noted to be grid independent and independent on the angular discretization number when Nϕ16. As a conclusion, the validated/verified numerical approach offers a general open-source framework for coupled CHT-radiation problems with applicability beyond the studied drop tube reactor.
生物质快速热解被认为是一种很有前途的生物油生产方法,可以进一步用于生产可持续燃料。为了验证离散坐标法(DOM)在OpenFOAM开源软件中的实现,进行了数值仿真。除了二维测试案例外,还研究了一维和三维测试问题,包括共轭传热和辐射传热。主要应用是三维太阳能辅助滴管反应器,从反应器内热分布的角度进行了研究。研究的主要结果如下:(1)一维模拟表明,瞬态和稳态配置下的热流密度是正确的。(2)二维矩形框研究表明,在OpenFOAM中viewFactor和fvDOM方法的热通量实现是正确的。(3)在OpenFOAM和STAR-CCM+中的三维反应器研究表明,在峰值温度偏差2%以内,热分布高度相似。当Nϕ≥16时,最终的三维结果与网格无关,与角离散化数无关。综上所述,经过验证的数值方法为耦合cht辐射问题提供了一个通用的开源框架,其适用性超出了所研究的滴管反应器。
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引用次数: 0
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Applied Thermal Engineering
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