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Lignin-hydrothermal fabrication of 3D hierarchical porous carbon for energy storage application 木质素-水热法制备三维分层多孔碳用于储能应用
Q1 Environmental Science Pub Date : 2024-06-01 DOI: 10.1016/j.biteb.2024.101883
Johnson Kehinde Abifarin , Fredah Batale Abifarin , Joseph Chukwuka Ofodu

In this groundbreaking study, the Taguchi-Probability method is employed to optimize the energy storage performance of porous hierarchical carbon (PHC) by investigating lignin doping and controlling hydrothermal synthesis conditions. The findings indicate that optimal lignin contents range from 63 to 70 % carbon, 0.75–1.0 % nitrogen, <2.0 % sulfur, and < 30 % oxygen, with varying hydrogen percentages. Ideal hydrothermal conditions involve a temperature of 220 °C, duration of 18 h, concentration of 80 g/L, and pH of 4. Remarkably, pH has the most significant impact (33.30 %) on energy storage enhancement, followed by reaction time (24.73 %), concentration, and temperature. These results highlight the pivotal role of hydrothermal conditions in enhancing PHC's energy storage capabilities, offering promising avenues for sustainable energy storage solutions.

在这项突破性研究中,通过研究木质素掺杂和控制水热合成条件,采用田口概率法优化了多孔分层碳(PHC)的储能性能。研究结果表明,最佳木质素含量范围为 63% 至 70% 的碳、0.75% 至 1.0% 的氮、2.0% 的硫和 30% 的氧,氢的比例各不相同。理想的水热条件包括温度 220 °C、持续时间 18 小时、浓度 80 克/升、pH 值 4。值得注意的是,pH 值对能量储存的增强影响最大(33.30%),其次是反应时间(24.73%)、浓度和温度。这些结果凸显了水热条件在增强 PHC 储能能力方面的关键作用,为可持续储能解决方案提供了广阔的前景。
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引用次数: 0
Enhancement of biochemical parameters and enzyme activity in solid-state fermented and biofortified maize cobs utilizing yeasts and plant extracts 利用酵母和植物提取物提高固态发酵和生物强化玉米棒的生化参数和酶活性
Q1 Environmental Science Pub Date : 2024-06-01 DOI: 10.1016/j.biteb.2024.101874
Egoamaka O. Egbune , Olisemeke U. Egbune , Theresa Ezedom , Uche Dennis-Eboh , Linda I. Eraga , Patrick C. Ichipi-Ifukor , Osuvwe C. Orororo , Nduchukwuyenum G. Adoh , David L. Adongoi , Christabel A. Afure , Hannah R. Agbigbi , Oghenemarien Agofure , Oghenetega J. Avwioroko , Akpovwehwee A. Anigboro , Nyerhovwo J. Tonukari

This study investigated the impact of solid-state fermentation and biofortification of maize cobs using yeast and plant extracts on their biochemical properties and enzyme activity. Maize cobs were fermented with extracts from elephant grass, cassava leaves, or Siam weed, combined with baker's yeast or palm wine yeast. In vitro assays revealed increased l-lysine concentration (up to 8.6 mg/g), soluble protein content (up to 27.4 mg/g), total phenolic content (up to 15.5 μg GAE/g), total flavonoid content (up to 23.4 μg CE/g), and xylanase activity (up to 25.7 Units) compared to controls. Glucose concentration decreased (to 0.8 mg/mL), indicating efficient utilization. Amylase and protease activities varied, with some combinations showing higher enzymatic activity (amylase at 35.4 Units, protease at 39.2 Units). These results underscore the potential of solid-state fermentation and biofortification to enhance the nutritional quality of agro-residues, offering novel insights into sustainable food production and waste utilization strategies.

本研究调查了使用酵母和植物提取物对玉米棒进行固态发酵和生物强化对其生化特性和酶活性的影响。玉米棒用象草、木薯叶或暹罗草提取物与面包酵母或棕榈酒酵母一起发酵。与对照组相比,体外测定显示赖氨酸浓度(高达 8.6 毫克/克)、可溶性蛋白质含量(高达 27.4 毫克/克)、总酚含量(高达 15.5 微克 GAE/克)、总黄酮含量(高达 23.4 微克 CE/克)和木聚糖酶活性(高达 25.7 单位)均有所增加。葡萄糖浓度下降(降至 0.8 毫克/毫升),表明葡萄糖得到了有效利用。淀粉酶和蛋白酶的活性各不相同,一些组合显示出更高的酶活性(淀粉酶为 35.4 单位,蛋白酶为 39.2 单位)。这些结果凸显了固态发酵和生物强化提高农业残留物营养质量的潜力,为可持续食品生产和废物利用战略提供了新的见解。
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引用次数: 0
An alternative process for bioethanol production from marine and freshwater algae using yeast for hydrolysis 利用酵母水解海洋和淡水藻类生产生物乙醇的替代工艺
Q1 Environmental Science Pub Date : 2024-06-01 DOI: 10.1016/j.biteb.2024.101876
Siti Mushlihah , Maazuza Z. Othman , Sutiman Bambang Sumitro , Anthon Efani , Sulfahri

This research develops a new process for production of bioethanol from marine and freshwater algae based on hydrolysis using yeast rather than the established methods of enzyme and acid hydrolysis. Yeast were isolated and adapted specifically for this process and the effectiveness of this hydrolysis was evaluated. This method was then evaluated within a full ethanol production process involving ozone pretreatment, and both hydrolysis and fermentation using yeast, under different nutrient supplementation regimes. The process effectiveness was evaluated for species of freshwater (Spirogyra hyalina) and marine (Kappaphycus alvarezii) algae. The yeast-based hydrolysis method outperformed acid and enzyme hydrolysis for both species of freshwater and marine algae, with particularly significant results for the freshwater algae. In the whole of process treatment, the yeast-based hydrolysis approach was effective when combined with ozone pretreatment for marine algae, and without any pretreatment for freshwater algae. The highest ethanol yield was achieved through fermentation with a yeast extract supplement present. These results indicate that ozone pretreatment, hydrolysis using yeast, and fermentation with the use of yeast extract as a nutrient are promising methods for economic ethanol production from seawater algae, and for freshwater algae where ozone pretreatment is not required.

这项研究开发了一种从海洋和淡水藻类中生产生物乙醇的新工艺,其基础是利用酵母进行水解,而不是采用酶水解和酸水解等既有方法。酵母被分离出来并专门用于这一工艺,并对这种水解的有效性进行了评估。然后,在一个完整的乙醇生产过程中对这种方法进行了评估,该过程包括臭氧预处理、水解和酵母发酵,以及不同的营养补充制度。对淡水(Spirogyra hyalina)和海洋(Kappaphycus alvarezii)藻类的工艺效果进行了评估。在淡水藻类和海水藻类中,酵母水解法的效果优于酸水解法和酶水解法,其中淡水藻类的效果尤为显著。在整个工艺处理过程中,酵母水解法与臭氧预处理相结合对海洋藻类有效,而对淡水藻类则无需任何预处理。发酵过程中添加酵母提取物的乙醇产量最高。这些结果表明,臭氧预处理、使用酵母的水解以及使用酵母提取物作为营养物的发酵是利用海水藻类生产经济型乙醇的有效方法,而对于不需要臭氧预处理的淡水藻类来说也是如此。
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引用次数: 0
Biochar production from cassava waste biomass: A techno-economic development approach in the Colombian context 利用木薯废生物质生产生物炭:哥伦比亚的技术经济发展方法
Q1 Environmental Science Pub Date : 2024-06-01 DOI: 10.1016/j.biteb.2024.101872
L.A. Alonso-Gómez , D.D. Celis-Carmona , Y.F. Rodríguez-Sánchez , J.R. Castro-Ladino , J.C. Solarte-Toro

Biochar has been proposed as a potential bioproduct since applications have been elucidated in the agricultural and energy sectors. This research paper aims to (i) evaluate biochar production using cassava residues (i.e., branches and peels), (ii) elucidate potential biochar applications, and (iii) assess the economic potential of biochar production in Colombia. Biochar was produced through slow pyrolysis and characterized considering pH, conductivity, and thermal properties. The economic assessment was done by calculating profitability indicators. Higher biochar yields were obtained using cassava branches (0.11 tons/ton, wet basis). A slow pyrolysis plant with a processing scale higher than 3.4 tons/h, a feedstock cost of 148.7 USD/ton, and a biochar selling price of 1600 USD/ton is feasible in Colombia. Biochar is a business opportunity sine large quantity of waste is readily available in the cassava productive chain. Biochar has potential applications as biofuel, soil amendment, carbon capture agent, graphene-based material, and supercapacitor electrodes.

自阐明生物炭在农业和能源领域的应用以来,生物炭已被提议作为一种潜在的生物产品。本研究论文旨在:(i) 评估利用木薯残渣(即树枝和果皮)生产生物炭的情况;(ii) 阐明生物炭的潜在应用;(iii) 评估哥伦比亚生物炭生产的经济潜力。生物炭是通过缓慢热解产生的,并考虑了 pH 值、电导率和热特性。经济评估是通过计算盈利指标进行的。使用木薯枝获得了较高的生物炭产量(0.11 吨/吨,湿基)。在哥伦比亚,一个处理规模高于 3.4 吨/小时、原料成本为 148.7 美元/吨、生物炭售价为 1600 美元/吨的慢速热解工厂是可行的。木薯生产链中存在大量废弃物,因此生物炭是一个商机。生物炭具有作为生物燃料、土壤改良剂、碳捕获剂、石墨烯基材料和超级电容器电极的潜在用途。
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引用次数: 0
Effect of intermittent aeration on textile dyeing wastewater treatment in downflow hanging sponge column integrated with hollow fiber submerged anaerobic membrane bioreactor 间歇曝气对集成中空纤维浸没式厌氧膜生物反应器的下流式悬挂海绵柱处理纺织印染废水的影响
Q1 Environmental Science Pub Date : 2024-06-01 DOI: 10.1016/j.biteb.2024.101869
Syed Saquib , Helen Julian , Sri Harjati Suhardi , Takahiro Watari , Takashi Yamaguchi , Tjandra Setiadi

An HF-sAnMBR-DHS system was examined for enhanced RB5 diazo dye synthetic textile wastewater treatment. Natural aeration was provided during Phase-1 (51 days), while intermittent forced aeration (2 L/min for 5 min ON/OFF cycle) was purged into the DHS in Phase-2 (66 days). The mean tCOD and sCOD removal at P-1 were 88.43 ± 1.84 % and 90.82 ± 0.78 %, respectively, whereas in P-2, the removal reached 94.30 ± 2.01 % and 95.79 ± 0.67 %, respectively. Spectrophotometric analysis reveals 81.41 ± 5.02 % color reduction in P-1 whereas and P-2, 83.40 ± 6.93 % decolorization. The mean Pt-Co levels were 366.33 ± 112.91 and 222.13 ± 44.41 in both phases respectively. At the median initial flux (14.79 LMH), no significant fouling occurred in the membrane module. Microbial analysis revealed Clostridium as a major genus in the HF-AnMBR and DHS, attributed to azo dye-degrading bacteria. The abundance of aerobic microbes present in the DHS might help in further degradation of the intermediate aminated compounds.

研究了用于强化 RB5 重氮染料合成纺织废水处理的 HF-sAnMBR-DHS 系统。第一阶段(51 天)采用自然曝气,第二阶段(66 天)向 DHS 中注入间歇性强制曝气(2 升/分钟,5 分钟 ON/OFF 循环)。P-1 阶段的 tCOD 和 sCOD 平均去除率分别为 88.43 ± 1.84 % 和 90.82 ± 0.78 %,而 P-2 阶段的去除率分别为 94.30 ± 2.01 % 和 95.79 ± 0.67 %。分光光度分析表明,P-1 的色度降低率为 81.41 ± 5.02%,而 P-2 的脱色率为 83.40 ± 6.93%。两个阶段的铂-钴平均含量分别为 366.33 ± 112.91 和 222.13 ± 44.41。在中位初始通量(14.79 LMH)下,膜组件未出现明显污垢。微生物分析表明,梭状芽孢杆菌是高频-安瓿反应器和 DHS 中的主要菌属,属于偶氮染料降解菌。DHS 中存在的大量好氧微生物可能有助于进一步降解中间胺化化合物。
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引用次数: 0
Emerging strategies for enhancing microbial degradation of petroleum hydrocarbons: Prospects and challenges 加强石油碳氢化合物微生物降解的新兴战略:前景与挑战
Q1 Environmental Science Pub Date : 2024-06-01 DOI: 10.1016/j.biteb.2024.101866
S. Karishma, A. Saravanan, V.C. Deivayanai, Uthra Ajithkumar, P.R. Yaashikaa, A.S. Vickram

Microbial degradation presents a promising and feasible method for the detoxification of these pollutants by emerging methodologies like biostimulation. The review comprehensively outlines various petroleum hydrocarbons, delineating their sources and prevalence and elaborates on the pivotal enzymes and microbes that facilitate degradation, detailing their metabolic pathways. An in-depth analysis of the factors that influence the efficacy of remediation processes is crucial, as highlighted in the review. Additionally, the review explores innovative strategies such as bioaugmentation, bioreactor technologies, and genetic or metabolic engineering, along with phytoremediation. Methods have been evaluated for their potential to augment the removal of petroleum hydrocarbons, offering a sophisticated perspective on advancing this field. Advancements promising to increase efficacy and adaptability in bioremediation processes under challenging environmental conditions have been emphasized. However, they also pose challenges related to scalability, regulatory acceptance, and ecological impacts which are explained in the review for betterment of the current research.

通过生物刺激等新兴方法,微生物降解为这些污染物的解毒提供了一种前景广阔的可行方法。这篇综述全面概述了各种石油碳氢化合物,划定了它们的来源和流行程度,并阐述了促进降解的关键酶和微生物,详细介绍了它们的代谢途径。正如综述中所强调的,深入分析影响修复过程有效性的因素至关重要。此外,综述还探讨了生物增量、生物反应器技术、基因或代谢工程以及植物修复等创新战略。对各种方法在增强去除石油碳氢化合物方面的潜力进行了评估,为推动这一领域的发展提供了一个复杂的视角。在具有挑战性的环境条件下,有望提高生物修复过程的有效性和适应性的进展得到了强调。不过,这些方法也带来了与可扩展性、监管认可度和生态影响有关的挑战,本综述将对这些挑战进行解释,以便更好地开展当前的研究。
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引用次数: 0
Oleaginous microorganisms as a sustainable oil source with a focus on downstream processing and cost-lowering production strategies: A review 油脂微生物作为一种可持续油源,重点关注下游加工和降低成本的生产战略:综述
Q1 Environmental Science Pub Date : 2024-06-01 DOI: 10.1016/j.biteb.2024.101871
D.D. Nunes, V.L. Pillay, E. Van Rensburg, R.W.M. Pott

The increased demand for specialty oils, driven by a growing population and thus increased consumption as well as seasonal fluctuations, poses challenges for the environment and edible oil industries. Oleaginous microorganisms offer a promising solution as they are capable of yielding oils with high concentrations of polyunsaturated fatty acids or profiles similar to that of traditional fats. These oils have applications in diverse industries, including food, biofuels, pharmaceuticals, and healthcare. While multiple studies explore strains suitable for industrial-scale oil production, data comparison remains limited. Oleaginous microorganisms offer versatility in utilising various carbon sources, seasonal independence, and a minimal ecological footprint. However, downstream processing steps still hinder overall profitability and thus commercialisation. This review takes a bioprocess engineering approach, focusing on upstream and downstream processing, up-scale, practical and economic considerations, and innovative strategies developed to lower production costs.

由于人口增长、消费量增加以及季节性波动,对特种油的需求不断增加,这给环境和食用油行业带来了挑战。油脂微生物提供了一种前景广阔的解决方案,因为它们能够产生具有高浓度多不饱和脂肪酸或类似于传统脂肪特征的油。这些油类可应用于食品、生物燃料、制药和医疗保健等多个行业。虽然多项研究都在探索适合工业规模油脂生产的菌株,但数据比较仍然有限。油脂微生物具有利用各种碳源的多功能性、季节独立性和最小的生态足迹。然而,下游加工步骤仍然阻碍着整体盈利能力,进而影响商业化。本综述采用生物加工工程方法,重点关注上游和下游加工、上游规模、实用性和经济性考虑因素,以及为降低生产成本而开发的创新策略。
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引用次数: 0
Evaluation of composite matrix in constructed wetland for phosphorus removal 评估建造湿地中的复合基质除磷效果
Q1 Environmental Science Pub Date : 2024-05-23 DOI: 10.1016/j.biteb.2024.101870
Vandana Patyal , Dipika Jaspal , Kanchan Khare

Constructed wetlands (CWs) have been successfully used for the removal of several contaminants from wastewater. However, the phosphorus (P) removal can be boosted by using reactive materials as substrates in CWs. The present study addresses this issue by using low-cost materials as substrates for the treatment of domestic wastewater. Therefore, a novel composite substrate consisting of brick waste, tile waste, and gravel was assessed in CW. The total phosphorus (TP) and phosphate (PO43−) average removal efficiency was shown to be >72 % and >78 % respectively, from domestic wastewater. The chemical oxygen demand (COD) reduction efficiency was >80 % for the system. The efficacy of composite matrix CW in the reduction of TP and PO43− was supported by the SEM-EDX and FTIR analysis of the substrate materials. The study showed the robustness of the CW in pollutant removal when waste material was utilized as filler.

人工湿地(CWs)已成功用于去除废水中的多种污染物。然而,在建造湿地中使用活性材料作为基质可以提高磷(P)的去除率。本研究通过使用低成本材料作为处理生活废水的基质来解决这一问题。因此,在化武中评估了一种由砖块废料、瓷砖废料和砾石组成的新型复合基质。结果表明,生活废水中总磷 (TP) 和磷酸盐 (PO43-) 的平均去除率分别为 72% 和 78%。该系统的化学需氧量(COD)去除率为 80%。基质材料的 SEM-EDX 和 FTIR 分析证实了复合基质 CW 在减少 TP 和 PO43- 方面的功效。研究表明,当使用废料作为填料时,CW 在去除污染物方面具有很强的稳定性。
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引用次数: 0
Eggshell waste materials-supported metal oxide nanocomposites for the efficient photocatalytic degradation of organic dyes in water and wastewater: A review 蛋壳废料支撑的金属氧化物纳米复合材料用于高效光催化降解水和废水中的有机染料:综述
Q1 Environmental Science Pub Date : 2024-05-19 DOI: 10.1016/j.biteb.2024.101865
Hamza Badamasi , Saheed O. Sanni , Odunayo T. Ore , Ajibola A. Bayode , Daniel T. Koko , Olaniran Kolawole Akeremale , Stephen Sunday Emmanuel

Pollution from dye-containing water and wastewater is increasingly a global concern. Traditional treatment technologies, such as membrane separation, adsorption, and chemical precipitation, have limitations such as incomplete removal, high costs, and a lack of sustainability. Photocatalytic degradation using metal oxide (MO) semiconductors has recently replaced these methods. However, MO's limitations, such as UV radiation's operating range and the electron-hole pair's recombination, have limited their applications. The applications of eggshell waste materials (ESWMs) as a cost-effective, eco-friendly, and sustainable support for MO semiconductor synthesis are gaining popularity, addressing MO limitations and improving photocatalytic performance. This paper discusses the efficient photocatalytic removal of organic dyes from water and wastewater using ESWM-supported MO nanocomposites. Literature surveys and compilations confirmed the exceptional photocatalytic performance of ESWM-supported MO nanocomposites, with an average 92 % organic dye degradation capacity compared to pure MO, highlighting the potential for novel, economical, and environmentally friendly techniques for tackling water pollution problems.

含染料的水和废水污染日益成为全球关注的问题。膜分离、吸附和化学沉淀等传统处理技术存在去除不彻底、成本高昂和缺乏可持续性等局限性。最近,使用金属氧化物(MO)半导体的光催化降解技术取代了这些方法。然而,MO 的局限性,如紫外线辐射的工作范围和电子-空穴对的重组,限制了其应用。蛋壳废料(ESWMs)作为一种具有成本效益、生态友好和可持续的 MO 半导体合成支持材料,在解决 MO 的局限性和提高光催化性能方面的应用越来越受欢迎。本文讨论了利用 ESWM 支持的 MO 纳米复合材料高效光催化去除水和废水中的有机染料。文献调查和汇编证实了 ESWM 支持的 MO 纳米复合材料具有优异的光催化性能,与纯 MO 相比,其有机染料降解能力平均达到 92%,这凸显了新型、经济和环保技术在解决水污染问题方面的潜力。
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引用次数: 0
Assessment of mechanical, physical, and thermal characterization of jujube seed shell briquettes 评估枣核压块的机械、物理和热特性
Q1 Environmental Science Pub Date : 2024-05-19 DOI: 10.1016/j.biteb.2024.101868
S.A. Adesanya, J.S. Ibrahim, A. Kuhe, A.A. Ndah

The escalating challenges of energy scarcity and environmental concerns stemming from fossil fuel usage have intensified the exploration of renewable energy sources, including municipal waste and agricultural residues. Despite their availability, indigenous nature, and environmental friendliness, certain residues necessitate conversion through processes such as briquetting because of the high relative humidity and low specific heat. This study delves into the examination of the mechanical, thermophysical, and physical properties of Jujube seed shell-based briquettes without the use of binders. Three distinct particle sizes; fine particles (<0.6 mm), medium particles (<2.36 mm), and coarse particles (<3.35 mm) were respectively experimented. The produced briquettes underwent analysis for density, durability, shatter resistance index, relaxation ratio, compressive strength, volatile matter (VM), and specific heat of combustion. Results unveiled a density range of 1909 kg/m3 to 2158 kg/m3, with fine particles exhibiting the highest density at 2158 kg/m3. Calorific values varied between 26,430 kJ/kg and 27,175 kJ/kg. Moisture content ranged from 3.0 % to 7 %, ash content from 1.51 % to 1.68 %, volatile matter from 73.1 % to 77.2 %, and fixed carbon from 17.29 % to 18.39 %. This comprehensive exploration provides valuable insights into the potential of Jujube seed shell briquettes as a sustainable and efficient alternative energy source, contributing to the ongoing discourse on renewable energy utilization.

由于化石燃料的使用,能源短缺和环境问题日益严峻,因此人们加大了对可再生能源(包括城市垃圾和农业残留物)的开发力度。尽管某些残留物具有可获得性、本土性和环境友好性,但由于其相对湿度高、比热低,因此必须通过压块等工艺进行转化。本研究深入探讨了在不使用粘合剂的情况下,基于枣核壳的压块的机械、热物理和物理性能。实验分别采用了三种不同的颗粒尺寸:细颗粒(0.6 毫米)、中颗粒(2.36 毫米)和粗颗粒(3.35 毫米)。对生产出的煤球进行了密度、耐久性、抗碎指数、松弛比、抗压强度、挥发性物质(VM)和燃烧比热分析。结果显示,密度范围为 1909 kg/m3 至 2158 kg/m3,其中细颗粒密度最高,为 2158 kg/m3。热值介于 26,430 千焦/千克和 27,175 千焦/千克之间。水分含量从 3.0 % 到 7 % 不等,灰分含量从 1.51 % 到 1.68 % 不等,挥发物含量从 73.1 % 到 77.2 % 不等,固定碳含量从 17.29 % 到 18.39 % 不等。这一全面探索为了解枣核压块作为一种可持续和高效替代能源的潜力提供了宝贵的见解,为当前有关可再生能源利用的讨论做出了贡献。
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引用次数: 0
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