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Short rotation coppice trees in contaminated sites: A study of wood characteristics for bio-concrete applications 污染场地中的短轮伐乔木:生物混凝土应用的木材特性研究
Q1 Environmental Science Pub Date : 2025-12-30 DOI: 10.1016/j.biteb.2025.102515
Percy Alao , Edern Philippot , Silvia Bibbo , Dmitry Tarasov , Floran Pierre , Jiayun Xu , Chunlin Xu , Stergios Adamopoulos
Short rotation coppice trees, including poplar (Populus spp.), willow (Salix spp.), and black locust (Robinia pseudoacacia L.), present an exciting opportunity for sustainable biomass production, while also contributing to soil remediation efforts. Harnessing this biomass in construction concrete supports and aligns perfectly with the EU's ambitious 2030 emission targets. Therefore, this study evaluates metal and mineral accumulation and investigates the potential of utilizing wood aggregates as alternative biomass fillers in concrete. Consequently, the cell wall composition, sorption characteristics, metal impurity concentrations, pH, pH buffering capacity, and mineral and ash content of wood and bark obtained from an industrially contaminated site were analysed. The findings reveal that the biomass from the contaminated site had higher mineral content than samples from sawmills. The bark—particularly from black locust—displayed a notable ash content of 8.3 %, largely due to sizeable presence of calcium minerals. In contrast, the wood's ash content was 0.76 %, approximately 1.9 times higher than sawmill wood (0.4 %). Subtle cell wall composition variations were also observed compared to sawmill wood. Overall, the sorption properties, particularly concerning moisture retention, were reflective of lignin content. When evaluating concrete viability, the pH buffering capacity of all examined wood samples was lower, while the bark samples boasted a higher capacity compared to the reference hemp shives. Notably, poplar bark from the contaminated site achieved an average buffering capacity that surpassed the reference bark by 10.9 %. Poplar wood aggregate concretes achieved 0.16 MPa strength and 373 kg/m3 density, showing optimization potential.
短轮作乔木,包括杨树(Populus spp.)、柳树(Salix spp.)和刺槐(Robinia pseudoacacia L.),为可持续生物质生产提供了令人兴奋的机会,同时也有助于土壤修复工作。在建筑混凝土中利用这种生物质支持并完全符合欧盟雄心勃勃的2030年排放目标。因此,本研究评估了金属和矿物的积累,并调查了利用木材骨料作为混凝土中替代生物质填料的潜力。因此,细胞壁组成,吸附特性,金属杂质浓度,pH值,pH缓冲能力,以及从工业污染场地获得的木材和树皮的矿物质和灰分含量进行了分析。研究结果表明,来自污染地点的生物质比来自锯木厂的样品矿物质含量更高。树皮——尤其是黑蝗虫的树皮——显示出8.3%的显著灰分含量,这主要是由于大量钙矿物质的存在。相比之下,木材的灰分含量为0.76%,约为锯木厂木材(0.4%)的1.9倍。与锯木厂的木材相比,还观察到细微的细胞壁组成变化。总体而言,木质素的吸附性能,特别是水分保持性能,反映了木质素的含量。当评估混凝土活力时,所有检查木材样品的pH缓冲能力较低,而树皮样品与参考大麻片相比具有更高的容量。值得注意的是,污染场地的杨树树皮的平均缓冲能力比参考树皮高出10.9%。杨木骨料混凝土强度达到0.16 MPa,密度达到373 kg/m3,具有优化潜力。
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引用次数: 0
A review on bio-derived activated carbon and their functionalisation: Mechanistic approach for supercapacitor applications 生物源活性炭及其功能化研究进展:超级电容器应用的机理研究
Q1 Environmental Science Pub Date : 2025-12-30 DOI: 10.1016/j.biteb.2025.102506
Nidhi Puri , Anjali Gupta
The global rise in energy demand has recurrently given a scope in groundbreaking advancements for electrochemical energy storage systems. Supercapacitors amongst them are the leading sustainable contenders because of their characteristics viz. stability, power density, and rapid charge/discharge potential. Though, their low energy density has always become an obstacle for their industrial applications. To address this limitation, focused research is essential to explore advanced materials for supercapacitance electrodes. In this regard, biomass-based activated carbon (AC) has presented a sustainable solution to address this crisis. This has also given an additional advantage for conversion of waste to useful products especially disposing agricultural waste like sugarcane bagasse, waste leaves, corncob and rice husk. This review provides a comprehensive progress in the advancement of bagasse, waste leaves and rice husk derived AC, their surface modification, and their electrochemical performance.
全球能源需求的增长为电化学储能系统的突破性进展提供了空间。其中,超级电容器因其稳定性、功率密度和快速充放电潜力等特点而成为领先的可持续竞争者。然而,它们的低能量密度一直是它们工业应用的障碍。为了解决这一限制,重点研究对于探索超级电容电极的先进材料至关重要。在这方面,生物质活性炭(AC)为解决这一危机提供了一种可持续的解决方案。这也为废物转化为有用产品提供了额外的优势,特别是处理农业废物,如甘蔗渣、废叶、玉米芯和稻壳。本文综述了甘蔗渣、废叶和稻壳衍生的交流电及其表面改性和电化学性能的研究进展。
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引用次数: 0
Iron‑carbon micro-electrolysis enhanced treatment of dyeing wastewater in intermittently aerated constructed wetlands 铁碳微电解强化间歇曝气人工湿地印染废水处理
Q1 Environmental Science Pub Date : 2025-12-30 DOI: 10.1016/j.biteb.2025.102507
Wenxiao Zhang , Changsheng Jiang , Yuhang He , Jiawei Ren , Shiwen Xu , Ziyao Wei , Yanxun Li , Qingju Hao
The discharge of dyeing wastewater causes severe aquatic contamination due to its toxic and recalcitrant pollutants. This study established four lab-scale constructed wetlands (CWs) with different fillers: gravel (GCW), zero-valent iron (ZVI, FeCW), biochar (BCW), and ZVI-biochar composite (FeBCW), to compare the efficacy in treating azo dyes (Acid Blue 113 and Basic Red 46) in textile wastewater. Compared to other CWs, FeBCW achieved the highest removal efficiencies for dyes (98.05–99.98 %), chemical oxygen demand (89.47–93.32 %), total nitrogen (92.40–95.35 %), and total phosphorus (92.02–93.54 %) (p < 0.05). The UV–vis and FTIR spectra analysis showed the superior dye degradation in FeBCW. Phytotoxicity tests found that FeBCW effluent supported the best growth of mung beans and onions, as well as the highest chlorophyll content (3.12 ± 0.06 mg·g−1) in calamus. These results indicated that using the ZVI-biochar composite as filler is a highly effective strategy for enhancing CW performance in treating dyeing wastewater.
印染废水的排放因其毒性和顽固性污染物而造成严重的水生污染。本研究建立了四个实验室规模的人工湿地(CWs),分别采用砾石(GCW)、零价铁(ZVI, FeCW)、生物炭(BCW)和ZVI-生物炭复合(FeBCW)填料,比较其对纺织废水中偶氮染料(酸性蓝113和碱性红46)的处理效果。FeBCW对染料(98.05 ~ 99.98%)、化学需氧量(89.47 ~ 93.32%)、总氮(92.40 ~ 95.35%)、总磷(92.02 ~ 93.54%)的去除率最高(p < 0.05)。紫外可见光谱和红外光谱分析表明,FeBCW具有较好的染料降解能力。植物毒性试验发现,FeBCW出水对绿豆和洋葱的生长效果最好,对菖蒲的叶绿素含量最高(3.12±0.06 mg·g−1)。以上结果表明,采用zvi -生物炭复合填料是提高印染废水连续处理性能的有效方法。
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引用次数: 0
Enhancing hydrochar properties via co-hydrothermal carbonization of cooked food waste and human faeces using human urine as reaction medium in the Indian context: Synergistic effects and combustion performance 在印度环境下,利用人类尿液作为反应介质,通过煮熟的食物垃圾和人类粪便的共水热碳化来增强碳氢化合物的特性:协同效应和燃烧性能
Q1 Environmental Science Pub Date : 2025-12-30 DOI: 10.1016/j.biteb.2025.102505
Zavin R. Gajera , Alka A. Mungray , Arvind Kumar Mungray
The issue of organic waste management is a global problem, as the rate of food waste continues to surge, and human organic waste, such as faeces and urine, is steadily increasing. Hydrothermal carbonization (HTC) is a promising thermochemical conversion technology that uses wet organic wastes to produce hydrochar rich in energy. Nevertheless, single-feedstock HTC frequently yields hydrochars of poor fuel attributes. The study demonstrates the co-hydrothermal carbonization (co-HTC) of cooked food waste (CFW) and human faeces (HF) using human urine as the reaction medium, aiming to harness the synergistic effects that enhance hydrochar quality and combustion efficiency. The mass ratio of CFW and HF was varied (1:0; 3:1; 1:1; 1:3; 0:1) to perform Co-HTC at 200 °C for 2 h. The derived hydrochars were characterized in terms of proximate and ultimate analysis, higher heating value (HHV), combustion kinetics, and micro morphology. Findings indicated that co-HTC produced HC(1:3) Hydrochar endorsed the binding reaction between carbohydrates and proteins, which increased carbon retention and reduced ash levels. Higher ignition and combustion stability in the CFW-rich hydrochars were also seen in thermogravimetric analysis. SEM and FTIR experiments demonstrated that the structure changes and increased aromaticity occurred due to the hydrothermal process, accompanied by an enhancement of CFW content in the feed. The results suggest that co-HTC of CFW and HF with human urine offers a viable route for recovering bioenergy and recycling nutrients, aligning with circular economy concepts.
有机废物管理问题是一个全球性问题,因为食物废物的比率持续飙升,人类的有机废物,如粪便和尿液,正在稳步增加。水热碳化(HTC)是一种很有前途的热化学转化技术,它利用湿性有机废物生产富含能量的碳氢化合物。然而,单原料HTC经常产生燃料属性差的碳氢化合物。本研究以人类尿液为反应介质,对熟食垃圾(CFW)和人类粪便(HF)进行了共水热碳化(co-HTC),旨在利用协同效应提高碳氢化合物的质量和燃烧效率。改变CFW和HF的质量比(1:0,3:1,1:1,1:3,0:1),在200℃下进行Co-HTC 2 h。衍生的氢炭在近似和最终分析,更高的热值(HHV),燃烧动力学和微观形貌方面具有特征。结果表明,co-HTC产生的HC(1:3)碳氢化合物支持碳水化合物和蛋白质之间的结合反应,增加了碳潴留,降低了灰分水平。热重分析表明,富cfw烃类具有较高的点火和燃烧稳定性。扫描电镜(SEM)和红外光谱(FTIR)实验表明,水热过程导致原料结构发生变化,芳香性增加,同时原料中CFW含量增加。结果表明,CFW和HF与人类尿液的共同htc为生物能源的回收和营养物质的循环利用提供了一条可行的途径,符合循环经济的概念。
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引用次数: 0
Isolation and characterization of bacteria associated with the cultured diatom Halamphora sp.: Focus on heavy metal resistance and bioremediation potential 培养硅藻Halamphora sp.相关细菌的分离与鉴定:重点研究重金属抗性及其生物修复潜力
Q1 Environmental Science Pub Date : 2025-12-29 DOI: 10.1016/j.biteb.2025.102510
Min-Ying Wang , Yi-Fang Chang , Sally Wang , Chen-Hao Lin , William E. Bentley , Su-Yuan Lai
Symbiotic relationships between microalgae and bacteria can play a crucial role in enhancing metal resistance and promoting bioremediation. The phycosphere refers to the microscale chemical boundary layer surrounding microalgal cells, where algae release dissolved organic matter and metabolites that attract and support associated microorganisms. In this study, 40 bacterial species were isolated and molecularly characterized directly from the phycosphere of the marine diatom Halamphora sp. (AQ4), and their resistance to heavy metal ions was subsequently evaluated under high-salt marine conditions. Our preliminary screening revealed two Brachybacterium strains (A4005, A4006) with exceptionally high tolerance to Co2+ up to 500 mM, and three Nitratireductor strains (A4017, A4019, and A4020) to 125 mM. For Ni2+, A4005 and A4017 displayed nearly 60 % viability at 125 mM. Strains A4005, A4006, and A4019 tolerated concentrations of 15.625 mM of Zn2+. Further testing confirmed that Brachybacterium strains exhibited higher viabilities across all tested metals compared to Nitratireductor, especially A4006, highlighting its potential for bioremediation. Future research will explore the mechanisms behind this metal tolerance and its practical applications in environmental biotechnology.
微藻与细菌的共生关系在增强金属抗性和促进生物修复方面发挥着至关重要的作用。藻球是指微藻细胞周围的微尺度化学边界层,藻类在其中释放溶解的有机物和代谢物,吸引和支持相关微生物。本研究从海洋硅藻Halamphora sp. (AQ4)的藻圈中分离出40种细菌,并对其进行了分子表征,并对其在高盐海洋环境下对重金属离子的抗性进行了评价。初步筛选结果显示,2株短支杆菌(A4005、A4006)和3株硝化还原剂(A4017、A4019和A4020)对Co2+的耐受性分别为500 mM和125 mM。对于Ni2+, A4005和A4017在125 mM下的生存力接近60%。菌株A4005、A4006和A4019对Zn2+的耐受性为15.625 mM。进一步的测试证实,与Nitratireductor(特别是A4006)相比,短支杆菌菌株在所有测试金属中表现出更高的生存能力,突出了其生物修复潜力。未来的研究将探索这种金属耐受性背后的机制及其在环境生物技术中的实际应用。
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引用次数: 0
Design and performance evaluation of a manual blazer for sustainable Karaya gum production from Sterculia urens 可持续卡拉亚树胶生产的手工运动器的设计和性能评估
Q1 Environmental Science Pub Date : 2025-12-29 DOI: 10.1016/j.biteb.2025.102509
Satish Chandra Sharma, Sanjay Kumar Pandey, Niranjan Prasad, Himanshu Raj, Saroj Kumar Giri, Abhijit Kar
Natural resins and gums are vital Non-Wood Forest Products (NWFPs) with significant economic and ecological value. Karaya gum is widely used in food, pharmaceutical, and industrial sectors due to its biodegradability and biocompatibility. Traditional gum tapping methods using axes or chisels cause excessive tree damage, inefficiency, and inconsistent yields, highlighting the need for sustainable and efficient tapping tools. This study aimed to design, develop, and evaluate a lightweight, manually operated gum tapping blazer to optimize karaya gum production by minimizing injury, reducing drudgery, and ensuring consistent blaze dimensions and depth. The blazer was designed and fabricated with stainless steel, featuring a semi-circular working blade, depth control mechanism, and ergonomic handle. Field trials were conducted comparing the blazer's performance with traditional chisel methods. Parameters evaluated included blazing time, gum yield, physical damage, operational cost, and gum quality. The blazer reduced blaze formation time to 9 min (vs. 15 min for chisels) and increased daily capacity to 50 blazes (vs. 30). It yielded higher gum production (average 166.79 g/month/tree vs. 33.27 g) with minimal injury (103.36cm2 area, 258.39cm3 volume). Operational costs were lower (Rs. 7.0/blaze vs. Rs. 11.67). Gum quality matched industry standards, confirming no adverse effects from the blazer. The developed blazer is a sustainable, user-friendly tool that enhances karaya gum productivity while minimizing tree damage and labor costs. Its adoption can improve livelihoods of forest-dependent communities and support India's NWFP trade. The study underscores the importance of mechanization in sustainable forest resource management.
天然树脂和树胶是重要的非木材林产品,具有重要的经济和生态价值。卡拉亚胶具有生物可降解性和生物相容性,广泛应用于食品、制药和工业领域。使用斧头或凿子的传统攻胶方法会对树木造成严重损害,效率低下,产量不稳定,这突出了对可持续和高效攻胶工具的需求。本研究旨在设计、开发和评估一种轻量化、手动操作的口香糖攻胶机,通过最大限度地减少伤害、减少苦工、确保一致的火焰尺寸和深度来优化卡拉亚口香糖的生产。该运动夹克采用不锈钢设计和制造,具有半圆形工作刀片,深度控制机构和符合人体工程学的手柄。进行了现场试验,比较了该blazer与传统凿法的性能。评估的参数包括燃烧时间、胶产量、物理损坏、操作成本和胶质量。blazer将火焰形成时间缩短至9分钟(凿子为15分钟),并将每日火焰生成能力增加至50次(相比之下为30次)。它的树胶产量更高(平均166.79 g/月/棵树vs. 33.27 g),伤害最小(面积103.36cm2,体积258.39cm3)。操作成本较低(7.0卢比/火焰比11.67卢比)。口香糖质量符合行业标准,确认没有不良影响的运动上衣。开发的夹克是一个可持续的,用户友好的工具,提高卡拉亚胶的生产力,同时最大限度地减少树木的损害和人工成本。它的采用可以改善依赖森林的社区的生计,并支持印度西北边境省的贸易。这项研究强调了机械化在可持续森林资源管理中的重要性。
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引用次数: 0
Bacterially secreted 3-hydroxybutyrate oligoesters production for polyurethane synthesis: Structural diversification and biodegradation test with seawater 合成聚氨酯用细菌分泌的3-羟基丁酸低聚酯:结构多样化和海水生物降解试验
Q1 Environmental Science Pub Date : 2025-12-29 DOI: 10.1016/j.biteb.2025.102513
Tetsuo Sakurai , Yuki Miyahara , Manami Ishii-Hyakutake , Hideki Abe , Seiichi Taguchi , Takeharu Tsuge
Bacterially secreted 3-hydroxybutyrate oligoester (3HBO) is a new fermentative product produced by modifying the polyhydroxyalkanoate (PHA) biosynthetic system. To enhance 3HBO secretion, alcoholic compounds must act as a chain transfer (CT) agent in the PHA polymerization process, resulting in conjugation of the CT agent to the 3HBO carboxyl terminus. The 3HBO can be utilized as a polyol macromonomer for the synthesis of 3HBO polyurethanes via polyaddition with diisocyanates. This study aimed to investigate the structural diversity and physical properties of 3HBO polyurethanes, as well as their biodegradability. First, eight diols were tested as CT agents by supplementing the culture of PHA-producing Escherichia coli. The highest 3HBO secretion was observed for diethylene glycol (DEG), and the primary alcohols induced greater 3HBO secretion than the secondary alcohols. Subsequently, polyurethanes were synthesized via a polyaddition of 3HBO, which was conjugated with DEG, 1,2-propanediol, or 1,3-propanediol, with three diisocyanates [4,4′-diphenylmethane diisocyanate (MDI), 1,6-hexamethylene diisocyanate (HDI), and toluene diisocyanate (TDI)]. The resulting 3HBO polyurethanes were all amorphous polymers. Their glass transition temperatures ranged from −4 °C to 56 °C, mainly depending on the type of diisocyanate used. The biodegradability tests were conducted for several 3HBO polyurethanes using seawater. The powders of MDI-based polyurethanes exhibited low biodegradability, whereas TDI- and HDI-based polyurethanes showed higher biodegradability. The biodegradability of 3HBO polyurethanes in seawater mainly depended on the structure of the diisocyanate used. These observations provide important insights that pave the way for utilizing 3HBO as a new building block for bio-based and biodegradable polyurethanes.
细菌分泌的3-羟基丁酸寡酯(3HBO)是通过对聚羟基烷酸酯(PHA)生物合成体系进行改性而产生的一种新型发酵产物。为了促进3HBO的分泌,酒精化合物必须在PHA聚合过程中作为链转移(CT)剂,导致CT剂与3HBO羧基末端结合。3HBO可以作为多元醇大单体,通过与二异氰酸酯的聚加成合成3HBO聚氨酯。本研究旨在研究3HBO聚氨酯的结构多样性、物理性能及其生物降解性。首先,通过补充产生pha的大肠杆菌的培养,测试了8种二醇作为CT剂。二甘醇(DEG)的3HBO分泌量最高,伯醇诱导的3HBO分泌量大于仲醇。随后,通过3HBO与DEG, 1,2-丙二醇或1,3-丙二醇的多加成合成聚氨酯,并与三种二异氰酸酯[4,4 ' -二苯基甲烷二异氰酸酯(MDI), 1,6-六亚甲基二异氰酸酯(HDI)和甲苯二异氰酸酯(TDI)]偶联。所得的3HBO聚氨酯均为无定形聚合物。它们的玻璃化转变温度范围从- 4°C到56°C,主要取决于所使用的二异氰酸酯的类型。用海水对几种3HBO聚氨酯进行了生物降解性试验。mdi基聚氨酯粉末具有较低的生物降解性,而TDI和hdi基聚氨酯粉末具有较高的生物降解性。3HBO聚氨酯在海水中的生物降解性主要取决于所使用的二异氰酸酯的结构。这些观察结果提供了重要的见解,为利用3HBO作为生物基和可生物降解聚氨酯的新基石铺平了道路。
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引用次数: 0
Oxygen transfer and kinetic modeling in the scale-up of gibberellic acid production by Gibberella fujikuroi in submerged culture 富庶赤霉素深层培养中氧传递及动力学模型的研究
Q1 Environmental Science Pub Date : 2025-12-29 DOI: 10.1016/j.biteb.2025.102511
David Antonio Flores-Méndez , Giovanni Alexander Escamilla-García , Hugo Jiménez-Islas , Miriam Granados-Vallejo , Pedro Alberto Quintana-Hernández , Eleazar Máximo Escamilla-Silva
Gibberellic acid (GA3) is a key plant hormone that has been studied for over a century. There is limited information on scaling up the GA3 production process. This study evaluates the effects of progressive laboratory scale-up on GA₃ production and develops a kinetic model. Scale-up was performed from 500 mL to 20 L, providing sufficient data to transition from flasks to bioreactors. The highest GA3 production (519.8 mg L−1) and maximum productivity (4.899 mg L−1 h−1) coincided with an operating volume of 5 L; scaling to 20 L reduced GA3 production to 388.2 mg L−1. Biomass growth remained robust across scales (8.6–11.6 g L−1), with specific growth rates (μ) ranging from 0.021 to 0.032 h−1. The volumetric mass transfer coefficient (KLa) increased 1.4-fold when the medium volume increased from 3 to 20 L. Compared to experimental data, the proposed kinetic model satisfactorily describes (R2 > 0.96) the dynamics of the fermentation process at various scales. These findings provide insights into progressive laboratory scale-up of GA3 production and demonstrate its potential at larger working volumes in stirred bioreactors.
赤霉素酸(GA3)是一种重要的植物激素,已经被研究了一个多世纪。关于扩大GA3生产过程的信息有限。这项研究评估了逐步扩大实验室规模对GA₃生产的影响,并建立了一个动力学模型。从500ml放大到20l,为从烧瓶过渡到生物反应器提供足够的数据。操作体积为5 L时,GA3产量最高(519.8 mg L−1),产率最高(4.899 mg L−1 h−1);缩放至20 L可使GA3产量降至388.2 mg L−1。生物量在各尺度(8.6 ~ 11.6 g L−1)上保持强劲增长,比增长率(μ)在0.021 ~ 0.032 h−1之间。当培养基体积从3 l增加到20 l时,体积传质系数(KLa)增加了1.4倍,与实验数据相比,所建立的动力学模型(R2 > 0.96)较好地描述了不同尺度下发酵过程的动力学特性。这些发现为逐步扩大GA3生产的实验室规模提供了见解,并证明了其在搅拌生物反应器中更大工作量的潜力。
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引用次数: 0
Selective recovery of gibberellic acid using amberlite resins: Adsorption–desorption process and performance evaluation 琥珀石树脂选择性回收赤霉素酸:吸附-解吸工艺及性能评价
Q1 Environmental Science Pub Date : 2025-12-28 DOI: 10.1016/j.biteb.2025.102490
David Antonio Flores-Méndez , Miriam Granados-Vallejo , Omar González-Ortega , Fernando Jonathan Lona-Ramírez , Giovanni Alexander Escamilla-García , Eleazar Maximo Escamilla-Silva
Gibberellic acid (GA3) is a plant growth regulator traditionally recovered by liquid-liquid extraction, a process limited by low yields and high energy demands. This study presents a novel adsorption-based approach for the selective recovery of GA3 from synthetic solutions and fermentation broth using Amberlite XAD-4S, XAD-4R, and IRA-400 resins. Among them, XAD-4S exhibited the highest adsorption capacity (5.7 × 10−3 g/g) and desorption efficiency (98%) with 85% methanol as eluent. Adsorption equilibrium data were best described by the Freundlich isotherm (R2 = 0.99), indicating multilayer adsorption on a heterogeneous surface. Fixed-bed column experiments using XAD-4S demonstrated that breakthrough curves were effectively predicted by the Thomas, Yoon-Nelson, and BDST models (R2 > 0.97), with a breakthrough time of approximately 100 min. Additionally, the resin achieved a GA₃ recovery of approximately 97% from fermentation broth. These results confirm that XAD-4S is an efficient alternative for GA₃ isolation, offering a viable replacement to conventional extraction techniques in biotechnological applications.
赤霉素酸(GA3)是一种植物生长调节剂,传统上是通过液-液萃取法回收的,这一工艺受到低产量和高能量需求的限制。本研究采用Amberlite XAD-4S、XAD-4R和IRA-400树脂从合成溶液和发酵液中选择性回收GA3。其中,XAD-4S吸附量最高(5.7 × 10−3 g/g),以85%甲醇为洗脱液时解吸效率最高(98%)。Freundlich等温线(R2 = 0.99)最能描述吸附平衡数据,表明在非均质表面上有多层吸附。利用XAD-4S进行的固定床柱实验表明,Thomas、Yoon-Nelson和BDST模型(R2 > 0.97)可以有效地预测突破曲线,突破时间约为100 min。此外,该树脂从发酵液中获得了大约97%的GA₃回收率。这些结果证实了XAD-4S是GA₃分离的有效替代品,在生物技术应用中为传统的提取技术提供了可行的替代品。
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引用次数: 0
Transforming amorphous cellulose into crystalline form using microwave irradiation in a non-reactive medium 在非反应介质中使用微波照射将无定形纤维素转化为结晶形式
Q1 Environmental Science Pub Date : 2025-12-27 DOI: 10.1016/j.biteb.2025.102504
Erik Gómez Hernández , Carlos Alberto Gómez Aldapa , Israel Sifuentes Nieves , Guadalupe Paola Radilla Serrano , Carlos Alberto Gallardo Vega , Yucundo Mendoza Tolentino , Gabriela Yolotzín Romero Zúñiga , Ernesto Hernández Hernández , Pablo González Morones
This research investigated how microwaves transform amorphous cellulose from agro-industrial waste of barley husks (BH's) into its crystalline form. The process involves two consecutive microwave (MW) treatments of pure BH's, which show an amorphous halo at 20.3° in 2θ and have a low cellulose concentration (12.86 % by weight). After the first treatment (MW-1), the cellulose concentration increases 3.7 times, enabling the extraction of cellulose microfibrils (CM's) with a crystallinity index (CrI) of 68.27 %. The second MW treatment (MW-2) further increases cellulose concentration (by 1.7 times compared to MW-1), raising the CrI to 91.04 % and promoting the formation of type II cellulose crystals (CII). The results indicate that during MW-1, the extraction and purification of CM's dominate, consuming most of the MW energy. In contrast, during MW-2, which processes the CM's from MW-1, energy is mainly used to complete the purification of CM's and encourage the structural reorganization of amorphous regions, thereby increasing the material's crystallinity. This MW treatment provides a novel and alternative method to traditional MW processes using alkaline or acidic substances, which tend to degrade amorphous regions of cellulose and extract its crystalline fraction as nanocrystals.
本研究调查了微波如何将大麦壳(BH's)农业工业废料中的无定形纤维素转化为结晶形式。该工艺包括两个连续的微波(MW)处理纯BH's,在2θ的20.3°处显示出无定形晕,并且纤维素浓度低(重量比12.86%)。第一次处理(MW-1)后,纤维素浓度增加3.7倍,可提取结晶度指数(CrI)为68.27%的纤维素微原纤维(CM’s)。第二个MW处理(MW-2)进一步提高了纤维素浓度(比MW-1提高了1.7倍),使CrI提高到91.04%,促进了II型纤维素晶体(CII)的形成。结果表明,在MW-1过程中,CM的提取和纯化占主导地位,消耗了大部分MW能量。而从MW-1加工CM -2的过程中,能量主要用于完成CM -1的纯化,促进无定形区域的结构重组,从而提高材料的结晶度。这种微波处理提供了一种新的替代方法,传统的微波处理方法使用碱性或酸性物质,这些物质倾向于降解纤维素的无定形区域并提取其晶体部分作为纳米晶体。
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Bioresource Technology Reports
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