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Bulletin of the National Technical University "KhPI". Series: Chemistry, Chemical Technology and Ecology最新文献

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NEAR HYDRATION OF SINGLY CHARGED MONOATOMIC IONS IN EXTREMELY DILUTED SOLUTIONS: THE EFFECT OF TEMPERATURE AND PRESSURE 带单电荷的单原子离子在极稀溶液中的接近水化作用:温度和压力的影响
Viktor Ivanovych Булавин, I. V’unik, A. Kramarenko, A. Rusinov
The diffusion coefficient  and the distance of translational displacement of Li+, Na+ K+, Cs+, Cl– and Br– ions  in water at 298.15 K – 423.15 K (25 K step) and pressure from 0.0981 to 784.5 MPa (98.1 MPa step) were calculated from the literature data on limiting molar electrical conductivity. The  values for these ions increase with pressure growth from 0.0981  to 98.1 MPa at 298.15 K. Further pressure increase (up to 785 MPa) leads to decrease in . Temperature growth under isobaric conditions leads to an increase in . Parameter (– ri) (deviation from the Stokes–Einstein law, ri is ion structural radius) was used as a criterion for the type of ion solvation. It is shown that Li+ and Na+ ions behave as cosmotropes, or positively solvated structure–forming ions having (– ri) > 0. The Cs+, Cl–, Br– ions behave as chaotropes, or negatively solvated structure–breaking ions having (– ri) < 0. For the K+ ion, the (– ri) deviation is alternating. At 0.0981 MPa and 298.15 K, the K+ ion is a chaotrope. But at 320 K (Tlim) parameter (– ri) = 0. It corresponds to the transition from negative to positive solvation. Above Tlim at P = const, the K+ ion is a cosmotrope. At 298.15 K and up to 98.1 MPa, the pressure causes the same change in the (– ri) deviation as the temperature. On the contrary, at 320 K and higher, the pressure affects the near hydration in the direction opposite to the temperature.
利用极限摩尔电导率的文献数据,计算了在298.15 K ~ 423.15 K (25 K步)和0.0981 ~ 784.5 MPa (98.1 MPa步)压力下,Li+、Na+ K+、Cs+、Cl -和Br -离子在水中的扩散系数和平移位移距离。在298.15 K下,这些离子的值随压力的增加而增加,从0.0981 MPa增加到98.1 MPa。进一步增加压力(高达785兆帕)会导致压力下降。等压条件下的温度升高导致。参数(- ri)(偏离斯托克斯-爱因斯坦定律,ri为离子结构半径)被用作离子溶剂化类型的判据。结果表明,Li+和Na+离子表现为具有(- ri) >的正溶剂化结构形成离子。Cs+, Cl -, Br -离子表现为乱相或负溶剂化的结构破坏离子,其(- ri) < 0。对于K+离子,(- ri)偏差是交替的。在0.0981 MPa和298.15 K下,K+离子为混沌态。但在320k (lim)时,参数(- ri) = 0。它对应于从负溶剂化到正溶剂化的转变。在P = const上,K+离子是一个宇宙观。在298.15 K和高达98.1 MPa时,压力引起的(- ri)偏差变化与温度相同。相反,在320 K及更高温度下,压力对近水化的影响方向与温度相反。
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引用次数: 0
COMPARATIVE ASSESSMENT OF GASEOUS FUEL EMISSION 气体燃料排放的比较评估
O. Levytska, Y. V. Voytenko, Anastasiia Oleksiivna Orishechok
The work presents estimated comparative assessment of emissions release in combustion products during work of high–power steam boilers with the use of traditional fuel – natural gas and alternative fuels – blast–furnace and coke–oven gases generated in the process of technological cycle at iron and steel and coke–chemical enterprises. Calculation algorithm is shown and formulas for assessment of carbon content in exhaust gases are defined, conclusions on ecological efficiency of gaseous fuels are given. The purpose of the work was to evaluate the emissions of harmful substances generated during the combustion of natural, blast furnace and coke oven gases, justification of the calculation of carbon content of a given chemical composition and determine the optimal environmental impact of analogues of natural gas. The comparative estimation of pollutant emissions into atmospheric air during combustion of natural, coke oven and blast furnace gases revealed: – high sulfur dioxide emissions from combustion of blast furnace and coke oven gases due to the presence of sulfur compounds in the composition of these gases; – relatively high emissions of nitrogen compounds for natural and coke oven gases and relatively low emissions for blast furnace gas; – сarbon emissions are high for all types of fuels which have been considered, most carbon dioxide gets into  the air when burning natural gas, least – when burning blast furnace gas; – significantly higher methane emissions are observed during the combustion of natural and coke oven gases, respectively, smaller – for blast–furnace gas combustion; – coke oven and natural gases are characterized by low mercury emissions. Comparative assessment of the calculated values of hazardous substances emissions in the combustion products in the process of combustion of natural, coke–oven and blast–furnace gases shows that even at lower working heat of combustion values the coke–oven and blast–furnace gases can compete with natural gas. For the first time, a comparative characterization of the emissions of harmful substances in the combustion of natural, coke oven and blast furnace gases is presented, and it is shown that the gases used in coke and metallurgical industries, which are used as analogues of natural, are logical to use, but require the installation of treatment systems. The paper defines a formula for calculating the carbon content in natural gas from the Urengoy–Uzhhorod gas pipeline. The provided calculations and the introduction of simplified formulas serve as an example for the calculation of emission factors and emissions in assessing the level of safety of existing equipment and can be used in the development of permit documents of enterprises that carry out emissions of harmful substances to the environment.
本文对钢铁和焦化企业大功率蒸汽锅炉与使用传统燃料天然气和替代燃料高炉煤气和焦炉煤气在工艺循环过程中产生的燃烧产物排放进行了估计比较评价。给出了计算算法,定义了废气碳含量的计算公式,给出了气体燃料生态效率的结论。这项工作的目的是评估天然、高炉和焦炉气体燃烧过程中产生的有害物质排放,证明计算特定化学成分碳含量的合理性,并确定天然气类似物对环境的最佳影响。对天然煤气、焦炉煤气和鼓风炉煤气燃烧时排放到大气中的污染物的比较估计表明:-由于鼓风炉煤气和焦炉煤气的成分中含有硫化合物,燃烧时产生的二氧化硫排放量很高;-天然煤气和焦炉煤气的氮化合物排放量相对较高,高炉煤气的排放量相对较低;-所有类型的燃料的碳排放量都很高,燃烧天然气时大多数二氧化碳进入空气,燃烧高炉煤气时最少;-在燃烧天然气体和焦炉气体时,甲烷排放量分别显著增加,而在燃烧高炉气体时,甲烷排放量则较小;-焦炉和天然气的特点是汞排放量低。通过对天然煤气、焦炉煤气和高炉煤气燃烧过程中燃烧产物中有害物质排放计算值的对比评价表明,即使在较低的燃烧工热值下,焦炉煤气和高炉煤气也可以与天然气相媲美。本文首次对天然煤气、焦炉煤气和鼓风炉煤气燃烧中有害物质的排放进行了比较,结果表明,焦炭和冶金工业中使用的煤气作为天然煤气的类似物,使用起来是合乎逻辑的,但需要安装处理系统。本文定义了一个计算乌连戈伊-乌日霍罗德输气管道天然气含碳量的公式。所提供的计算方法和所采用的简化公式可作为评估现有设备安全水平时计算排放系数和排放量的范例,并可用于编制向环境排放有害物质的企业的许可证文件。
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引用次数: 0
FLAMMABILITY OF HYDROCARBON FRACTIONS OBTAINED BY DESTRUCTION OF POLYMER RAW MATERIALS 通过破坏聚合物原料获得的烃类馏分的可燃性
K. Shevchenko, A. Grigorov
The article discusses the possibility of using hydrocarbon fractions – products of thermal destruction of polymer raw materials (polyethylene and polypropylene) at atmospheric pressure as components of commercial diesel fuels. This approach allows, on the one hand, to improve the properties of commercial diesel fuel, on the other, to increase the competitiveness of domestically produced products. In addition, the problem associated with the accumulation of polymer waste and their negative impact on the environment is also partially solved. The nature of the dependences between such indicators of the quality of fractions 160–350 °C, 200–350 °C, 240–350 °C as the autoignition temperature, the initial boiling point of the fraction and the cetane number as an indicator characterizing the flammability, has been established. The dependence of the autoignition temperature on the boiling point of the fractions has a polynomial character and indicates a decrease in the autoignition temperature with an increase in the boiling point of the fractions. The dependence of the cetane number on the initial boiling point of the fractions is linear and indicates an increase in the cetane number with an increase in the initial boiling point of the fractions. The dependence of the cetane number on the autoignition temperature of the fractions has a polynomial character and indicates a decrease in the cetane number with an increase in the autoignition temperature of the fractions. It was found that the autoignition temperature of the investigated fractions, regardless of the type of polymer raw material, fluctuates in a rather narrow range, from 229 to 348 ° C, and the cetane number – from 41 to 55 units. Based on the literature data, we note that exactly this range is close to the range that commercial diesel fuels have, and the fractions studied by us can be used in the production of diesel fuel.
本文讨论了利用烃类馏分——聚合物原料(聚乙烯和聚丙烯)在常压下热破坏的产物——作为商用柴油组分的可能性。这种方法一方面可以改善商用柴油的性能,另一方面可以提高国内生产产品的竞争力。此外,与聚合物废物积累及其对环境的负面影响相关的问题也得到了部分解决。已经确定了160-350℃、200-350℃、240-350℃馏分质量指标(自燃温度)、馏分的初沸点和表征可燃性的十六烷数之间的依赖关系的性质。自燃温度与馏分沸点的关系具有多项式特征,表明自燃温度随馏分沸点的升高而降低。十六烷数与馏分初沸点的关系是线性的,表明十六烷数随馏分初沸点的增加而增加。十六烷数与馏分自燃温度的关系具有多项式特征,表明十六烷数随馏分自燃温度的升高而降低。研究发现,无论聚合物原料的类型如何,所研究的馏分的自燃温度在229 ~ 348℃的范围内波动,十六烷值在41 ~ 55个单位之间波动。根据文献数据,我们注意到这个范围正好接近于商业柴油的范围,我们所研究的馏分可以用于柴油的生产。
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引用次数: 0
PROVISION OF CONDITIONS OF COMPARABILITY OF RESULTS IN FIELD BIOTECHNOLOGICAL RESEARCH USING A COMPUTER EXPERIMENT 利用计算机实验提供野外生物技术研究结果的可比性条件
L. Gorbunov, Nadiia Larintseva, O. Zviahintseva
When conducting biotechnological field studies using plant objects, there is a problem of taking into account the heterogeneity of the results, the imperfection of methods leads to the need for multiple repetitions of experiments, but the issue of reproducibility and comparability of research results is not resolved, therefore, the use of mathematical models in research makes it possible not only to identify, but also to explain the obtained patterns. The subject of the study in the article is a simulation model for estimating the mass of corn grains taking into account their genotype and growing conditions. The model is based on an analytical expression that reflects the main reasons for the growth of corn seeds after pollination of the plant. The mass of corn grains depends on a number of biological factors (genotype), technological – soil structure (its fertility and methods of cultivation), and climatic conditions (humidity, light intensity). The aim of the study is to create a simulation model to ensure the comparability of the results obtained when growing corn for grain in different conditions. Biological (cultivation) and mathematical (simulation model) methods were used as methods for obtaining and constructing results. The discrepancy in the estimation of the mass of grain of the same genotype grown in different research farms of different climatic zones of Ukraine and obtained by calculation was not more than 18 % and obtained experimentally up to 64 %. A feature of the model is the independence of the heterogeneity of the bioobject (studied lines and hybrids) from the conditions of their cultivation (soil structure and climatic conditions). The application of mathematical modeling makes it possible to reduce the differences in the studied indicators up to 25 times, which were obtained in different experiments, thereby significantly reducing time, money and provide a condition for comparability of results to obtain a reliable result.
在使用植物对象进行生物技术领域研究时,存在考虑结果异质性的问题,方法的不完善导致需要多次重复实验,但研究结果的可重复性和可比性问题并未得到解决,因此,在研究中使用数学模型不仅可以识别,而且可以解释所获得的模式。本文研究的主题是考虑玉米基因型和生长条件的玉米籽粒质量估算的模拟模型。该模型基于反映植物授粉后玉米种子生长的主要原因的解析表达式。玉米籽粒的质量取决于许多生物因素(基因型)、技术土壤结构(其肥力和栽培方法)和气候条件(湿度、光照强度)。本研究的目的是建立一个仿真模型,以保证不同条件下玉米作粮种植所得结果的可比性。采用生物(培养)法和数学(模拟模型)法作为获取和构建结果的方法。在乌克兰不同气候带的不同研究农场中种植的同一基因型谷物的质量,通过计算得到的估计值的差异不超过18%,而实验得到的差异高达64%。该模型的一个特点是生物对象(研究的品系和杂交种)的异质性与其栽培条件(土壤结构和气候条件)的独立性。数学建模的应用使得所研究的指标在不同实验中得到的差异可以减少到25倍,从而大大减少了时间和金钱,并为结果的可比性提供了条件,从而获得可靠的结果。
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引用次数: 0
THERMAL INTEGRATION OF COMPRESSION REFRIGERATION UNITS IN DAIRY FACILITIES 乳品厂压缩制冷装置的热集成
S. Bykanov, Babak Tetiana Babak, Roman Stotskyi
The heat integration of an ammonia compression refrigeration unit, that is used in different dairy facilities, was carried out by the pinch analysis methods. The schematic diagram of such unit with a cooling capacity of 1000 kW was taken as a basis. The main cycle temperatures, refrigerant consumption and its specific heat capacity were calculated for a given refrigerating capacity. Based on these data, a stream table was formed, that included a hot stream of a refrigerant – ammonia – and also two cold streams: water for chemical water treatment and water for technology. The hot stream of ammonia was divided into three streams: cooling of ammonia vapors, condensation and subcooling. Heat capacities flowrates and heat loads (stream enthalpy change) of the streams were determined. The minimum temperature difference in heat exchangers DTmin = 8°С was determined on the basis of technical and economic calculations for this process. The composite curves were plotted for the minimum temperature difference. The pinch temperatures were determined by the problem table algorithm for the hot and cold streams. The minimum values of hot and cold utilities load (QHmin and QСmin) were determined. The heat recovery capacity was determined, which was 701.8 kW. A grid diagram was built and heat exchangers are arranged in accordance with CP and N rules. The retrofit of process flowsheet is proposed on the basis of the grid diagram that includes the installation of three heat exchangers, one cooler and two heaters to achieve the target temperatures and flow rates. The use of Alfa Laval plate heat exchangers is proposed as heat exchange equipment. The payback period of the design is about two years.
采用夹点分析方法,对不同奶牛场的氨压缩制冷装置进行了热集成。以该机组1000kw制冷量的原理图为依据。计算了给定制冷量下的主循环温度、制冷剂消耗量及其比热容。根据这些数据,形成了一个流表,其中包括制冷剂氨的热流和两种冷流:化学水处理用水和技术用水。氨热流分为氨蒸气冷却、冷凝和过冷三种流。测定了各流的热容、流量和热负荷(流焓变)。换热器的最小温差DTmin = 8°С是根据该工艺的技术经济计算确定的。绘制了最小温差的复合曲线。采用问题表算法确定了冷热流的夹点温度。确定了冷热负荷最小值(QHmin和QСmin)。确定热回收能力为701.8 kW。建立网格图,按照CP和N规则布置换热器。根据网格图提出了工艺流程的改造方案,包括安装3台换热器、1台冷却器和2台加热器,以达到目标温度和流量。建议采用阿法拉伐板式换热器作为换热设备。本设计投资回收期约为两年。
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引用次数: 0
RESEARCH OF PROCESSES OF FORMATION OF STRUCTURE OF COMPOSITE THERMAL INSULATION MATERIALS ON THE BASIS OF LIQUID GLASS BTAINED WITH THE USE OF ENVIRONMENTALLY SAFE MICROWAVE TECHNOLOGIES 以环境安全微波技术制备的液态玻璃为基础,研究复合保温材料的结构形成过程
T. Rymar, O. Suvorin
Improving the efficiency of energy use is one of the main tasks in the chemical industry not only in Ukraine but also around the world, which is due to the steady rise in energy prices. In this regard, an effective way to save energy is the thermal modernization of buildings, industrial equipment and communications with thermal insulation materials. It should be noted that the share of domestic materials in the Ukrainian market is not more than 30 %. Therefore, the creation of new types of insulation materials is a very important task. This material is a heat–insulating material based on liquid glass, created with the involvement of microwave radiation as an alternative to traditional convective thermal heating. The technology of production of heat–insulating materials on the basis of liquid glass by hot foaming involves obtaining the material in the form of granules, not plates, due to the difficulty of uniform heating of the inner layers of large samples. The problem of large–scale production of high–quality thermal insulation materials based on liquid glass in plate form is not solved due to poor heating of the inner layers of the plate due to the low thermal conductivity of the swollen outer layers. That is why the production of composite thermal insulation materials based on granular filler and liquid glass binder is proposed to be carried out under the action of microwave radiation. Thermal insulation properties of expanded materials are directly determined by their macrostructure. Therefore, the purpose of this study is to determine changes in the structure of the material from the type and amount of ingredients used in the liquid glass composition. On the basis of the conducted researches it is shown that the materials with use as a filler of zinc oxide and as a gas–forming agent of hydrogen peroxide have the most ordered structure. It is established that their use in the amount of 9–10 wt.h. provides a rate of gas evolution and growth of pore centers, which is comparable to the process of curing composition, which allows to obtain materials with a homogeneous, fine and closed–porous structure, which provides high insulating properties with a thermal conductivity coefficient of 0.05–0.055 W / m · K, which meets the requirements for thermal insulation materials.
提高能源使用效率是化学工业的主要任务之一,不仅在乌克兰,而且在世界各地,这是由于能源价格的稳步上涨。对此,节能的有效途径是建筑、工业设备和通信的热力现代化使用保温材料。需要指出的是,国内材料在乌克兰市场的份额不超过30%。因此,创造新型保温材料是一项非常重要的任务。这种材料是一种基于液态玻璃的隔热材料,是在微波辐射的参与下创造的,作为传统对流热加热的替代品。在液态玻璃的基础上通过热发泡生产隔热材料的技术涉及到以颗粒的形式获得材料,而不是板,因为大样品的内层难以均匀加热。以平板形式的液态玻璃为基础的高质量保温材料的规模化生产问题,由于外层膨胀热导率低,导致板材内层受热率差,无法解决。因此,提出在微波辐射作用下进行基于颗粒填料和液态玻璃粘结剂的复合保温材料的生产。膨胀材料的保温性能直接决定于其宏观结构。因此,本研究的目的是从液体玻璃组成中所使用的成分的类型和数量来确定材料结构的变化。研究结果表明,作为氧化锌填料和过氧化氢成气剂的材料结构最有序。确定其用量为9-10 wth。提供了气体的演化速率和孔中心的生长速率,这与固化成分的过程相当,从而可以获得均匀、精细和封闭的多孔结构的材料,具有较高的保温性能,导热系数为0.05-0.055 W / m·K,满足了保温材料的要求。
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引用次数: 0
ELECTROCHEMICAL DEPOSITION OF TIN–ZINC ALLOY FROM CITRATE–AMMONIA ELECTROLYTE 柠檬酸盐-氨电解质中锡锌合金的电化学沉积
Svitlana Hermanivna Deribo, S. Leshchenko, Valrii Pavlovych Gomozov, Yuliia Ivanivna Kovalenko
The cathodic processes of electrochemical deposition of a tin–zinc alloy in citrate–ammonia electrolytes have been investigated. The content of the main components of the investigated electrolyte (g/dm3): SnCl2·2H2O – 44, ZnO – 4, NH4Cl – 100, Na3C6H5O7 – 100. Wood glue (1.5 g/dm3) and neonol (4 ml/dm3) were added to the electrolyte as surfactants. It was found that high–quality coatings are deposited without heating and stirring only in the pH range from 6,0 to 7,0. The addition of these substances to the electrolyte is predicted to lead to inhibition of the reduction of metals, an improvement in the crystal structure of the deposit, but decreases the cathodic current efficiency. Hull cell studies showed that an electrolyte containing neonol as a surfactant showed better throwing power compared to other solutions. The dependence of the current efficiency of the alloy on the cathode current density showed that in the range of current densities from 0.5 A/dm2 to 4 A/dm2, the current efficiency decreases nonlinearly from 82 % to 52 %. The experimentally obtained dependence of the zinc content in the alloy on the cathodic current density showed the possibility of obtaining alloys with a zinc content of 8 % to 33 %. The obtained results allowed us to determine that for the deposition of an alloy with a zinc content of 20–25 %, which provides the best anti–corrosion properties of the coating, it is necessary to carry out the process at a cathodic current density of 1,5–2,0 A/dm2, while the current efficiency is about 70 %, and the deposition rate alloy is 0,44–0,54 μm/min. The received coatings have a semi–bright appearance, a fine–grained structure, light gray color, they are strongly adhered to the substrate.
研究了锡锌合金在柠檬酸盐-氨电解质中电化学沉积的阴极过程。电解液主要成分含量(g/dm3): SnCl2·2H2O - 44、ZnO - 4、NH4Cl - 100、Na3C6H5O7 - 100。电解液中加入木胶(1.5 g/dm3)和新醇(4 ml/dm3)作为表面活性剂。研究发现,只有在pH值为6,0 ~ 7,0的范围内,才能在不加热和搅拌的情况下沉积高质量的涂层。在电解液中加入这些物质预计会抑制金属的还原,改善镀层的晶体结构,但会降低阴极电流效率。赫尔电池研究表明,与其他溶液相比,含有新醇作为表面活性剂的电解质具有更好的投掷力。合金的电流效率与阴极电流密度的关系表明,在0.5 A/dm2到4 A/dm2的电流密度范围内,电流效率在82%到52%之间呈非线性下降。实验得到的合金锌含量与阴极电流密度的关系表明,可以得到锌含量为8% ~ 33%的合金。研究结果表明,为使镀层具有最佳的防腐性能,锌含量为20 ~ 25%的合金的沉积需要在阴极电流密度为1,5 ~ 2,0 a /dm2的条件下进行,而电流效率约为70%,沉积速率为0,44 ~ 0,54 μm/min。收到的涂层具有半光亮的外观,细颗粒结构,浅灰色,它们与基材有很强的附着力。
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引用次数: 0
PNEUMATIC FRACTURING PROBLEMS FOR HYDROCARBON FEEDSTOCK PRODUCTION INTENSIFICATION AT GAS CONDENSATE FIELDS IN UKRAINE 乌克兰凝析气田油气原料集约化生产中的气动压裂问题
I. Zezekalo, Hanna Anatoliyivna Dumenko
The current state of the oil and gas industry of Ukraine and the possibility of increasing the hydrocarbon base due to the introduction of fields with compacted reservoirs, which contain significant gas resources. Some methods of intensification of wells that are used in Ukraine, such as hydraulic fracturing and the GasGun method, are considered. Their main shortcomings are given: unforeseen situations of depressurization of the water horizon, use of large volumes of water, utilization of process water, incomplete release of rupture fluid from the reservoir, swelling and hydration of clay components of the reservoir, impossibility of use at extremely high temperatures and pressures. The world modern technologies based on the action of inert gases in hydrocarbon production are covered. Studies on the application of anhydrous rock breaks and intensification methods using inert gases are analyzed. The application of the method of pneumatic compaction of coal seams in Ukraine with the use of flue gases for the release of methane and degassing of coal mines is presented. Modern studies on the use of liquid nitrogen and liquefied carbon dioxide as fracturing agents with rocks with low filtration–capacity properties are presented. The main advantages of using nitrogen, liquefied and supercritical carbon dioxide as reservoir decompression agents are presented. It is proposed to study the method of pneumatic compaction on different samples of rocks in the laboratory using various agents and surfactants, select the appropriate reagents and develop technology for pneumatic rupture of hydrocarbon reservoirs as a cheap and environmentally friendly alternative to existing methods.
乌克兰石油和天然气工业的现状以及由于引入具有致密储层的油田而增加碳氢化合物基础的可能性,这些油田含有大量的天然气资源。考虑了乌克兰使用的一些井强化方法,如水力压裂和GasGun方法。它们的主要缺点是:不可预见的水层降压情况、大量水的使用、工艺用水的利用、破裂液从储层中释放不完全、储层粘土组分的膨胀和水化、在极高的温度和压力下不可能使用。介绍了以惰性气体在油气生产中的作用为基础的世界现代技术。分析了无水岩石裂隙的应用研究和惰性气体加固方法。介绍了在乌克兰利用烟道气对煤层进行气压压实的方法,以释放煤矿的甲烷和脱气。介绍了利用液氮和液化二氧化碳作为压裂剂对低过滤能力岩石进行压裂的现代研究。介绍了氮气、液化二氧化碳和超临界二氧化碳作为储层减压剂的主要优点。建议在实验室研究不同岩石样品的气压压实方法,使用不同的药剂和表面活性剂,选择合适的试剂,开发油气储层气压压实技术,作为现有方法的一种廉价、环保的替代方法。
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引用次数: 1
FEATURES OF THE STRUCTURE FORMATION OF SPODUMENS-CONTAINING GLASS-CRYSTAL MATERIALS AFTER HEAT TREATMENT 含锂辉石玻璃晶体材料热处理后的结构形成特征
O. Savvova, G. Voronov, Svіatoslav Rіabinin, A. Fesenko, Dmitry Svishov
The promising areas of application of spodumene–containing glass–crystalline materials in various branches of science and technology, in particular, to increase the defense capability of the state, have been determined. The relevance of the development of lightweight high–strength sitalls based on them, taking into account the aspects of energy saving for obtaining armored elements, has been determined. It has been established that the use of IR spectroscopy is promising for studying the nanostructure of glass–crystalline materials. The compositions of lithium aluminum silicate glasses and the modes of their heat treatment have been developed. The features of the structure formation of spodumene–containing glass–crystalline materials obtained under the conditions of two–stage low–temperature heat treatment have been investigated. Taking into account the analysis of the nature of the IR spectra of chain silicates, the structure of glass–crystalline materials was investigated according to the IR spectra and the nature of structure formation was established depending on the initial composition of the glass. It has been established that the formation of a structural glass network with the participation of tetrahedra [AlO4], [BO4] and [SiO4] and the presence of cybotaxic groups [Si2O6] allows, under conditions of two–stage low–temperature treatment, to provide bulk crystallization of spodumene–containing glass–crystalline materials. It has been established that the formation of the vitrified structure of glass–crystalline materials allows to ensure their high values of Vickers hardness, microhardness and crack resistance and by the presence of a glass phase, which plays the role of a damper, to ensure their high armor resistance. This will increase the efficiency and make it possible to use them as an energy–destructive and energy–absorbing layer in the composition of the armor element «metal alloy – ceramics – sitall». The introduction of spodumene–containing glass–crystalline materials will increase the competitiveness of competitive domestic armored elements for personal protection.
确定了含锂辉石玻璃晶体材料在各科学技术领域,特别是在提高国家国防能力方面的应用前景。在此基础上开发轻量化高强度sitalls的相关性已经确定,同时考虑到获得装甲元件的节能方面。红外光谱技术在研究玻璃晶体材料的纳米结构方面具有广阔的应用前景。研究了硅酸铝锂玻璃的组成及其热处理方式。研究了两段低温热处理条件下含锂辉石玻璃晶材料的结构形成特点。结合对链硅酸盐红外光谱性质的分析,根据红外光谱研究了玻璃晶体材料的结构,并根据玻璃的初始成分确定了结构形成的性质。研究发现,在四面体[AlO4]、[BO4]和[SiO4]的参与下,形成一个结构玻璃网络,并存在cybotaxic [Si2O6],可以在两段低温处理的条件下,提供含锂辉石玻璃晶体材料的大块结晶。已经确定,玻璃晶体材料的玻璃化结构的形成可以确保其高维氏硬度、显微硬度和抗裂性,并且通过玻璃相的存在,起到阻尼器的作用,确保其高抗装甲。这将提高效率,并有可能将它们用作装甲元件“金属合金-陶瓷-硅石”组成中的能量破坏和能量吸收层。引入含锂辉石玻璃晶体材料将提高国内竞争性装甲元件的竞争力,用于个人保护。
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引用次数: 0
APPLICATION OF MODERN BIOTECHNOLOGY METHODS TO IMPROVE SOIL FERTILITY 应用现代生物技术方法提高土壤肥力
M. Zinchenko, E. Ponomarenko, Kateryna Shumeiko
A person’s desire to improve the quality of life makes the individual reconsider the attitude towards the quality of consumed food. Despite the fact that the prices of natural products are several times higher than of those grown with the use of herbicides and pesticides, organic food is getting more popular in all countries around the world. Such products can only be received when crops are grown using organic farming methods, one of the principles of which is to increase the amount humus in the soil. The preservation of soil fertility can be ensured using the methods of modern biotechnology, which are based on the vital activity of microorganisms capable of converting organic matter from animal waste into environmentally friendly fertilizers. In animal husbandry, the main portion of agricultural waste is cattle and pig manure. The most economical way to dispose it is to use methane digestion, when biogas and fertilizers are obtained. However, when processing manure bedding materials in biogas reactors, the straw fractions and lignin–containing components of the bedding are not decomposed by bacteria and pass into the solid fraction of the fermented biomass unchanged, which is a problem. The infiltration of such an unprocessed residue into the soil leads to deterioration of soil properties. Thereby, the solid fraction of the fermented biomass requires additional processing to improve its agrochemical properties. Most expedient is to use vermicomposting, that is, process organic waste with the help of earthworms. Biohumus, or vermicompost, is one of the end products of this method. In this work, we studied the procedure of processing the solid fraction of fermented pig manure by Eisenia foetida compost worms (red Californian worm). In order to determine the optimal approach of vermicomposting, the experiment was planned. As a result, a high–quality organic fertilizer was obtained – biohumus –and the optimal parameters of the environment were determined(pH and humidity), at which the worms have the highest biological activity.
一个人对提高生活质量的渴望使他重新考虑对所消费食物质量的态度。尽管天然产品的价格比使用除草剂和杀虫剂种植的产品高出几倍,但有机食品在世界各国越来越受欢迎。这样的产品只有在作物采用有机耕作方法种植时才能收到,有机耕作方法的原则之一是增加土壤中的腐殖质。利用现代生物技术的方法可以确保土壤肥力的保持,这些方法是基于能够将动物粪便中的有机物转化为环境友好肥料的微生物的重要活动。在畜牧业中,农业废弃物的主要部分是牛粪和猪粪。最经济的处理方法是利用沼气消化,当沼气和肥料得到。然而,在沼气反应器中处理粪肥垫层材料时,垫层中的秸秆馏分和含木质素成分未被细菌分解,未改变地进入发酵生物质的固体馏分,这是一个问题。这种未经处理的残留物渗入土壤会导致土壤性质的恶化。因此,发酵生物质的固体部分需要额外的处理以改善其农用化学性质。最权宜之计是使用蚯蚓堆肥,即在蚯蚓的帮助下处理有机废物。生物腐殖质,或蚯蚓堆肥,是这种方法的最终产物之一。本研究以红加利福尼亚虫为原料,对发酵猪粪的固体部分进行了处理。为了确定蚯蚓堆肥的最佳方式,进行了试验设计。结果,获得了一种高质量的有机肥——生物腐殖质,并确定了最佳环境参数(pH和湿度),在此条件下蠕虫具有最高的生物活性。
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引用次数: 0
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Bulletin of the National Technical University "KhPI". Series: Chemistry, Chemical Technology and Ecology
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