B. Naveen, S. Sivamani, Azucena Cuento, S. Pachiyappan
Citrus fruits contain sufficient citric acid which is a main tricarboxylic acid. The properties of citric acid make it an important additive in various process industries. The aim of this experimental study is to produce citric acid from orange and grape juices. The chemical route for synthesis of citric acid from citrus juices involves three steps: (i) Neutralization to adjust pH (9-11) with 2.8 M NaOH solution, (ii) Addition of CaCl2 solution (40.3-41.1% (w/v)), and (iii) Acidification with H2SO4 solution (1.5-2.3 M) to produce citric acid. In this study, the fruits were peeled, crushed, filtered, neutralized, added CaCl2 solution and acidified to obtain citric acid. The experiments were carried out by varying final pH of solution, concentrations of CaCl2 and H2SO4 solutions maintaining volume constant. A maximum yield of citric acid at 91.1 and 79.8% from orange and grape fruits at optimum final pH of solution, concentrations of CaCl2 and H2SO4 solutions at 10, 40.7% (w/v) and 1.9 M respectively were achieved. Finally, the purified citric acid crystals were characterized using FTIR and XRD. Thus, it could be concluded that orange fruit would be a promising source for the production of citric acid than grape.
柑橘类水果含有充足的柠檬酸，柠檬酸是主要的三羧酸。柠檬酸的特性使其成为各种加工工业的重要添加剂。本实验研究的目的是从橙汁和葡萄汁中提取柠檬酸。柑桔汁合成柠檬酸的化学路线包括三个步骤:(i)用2.8 M NaOH溶液中和以调节pH (9-11)， (ii)加入CaCl2溶液(40.3-41.1% (w/v))， (iii)用H2SO4溶液(1.5-2.3 M)酸化生成柠檬酸。在本研究中，水果剥皮，粉碎，过滤，中和，加入CaCl2溶液，酸化得到柠檬酸。实验通过改变溶液的最终pH值，CaCl2和H2SO4溶液的浓度保持体积恒定来进行。在最终pH、CaCl2和H2SO4浓度分别为10、40.7% (w/v)和1.9 M的条件下，柑橘和葡萄柠檬酸产率最高，分别为91.1%和79.8%。最后，用FTIR和XRD对纯化后的柠檬酸晶体进行了表征。由此可见，与葡萄相比，柑橘是生产柠檬酸的理想原料。
{"title":"Chemical route for synthesis of citric acid from orange and grape juices","authors":"B. Naveen, S. Sivamani, Azucena Cuento, S. Pachiyappan","doi":"10.2298/ciceq200820025n","DOIUrl":"https://doi.org/10.2298/ciceq200820025n","url":null,"abstract":"Citrus fruits contain sufficient citric acid which is a main tricarboxylic acid. The properties of citric acid make it an important additive in various process industries. The aim of this experimental study is to produce citric acid from orange and grape juices. The chemical route for synthesis of citric acid from citrus juices involves three steps: (i) Neutralization to adjust pH (9-11) with 2.8 M NaOH solution, (ii) Addition of CaCl2 solution (40.3-41.1% (w/v)), and (iii) Acidification with H2SO4 solution (1.5-2.3 M) to produce citric acid. In this study, the fruits were peeled, crushed, filtered, neutralized, added CaCl2 solution and acidified to obtain citric acid. The experiments were carried out by varying final pH of solution, concentrations of CaCl2 and H2SO4 solutions maintaining volume constant. A maximum yield of citric acid at 91.1 and 79.8% from orange and grape fruits at optimum final pH of solution, concentrations of CaCl2 and H2SO4 solutions at 10, 40.7% (w/v) and 1.9 M respectively were achieved. Finally, the purified citric acid crystals were characterized using FTIR and XRD. Thus, it could be concluded that orange fruit would be a promising source for the production of citric acid than grape.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68461396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abulhassan Ali, K. Maqsood, A. Abdulrahman, A. Alsaadi, Abdullah Mahfouz Bin
High-performance polymeric membrane technology is rapidly developing worldwide with the introduction of new materials and processes. Considerable research efforts are being made to establish a polymer membrane that can be used for ultrafiltration (UF) or nanofiltration (NF) applications. The development of modified polyamide-66 polymer and its compatibility in wastewater are essential elements in the quest for advances and improvements in membrane technology. The optimized conditions for membrane synthesis are critical in making it commercially viable. Response Surface Methodology (RSM) was used to find the optimum dissolution of polyamide-66 in formic acid. A model was developed and validated with experimental data, and it showed good agreement with R2 0.9984. The optimized condition for minimizing viscosity was determined. For minimum viscosity (3.64cp), the optimum temperature and wt.% were 20?C and 0.6, respectively.
{"title":"Optimal dissolution and viscoelastic behavior of polyamide-66 in formic acid for membrane fabrication","authors":"Abulhassan Ali, K. Maqsood, A. Abdulrahman, A. Alsaadi, Abdullah Mahfouz Bin","doi":"10.2298/ciceq210320032a","DOIUrl":"https://doi.org/10.2298/ciceq210320032a","url":null,"abstract":"High-performance polymeric membrane technology is rapidly developing worldwide with the introduction of new materials and processes. Considerable research efforts are being made to establish a polymer membrane that can be used for ultrafiltration (UF) or nanofiltration (NF) applications. The development of modified polyamide-66 polymer and its compatibility in wastewater are essential elements in the quest for advances and improvements in membrane technology. The optimized conditions for membrane synthesis are critical in making it commercially viable. Response Surface Methodology (RSM) was used to find the optimum dissolution of polyamide-66 in formic acid. A model was developed and validated with experimental data, and it showed good agreement with R2 0.9984. The optimized condition for minimizing viscosity was determined. For minimum viscosity (3.64cp), the optimum temperature and wt.% were 20?C and 0.6, respectively.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68462128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This paper aims to analyze the thermal performance of four different heat transfer fluids in a hot oil system located in a paraffin hydrotreatment and fractionation plant of a petroleum refinery. The software Petro-SIM? (KBC- -Yokogawa) was employed to elaborate steady-state simulations intended to compare the heat transfer fluid currently used (eutectic of biphenyl and diphenyl oxide) and three fluids proposed as substitutes: paraffin oil (namely n-C13 +) produced in the same industrial unit, a nanofluid of eutectic of biphenyl and diphenyl oxide and copper at a 6% volume fraction, and a CuO/polydimethylsiloxane nanofluid at a 6% volume fraction. The results showed that n-C13 + was the only heat transfer fluid that could replace the eutectic diphenyl oxide/biphenyl in the system under analysis since it absorbed the heat duty of 13.79 Gcal/h, which exceeded the thermal energy of 10.57 Gcal/h absorbed by the heat transfer fluid currently used at the same operating parameters. The Cu/eutectic of biphenyl and diphenyl oxide and CuO/polydimethylsiloxane nanofluids presented lower heat duty than the energy needed for the operation of the hot oil system, which was 8.31 and 8.51 Gcal/h, respectively.
{"title":"Thermal performance evaluation of hot oils and nanofluids by simulation of an indirect heating plant","authors":"Li Da, S. Mattedi","doi":"10.2298/ciceq191011023o","DOIUrl":"https://doi.org/10.2298/ciceq191011023o","url":null,"abstract":"This paper aims to analyze the thermal performance of four different heat transfer fluids in a hot oil system located in a paraffin hydrotreatment and fractionation plant of a petroleum refinery. The software Petro-SIM? (KBC- -Yokogawa) was employed to elaborate steady-state simulations intended to compare the heat transfer fluid currently used (eutectic of biphenyl and diphenyl oxide) and three fluids proposed as substitutes: paraffin oil (namely n-C13 +) produced in the same industrial unit, a nanofluid of eutectic of biphenyl and diphenyl oxide and copper at a 6% volume fraction, and a CuO/polydimethylsiloxane nanofluid at a 6% volume fraction. The results showed that n-C13 + was the only heat transfer fluid that could replace the eutectic diphenyl oxide/biphenyl in the system under analysis since it absorbed the heat duty of 13.79 Gcal/h, which exceeded the thermal energy of 10.57 Gcal/h absorbed by the heat transfer fluid currently used at the same operating parameters. The Cu/eutectic of biphenyl and diphenyl oxide and CuO/polydimethylsiloxane nanofluids presented lower heat duty than the energy needed for the operation of the hot oil system, which was 8.31 and 8.51 Gcal/h, respectively.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68459820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Gudić, L. Vrsalović, A. Radeljić, E. O. Emeka, I. Ivanić, S. Kožuh, M. Gojić
A comparative corrosion study of Cu and Cu-Al, Cu-Al-Ni, Cu-Al-Mn, and Cu-Al-Mn-Ni in 0.5 mol dm-3 NaCl solution was performed using an open circuit potential, potentiodynamic polarization, and electrochemical impedance spectroscopy measurements (EIS). Scanning electron microscopy/Energy-dispersive X-ray spectroscopy (SEM/EDS) analysis was used to evaluate corrosive damage on the sample surface after polarization measurements. The reported results suggest that the alloying elements have reduced cathodic and anodic current densities in the Tafel region, increased anodic currents at higher anodic potentials, and slightly displaced corrosion potential towards more positive values. Overall, impedance increases in the following order: Cu < Cu-Al < Cu-Al-Ni < Cu-Al-Mn < Cu-Al-Mn-Ni. This indicates that Cu alloys possess better corrosion resistance. SEM and EDS analysis after polarization measurements showed uniform dissolution of pure Cu, as well as the presence of a surface oxide layer, consisting of a mixture of the corresponding alloying elements, on all investigated alloys. Aggressive anodic polarization severely damaged the barrier layers on the Cu alloy specimens.
利用开路电位、动电位极化和电化学阻抗谱测量(EIS)对Cu和Cu- al、Cu- al - ni、Cu- al - mn和Cu- al - mn - ni在0.5 mol dm-3 NaCl溶液中的腐蚀进行了比较研究。利用扫描电镜/能谱分析(SEM/EDS)对极化测量后样品表面的腐蚀损伤进行评价。结果表明，合金元素降低了Tafel区的阴极和阳极电流密度，在较高的阳极电位下增加了阳极电流，并使腐蚀电位向更正的方向偏移。总体而言，阻抗的增加顺序为:Cu < Cu- al < Cu- al - ni < Cu- al - mn < Cu- al - mn - ni。这说明Cu合金具有较好的耐蚀性。极化测量后的SEM和EDS分析表明，纯Cu均匀溶解，并且在所研究的合金上存在由相应合金元素混合物组成的表面氧化层。侵略性阳极极化严重破坏了Cu合金试样上的阻挡层。
{"title":"Comparison of corrosion behaviour of copper and copper alloys in aqueous chloride solution","authors":"S. Gudić, L. Vrsalović, A. Radeljić, E. O. Emeka, I. Ivanić, S. Kožuh, M. Gojić","doi":"10.2298/CICEQ200701007G","DOIUrl":"https://doi.org/10.2298/CICEQ200701007G","url":null,"abstract":"A comparative corrosion study of Cu and Cu-Al, Cu-Al-Ni, Cu-Al-Mn, and Cu-Al-Mn-Ni in 0.5 mol dm-3 NaCl solution was performed using an open circuit potential, potentiodynamic polarization, and electrochemical impedance spectroscopy measurements (EIS). Scanning electron microscopy/Energy-dispersive X-ray spectroscopy (SEM/EDS) analysis was used to evaluate corrosive damage on the sample surface after polarization measurements. The reported results suggest that the alloying elements have reduced cathodic and anodic current densities in the Tafel region, increased anodic currents at higher anodic potentials, and slightly displaced corrosion potential towards more positive values. Overall, impedance increases in the following order: Cu < Cu-Al < Cu-Al-Ni < Cu-Al-Mn < Cu-Al-Mn-Ni. This indicates that Cu alloys possess better corrosion resistance. SEM and EDS analysis after polarization measurements showed uniform dissolution of pure Cu, as well as the presence of a surface oxide layer, consisting of a mixture of the corresponding alloying elements, on all investigated alloys. Aggressive anodic polarization severely damaged the barrier layers on the Cu alloy specimens.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68461326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Grahovac, Ivana Pajčin, Vanja Vlajkov, Z. Rončević, J. Dodić, D. Cvetković, A. Jokić
Black rot, caused by Xanthomonas campestris pv. campestris, is one of the most important diseases of cruciferous crops which causes significant yield losses. Biological control of black rot by microbial biocontrol agents represents a promising alternative to chemical treatments and good agricultural practices which show only limited success. This study was carried out to assess a potential of different antagonists, including Bacillus, Pseudomonas, Lactobacillus, Streptomyces, Saccharomyces and Trichoderma genera, for biological control of black rot. Cultivation broth samples and their filtrates were examined against seven X. campestris strains, isolated from diseased cruciferous plants, using the diffusion-disc method. Bacillus velezensis has showed the highest inhibition zone diameter of 35.62?3.76 mm. Afterwards, different combinations of carbon and nitrogen sources were used in the cultivation medium to maximize antagonistic activity of B. velezensis. The best combinations were glycerol and yeast extract, lactose and peptone, as well as sucrose and yeast extract, suggesting the potential of biodiesel, dairy and sugar industry effluents in the production of bioactive compounds effective against the black rot pathogen. The validation experiment was performed in a laboratory-scale bioreactor, in order to investigate bioprocess kinetics of biomass growth and carbon source consumption, using the cultivation medium containing the optimal carbon and nitrogen source.
{"title":"Xanthomonas campestris biocontrol agent: Selection, medium formulation and bioprocess kinetic analysis","authors":"J. Grahovac, Ivana Pajčin, Vanja Vlajkov, Z. Rončević, J. Dodić, D. Cvetković, A. Jokić","doi":"10.2298/ciceq200508032g","DOIUrl":"https://doi.org/10.2298/ciceq200508032g","url":null,"abstract":"Black rot, caused by Xanthomonas campestris pv. campestris, is one of the most important diseases of cruciferous crops which causes significant yield losses. Biological control of black rot by microbial biocontrol agents represents a promising alternative to chemical treatments and good agricultural practices which show only limited success. This study was carried out to assess a potential of different antagonists, including Bacillus, Pseudomonas, Lactobacillus, Streptomyces, Saccharomyces and Trichoderma genera, for biological control of black rot. Cultivation broth samples and their filtrates were examined against seven X. campestris strains, isolated from diseased cruciferous plants, using the diffusion-disc method. Bacillus velezensis has showed the highest inhibition zone diameter of 35.62?3.76 mm. Afterwards, different combinations of carbon and nitrogen sources were used in the cultivation medium to maximize antagonistic activity of B. velezensis. The best combinations were glycerol and yeast extract, lactose and peptone, as well as sucrose and yeast extract, suggesting the potential of biodiesel, dairy and sugar industry effluents in the production of bioactive compounds effective against the black rot pathogen. The validation experiment was performed in a laboratory-scale bioreactor, in order to investigate bioprocess kinetics of biomass growth and carbon source consumption, using the cultivation medium containing the optimal carbon and nitrogen source.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68460535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The use of micro components is increasing day by day in the industries such as aviation, power circuit boards, inkjet nozzle and biomedical. Among various non-traditional micromachining methods, electrochemical micromachining (EMM) shows unique characteristics such as no tool wear, no residual stress and high accuracy. In this research EMM is considered to study the effect of square shaped stainless steel (SS) and aluminum metal matrix composite (AMC) tool on square hole generation. The significant process parameters such as machining voltage, duty cycle and aqueous sodium nitrate (NaNO3) electrolyte of varying concentration is considered for the study. The performances of EMM process are evaluated in terms of machining rate (MR) and Overcut (OC). The AMC tool shows 43.22 % lesser OC than the SS tool at the parameter combinations of 8V, 85% and 23 g/l. Also, for the same parameter combination MR for SS tool is 71.6 % higher than the AMC tool. Field emission scanning electron microscope image (FESEM) analysis shows that the micro square hole generated using composite electrode shows micro-pits on the circumference of the square hole. The energy dispersive X-ray spectroscopy (EDAX) analysis is conducted to verify presence and distributions of reinforcement in AMC tool.
{"title":"Performance study of electrochemical micromachining using square composite electrode for copper","authors":"T. Arul, Varatharaju Perumal, R. Thanigaivelan","doi":"10.2298/ciceq210501036a","DOIUrl":"https://doi.org/10.2298/ciceq210501036a","url":null,"abstract":"The use of micro components is increasing day by day in the industries such as aviation, power circuit boards, inkjet nozzle and biomedical. Among various non-traditional micromachining methods, electrochemical micromachining (EMM) shows unique characteristics such as no tool wear, no residual stress and high accuracy. In this research EMM is considered to study the effect of square shaped stainless steel (SS) and aluminum metal matrix composite (AMC) tool on square hole generation. The significant process parameters such as machining voltage, duty cycle and aqueous sodium nitrate (NaNO3) electrolyte of varying concentration is considered for the study. The performances of EMM process are evaluated in terms of machining rate (MR) and Overcut (OC). The AMC tool shows 43.22 % lesser OC than the SS tool at the parameter combinations of 8V, 85% and 23 g/l. Also, for the same parameter combination MR for SS tool is 71.6 % higher than the AMC tool. Field emission scanning electron microscope image (FESEM) analysis shows that the micro square hole generated using composite electrode shows micro-pits on the circumference of the square hole. The energy dispersive X-ray spectroscopy (EDAX) analysis is conducted to verify presence and distributions of reinforcement in AMC tool.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68462354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nahide Deniz Gulsah, C. Sayil, E. Öner, O. Atak, M. Stasevych
A series of disperse dyes, 9,10-anthraquinone containing dithiocarbamate, thiourea and triazole fragments, were prepared via consecutive refunctionalization of aminoanthraquinones in our previous studies and their structures were confirmed by the 1H, 13C NMR, IR spectra, LC-MS and elemental analysis data. The obtained compounds were applied on polyester fabrics by the exhaustion method at 130°C at pH 4.0-5.0, and their dyeing properties were evaluated by color measurements, the washing fastness test and the light fastness test. Many of these dyes gave solid and level dyeings on polyester fabric with low % concentration of dye. The dyed samples displayed very good color fastnesses. The color change and staining test results were quite good with ratings of “4-5” or above. The light fastness test results were also satisfactory for the most of the dyed samples.
{"title":"Dyeing of polyester fibers with sulfur- and nitrogen-containing anthraquinone derivatives","authors":"Nahide Deniz Gulsah, C. Sayil, E. Öner, O. Atak, M. Stasevych","doi":"10.2298/CICEQ210125015D","DOIUrl":"https://doi.org/10.2298/CICEQ210125015D","url":null,"abstract":"A series of disperse dyes, 9,10-anthraquinone containing dithiocarbamate, thiourea and triazole fragments, were prepared via consecutive refunctionalization of aminoanthraquinones in our previous studies and their structures were confirmed by the 1H, 13C NMR, IR spectra, LC-MS and elemental analysis data. The obtained compounds were applied on polyester fabrics by the exhaustion method at 130°C at pH 4.0-5.0, and their dyeing properties were evaluated by color measurements, the washing fastness test and the light fastness test. Many of these dyes gave solid and level dyeings on polyester fabric with low % concentration of dye. The dyed samples displayed very good color fastnesses. The color change and staining test results were quite good with ratings of “4-5” or above. The light fastness test results were also satisfactory for the most of the dyed samples.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80408897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Vučurović, Vesna Radovanović, J. Filipović, V. Filipović, M. Košutić, N. Novković, V. Radojević
Considerable interest in the consumption of bread from ancient spelt wheat with superior nutritional properties, easy digestibility and pleasant taste and aroma, has arisen recently. Yeast extract (YE) is nowadays frequently used as natural flavor enhancer for improving organoleptic properties such as meaty, cheesy and savory attributes of different food products. YE is a natural product from baker?s yeast industry with high nutritional richness containing amino acids, peptides, nucleotides, vitamins and minerals. In this work the effect of YE, table salt and white sugar content on fermentative activity of yeast and technological properties of spelt bread was investigated by response surface methodology (RSM) aiming to define the optimal conditions for obtaining a new functional product. The addition of YE, salt and white sugar slightly decreased yeast fermentative activity, while CO2 retention in dough was found to depend more on its chemical composition. YE addition (up to 5%) was found to increase volume and decrease firmness of bread prepared from dough with sugar content up to 5%, while the opposite effect was established in bread with higher sugar content. Maximal bread elasticity was obtained for YE content of 1.57%, table salt content of 2.01% and sugar content of 7.15%.
{"title":"Influence of yeast extract enrichment on fermentative activity of Saccharomyces cerevisiae and technological properties of spelt bread","authors":"V. Vučurović, Vesna Radovanović, J. Filipović, V. Filipović, M. Košutić, N. Novković, V. Radojević","doi":"10.2298/CICEQ200915016V","DOIUrl":"https://doi.org/10.2298/CICEQ200915016V","url":null,"abstract":"Considerable interest in the consumption of bread from ancient spelt wheat with superior nutritional properties, easy digestibility and pleasant taste and aroma, has arisen recently. Yeast extract (YE) is nowadays frequently used as natural flavor enhancer for improving organoleptic properties such as meaty, cheesy and savory attributes of different food products. YE is a natural product from baker?s yeast industry with high nutritional richness containing amino acids, peptides, nucleotides, vitamins and minerals. In this work the effect of YE, table salt and white sugar content on fermentative activity of yeast and technological properties of spelt bread was investigated by response surface methodology (RSM) aiming to define the optimal conditions for obtaining a new functional product. The addition of YE, salt and white sugar slightly decreased yeast fermentative activity, while CO2 retention in dough was found to depend more on its chemical composition. YE addition (up to 5%) was found to increase volume and decrease firmness of bread prepared from dough with sugar content up to 5%, while the opposite effect was established in bread with higher sugar content. Maximal bread elasticity was obtained for YE content of 1.57%, table salt content of 2.01% and sugar content of 7.15%.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78181111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The aim of this research was to evaluate the impact of most commonly used agents for tartaric stabilization of wine, such as metatartaric acid, carboxymethyl cellulose (CMC), mannoproteins and gum arabic, on the filterability of white, rose and red wine previously pre-filtered and prepared for the final filtration and bottling. Wine filterability after sweetening with rectified concentrated must was also assessed. The experiments were carried out using Quality Filterability Test and the obtained results were expressed through filterability index (FI), and maximum filterable volume (Vmax). The results confirmed that used enological agents for the inhibition of tartaric instabilities generally did not worsen the filterability of white and rose wine (FI<20). However, it was evident that products containing mannoproteins and metatartaric acid considerably reduced red wine filterability (FI>500). The correlation between white and rose wine turbidity and filterability was recorded in the trials but the same trend was not registered for the red wine. The results of this study are important since membrane (final) filtration of improperly prepared wine characterized by low filterability can both increase the costs and lead to hold up on the bottling line.
{"title":"The impact of enological products for tartaric stabilization on wine filterability","authors":"V. Puškaš, U. Miljić, V. Vučurović","doi":"10.2298/CICEQ200913003P","DOIUrl":"https://doi.org/10.2298/CICEQ200913003P","url":null,"abstract":"The aim of this research was to evaluate the impact of most commonly used agents for tartaric stabilization of wine, such as metatartaric acid, carboxymethyl cellulose (CMC), mannoproteins and gum arabic, on the filterability of white, rose and red wine previously pre-filtered and prepared for the final filtration and bottling. Wine filterability after sweetening with rectified concentrated must was also assessed. The experiments were carried out using Quality Filterability Test and the obtained results were expressed through filterability index (FI), and maximum filterable volume (Vmax). The results confirmed that used enological agents for the inhibition of tartaric instabilities generally did not worsen the filterability of white and rose wine (FI<20). However, it was evident that products containing mannoproteins and metatartaric acid considerably reduced red wine filterability (FI>500). The correlation between white and rose wine turbidity and filterability was recorded in the trials but the same trend was not registered for the red wine. The results of this study are important since membrane (final) filtration of improperly prepared wine characterized by low filterability can both increase the costs and lead to hold up on the bottling line.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68461377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Manikkampatty Murugesan Palanisamy, K. Kandasamy, Venkata Myneni Ratnam
The rapid growth of technology plays an inevitable role in humankind?s life and has a significant stint in the generation of e-waste. The electronic waste possess tremendous environmental and health effects and one such major contributor to it is printed circuit boards (PCBs). The present work deals with the recovery of heavy metals from PCBs by using aqua regia as leaching reagent by two stages (first stage HCl and HNO3 and second stage HCl and H2SO4). The studies carried by Response surface methodology (RSM) to determine the optimal conditions of recovery for the heavy metal ions showed that time 5 hrs, pulp density 25 gm L-1, and temperature 90.10C with desirability 0.761. These optimized values provide maximum recovery rate of Cu (97.06%), Sn (94.66%), Zn (96.64%) and Pb (96.89%) respectively. EDXs is used to analyze the metal concentrations of the sample before and after treatment.
科技的快速发展在人类生活中扮演着不可避免的角色。在电子垃圾的产生方面也有很大的限制。电子垃圾具有巨大的环境和健康影响，其中一个主要贡献者是印刷电路板(pcb)。以王水为浸出剂，分两阶段(第一阶段HCl和HNO3，第二阶段HCl和H2SO4)回收多氯联苯中的重金属。采用响应面法(RSM)确定重金属离子的最佳回收条件为:时间5 h，矿浆密度25 gm L-1，温度90.10℃，最佳回收率为0.761。优化后的回收率最高，Cu (97.06%)， Sn (94.66%)， Zn (96.64%)， Pb(96.89%)。edx用于分析处理前后样品的金属浓度。
{"title":"Two phase leaching for metal recovery from waste printed circuit boards: Statistical optimization","authors":"Manikkampatty Murugesan Palanisamy, K. Kandasamy, Venkata Myneni Ratnam","doi":"10.2298/CICEQ210115022M","DOIUrl":"https://doi.org/10.2298/CICEQ210115022M","url":null,"abstract":"The rapid growth of technology plays an inevitable role in humankind?s life and has a significant stint in the generation of e-waste. The electronic waste possess tremendous environmental and health effects and one such major contributor to it is printed circuit boards (PCBs). The present work deals with the recovery of heavy metals from PCBs by using aqua regia as leaching reagent by two stages (first stage HCl and HNO3 and second stage HCl and H2SO4). The studies carried by Response surface methodology (RSM) to determine the optimal conditions of recovery for the heavy metal ions showed that time 5 hrs, pulp density 25 gm L-1, and temperature 90.10C with desirability 0.761. These optimized values provide maximum recovery rate of Cu (97.06%), Sn (94.66%), Zn (96.64%) and Pb (96.89%) respectively. EDXs is used to analyze the metal concentrations of the sample before and after treatment.","PeriodicalId":9716,"journal":{"name":"Chemical Industry & Chemical Engineering Quarterly","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68461729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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