Pub Date : 2024-12-30DOI: 10.1016/j.chip.2024.100125
Peiding Liu , Xing Zhang , Bolei Zhang , Yong Wang , Wanbiao Hu , Feng Qiu
Highly optical-absorption hybrid perovskites with upgraded stability and superior photoelectronic properties are essential for optoelectronics. However, various defects are generated by the solution-based film quality inevitably produces during the crystallization process, which leads to non-radiative recombination and interface mismatch. In this work, polyvinylpyrrolidone (PVP) molecule layer was implemented as the interfacially multifunctional layer and selective transport layer to fabricate an effective photodetector. Interfacial PVP is conductive to the bond coordination between the PVP molecule and the MAPbI3 surface, which could lower the work function of the perovskite film and effectively improve its surface morphology so as to isolate it from water and oxygen molecules. The interfacial passivation for the undercoordinated Pb2+ defects was also verified via first-principles calculations. The electron injection barrier can be regulated via interfacial molecule engineering, leading to the result that the dark current is suppressed by five orders of magnitude to 1.57 × 10−11 A, and the specific detectivity improved by about three orders of magnitude reaching 2.9 × 1012 Jones. These results provide a feasible route to fabricate highly sensitive and stable hybrid perovskite photodetectors.
{"title":"Molecular engineering enables high-performance hybrid perovskite photodetector","authors":"Peiding Liu , Xing Zhang , Bolei Zhang , Yong Wang , Wanbiao Hu , Feng Qiu","doi":"10.1016/j.chip.2024.100125","DOIUrl":"10.1016/j.chip.2024.100125","url":null,"abstract":"<div><div>Highly optical-absorption hybrid perovskites with upgraded stability and superior photoelectronic properties are essential for optoelectronics. However, various defects are generated by the solution-based film quality inevitably produces during the crystallization process, which leads to non-radiative recombination and interface mismatch. In this work, polyvinylpyrrolidone (PVP) molecule layer was implemented as the interfacially multifunctional layer and selective transport layer to fabricate an effective photodetector. Interfacial PVP is conductive to the bond coordination between the PVP molecule and the MAPbI<sub>3</sub> surface, which could lower the work function of the perovskite film and effectively improve its surface morphology so as to isolate it from water and oxygen molecules. The interfacial passivation for the undercoordinated Pb<sup>2+</sup> defects was also verified via first-principles calculations. The electron injection barrier can be regulated via interfacial molecule engineering, leading to the result that the dark current is suppressed by five orders of magnitude to 1.57 × 10<sup>−11</sup> A, and the specific detectivity improved by about three orders of magnitude reaching 2.9 × 10<sup>12</sup> Jones. These results provide a feasible route to fabricate highly sensitive and stable hybrid perovskite photodetectors.</div></div>","PeriodicalId":100244,"journal":{"name":"Chip","volume":"4 1","pages":"Article 100125"},"PeriodicalIF":0.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143464591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-27DOI: 10.1016/j.chip.2024.100121
Yiqing Liu , Jinwen Lv , Ye Fan , Meixue Zong , Shubin Zhang , Zhengji Xu
Metasurface-enabled bound states in the continuum (BICs) provide a novel solution for achieving exceptionally high quality factors (Q factors), which could overcome the limitations of traditional mid-infrared filters, sensors, lasers, and nonlinear sources. However, most BIC metasurfaces are restricted by their sensitivity to specific incident angles, limiting their practical applications. Here, we introduced a germanium-based metasurface that supports two BIC modes for different polarizations, exhibiting robust angle insensitivity. By leveraging geometric asymmetry, we effectively controlled BIC leakage and coupling. The device maintained infinite Q factors under oblique incidence with preserved symmetry, and exhibited stable quasi-BIC resonance wavelengths and linewidths even with broken symmetry, regardless of TE or TM polarization. This angular robustness has been validated both theoretically and experimentally, demonstrating its potential for broadening the applicability of high-performance mid-infrared optical devices.
{"title":"Angle-insensitive dual bound states in the continuum on germanium metasurface","authors":"Yiqing Liu , Jinwen Lv , Ye Fan , Meixue Zong , Shubin Zhang , Zhengji Xu","doi":"10.1016/j.chip.2024.100121","DOIUrl":"10.1016/j.chip.2024.100121","url":null,"abstract":"<div><div>Metasurface-enabled bound states in the continuum (BICs) provide a novel solution for achieving exceptionally high quality factors (<em>Q</em> factors), which could overcome the limitations of traditional mid-infrared filters, sensors, lasers, and nonlinear sources. However, most BIC metasurfaces are restricted by their sensitivity to specific incident angles, limiting their practical applications. Here, we introduced a germanium-based metasurface that supports two BIC modes for different polarizations, exhibiting robust angle insensitivity. By leveraging geometric asymmetry, we effectively controlled BIC leakage and coupling. The device maintained infinite <em>Q</em> factors under oblique incidence with preserved symmetry, and exhibited stable quasi-BIC resonance wavelengths and linewidths even with broken symmetry, regardless of TE or TM polarization. This angular robustness has been validated both theoretically and experimentally, demonstrating its potential for broadening the applicability of high-performance mid-infrared optical devices.</div></div>","PeriodicalId":100244,"journal":{"name":"Chip","volume":"4 1","pages":"Article 100121"},"PeriodicalIF":0.0,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-27DOI: 10.1016/j.chip.2024.100122
Dongsheng Cui , Mengjiao Pei , Zhenhua Lin , Yifei Wang , Hong Zhang , Xiangxiang Gao , Haidong Yuan , Yun Li , Jincheng Zhang , Yue Hao , Jingjing Chang
The human brain possesses a highly developed capability for sensing-memory-computing, and the integration of hardware with brain-like functions represents a novel approach to overcoming the von Neumann bottleneck. In this study, Ga2O3 photoelectric memristors were successfully fabricated, enabling efficient visual information processing and complex recognition through the integration of optoelectronic synapses with digital storage. The memristors with a Pt/Ga2O3/Pt sandwich structure exhibit the coexistence of unipolar resistive switching (URS) and bipolar resistive switching (BRS), coupled with an impressive switching ratio and stable retention characteristics. The device demonstrates robust photo-responsive properties to ultraviolet (UV) light, which enables the realization of an array of 16 photoconductor types through the manipulation of four-timeframe pulse sequences. Exposure of the device to UV light elicits stable synaptic behaviors, including paired-pulse facilitation (PPF), short-term memory (STM), long-term memory (LTM), as well as learning-forgetting-relearning behavior. Moreover, the device exhibits outstanding image sensing, image memory, and neuromorphic visual pre-processing capabilities as a neuromorphic vision sensor (NVS). The integration of light pulse potentiation with electrical pulse depression yields a remarkable 100 conductances with superior linearity. This advanced functionality is further validated by the ability of the device to facilitate the recognition of 85.3% of handwritten digits by artificial neural networks (ANNs), which underscores the significant potential of artificial synapses in mimicking biological neural.
{"title":"Coexistence of unipolar and bipolar resistive switching in optical synaptic memristors and neuromorphic computing","authors":"Dongsheng Cui , Mengjiao Pei , Zhenhua Lin , Yifei Wang , Hong Zhang , Xiangxiang Gao , Haidong Yuan , Yun Li , Jincheng Zhang , Yue Hao , Jingjing Chang","doi":"10.1016/j.chip.2024.100122","DOIUrl":"10.1016/j.chip.2024.100122","url":null,"abstract":"<div><div>The human brain possesses a highly developed capability for sensing-memory-computing, and the integration of hardware with brain-like functions represents a novel approach to overcoming the von Neumann bottleneck. In this study, Ga<sub>2</sub>O<sub>3</sub> photoelectric memristors were successfully fabricated, enabling efficient visual information processing and complex recognition through the integration of optoelectronic synapses with digital storage. The memristors with a Pt/Ga<sub>2</sub>O<sub>3</sub>/Pt sandwich structure exhibit the coexistence of unipolar resistive switching (URS) and bipolar resistive switching (BRS), coupled with an impressive switching ratio and stable retention characteristics. The device demonstrates robust photo-responsive properties to ultraviolet (UV) light, which enables the realization of an array of 16 photoconductor types through the manipulation of four-timeframe pulse sequences. Exposure of the device to UV light elicits stable synaptic behaviors, including paired-pulse facilitation (PPF), short-term memory (STM), long-term memory (LTM), as well as learning-forgetting-relearning behavior. Moreover, the device exhibits outstanding image sensing, image memory, and neuromorphic visual pre-processing capabilities as a neuromorphic vision sensor (NVS). The integration of light pulse potentiation with electrical pulse depression yields a remarkable 100 conductances with superior linearity. This advanced functionality is further validated by the ability of the device to facilitate the recognition of 85.3% of handwritten digits by artificial neural networks (ANNs), which underscores the significant potential of artificial synapses in mimicking biological neural.</div></div>","PeriodicalId":100244,"journal":{"name":"Chip","volume":"4 1","pages":"Article 100122"},"PeriodicalIF":0.0,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143464590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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