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World Natural Gas (NG) Reserves, NG Production and Consumption Trends and Future Appearance 世界天然气储量、生产和消费趋势及未来展望
Pub Date : 2005-07-01 DOI: 10.1080/00908310490449027
M. Balat
Abstract Natural gas is the fastest growing primary energy source in the world. Because it is a cleaner fuel than oil or coal and not as controversial as nuclear power, gas is expected to be the fuel of choice for many countries in the future. Positive contribution of NG on environmental pollution must also be considered in economical aspects. NG is widely available. CO 2 emission of NG is lower than both diesel fuel and gasoline, which makes NG engines favorable also in terms of the greenhouse effect. The correlation equations for production and consumption trends of natural gas (VNG) versus year (Y) are:
天然气是世界上增长最快的一次能源。由于天然气是一种比石油或煤炭更清洁的燃料,而且不像核能那样有争议,因此预计天然气将成为许多国家未来的首选燃料。天然气对环境污染的积极贡献也必须在经济方面加以考虑。NG广泛可用。天然气的二氧化碳排放量比柴油和汽油都低,这使得天然气发动机在温室效应方面也很有利。天然气(VNG)生产和消费趋势与年(Y)的相关方程为:
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引用次数: 12
Pyrolysis of Waste Paper: Characterization and Composition of Pyrolysis Oil 废纸热解:热解油的表征与组成
Pub Date : 2005-07-01 DOI: 10.1080/00908310490450872
Lin Li, Hongxun Zhang, X. Zhuang
This article presents the results of an experimental study of waste paper pyrolysis in tubular furnace pyrolysis equipment. Pyrolysis of waste paper has been conducted in different pyrolysis temperatures and heating rates to investigate the product distribution and yields of pyrolysis products. The pyrolysis oil was characterized by elemental analysis and various chromatographic and spectroscopic techniques, which are HPLC, 1H NMR, FTIR, and UV. The results of spectroscopic and chromatographic analysis show that there are four main different compounds in bio-oil: anhydrosugars, carboxyl compounds, carbonyl compounds and aromatic compounds.
本文介绍了在管式炉热解装置上对废纸进行热解的实验研究结果。在不同的热解温度和升温速率下对废纸进行热解,考察热解产物的分布和产率。采用元素分析、HPLC、1H NMR、FTIR、UV等多种色谱和光谱技术对热解油进行了表征。光谱和色谱分析结果表明,生物油中主要有四种不同的化合物:无水糖、羧基化合物、羰基化合物和芳香族化合物。
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引用次数: 45
Effect of Heating Rate and Particle Size on the Pyrolysis of Göynük Oil Shale 升温速率和粒径对Göynük油页岩热解的影响
Pub Date : 2005-07-01 DOI: 10.1080/00908310490449531
L. Degirmenci, T. Durusoy
Pyrolysis kinetics of (−210 + 149), (−250 + 210) and (−420 + 250) μm particle size Göynük oil shale was investigated under non-isothermal conditions with a heating rate of 10–60 K/min in the 298–1173 K pyrolysis temperature interval under argon atmosphere. The pyrolysis characteristics of the samples were analyzed using TG/DTG curves. Differential thermogravimetric data were analyzed by a model assuming first order kinetics. Minimum activation energy was obtained as 0.6 kJ/mol with 60 K/min in (−210 + 149) μm. It appears from the results that higher heating rate values have a limiting effect on the behavior of the pyrolysis reaction.
研究了(−210 + 149)、(−250 + 210)和(−420 + 250)μm粒径Göynük油页岩在298 ~ 1173 K热解温度区间内升温速率为10 ~ 60 K/min的非等温条件下的热解动力学。采用TG/DTG曲线分析了样品的热解特性。采用一阶动力学模型对差热重数据进行了分析。最小活化能为0.6 kJ/mol,反应温度为60 K/min(−210 + 149)μm。结果表明,较高的升温速率值对热解反应的行为有限制作用。
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引用次数: 23
A Review of: “Van Nostrand's Encyclopedia of Chemistry, Fifth Edition” 评《范·诺斯特兰德化学百科全书第五版》
Pub Date : 2005-06-01 DOI: 10.1080/00908310590967247
J. Speight
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引用次数: 0
A Review of: “Surfactants and Interfacial Phenomena” “表面活性剂与界面现象”综述
Pub Date : 2005-06-01 DOI: 10.1080/00908310590967274
J. Speight
The book gives a detailed practical approach to improve the energy efficiency in petroleum processing and deals with the role of management and refinery operators in achieving the best technological parameters, the most rational utilization of energy, as well as the greatest possible economic success. The book contains chapters related to: Technological and Energy Characteristics of the Chemical Process Industry, Techno-Economic Aspects of Efficiency and Effectiveness of an Oil Refinery, Instruments for Determining Energy and Processing Efficiency of an Oil Refinery, Blending of Semi-Products into Finished Products and Determining Fished Product Cost Prices, and Management in the Function of Increasing Energy and Processing Efficiency and Effectiveness. This book provides an interesting and apparent introspective look at the efficiency of refineries and how this efficiency can be adapted to future needs. It provides interesting and thought-provoking reading.
这本书给出了一个详细的实际方法,以提高能源效率在石油加工和处理管理和炼油厂运营商的作用,在实现最佳的技术参数,最合理的利用能源,以及最大可能的经济成功。本书包含的章节涉及:化学加工工业的技术和能源特性,炼油厂效率和有效性的技术经济方面,确定炼油厂能源和加工效率的工具,将半成品混合成成品并确定渔产品成本价格,以及提高能源和加工效率和有效性的管理功能。这本书提供了一个有趣的和明显的内省看炼油厂的效率,以及如何这种效率可以适应未来的需求。它提供了有趣和发人深省的阅读。
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引用次数: 3
Clean Production of Hydrogen via Laser-Induced Methane Conversion 通过激光诱导甲烷转化清洁生产氢气
Pub Date : 2005-06-01 DOI: 10.1080/00908310490449351
Z. Yamani
A novel technique based on the multi-photon dissociation of methane for hydrogen production has been developed. The study was carried out with a simple setup using UV laser radiation at 355 nm wavelength. The hydrogen yield achieved at ambient temperature and one atmospheric pressure is 6.6 mole %. The conversion process of methane to produce hydrogen was investigated under different experimental parameters such as laser exposure time, laser power, and methane pressure. The quantum efficiency of these processes was also estimated. The maximum quantum efficiency of 42% was attained for 30 minutes of laser exposure of methane at 1 atmospheric pressure.
提出了一种基于甲烷多光子解离制氢的新技术。该研究是在一个简单的装置上进行的,使用波长为355nm的紫外激光辐射。在环境温度和一个大气压下的产氢率为6.6摩尔%。在激光曝光时间、激光功率和甲烷压力等不同实验参数下,研究了甲烷制氢过程。并对这些过程的量子效率进行了估计。在1个大气压下,激光照射甲烷30分钟,量子效率达到42%的最大值。
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引用次数: 4
A Review of: “Thermodynamic Properties of Complex Fluid Mixtures: Research Report” 《复杂流体混合物热力学性质研究报告》综述
Pub Date : 2005-06-01 DOI: 10.1080/00908310590967292
J. Speight
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引用次数: 0
A Study on Thermal Decomposition Kinetics of Some Turkish Coals 土耳其煤的热分解动力学研究
Pub Date : 2005-06-01 DOI: 10.1080/00908310490450944
M. Günes, S. Günes
The kinetic model that describes the weight loss of Turkish coals under pyrolysis conditions has been investigated. Nonisothermal thermogravimetric analysis data on 12 Turkish coals have been compared with the predictions of single first-order and distributed activation energy models. It was observed that the distributed activation energy model appears to provide a quantitatively satisfactory description of the devolatilization behavior of Turkish coals.
研究了土耳其煤在热解条件下失重的动力学模型。对12种土耳其煤的非等温热重分析数据与单一一阶和分布式活化能模型的预测结果进行了比较。据观察,分布式活化能模型似乎对土耳其煤的脱挥发行为提供了定量的令人满意的描述。
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引用次数: 17
A Simple Evaluation of SO2 and PM Data on Ambient Air Quality SO2和PM数据对环境空气质量的简单评价
Pub Date : 2005-06-01 DOI: 10.1080/00908310490450449
M. Günes
This study includes a simple and very general evaluation of sulphurdioxide (SO 2 ) and particulate matter (PM) data on the ambient air of the city centers in Turkey. Annual averages of SO 2 and PM data were studied between 1993–2002 during the winter season (October–March). It was observed that lignite, which is commonly used for heating in Turkey, is a significant component of SO 2 and PM formation. Variation of SO 2 and PM data in the city centers that consume natural gas was compared with the data of some city centers that do not consume natural gas. It was observed that SO 2 and PM averages of the city centers that started to consume natural gas have regularly diminished.
本研究包括对土耳其城市中心环境空气中二氧化硫(so2)和颗粒物(PM)数据进行简单而非常全面的评估。研究了1993-2002年冬季(10 - 3月)so2和PM的年平均值。据观察,在土耳其通常用于供暖的褐煤是so2和PM形成的重要组成部分。比较了使用天然气的城市中心与部分不使用天然气的城市中心so2和PM数据的变化情况。据观察,开始使用天然气的城市中心的so2和PM平均值有规律地下降。
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引用次数: 4
Investigating Uncertainties in Relative Permeability Measurements 研究相对渗透率测量中的不确定性
Pub Date : 2005-06-01 DOI: 10.1080/00908310490450638
F. Boukadi, A. Bemani, T. Babadagli
In this article, relative permeability measurement methods for water-oil systems mimicking displacement processes in porous media when reservoir pressure is supported by an active aquifer or a water injection scheme are compared. The measurement methods are compared within the context of reservoir wettability. It is suggested that for reservoirs with predominant water-wetness, unsteady-state experiments could be run under the suggested Peters and Khataniar (1987) stability criteria. Steady-state experiments could also be run for comparative and in turn quality control purposes. In addition, a combination of unsteady-, steady-state and centrifugal experiments could be adopted to generate trustful results for reservoirs with intermediate wettability, but only if one has a reliable initial relative permeability to oil (k ro ) at a representative initial water saturation (S wi ). As such, it is recommended to use an unsteady-state technique for the initiation of the displacement experiments, a steady-state method for mid-range saturations, and the centrifuge for tail-end saturations. It should be noted that for the centrifugal method, comparable centrifugal and viscous forces are required to mimic displacement processes. Coyne's procedure could also be used for comparative and quality control purposes.
本文比较了模拟多孔介质中储层压力由活动含水层支撑或注水方案支撑时驱替过程的水-油系统相对渗透率测量方法。在储层润湿性的背景下,比较了这些测量方法。建议对于以水湿为主的储层,可以根据建议的Peters和Khataniar(1987)稳定性标准进行非稳态实验。稳态实验也可以用于比较和反过来的质量控制目的。此外,对于具有中等润湿性的储层,可以采用非定常、稳态和离心实验相结合的方法得出可靠的结果,但前提是在具有代表性的初始含水饱和度(S wi)下具有可靠的初始相对渗透率(k ro)。因此,建议使用非稳态技术来启动位移实验,使用稳态方法进行中程饱和,使用离心机进行末端饱和。应该注意的是,对于离心法,需要相当的离心力和粘性力来模拟位移过程。Coyne的程序也可用于比较和质量控制目的。
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引用次数: 7
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Energy Sources
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