High-purity ternary titanium–niobium nitride nanoparticles were prepared by an induction thermal plasma. Metallic Ti and Nb powders served as raw materials. Molar fractions of Nb/(Ti+Nb) were set at various levels including 0, 0.25, 0.5, 0.75, and 1. Ammonia was introduced from the bottom into the plasma equipment as a quench gas. Nanoparticles crystallized in a cubic rock salt structure in the crystallographic space group Fm-3m. All nanoparticles exhibited similar morphology. The average particle size across all samples is approximately 10–14 nm. Elements Ti, Nb, and N are almost uniformly distributed in the nanoparticles. Investigations into the formation mechanism were conducted by examining nucleation temperature and thermodynamic analysis. Ternary titanium–niobium nitride nanoparticles form rapidly through nucleation, condensation, and coagulation with a nitridation reaction. Induction thermal plasma proves to be a highly efficient method for synthesizing ternary titanium–niobium nitride nanoparticles.
利用感应热等离子体制备了高纯度三元氮化钛铌纳米粒子。金属钛粉和铌粉为原材料。氨气作为淬火气体从底部进入等离子体设备。纳米粒子以立方岩盐结构结晶,晶体空间群为 Fm-3m。所有纳米颗粒的形态相似。所有样品的平均粒度约为 10-14 纳米。元素 Ti、Nb 和 N 几乎均匀地分布在纳米颗粒中。通过研究成核温度和热力学分析,对形成机制进行了研究。三元氮化钛铌纳米粒子通过成核、凝结和氮化反应凝结迅速形成。事实证明,感应热等离子体是合成三元氮化钛铌纳米粒子的高效方法。
{"title":"Synthesis of ternary titanium–niobium nitride nanoparticles by induction thermal plasma","authors":"Yirong Wang, Kaiwen Zhang, Motonori Hirose, Junya Matsuno, Manabu Tanaka, Takayuki Watanabe","doi":"10.35848/1347-4065/ad70be","DOIUrl":"https://doi.org/10.35848/1347-4065/ad70be","url":null,"abstract":"High-purity ternary titanium–niobium nitride nanoparticles were prepared by an induction thermal plasma. Metallic Ti and Nb powders served as raw materials. Molar fractions of Nb/(Ti+Nb) were set at various levels including 0, 0.25, 0.5, 0.75, and 1. Ammonia was introduced from the bottom into the plasma equipment as a quench gas. Nanoparticles crystallized in a cubic rock salt structure in the crystallographic space group <italic toggle=\"yes\">Fm</italic>-3<italic toggle=\"yes\">m</italic>. All nanoparticles exhibited similar morphology. The average particle size across all samples is approximately 10–14 nm. Elements Ti, Nb, and N are almost uniformly distributed in the nanoparticles. Investigations into the formation mechanism were conducted by examining nucleation temperature and thermodynamic analysis. Ternary titanium–niobium nitride nanoparticles form rapidly through nucleation, condensation, and coagulation with a nitridation reaction. Induction thermal plasma proves to be a highly efficient method for synthesizing ternary titanium–niobium nitride nanoparticles.","PeriodicalId":14741,"journal":{"name":"Japanese Journal of Applied Physics","volume":"423 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142218181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-04DOI: 10.35848/1347-4065/ad6d74
S. Aphayvong, K. Takaki, N. Fujimura, T. Yoshimura
The epitaxial growth of perovskite-type ferroelectric thin films on Si substrates is expected to be a method that dramatically improves the electrical properties, including the piezoelectricity. Here, we report the epitaxial growth of all films from the buffer layer to the ferroelectric layer in a single sputtering chamber. This achievement was driven by the use of the TiN buffer layer and the search for adhesion layers to improve the low adhesion between Pt and TiN. As a demonstration of the epitaxial growth of ferroelectric films, (100) BiFeO3 films were fabricated using the biaxial combinatorial method. The films exhibited a crystal structure and electrical properties different from epitaxial films grown on oxide single crystals and oriented films. Under optimized conditions, the films showed well-developed polarization electric-field properties and a transverse piezoelectric constant e