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Carbon nanotube thin film pn junction diode with high-temperature tolerance using chemical dopants 利用化学掺杂剂实现耐高温的碳纳米管薄膜 pn 结二极管
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-20 DOI: 10.35848/1347-4065/ad68e0
Yuki Matsunaga, Haruki Uchiyama, Haruka Omachi, Jun Hirotani
Chemical doping of carbon nanotubes (CNTs) by adsorption with high-temperature-tolerant molecules is required for the fabrication of various types of electronic devices for their performance maintenance under harsh thermal conditions during the fabrication and operation processes. Here, we demonstrate the fabrication of CNT thin film pn junction diodes using a combination of 1,4,5,8,9,11-hexaazatriphenylenehexacarbonitrile as a p-dopant and a complex salt of potassium hydroxide and benzo-18-crown-6 ether as an n-dopant. The fabricated devices demonstrated a reasonably stable rectifying behavior, even after heating to 200 °C for 300 min.
通过吸附耐高温分子对碳纳米管(CNTs)进行化学掺杂是制造各类电子器件所必需的,以便在制造和运行过程中的苛刻热条件下保持其性能。在此,我们展示了以 1,4,5,8,9,11-六氮杂三苯六腈作为 p 掺杂剂,以氢氧化钾和苯并-18-冠醚的复盐作为 n 掺杂剂,制备 CNT 薄膜 pn 结二极管的过程。即使在加热到 200 °C 300 分钟后,所制造的器件仍能表现出相当稳定的整流特性。
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引用次数: 0
Study on carbon allotrope abrasive particles based on C60 molecule for diamond chemical mechanical polishing 基于 C60 分子的碳同位素磨料颗粒在金刚石化学机械抛光中的应用研究
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-13 DOI: 10.35848/1347-4065/ad59e9
Junpei Takeiri, Keisuke Suzuki, Hiroaki Iura, Taisuke Hantani, Masaki Morii, Hideaki Nisizawa
In this study, we developed C60 reactive diamond composite particles for the chemical mechanical polishing (CMP) of diamond substrates by applying the high hardness and high reactivity of the C60 molecule. When diamond substrates were polished using these C60 diamond composite particles, the polished surface was found to be superior to that of diamond particles. In addition, when the composite particles were irradiated with ultraviolet light to produce polishing fine particles, the polishing rate was improved by about 30%. These results indicate that the composite nanoparticles that reacted with C60 have the potential to remove even the hardest of diamond substrates.
在这项研究中,我们利用 C60 分子的高硬度和高反应活性,开发了用于金刚石基底化学机械抛光(CMP)的 C60 反应金刚石复合颗粒。当使用这些 C60 金刚石复合颗粒抛光金刚石基底时,发现抛光表面优于金刚石颗粒。此外,当用紫外线照射复合颗粒以产生抛光细颗粒时,抛光率提高了约 30%。这些结果表明,与 C60 反应的复合纳米粒子具有去除最坚硬的金刚石基底的潜力。
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引用次数: 0
Investigation of the decomposition performances of Cu-EDTA using pulsed streamer discharge 利用脉冲流放电研究 Cu-EDTA 的分解性能
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-05 DOI: 10.35848/1347-4065/ad5921
Most Tauhida Tabassum, Yusuke Nakagawa and Fumiyoshi Tochikubo
The decomposition of Cu-Ethylenediaminetetraacetic Acid (Cu-EDTA) using a pulsed streamer discharge in contact with liquid is reported under various experimental conditions, and the efficacy of OH radicals is investigated. The change in Cu-EDTA concentration was characterized using high-performance liquid chromatography. H2O2, NO2−, NO3−, and O3 were detected using water inspection test kits and an UV-visual spectrophotometer. The OH yield was estimated using a colorimetric method with disodium terephthalate. The results revealed that approximately 70% of the Cu-EDTA decomposed with an energy efficiency of 15 mmol kWh−1 in the Ar discharge, whereas the decomposition rate and energy efficiency in the air discharge were 80% and 16 mmol kWh−1, respectively, within 60 min of treatment. The decomposition in Ar was primarily driven by the OH generated during discharge, whereas a combined effect of O3 and OH was observed during air discharge. The discharge-generated OH was the dominant species in Cu-EDTA decomposition in this study.
报告了在各种实验条件下使用脉冲流束放电与液体接触分解铜-乙二胺四乙酸(Cu-EDTA)的过程,并研究了 OH 自由基的功效。Cu-EDTA 浓度的变化采用高效液相色谱法进行表征。使用水检测试剂盒和紫外可见分光光度计检测 H2O2、NO2-、NO3- 和 O3。用对苯二甲酸二钠比色法估算羟基产率。结果显示,在氩气放电中,约 70% 的 Cu-EDTA 分解,能量效率为 15 mmol kWh-1;而在空气放电中,在处理 60 分钟内,分解率和能量效率分别为 80% 和 16 mmol kWh-1。在氩气中的分解主要是由放电过程中产生的 OH 驱动的,而在空气放电过程中则观察到 O3 和 OH 的共同作用。在本研究中,放电产生的 OH 是 Cu-EDTA 分解过程中的主要物质。
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引用次数: 0
A study of acoustic focusing based on the taboo genetic algorithm 基于禁忌遗传算法的声学聚焦研究
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-07-31 DOI: 10.35848/1347-4065/ad5b9f
Shulei Gong, Jinyu Zhao, Mengchun Yang, Zihao Liu, Yuan Liu, Yongchang Li
Acoustic metasurfaces have shown great promise for applications in many acoustic wave modulation fields, while the use of intelligent optimization algorithms has facilitated the design of acoustic metasurfaces. In this paper, we utilize the stop band properties of phononic crystals to design a metasurface that can achieve both transmission focusing and reflection focusing, as well as a metasurface that utilizes acoustic focusing to filter the incident acoustic wave. In order to achieve the best effect, this paper uses the taboo genetic algorithm to optimize the arrangement order of the structural units controlling different focuses in the acoustic metasurface, and the optimization achieves a good focusing effect, which expands the design of acoustic metasurfaces as well as the application scenarios of acoustic focusing.
声学元表面在许多声波调制领域都显示出巨大的应用前景,而智能优化算法的使用则促进了声学元表面的设计。在本文中,我们利用声子晶体的止带特性设计了一种既能实现透射聚焦又能实现反射聚焦的元表面,以及一种利用声聚焦过滤入射声波的元表面。为了达到最佳效果,本文利用禁忌遗传算法优化了声学元表面中控制不同聚焦的结构单元的排列顺序,优化后达到了良好的聚焦效果,拓展了声学元表面的设计以及声学聚焦的应用场景。
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引用次数: 0
Boosting quantum-structured solar cell light absorption through compressively strained superlattices 通过压缩应变超晶格提高量子结构太阳能电池的光吸收能力
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-07-24 DOI: 10.35848/1347-4065/ad5b32
Meita Asami, Kentaroh Watanabe, Yoshiaki Nakano and Masakazu Sugiyama
The escalating demand for improved energy conversion efficiency in vehicular applications of solar cells underscores the need for innovative solutions. This study focuses on enhancing the current density of GaAs middle cells within conventional Ge-based triple-junction solar cells to realize unprecedented levels of energy conversion efficiency. We introduced a novel superlattice configuration termed a compressively strained superlattice (CSSL) and demonstrated its integration into a p-i-n junction GaAs solar cell, achieving a current density increase of 1.03 mA cm−2 over conventional GaAs solar cells. Prior investigations have explored a strain-balanced superlattice (SBSL) to enhance GaAs middle cell current density. However, our findings establish the superiority of the CSSL over the SBSL in terms of current density improvement, with the CSSL featuring 1.59 times more quantum wells per unit length than the SBSL. This increase in quantum well quantity significantly enhances light absorption efficiency and consequently, the current density.
在太阳能电池的车载应用中,对提高能量转换效率的需求不断增长,这凸显了对创新解决方案的需求。本研究的重点是在传统的砷化镓三结太阳能电池中提高砷化镓中间电池的电流密度,以实现前所未有的能量转换效率。我们引入了一种称为压缩应变超晶格(CSSL)的新型超晶格配置,并展示了将其集成到 pi-n 结砷化镓太阳能电池中的效果,与传统砷化镓太阳能电池相比,电流密度提高了 1.03 mA cm-2。之前的研究探索了应变平衡超晶格(SBSL),以提高砷化镓中间电池的电流密度。然而,我们的研究结果表明,在提高电流密度方面,CSSL 优于 SBSL,CSSL 的单位长度量子阱数量是 SBSL 的 1.59 倍。量子阱数量的增加大大提高了光吸收效率,从而提高了电流密度。
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引用次数: 0
MOCVD growth of Si-doped α-(AlGa)2O3 on m-plane α-Al2O3 substrates 在 m 平面 α-Al2O3 衬底上以 MOCVD 生长掺杂硅的α-(AlGa)2O3
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-07-22 DOI: 10.35848/1347-4065/ad5cb2
Hironori Okumura and Joel B. Varley
We reported the growth of (AlGa)2O3 layers on (10 ) α-Al2O3 substrates using cold-wall metalorganic chemical vapor deposition, and the electrical characterization of Si-doped (AlGa)2O3 layers. In the Ga2O3 growth, the α phase was dominant at low growth temperature, achieving the growth rate of 2.4 μm h−1 at 650 °C. Sheet resistance and electrical conductivity of the Ga2O3 layers with a Si concentration of 3 × 1020 cm−3 were 1 × 104 Ω/square and 8.3 S cm−1, respectively, at the measurement temperature of 500 °C. The Al composition in the (AlGa)2O3 layers was controlled from 0% to 74%. In our initial attempts, we obtained electrically conductive α-(AlGa)2O3 layers by Si doping (2 × 10−9 S cm−1 in the sample with an Al composition of 56%). Hybrid functional calculations suggest the conductivities are limited by compensation of Si through cation vacancy complexes, and not by the significant amounts of co-incorporated C and N that are predicted to be electrically passivated by hydrogen.
我们报道了利用冷壁金属有机化学气相沉积技术在 (10 ) α-Al2O3 基底上生长 (AlGa)2O3 层的过程,以及掺杂硅的 (AlGa)2O3 层的电学特性。在 Ga2O3 生长过程中,α 相在低生长温度下占主导地位,650 ℃ 时的生长速率为 2.4 μm h-1。在测量温度为 500 ℃ 时,硅浓度为 3 × 1020 cm-3 的 Ga2O3 层的薄层电阻和导电率分别为 1 × 104 Ω/square 和 8.3 S cm-1。(AlGa)2O3 层中的铝成分控制在 0% 到 74% 之间。在最初的尝试中,我们通过掺杂硅获得了导电的 α-(AlGa)2O3层(在铝成分为 56% 的样品中为 2 × 10-9 S cm-1)。混合函数计算表明,导电性受限于通过阳离子空位复合物对硅的补偿,而不是受限于预计会被氢钝化的大量共掺杂 C 和 N。
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引用次数: 0
Germanium nanostructures by helium plasma irradiation 通过氦等离子体辐照制造锗纳米结构
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-07-22 DOI: 10.35848/1347-4065/ad5afe
Shin Kajita, Quan Shi, Kiho Tabata, Tatsuya Kuwabara, Hirohiko Tanaka and Noriyasu Ohno
The effects of helium plasma irradiation, which has been widely studied on metals, on germanium have been experimentally investigated. The irradiation temperature ranges from 430 to 720 K, and the incident ion energy ranges from 30 to 100 eV. From the scanning electron microscope (SEM) observation, it was found that various morphological changes including pits, nanocones, nanopillars, and roughened surfaces occur. The spatial scale of the morphological change was analyzed by applying fast Fourier transform to SEM micrographs. Thermal desorption spectroscopy analysis suggests that He atoms implanted on Ge play major roles in forming roughened surfaces at a surface temperature higher than 500 K.
实验研究了氦等离子体辐照对锗的影响,氦等离子体辐照对金属的影响已被广泛研究。辐照温度范围为 430 至 720 K,入射离子能量范围为 30 至 100 eV。通过扫描电子显微镜(SEM)观察发现,锗上出现了各种形态变化,包括凹坑、纳米锥、纳米柱和粗糙表面。通过对扫描电子显微镜显微照片进行快速傅立叶变换,分析了形态变化的空间尺度。热解吸光谱分析表明,在表面温度高于 500 K 时,植入 Ge 的 He 原子在形成粗糙表面的过程中发挥了主要作用。
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引用次数: 0
Large-scale fabrication of thulium iron garnet film with perpendicular magnetic anisotropy using RF magnetron sputtering 利用射频磁控溅射大规模制造具有垂直磁各向异性的铥铁石榴石薄膜
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-07-22 DOI: 10.35848/1347-4065/ad5aff
Marlis N. Agusutrisno, Sora Obinata, Takamasa Okumura, Kunihiro Kamataki, Naho Itagaki, Kazunori Koga, Masaharu Shiratani and Naoto Yamashita
Large-scale fabrication of thulium iron garnet (TmIG) films on gadolinium gallium garnet (GGG) substrates, with a total area of 25 cm2, has been demonstrated by rotating substrate holders during on-axis sputtering. By optimizing the growth parameters based on the pressure and flow rate of the oxygen ratio, a Tm/Fe ratio of 0.65 was obtained, which is close to the stoichiometry of TmIG. The increase in post-annealing temperature has induced the growth of the TmIG structure by the strain of the lattice constant mechanism. At the highest post-annealing temperature, the crystal structure of TmIG (444) and the perpendicular magnetic anisotropy (PMA) were obtained. This result demonstrates the potential method for large-scale fabrication of TmIG film with PMA.
在钆镓石榴石(GGG)衬底上大规模制备铥铁石榴石(TmIG)薄膜(总面积为 25 平方厘米),是在同轴溅射过程中通过旋转衬底支架实现的。通过优化基于氧比压力和流速的生长参数,获得了 0.65 的 Tm/Fe 比值,接近 TmIG 的化学计量学。 提高退火后温度通过晶格常数机制的应变诱导了 TmIG 结构的生长。在最高的后退火温度下,得到了 TmIG 的晶体结构(444)和垂直磁各向异性(PMA)。这一结果证明了大规模制造具有 PMA 的 TmIG 薄膜的潜在方法。
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引用次数: 0
Noise mechanism clarification in external-modulation Brillouin optical correlation-domain reflectometry with double-sideband modulator 使用双侧带调制器的外部调制布里渊光相关域反射测量中的噪声机制分析
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-07-15 DOI: 10.35848/1347-4065/ad5f6c
Kouta Ozaki, Keita Kikuchi, Guangtao Zhu, Kohei Noda, Yuguo Yao, Yuangang Lu, Rajan Jha, Heeyoung Lee and Yosuke Mizuno
Brillouin optical correlation-domain reflectometry (BOCDR) allows for relatively high spatial resolution and random accessibility with single-end light injection into the sensing fiber. Typically, BOCDR relies on directly modulating the laser diode’s driving current, which facilitates sinusoidal frequency modulation for distributed sensing but also introduces unintended power modulation that can degrade performance. To address these power variations, external-modulation BOCDR using a double-sideband modulator has been developed. However, this method generates substantial noise, overpowering the Brillouin signal and impeding accurate strain and temperature measurements. This study clarifies the previously unexplained noise mechanisms and suggests system design optimizations to mitigate their impact.
布里渊光相关域反射仪(BOCDR)可实现相对较高的空间分辨率,并通过将单端光注入传感光纤实现随机接入。通常情况下,布里渊光相关域反射仪依靠直接调制激光二极管的驱动电流,这有利于分布式传感的正弦频率调制,但也会引入意外的功率调制,从而降低性能。为了解决这些功率变化问题,人们开发了使用双侧带调制器的外部调制 BOCDR。然而,这种方法会产生大量噪声,使布里渊信号过强,妨碍应变和温度的精确测量。本研究澄清了以前无法解释的噪声机制,并提出了系统设计优化建议,以减轻其影响。
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引用次数: 0
An experimental feasibility study of a 4π gamma-ray imager using detector response patterns 利用探测器响应模式对 4π 伽马射线成像仪进行实验可行性研究
IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-07-15 DOI: 10.35848/1347-4065/ad5ba0
Yoshiharu Kitayama, Mitsuhiro Nogami and Keitaro Hitomi
We constructed a gamma-ray imager that estimates the distribution of gamma-ray sources based on the response patterns of multiple gamma-ray detectors randomly positioned in three-dimensional space. The Coded Cube Camera for Gamma-ray (C3G), comprising eight Gd3Al2Ga3O12 (Ce) scintillator and eighteen lead cubes is housed in a cubical casing with an 86 mm edge length and weighs approximately 600 g. The results of the 4π imaging experiment confirmed the feasibility of imaging a 10 MBq 137Cs source 3 m away for a 10 min measurement. C3G operates with only eight channels, instead of the hundreds needed by a typical imager. This setup allows for a simplified circuit and reconstruction algorithm, resulting in a cost-effective and reliable system. With its compact and lightweight design and 4π field of view, this technology is expected to find extensive applications in astronomy, medicine, nuclear security, and decommissioning projects.
我们建造了一个伽马射线成像仪,它可以根据随机放置在三维空间中的多个伽马射线探测器的响应模式来估计伽马射线源的分布。伽马射线编码立方体照相机(C3G)由八个Gd3Al2Ga3O12(Ce)闪烁体和十八个铅立方体组成,安装在一个边长为86毫米的立方体外壳中,重约600克。4π成像实验的结果证实了对3米外的10 MBq 137Cs源进行10分钟成像测量的可行性。C3G 仅使用 8 个通道,而非典型成像仪所需的数百个通道。这种设置简化了电路和重构算法,使系统既经济又可靠。该技术设计小巧轻便,视场为 4π,有望在天文学、医学、核安全和退役项目中得到广泛应用。
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引用次数: 0
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Japanese Journal of Applied Physics
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