Pub Date : 2023-01-02DOI: 10.1080/21870764.2022.2156668
P. Wannasut, P. Jaiban, P. Jaita, M. Promsawat, O. Khamman, A. Watcharapasorn
ABSTRACT New lead-free (1-y)[0.995Bi0.5(Na0.80K0.20)0.5TiO3-0.005LiNbO3]-y[(Ba0.7Sr0.3)TiO3] or (1-y)[0.995BNKT-0.005LN]-y[BST] (where y = 0, 0.01, 0.02, 0.03, 0.04 and 0.05 mol fraction) ceramics were fabricated by a conventional sintering method with two calcination steps. All ceramics sintered at 1125°C for 2 hours showed an optimum relative density of ~98% and a linear shrinkage of ~18%. X-ray diffraction patterns indicated that all ceramics possessed a pure perovskite phase with coexisting rhombohedral and tetragonal structures. Electrical and energy harvesting properties of 0.995BNKT–0.005LN ceramics were improved with 0.03 mol fraction BST addition (d 33 = 287 pC/N, d*33 = 440 pm/V, g33 = 13.40 × 10−3 V/mN and FoM = 3.85 pm2/N). From the observed results, the 0.97[0.995BNKT-0.005LN]-0.03[BST] ceramic is a promising candidate for lead-free piezoelelectric sensor-actuator and energy harvester.
{"title":"Improvement of electrical and energy harvesting properties of new lead-free BST modified 0.995BNKT–0.005LN ceramics","authors":"P. Wannasut, P. Jaiban, P. Jaita, M. Promsawat, O. Khamman, A. Watcharapasorn","doi":"10.1080/21870764.2022.2156668","DOIUrl":"https://doi.org/10.1080/21870764.2022.2156668","url":null,"abstract":"ABSTRACT New lead-free (1-y)[0.995Bi0.5(Na0.80K0.20)0.5TiO3-0.005LiNbO3]-y[(Ba0.7Sr0.3)TiO3] or (1-y)[0.995BNKT-0.005LN]-y[BST] (where y = 0, 0.01, 0.02, 0.03, 0.04 and 0.05 mol fraction) ceramics were fabricated by a conventional sintering method with two calcination steps. All ceramics sintered at 1125°C for 2 hours showed an optimum relative density of ~98% and a linear shrinkage of ~18%. X-ray diffraction patterns indicated that all ceramics possessed a pure perovskite phase with coexisting rhombohedral and tetragonal structures. Electrical and energy harvesting properties of 0.995BNKT–0.005LN ceramics were improved with 0.03 mol fraction BST addition (d 33 = 287 pC/N, d*33 = 440 pm/V, g33 = 13.40 × 10−3 V/mN and FoM = 3.85 pm2/N). From the observed results, the 0.97[0.995BNKT-0.005LN]-0.03[BST] ceramic is a promising candidate for lead-free piezoelelectric sensor-actuator and energy harvester.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45197129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2022.2161153
Ho-Yong Shin, Ho-Yong Lee, Il-Gok Hong, Jong-Ho Kim, J. Im
ABSTRACT The piezoelectric properties of a piezoelectric single crystal are typically determined using a resonance method. However, it is challenging to evaluate these properties in single crystals owing to their high sensitivity and property variations. In this study, to accurately determine the piezoelectric properties, initial values were obtained using two types of samples (TE and TS modes). Impedance spectrum tendency analysis was performed according to the variables to develop a property estimation method. To determine the reliability of this method, the piezoelectric single crystal properties were evaluated and compared using the resonance method. Hence, it was confirmed that high-accuracy piezoelectric properties were obtained in a cost effective and timeous manner.
{"title":"Piezoelectric property optimization for piezoelectric single crystals using parametric estimation","authors":"Ho-Yong Shin, Ho-Yong Lee, Il-Gok Hong, Jong-Ho Kim, J. Im","doi":"10.1080/21870764.2022.2161153","DOIUrl":"https://doi.org/10.1080/21870764.2022.2161153","url":null,"abstract":"ABSTRACT The piezoelectric properties of a piezoelectric single crystal are typically determined using a resonance method. However, it is challenging to evaluate these properties in single crystals owing to their high sensitivity and property variations. In this study, to accurately determine the piezoelectric properties, initial values were obtained using two types of samples (TE and TS modes). Impedance spectrum tendency analysis was performed according to the variables to develop a property estimation method. To determine the reliability of this method, the piezoelectric single crystal properties were evaluated and compared using the resonance method. Hence, it was confirmed that high-accuracy piezoelectric properties were obtained in a cost effective and timeous manner.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48207274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2023.2166655
Xiong Huang, Lei Zhang, Pengfei Wang, Gang Jian, Jun Yang, Bo Li, Shuhui Yu, Rong Sun, Zhen-Guo Fu, Xiuhua Cao
ABSTRACT High-temperature stability and reliability are in high demand for ultra-thin multilayer ceramic capacitors (MLCCs), which are ubiquitous in electronic industries. Here, two doping matrices of BaTiO3 (BT) and Ba0.97Ca0.03TiO3 (BCT) are chosen to prepare ultra-thin MLCCs, whose effects on the microstructure, nonlinear dielectric properties, temperature stability, and reliability of the capacitors were investigated. Compared with BT-based MLCCs, BCT-based MLCCs possess better core-shell structures, thus, leading to a higher Schottky barrier for inhibiting carrier migration and improving aging performance. For the 1.5 μm-thickness capacitors using the BCT doping matrix rather than BT, the temperature coefficient of capacitance reaches the X7R standard, and the breakdown field increases from 148 to 172 V/μm. Moreover, the ability to resist insulation resistance degradation has been significantly improved. This work demonstrates the great potential of using BCT as the doping matrix to prepare ultra-thin MLCCs with excellent temperature stability and reliability.
{"title":"Excellent permittivity-temperature stability and reliability performance of ultra-thin Ba0.97Ca0.03TiO3-based MLCCs","authors":"Xiong Huang, Lei Zhang, Pengfei Wang, Gang Jian, Jun Yang, Bo Li, Shuhui Yu, Rong Sun, Zhen-Guo Fu, Xiuhua Cao","doi":"10.1080/21870764.2023.2166655","DOIUrl":"https://doi.org/10.1080/21870764.2023.2166655","url":null,"abstract":"ABSTRACT High-temperature stability and reliability are in high demand for ultra-thin multilayer ceramic capacitors (MLCCs), which are ubiquitous in electronic industries. Here, two doping matrices of BaTiO3 (BT) and Ba0.97Ca0.03TiO3 (BCT) are chosen to prepare ultra-thin MLCCs, whose effects on the microstructure, nonlinear dielectric properties, temperature stability, and reliability of the capacitors were investigated. Compared with BT-based MLCCs, BCT-based MLCCs possess better core-shell structures, thus, leading to a higher Schottky barrier for inhibiting carrier migration and improving aging performance. For the 1.5 μm-thickness capacitors using the BCT doping matrix rather than BT, the temperature coefficient of capacitance reaches the X7R standard, and the breakdown field increases from 148 to 172 V/μm. Moreover, the ability to resist insulation resistance degradation has been significantly improved. This work demonstrates the great potential of using BCT as the doping matrix to prepare ultra-thin MLCCs with excellent temperature stability and reliability.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48994646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2023.2173851
Muh. Sadat Hamzah, M. W. Wildan, Kusmono, E. Suharyadi
ABSTRACT This study aims to determine the effect of the sintering temperature of nanosilica on physical, mechanical, dielectric, and output voltage properties. The nanosilica particles used in this experiment were produced using the alkaline fusion method from natural sand. The green bodies were uniaxially formed with a pressure of 75 MPa and then were pressureless sintered at various temperatures of 1330, 1360, 1390, 1420, and 1450°C for 2 hours in an air atmosphere. The results of sintering showed that the highest bulk density and the relative density of 2.49 ± 0.03 g/cm3 and 94.03 ± 0.01% respectively were achieved at a sintering temperature of 1390°C. The XRD patterns of the sintered silica indicated phases of quartz, tridymite, and cristobalite, with the strongest peak corresponding to the cristobalite phase. The highest compressive strength and diametral tensile strength values of 17.23 ± 0.27 MPa and 6.06 ± 0.71 MPa respectively were obtained on specimens sintered at 1390°C. However, the highest values of the dielectric constant of 544.28, dielectric loss of 195.94, and output voltage of 1.58 mV were obtained at a sintering temperature of 1330°C. Various sintering temperatures do not significantly influence the characteristic of dielectric and output voltage of the sintered specimens.
{"title":"Effect of sintering temperature on physical, mechanical, and electrical properties of nano silica particles synthesized from Indonesia local sand for piezoelectric application","authors":"Muh. Sadat Hamzah, M. W. Wildan, Kusmono, E. Suharyadi","doi":"10.1080/21870764.2023.2173851","DOIUrl":"https://doi.org/10.1080/21870764.2023.2173851","url":null,"abstract":"ABSTRACT This study aims to determine the effect of the sintering temperature of nanosilica on physical, mechanical, dielectric, and output voltage properties. The nanosilica particles used in this experiment were produced using the alkaline fusion method from natural sand. The green bodies were uniaxially formed with a pressure of 75 MPa and then were pressureless sintered at various temperatures of 1330, 1360, 1390, 1420, and 1450°C for 2 hours in an air atmosphere. The results of sintering showed that the highest bulk density and the relative density of 2.49 ± 0.03 g/cm3 and 94.03 ± 0.01% respectively were achieved at a sintering temperature of 1390°C. The XRD patterns of the sintered silica indicated phases of quartz, tridymite, and cristobalite, with the strongest peak corresponding to the cristobalite phase. The highest compressive strength and diametral tensile strength values of 17.23 ± 0.27 MPa and 6.06 ± 0.71 MPa respectively were obtained on specimens sintered at 1390°C. However, the highest values of the dielectric constant of 544.28, dielectric loss of 195.94, and output voltage of 1.58 mV were obtained at a sintering temperature of 1330°C. Various sintering temperatures do not significantly influence the characteristic of dielectric and output voltage of the sintered specimens.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46942441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2023.2173849
Keito Makise, T. Takei, N. Saito, Junichi Yamanaka, N. Kumada, Hiroyoshi Mori, Nobuki Itoi, Toshiki Goto
ABSTRACT A lepidocrocite-like potassium titanate, (Kx(LixTi1-x)O2; Lss) with a layered structure can provide a reactive interlayer space for soft-chemical reaction such as ion-exchange or intercalation and the hydrated sodium derivative (Lss-Na) was obtained by an ion-exchange reaction. The crystal structures of the hydrated and dehydrated Lss-Na were refined by using synchrotron powder X-ray diffraction data. Two steps of dehydrated processes for the Lss-Na were observed by in-situ synchrotron powder X-ray diffraction. The ion-exchange property for Lss-Na was superior to those for Lss and Lss-H and was corelated with the effective basal space which was expanded by formation of two layers of water molecules.
{"title":"Crystal structure and ion-exchange property of a lepidocrocite-like sodium titanate","authors":"Keito Makise, T. Takei, N. Saito, Junichi Yamanaka, N. Kumada, Hiroyoshi Mori, Nobuki Itoi, Toshiki Goto","doi":"10.1080/21870764.2023.2173849","DOIUrl":"https://doi.org/10.1080/21870764.2023.2173849","url":null,"abstract":"ABSTRACT A lepidocrocite-like potassium titanate, (Kx(LixTi1-x)O2; Lss) with a layered structure can provide a reactive interlayer space for soft-chemical reaction such as ion-exchange or intercalation and the hydrated sodium derivative (Lss-Na) was obtained by an ion-exchange reaction. The crystal structures of the hydrated and dehydrated Lss-Na were refined by using synchrotron powder X-ray diffraction data. Two steps of dehydrated processes for the Lss-Na were observed by in-situ synchrotron powder X-ray diffraction. The ion-exchange property for Lss-Na was superior to those for Lss and Lss-H and was corelated with the effective basal space which was expanded by formation of two layers of water molecules.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47195146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2022.2159928
Il-Gok Hong, Ho-Yong Shin, Jong-Ho Kim, U. Paik, J. Im
ABSTRACT Porous piezoelectric materials have been widely used in hydrophone applications owing to their excellent hydrostatic charge constant (dh) and voltage constant (gh). However, owing to the difficulty in sample manufacturing, the evaluation of the overall piezoelectric properties for reliable device design using simulations is challenging. Herein, a two-step simulation was performed to accurately determine the overall properties of the porous PZT. First, the piezoelectric charge constant was calculated by displacement calculations using the electrostrictive effect. Second, using the calculated piezoelectric charge constant and impedance spectrum obtained from the experiment, the initial value for optimizing the properties was selected, and the overall properties were obtained using the parametric estimation technique. These parametric estimation simulation procedures were performed with the samples of radial and thickness modes based on the IEEE standards. Finally, the piezoelectric properties obtained were compared and verified with the experimental values. Therefore, the overall piezoelectric properties include mechanical, frequency and dielectric properties according to the porosity were obtained with reliable results.
{"title":"Two-step simulation of piezoelectric properties of porous PZT according to porosity","authors":"Il-Gok Hong, Ho-Yong Shin, Jong-Ho Kim, U. Paik, J. Im","doi":"10.1080/21870764.2022.2159928","DOIUrl":"https://doi.org/10.1080/21870764.2022.2159928","url":null,"abstract":"ABSTRACT Porous piezoelectric materials have been widely used in hydrophone applications owing to their excellent hydrostatic charge constant (dh) and voltage constant (gh). However, owing to the difficulty in sample manufacturing, the evaluation of the overall piezoelectric properties for reliable device design using simulations is challenging. Herein, a two-step simulation was performed to accurately determine the overall properties of the porous PZT. First, the piezoelectric charge constant was calculated by displacement calculations using the electrostrictive effect. Second, using the calculated piezoelectric charge constant and impedance spectrum obtained from the experiment, the initial value for optimizing the properties was selected, and the overall properties were obtained using the parametric estimation technique. These parametric estimation simulation procedures were performed with the samples of radial and thickness modes based on the IEEE standards. Finally, the piezoelectric properties obtained were compared and verified with the experimental values. Therefore, the overall piezoelectric properties include mechanical, frequency and dielectric properties according to the porosity were obtained with reliable results.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49163726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2022.2163961
Lee Gwangseop, J. Koh
ABSTRACT In this study, lead-free 0.8(Bi,Na)TiO3-0.2(Sr,Ti)O3 piezoelectric ceramics were prepared using a two-step sintering process to analyze their sintering mechanisms. Two-step sintering process has benefits of being able to be conducted at lower temperatures than conventional sintering process, but the complicated sintering mechanisms involved in this process have not been yet fully investigated. Therefore, in the present study, two-step sintering mechanism for lead-free piezoelectric ceramics was analyzed by estimating the activation energy required depending on the sintering conditions. Using the two-step sintering process, the piezoelectric charge and electromechanical coupling coefficients improved from 146 pC/N and 0.347 to 163 pC/N and 0.377, respectively. By comparing the grain-growth mechanisms for the conventional and two-step sintering processes, it appeared that the sintering mechanisms differed. By introducing the two-step sintering process, piezoelectric ceramics with improved piezoelectric charge and electromechanical coupling coefficients were produced.
{"title":"The grain growth mechanisms for 0.8(Bi,Na)TiO3-0.2(Sr,Ti)O3 ceramics prepared using a two-step sintering process","authors":"Lee Gwangseop, J. Koh","doi":"10.1080/21870764.2022.2163961","DOIUrl":"https://doi.org/10.1080/21870764.2022.2163961","url":null,"abstract":"ABSTRACT In this study, lead-free 0.8(Bi,Na)TiO3-0.2(Sr,Ti)O3 piezoelectric ceramics were prepared using a two-step sintering process to analyze their sintering mechanisms. Two-step sintering process has benefits of being able to be conducted at lower temperatures than conventional sintering process, but the complicated sintering mechanisms involved in this process have not been yet fully investigated. Therefore, in the present study, two-step sintering mechanism for lead-free piezoelectric ceramics was analyzed by estimating the activation energy required depending on the sintering conditions. Using the two-step sintering process, the piezoelectric charge and electromechanical coupling coefficients improved from 146 pC/N and 0.347 to 163 pC/N and 0.377, respectively. By comparing the grain-growth mechanisms for the conventional and two-step sintering processes, it appeared that the sintering mechanisms differed. By introducing the two-step sintering process, piezoelectric ceramics with improved piezoelectric charge and electromechanical coupling coefficients were produced.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41544561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRACT Due to the processing of alumina ceramic cutting tools with complex shapes using traditional methods is difficult and time-consuming, vat-photopolymerization-based 3D printing was adopted to fabricate Al2O3 ceramic cutting tools with grooves for the first time. Subsequently, cutting performance evaluation and wear mechanism analysis were conducted. The relative density, Vickers hardness, and bending strength of the alumina cutting tools were determined. The effects of the cutting speed, feed rate, and cutting depth on the cutting performance and wear mechanism of the cutting tools were systematically investigated. In addition, two commercial cutting tools, namely cemented carbide and ceramic tools without grooves, were used for comparison. The cutting speed has the highest influence on the cutting performance, whereas the cutting depth has the least influence. The cutting performance of the prepared alumina cutting inserts with chip breaker grooves superior to that those without chip-breaking grooves and that of the cemented carbide tools. The wear mechanisms of the prepared alumina cutting tools and commercial tools were determined to be abrasive and adhesive wear, and those of the cemented carbide tools were adhesive wear and breakage. This work opens a new avenue for the future preparation of high-performance and complex-shaped ceramic cutting tools.
{"title":"Vat photopolymerization-based 3D printing of complex-shaped and high-performance Al2O3 ceramic tool with chip-breaking grooves: Cutting performance and wear mechanism","authors":"Haidong Wu, Wei Liu, Yuerui Xu, Lifu Lin, Yehua Li, Shanghua Wu","doi":"10.1080/21870764.2023.2168343","DOIUrl":"https://doi.org/10.1080/21870764.2023.2168343","url":null,"abstract":"ABSTRACT Due to the processing of alumina ceramic cutting tools with complex shapes using traditional methods is difficult and time-consuming, vat-photopolymerization-based 3D printing was adopted to fabricate Al2O3 ceramic cutting tools with grooves for the first time. Subsequently, cutting performance evaluation and wear mechanism analysis were conducted. The relative density, Vickers hardness, and bending strength of the alumina cutting tools were determined. The effects of the cutting speed, feed rate, and cutting depth on the cutting performance and wear mechanism of the cutting tools were systematically investigated. In addition, two commercial cutting tools, namely cemented carbide and ceramic tools without grooves, were used for comparison. The cutting speed has the highest influence on the cutting performance, whereas the cutting depth has the least influence. The cutting performance of the prepared alumina cutting inserts with chip breaker grooves superior to that those without chip-breaking grooves and that of the cemented carbide tools. The wear mechanisms of the prepared alumina cutting tools and commercial tools were determined to be abrasive and adhesive wear, and those of the cemented carbide tools were adhesive wear and breakage. This work opens a new avenue for the future preparation of high-performance and complex-shaped ceramic cutting tools.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41838560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2022.2153473
Hanaa Hajjou, K. Tabit, L. Saâdi, M. Waqif
ABSTRACT Cordierite-based ceramic is one of the most interesting engineering materials that has attractive and multidisciplinary assets, such as low thermal expansion coefficient, excellent thermal shock resistance, high refractoriness, good mechanical properties, and so on. In this work, cordierite-based ceramics were prepared mainly from stevensite-rich clay or coal fly ash (CFA) and stevensite-rich clay using a solid-state interaction process. The influence of heating temperature, in the range of 800–1250°C, and starting materials on the microstructure-temperature evolutions and mechanical strength were evaluated using TGA-DTA, XRD, FTIR, SEM, and dilatometric analysis. The results revealed, for both formulations heating in the temperature range 800–1100°C, the transformation of stevensite-rich clay into enstatite and its polymorphisms. Further heating induced the formation of the cordierite phase at 1200°C, for the formulation consisted mainly of stevensite-rich clay and CFA, and at 1250°C for that contained mainly stevensite-rich clay. The addition of CFA to stevensite-rich clay enhanced its reactivity and involved the increase in mechanical strength from 5 MPa to 15 MPa at 1200°C.
{"title":"Cordierite-based ceramics from stevensite clay and coal fly ash","authors":"Hanaa Hajjou, K. Tabit, L. Saâdi, M. Waqif","doi":"10.1080/21870764.2022.2153473","DOIUrl":"https://doi.org/10.1080/21870764.2022.2153473","url":null,"abstract":"ABSTRACT Cordierite-based ceramic is one of the most interesting engineering materials that has attractive and multidisciplinary assets, such as low thermal expansion coefficient, excellent thermal shock resistance, high refractoriness, good mechanical properties, and so on. In this work, cordierite-based ceramics were prepared mainly from stevensite-rich clay or coal fly ash (CFA) and stevensite-rich clay using a solid-state interaction process. The influence of heating temperature, in the range of 800–1250°C, and starting materials on the microstructure-temperature evolutions and mechanical strength were evaluated using TGA-DTA, XRD, FTIR, SEM, and dilatometric analysis. The results revealed, for both formulations heating in the temperature range 800–1100°C, the transformation of stevensite-rich clay into enstatite and its polymorphisms. Further heating induced the formation of the cordierite phase at 1200°C, for the formulation consisted mainly of stevensite-rich clay and CFA, and at 1250°C for that contained mainly stevensite-rich clay. The addition of CFA to stevensite-rich clay enhanced its reactivity and involved the increase in mechanical strength from 5 MPa to 15 MPa at 1200°C.","PeriodicalId":15130,"journal":{"name":"Journal of Asian Ceramic Societies","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46604706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-02DOI: 10.1080/21870764.2022.2156676
J. Cui, Kang Guan, Pinggen Rao, Cheng Peng, Q. Zeng, Jiantao Liu, Shuyan Yu
ABSTRACT The single-edged V-notch beam (SEVNB) method is considered as an effective method for evaluating the fracture toughness values of brittle materials. In this method, it is assumed that the V-notch is a natural crack. However, this assumption may cause an overestimation of the fracture toughness due to the “notch passivation effect”. To investigate the effects of the V-notch and groove tip angles on the fracture toughness testing of ceramic materials, three typical models were established in this work. The stress intensity factors of these models were calculated using a J-integral based on the linear finite element method (LFEM). The results indicated that the measured fracture toughness values could be overestimated by 0.5%- 13.7% when the angle of the V-notch tip increased from 10° to 60°. Increasing the angle formed by the V-notch and groove from 10° to 60°, fracture toughness was overevaluated by about 0% – 2.0%. When the angle formed by the V-notch and groove increased to 120°, the fracture toughness was overevaluated by about 31%. Finally, two equations were fitted to assess the angles effects on fracture toughness, and the results have been validated by experiments. An important reference for the SEVNB method can be found in this work.
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