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Effect of heat treatment on hardness and wear resistance of high carbon-high chromium steel (fmu-11) 热处理对高碳高铬钢(fmu-11)硬度和耐磨性的影响
Pub Date : 2021-01-27 DOI: 10.30544/596
A. Darvishi, Aria Daneshmayeh, A. Salehi, M. Ahmadi, A. Soleymani
In the present study, microstructure, hardness, and abrasion resistance of a heat-treated high carbon-high chromium steel (FMU-11) used in the cement mills were investigated. To investigate the best heat-treating cycle for the FMU-11 steel, three sets of samples were heat treated. The first set was tempered two times, the second set was re-hardened, and the third set was cryogenically heat treated. These samples were then compared with the conventionally heat-treated samples. The samples' microstructure was studied using an optical microscope, where traditional black and white etching, as well as color etching, were used. Scanning electron microscopy (SEM) was applied for higher magnification studies and in-depth analysis of the chemical composition. The mechanical properties were investigated by measuring the hardness and the wear resistance for the samples heat-treated in different cycles. The results showed that the cryogenic treatment and double-tempered samples had the highest hardness and wear resistance. In addition, the results showed that the re-hardening operation caused the carbides to be finely separated and evenly distributed in the steel matrix. The wear test results illustrated that the wear mechanism could be the delamination wear and the abrasive wear combined.
本文研究了一种用于水泥厂的热处理高碳高铬钢(FMU-11)的显微组织、硬度和耐磨性。为探讨FMU-11钢的最佳热处理周期,对三组试样进行了热处理。第一组经过两次回火,第二组再次硬化,第三组进行低温热处理。然后将这些样品与常规热处理样品进行比较。使用光学显微镜研究了样品的微观结构,其中使用了传统的黑白蚀刻和彩色蚀刻。应用扫描电子显微镜(SEM)进行高倍放大研究和深入分析化学成分。通过测定不同热处理周期试样的硬度和耐磨性,研究了其力学性能。结果表明,深冷处理和双回火处理的样品具有最高的硬度和耐磨性。结果表明,再硬化处理使碳化物在钢基体中分散均匀。磨损试验结果表明,磨损机制可能是脱层磨损和磨粒磨损的结合。
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引用次数: 3
Comprehensive review of various corrosion behaviours on 316 stainless steel 316不锈钢各种腐蚀行为的综合评述
Pub Date : 2021-01-26 DOI: 10.30544/570
K. Baranidharan, S ThirumalaiKumaran, M. Uthayakumar, P. Parameswaran
Corrosion is a destructive process that converts the pure metal into a chemically stabled form by hydroxide or sulphide and it is a slow process of destruction on the material by the chemical or electrochemical reaction in the environmental space. This kind of destruction has been typically produced from oxides or salt content on the material and it results in distinctive orange coloration. The classifications of corrosion act on atmospheric air and liquids as well as on contact of two solids. To resist the corrosion rate, stainless steel 316 has been chosen because of the presence of 2-3% molybdenum content and the presence of molybdenum plays a vital role in corrosion resistance. In this study, literature related to various works has been reviewed to explain the corrosion behaviour on cavitation, crevice, electrochemical, erosion, fatigue, galvanic, uniform, pitting, and stress corrosion which act on 316 stainless steel. In the present work, several coating processes and the additives, that have been added to SS 316 to enhance the outcomes according to various corrosion causes, are discussed.
腐蚀是由氢氧化物或硫化物将纯金属转化为化学稳定形式的破坏过程,是在环境空间中通过化学或电化学反应对材料进行缓慢破坏的过程。这种破坏通常是由材料上的氧化物或盐含量产生的,它导致独特的橙色。腐蚀的分类作用于大气、空气和液体以及两种固体的接触。为了抵抗腐蚀速率,选择了不锈钢316,因为存在2-3%的钼含量,钼的存在对耐腐蚀性起着至关重要的作用。本文对316不锈钢在空化、缝隙、电化学、侵蚀、疲劳、电偶、均匀腐蚀、点蚀和应力腐蚀等方面的腐蚀行为进行了综述。本文根据不同的腐蚀原因,讨论了几种涂层工艺和添加的添加剂,以提高316不锈钢的腐蚀效果。
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引用次数: 4
Simultaneous optimization of machine and tool parameters for EDM using WC/Co P/M electrode made with micron and nano sized particles 微米级和纳米级WC/Co P/M电极电火花加工的机床参数同步优化
Pub Date : 2021-01-21 DOI: 10.30544/582
Nadimpalli Sarada Purnima, S. Pujari, Siva Prasad Dora
Multi-response characteristic optimization is the most desired aspect of the components produced from electric discharge machining (EDM). Obtaining the optimal combination of parameters for surface roughness (SR) and micro-hardness (MH) is always a challenging task as the machining parameters favourable to one performance measure adversely affects the other. The present paper deals with the simultaneous optimization of SR and MH of D2 alloy steel during EDM with tungsten carbide (WC)/cobalt (Co) P/M electrode by considering electrode and machine tool parameters. Experimental run order was planned with Taguchi’s orthogonal arrays (OA) and in the present investigation, it is based on L18 OA. The analysis of variance (ANOVA) performed for the grey relational grade (GRG) showed that the tool parameter “particle size” (PS) is the most influential factor (61.43%) for simultaneous improvement of performance measures. The P/M electrode made of fine particle size (i.e., at nano level) has improved the process stability and reduced the arcing and short-circuiting results in reduced surface roughness. Simultaneously, the formation of the hard intermetallic phase’s viz., Fe3C, Cr23C6, W2C, Fe6W6C, and Cr2Fe14C on the EDMed surface has increased the surface hardness. The optimal set of parameters was validated through confirmation experiments.
多响应特性优化是电火花加工(EDM)零件最需要解决的问题。获得表面粗糙度(SR)和显微硬度(MH)参数的最佳组合一直是一项具有挑战性的任务,因为有利于一项性能指标的加工参数会对另一项性能指标产生不利影响。在考虑电极参数和机床参数的情况下,研究了碳化钨(WC)/钴(Co) P/M电极对D2合金钢电火花加工中SR和MH的同步优化。用田口正交阵列(Taguchi’s orthogonal arrays, OA)规划了实验运行顺序,本研究以L18正交阵列为基础。对灰色关联度(GRG)进行方差分析(ANOVA)表明,工具参数“粒径”(PS)是影响性能指标同步改进的最重要因素(61.43%)。细粒度(即纳米级)的P/M电极提高了工艺稳定性,减少了电弧和短路,降低了表面粗糙度。同时,EDMed表面形成了Fe3C、Cr23C6、W2C、Fe6W6C、Cr2Fe14C等硬质金属间相,提高了表面硬度。通过验证实验对最优参数集进行了验证。
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引用次数: 0
Arc Plasma Deposition of TiO2 Nanoparticles from Colloidal Solution 胶体溶液中TiO2纳米粒子的电弧等离子沉积
Pub Date : 2020-12-31 DOI: 10.30544/587
V. Maksimović, M. Stoiljković, V. Pavkov, J. Ciganovic, I. Cvijović-Alagić
Surface modifications of metallic biomaterials can in great merit, improve the properties of the hard-tissue implants and in that way contribute to the success of the surgical implantation process. Coating deposition stands out as one of the many surface-modifying techniques that can be used to improve implant surface properties and, in turn, induce successful osseointegration. Deposition of the TiO2 layer on the surface of the metallic implants has a great potential to enhance not only their osseointegration ability but also their biocompatibility and corrosion resistance. In the present study, the possibility of successful deposition of the TiO2 layer on the surface of commercially pure titanium (CP-Ti), as the most commonly used metallic implant material, by spraying the colloidal nanoparticles aqueous solution in the electric discharge plasma at atmospheric pressure was investigated. To characterize the colloidal TiO2 nanoparticle solution, used for the coating deposition process, transmission electron microscopy (TEM) was utilized, while scanning electron microscopy (SEM) and optical profilometry were used to investigate the deposited surface layer morphology and quality. Estimation of the deposited film quality and texture was used to confirm that the arc plasma deposition technique can be successfully used as an advanced and easy-to-apply method for coating the metallic implant material surface with the bioactive TiO2 layer which favors the osseointegration process through the improvement of the implant surface properties. The TiO2 coating was successfully deposited using the arc plasma deposition technique and covered the entire surface of the CP-Ti substrate without any signs of coating cracking or detachment.
金属生物材料的表面修饰可以极大地改善硬组织植入物的性能,从而有助于手术植入过程的成功。涂层沉积是众多表面修饰技术之一,可用于改善种植体表面特性,进而诱导成功的骨整合。在金属种植体表面沉积TiO2层,不仅可以增强金属种植体的骨整合能力,还可以提高金属种植体的生物相容性和耐腐蚀性。在本研究中,研究了在常压放电等离子体中喷射胶体纳米颗粒水溶液,成功在最常用的金属植入材料——商品纯钛(CP-Ti)表面沉积TiO2层的可能性。为了表征用于涂层沉积过程的胶体TiO2纳米粒子溶液,采用透射电镜(TEM),扫描电镜(SEM)和光学轮廓术(opilometry)对沉积的面层形貌和质量进行了研究。通过对沉积膜质量和质地的评价,证实了电弧等离子体沉积技术可以作为一种先进且易于应用的方法,在金属种植体材料表面涂覆具有生物活性的TiO2层,通过改善种植体表面性能,有利于骨整合过程。利用电弧等离子体沉积技术成功地沉积了TiO2涂层,并覆盖了CP-Ti基板的整个表面,没有任何涂层开裂或脱落的迹象。
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引用次数: 0
Characterization of carbon fibrous material from platanus achenes as platinum catalysts support 瘦果碳纤维材料作为铂催化剂载体的表征
Pub Date : 2020-12-31 DOI: 10.30544/588
B. Kaludjerovic, V. Jovanović, S. Stevanović, Ž. Bogdanov, S. Krstić, V. Dodevski
Carbon materials with developed porosity are usually used as supports for platinum catalysts. Physico-chemical characteristics of the support influence the properties of platinum deposited and its catalytic activity. In our studies, we deposited platinum on carbon fibrous like materials obtained from platanus seeds - achenes. The precursor was chemically activated with different reagents: NaOH, pyrogallol, and H2O2, before the carbonization process. Platinum was deposited on all substrates to study the influence of the substrate properties on the activity of the catalyst. Carbon materials were characterized by nitrogen adsorption/desorption isotherms measurements, X-ray diffraction, and scanning electron microscopy. It was noticed that the adsorption characteristics of carbon support affected the structure of platinum deposits and thus their activity.
多孔性较好的碳材料通常用作铂催化剂的载体。载体的理化性质影响着铂镀层的性能和催化活性。在我们的研究中,我们将铂沉积在从扁桃种子瘦果中获得的碳纤维状材料上。在炭化前,先用NaOH、邻苯三酚和H2O2对前驱体进行化学活化。在所有底物上沉积铂,研究底物性质对催化剂活性的影响。通过氮吸附/脱附等温线测量、x射线衍射和扫描电镜对碳材料进行了表征。碳载体的吸附特性影响铂镀层的结构,从而影响铂镀层的活性。
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引用次数: 0
Effect of chemical composition on the microstructure, hardness and electrical conductivity profiles of the Bi-Ge-In alloys 化学成分对Bi-Ge-In合金显微组织、硬度和电导率的影响
Pub Date : 2020-12-31 DOI: 10.30544/561
A. Djordjevic, M. Premović, D. Minić, M. Kolarević, M. Tomović
In this study, the microstructure, hardness, and electrical properties of selected ternary Bi-Ge-In alloys were investigated. Isothermal sections of the Bi-Ge-In system at 25, 200, and 300 ° C were extrapolated using optimized thermodynamic parameters from the literature. The used experimental techniques include optical microscopy, X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and energy dispersion spectrometry (EDS), Brinell hardness, and electrical conductivity measurements. The results of EDS phase composition analysis were compared with the calculated isothermal sections and a good overall agreement was reached. The results of the XRD were also in line with the predicted phase balance. By using ANOVA analysis and experimental results of Brinell hardness and electrical conductivity, a mathematical model was suggested for the calculation of these properties along with all composition ranges. The appropriated mathematical model was subsequently used for the prediction of hardness and electrical conductivity throughout the whole composition range.
本文研究了选定的三元Bi-Ge-In合金的显微组织、硬度和电性能。利用文献中优化的热力学参数外推了Bi-Ge-In系统在25、200和300°C时的等温截面。使用的实验技术包括光学显微镜,x射线粉末衍射(XRD),扫描电子显微镜(SEM)和能量色散光谱(EDS),布氏硬度和电导率测量。将EDS相组成分析结果与等温截面计算结果进行了比较,得到了较好的一致性。XRD结果也与预测相平衡一致。通过方差分析和布氏硬度和电导率的实验结果,提出了一个计算布氏硬度和电导率的数学模型。适当的数学模型随后用于预测整个成分范围内的硬度和电导率。
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引用次数: 0
Effect of process parameters on the phase transformation kinetics in copper-based alloys and composites 工艺参数对铜基合金及复合材料相变动力学的影响
Pub Date : 2020-11-26 DOI: 10.30544/571
M. Šimic, N. Radović, M. Gordić, J. Ružić
Copper-based alloys and composites, owing to their convenient properties, are being considered essential materials in various industries. Since copper possesses an ability to develop high corrosion resistance, putting it in the domain of a desirable material in the manufacturing of valves, pipes, and also systems that carry industrial gases and aqueous fluids. Its usage is also invaluable for cables and electrical wires. This review paper describes diversity in copper alloy processing techniques (powder and ingot metallurgy) which are alongside the phase transformation kinetics interpreted and explained in detail. Furthermore, the focus is put on the copper alloys, as well as the kinetics present in these systems, with the application being highlighted. Correlation between physical properties and phase transformation kinetics in copper alloys is made. It is shown that if certain alloying elements are to be added, different properties could be improved. The effect of phase precipitation on phase transformation kinetics of copper alloys is shown by studying the Cu–15Ni–8Sn alloy.
铜基合金和复合材料由于其方便的性能,被认为是各种工业的基本材料。由于铜具有很高的耐腐蚀性,因此它是制造阀门、管道以及输送工业气体和含水流体的系统的理想材料。它在电缆和电线上的使用也是无价的。本文介绍了铜合金加工技术(粉末冶金和铸锭冶金)的多样性,并对相变动力学进行了详细的解释和说明。此外,重点放在铜合金上,以及这些系统中存在的动力学,并强调了应用。研究了铜合金的物理性能与相变动力学之间的关系。结果表明,加入一定的合金元素可以改善合金的不同性能。通过对Cu-15Ni-8Sn合金的研究,揭示了相析出对铜合金相变动力学的影响。
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引用次数: 0
Mechanical and electrical properties of the Bi-Ge-Sn alloys Bi-Ge-Sn合金的力学和电学性能
Pub Date : 2020-11-23 DOI: 10.30544/562
M. Premović, A. Djordjevic, D. Minić, M. Tomović, B. Radičević, N. Kolarević
Mechanical and electrical properties of the ternary Bi-Ge-Sn alloys were investigated in this study. Calculation of isothermal section at 200, 300, and 25 oC was carried out by using optimized thermodynamic parameters for the constitutive binary systems. Microstructures of alloys were observed by using optical microscopy and scanning electron microscopy (SEM). Phases in microstructures have been detected by X-ray diffraction (XRD) analysis and compositions of the phase by energy dispersive spectrometry (EDS). EDS results were compared with the predicted isothermal section at 200 and 300 oC, and good agreement has been reached between them. The Brinell hardness and electrical conductivity of selected alloys were measured. Through ANOVA analysis and application of the obtained results, an appropriate mathematical model is proposed for every composition of alloys. By using the appropriated mathematical model for Brinell hardness and electrical conductivity, isolines for those properties were presented.
本文研究了三元Bi-Ge-Sn合金的力学性能和电学性能。利用优化后的热力学参数,计算了本构二元体系在200、300和25℃时的等温截面。采用光学显微镜和扫描电镜观察合金的显微组织。用x射线衍射(XRD)和能谱分析(EDS)分析了微观结构中的相。EDS结果与预测的200℃和300℃等温剖面进行了比较,两者吻合较好。测定了所选合金的布氏硬度和电导率。通过方差分析和对所得结果的应用,提出了适合各合金成分的数学模型。利用适当的布氏硬度和电导率数学模型,给出了布氏硬度和电导率的等值线。
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引用次数: 0
Friction and wear reduction by graphene nano platelets for hybrid nano Aluminium matrix composite under dry sliding conditions 干滑动条件下石墨烯纳米片对杂化纳米铝基复合材料的摩擦磨损降低作用
Pub Date : 2020-11-19 DOI: 10.30544/536
P. D. Srivyas, M. Charoo
Friction losses and wear losses are the main failure reasons in the internal combustion (IC) engine components i.e., cylinder liner and piston. So, it demands lightweight self-lubricating low friction and wear-resistant materials to increase the efficiency and reduce the emission issue of the IC engine. In this concern, tribological tests are performed on self-lubricating aluminium composites samples reinforced with 6 wt.% of γ-Al2O3 and Graphene Nano Platelets (GNP) with varying concentration (0.5 wt.% 5 wt.%), using ball-on-disc tribo-configuration under dry sliding conditions. The scope of this study is to investigate the anti-friction and anti-wear properties of GNP as reinforcement in the hybrid nanocomposite. The hybrid nanocomposite samples are fabricated using Spark Plasma Sintering (SPS) fabrication route. From the results, it is reported that friction and wear reduction percentage is 37.43 % and 51.64 %, respectively for the hybrid nanocomposite with 5 wt. % GNP. It is attributed to the inclusion of GNP, which reduces the Coefficient of Friction (COF) and improves wear resistance of the composite significantly.
摩擦损耗和磨损损耗是内燃机部件即缸套和活塞失效的主要原因。因此,需要采用轻量化、自润滑、低摩擦、耐磨的材料来提高内燃机的效率,减少排放问题。为此,在干滑动条件下,使用球盘摩擦配置,对含有6 wt.% γ-Al2O3和不同浓度(0.5 wt.% 5 wt.%)的石墨烯纳米片(GNP)增强的自润滑铝复合材料样品进行了摩擦学测试。本研究的范围是研究GNP作为增强剂在杂化纳米复合材料中的抗摩擦和抗磨损性能。采用火花等离子烧结(SPS)工艺制备了杂化纳米复合材料样品。结果表明,当复合材料的GNP为5 wt. %时,摩擦减少率为37.43%,磨损减少率为51.64%。这是由于GNP的加入,降低了摩擦系数(COF),显著提高了复合材料的耐磨性。
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引用次数: 2
An overview on potential hydrometallurgical processes for separation and recovery of manganese 锰分离与回收的潜在湿法冶金工艺综述
Pub Date : 2020-11-19 DOI: 10.30544/560
Dr.Sanghamitra Pradhan, Ms.Muskan Ram, Prof.Sujata Mishra
With rapid economic progress worldwide, the search for new resources for materials has become a priority due to mineral resource depletion. Enhanced requirements for manganese alloys and compounds for several commercial applications created a desperate demand for manganese recovery technologies from primary as well as secondary resources. The future demand for manganese alloys and compounds is expected to increase. The growing need of electrolytic manganese dioxide (EMD) for different battery usage in automobile and energy sectors could create a gap in the supply and demand of manganese. There is an urgent necessity for eco-friendly and efficient technologies to boost the production of manganese from low-grade ores as well as postconsumer products. The framework of effective leaching processes and proper solvent extraction techniques for the recovery of manganese could be a novel pathway to get a clean, green and healthy environment for a sustainable future in the automotive and energy segment where this metal has a significant contribution.
随着世界经济的迅速发展,由于矿物资源的枯竭,寻找新的材料资源已成为一个优先事项。一些商业应用对锰合金和锰化合物的需求增加,对初级和次级资源的锰回收技术产生了迫切的需求。未来对锰合金和锰化合物的需求预计会增加。汽车和能源行业对电解二氧化锰(EMD)的需求不断增长,可能会造成锰的供需缺口。迫切需要环保高效的技术来促进低品位矿石锰的生产以及后消费产品。有效的浸出工艺框架和适当的溶剂萃取技术可以为锰的回收提供一个新的途径,为汽车和能源领域的可持续未来提供清洁、绿色和健康的环境,在这些领域,锰具有重要的贡献。
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引用次数: 0
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Metallurgical and Materials Engineering
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