Thermally sprayed coatings are extensively used in the energy and aerospace sectors to protect surfaces against wear, oxidation, corrosion, and for thermal insulation; therefore their characterization is vital to preserving and protecting key infrastructural capabilities. In this study, we conduct experiments to examine the feasibility of using nonlinear ultrasonic/acoustic techniques such as nonlinear resonance acoustic spectroscopy (NRAS) and second harmonic generation (SHG) to characterize thermally sprayed nickel coatings. Nonlinear elastic parameters have been proven to be highly sensitive to microstructural features in materials. This work characterizes the and nonlinearity parameters which are related to the degree of micro-damages (interlamellar gap/void structures) intrinsic to sprayed coatings. In this work, thermally sprayed nickel coatings are sprayed onto stainless steel substrates at two particle sizes (Ni 101 - fine powder and Ni 969 - coarse powder) and spray distances (101.6 and 203.2 mm stand-off distance). The sprayed coatings are separated from their substrates to determine if the nonlinearity parameters can effectively measure microstructural changes in these samples. The nonlinearity parameters measured independently from two different nonlinear ultrasonic/acoustic techniques show an increasing trend with increasing particle sizes and spray distances. Furthermore, NRAS measurements of coatings with and without the substrate indicate that the nonlinearity of thermally sprayed coatings can still be characterized on the thicker substrate. In addition to estimating the nonlinear parameters, porosity, hardness, wave speed and attenuation are also reported. Our results suggest that these nonlinear ultrasonic/acoustic techniques can be potentially used as an inspection and quality control tool for thermal spray coatings.
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