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Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics最新文献

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Electrical properties of PZT thin films derived from sol-gel solution containing photo-sensitive water-generater 含光敏水发生器的溶胶-凝胶溶液制备PZT薄膜的电学性质
Y. Nakao, T. Nakamura, A. Kamisawa, H. Takasu, N. Soyama, G. Sasaki, T. Atsuki, T. Yonezawa, K. Ogi
The photo sensitivity of sol-gel solution of PbZr/sub x/Ti/sub 1-x/O/sub 3/ (PZT) was confirmed. A coated film of the sol-gel solution on Si and Ir/IrO/sub 2//SiO/sub 2//Si substrates was exposed to an excimer laser and developed with 2-methoxyethanol diluted with isopropyl alcohol. More than 900 mJ/cm/sup 2/ of exposure was required to obtain the micro patterns. The film was finally annealed at 700/spl deg/C for 60 s by rapid thermal annealing (RTA). From this process, half-micron patterns of PZT films were obtained. The 200-nm-thick film showed P/sub r/ of 16.6 /spl mu/C/cm/sup 2/ and E/sub c/ of 38.8 kV/cm. After 1/spl times/10/sup 12/ cycles of switching pulses, the films showed no degradation of remanent polarization. Studying for 1-transistor-type ferroelectric memory, metal-ferroelectric-metal-insulator-semiconductor (MFMIS) structure was prepared with this process.
确定了PbZr/sub x/Ti/sub 1-x/O/sub 3/ (PZT)溶胶-凝胶溶液的光敏性。在准分子激光照射下,用异丙醇稀释的2-甲氧基乙醇在Si和Ir/IrO/sub - 2//SiO/sub - 2//Si衬底上涂覆了溶胶-凝胶溶液薄膜。需要超过900兆焦耳/厘米/sup 2/的曝光才能获得微模式。最后采用快速热退火法(RTA)对薄膜在700/spl℃下退火60 s。在此过程中,得到了半微米的PZT薄膜。200 nm厚薄膜的P/sub r/为16.6 /spl mu/C/cm/sup 2/, E/sub C/为38.8 kV/cm。经过1/spl次/10/sup / 12次开关脉冲循环后,膜的残余极化没有退化。研究了单晶体管型铁电存储器,利用该工艺制备了金属-铁电-金属-绝缘体-半导体(MFMIS)结构。
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引用次数: 4
Characterization of PZT hollow-sphere transducers PZT空心球体换能器的表征
J. Fielding, D. Smith, R. Meyer, S. Trolier-McKinstry, R. Newnham
Millimeter size, hollow spheres of lead zirconate titanate have been fabricated by blowing gas through a fine-grained slurry of PZT-5. Techniques were developed for the classification of defects in green and sintered spheres. The spheres were poled radially between inner and outer electrodes. The dielectric and piezoelectric properties were characterized for poled spheres. The two principal resonances were a breathing mode near 700 KHz and a wall thickness mode near 10 MHz. Hydrostatic d/sub h/ coefficients /spl sim/1000 pC/N were measured. Pulse-echo measurements were also performed to characterize transducer performance. Potential applications for these miniature omnidirectional transducers include biomedical imaging, flow noise sensors and hydrophones.
通过向PZT-5细颗粒浆料中吹气,制备了毫米尺寸的锆钛酸铅空心球体。研究了生坯和烧结球缺陷分类技术。球体在内外电极之间呈径向极化。对极化球的介电和压电性能进行了表征。两个主要共振是700千赫附近的呼吸模式和10兆赫附近的壁厚模式。测量流体静力d/sub / h/系数/spl sim/1000 pC/N。还进行了脉冲回波测量来表征换能器的性能。这些微型全向传感器的潜在应用包括生物医学成像、流动噪声传感器和水听器。
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引用次数: 13
Electro-optic switching behaviour of a novel shortpitch ferroelectric liquid crystal mixture 一种新型短节距铁电液晶混合物的电光开关特性
K. Raina, H. Coles
Electro-optic effects have been studied in a shortpitch (/spl rho//sub 0/=0.43 /spl mu/m), large spontaneous polarization (P/sub s/=90 nC/cm/sup 2/) ferroelectric liquid crystal mixture. The material in the form of thin films was sandwiched between polyimide coated transparent conducting glass plates. The sample alignment was planar in an electric field without shearing. Disclination loops appeared at low voltages and were then removed at higher voltages to obtain a 'bookshelf' structure which gives higher contrast. This material shows bistability, fast switching times (40 /spl mu/sec at 8 V//spl mu/m) and multiplexability. These are useful parameters for the operation of a fast electro-optic liquid crystal display device.
研究了短间距(/spl rho//sub 0/=0.43 /spl mu/m)、大自发极化(P/sub s/=90 nC/cm/sup 2/)铁电液晶混合物的电光效应。薄膜形式的材料被夹在涂有聚酰亚胺的透明导电玻璃板之间。在无剪切电场作用下,样品排列呈平面排列。倾斜回路在低电压下出现,然后在高电压下移除,以获得“书架”结构,从而获得更高的对比度。该材料具有双稳定性,快速开关时间(8 V//spl mu/m时40 /spl mu/sec)和多路可复用性。这些参数对快速电光液晶显示装置的工作是有用的。
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引用次数: 0
Antiferroelectric/ferroelectric composite thin films 反铁电/铁电复合薄膜
D. Dausch, F. Wang, G. Haertling
PLZT-based antiferroelectric (AFE)/ferroelectric (FE) composite thin films were fabricated by automatic spin coating and crystallized by rapid thermal processing. A computer-controlled automatic spin coat reactor was used to spin composite thin films from acetate precursors with successive layers of FE and AFE composition. Films were spun on platinum-coated silicon substrates and rapid thermal thermally processed at 700/spl deg/C. Composite thin films exhibited improved AFE-type properties including increased dielectric constant (K) and saturation polarization (P/sub sat/) and decreased FE switching field (E/sub F/) compared to typical AFE compositions. X-ray diffraction results indicated that the composite thin films consisted of distinct AFE and FE phases. Modeling of the dielectric properties revealed linear series capacitor behavior within the composite thin films for low electric field conditions; however, nonlinear effects were apparent at high electric fields.
采用自动自旋镀膜法制备了plzt基反铁电(AFE)/铁电(FE)复合薄膜,并进行了快速热处理结晶。采用计算机控制的自动自旋膜反应器,将FE和AFE组成的连续层醋酸前驱体自旋成复合薄膜。薄膜在镀铂硅衬底上纺丝,并在700/spl℃下快速热处理。与典型的AFE成分相比,复合薄膜的FE型性能得到了改善,包括介电常数(K)和饱和极化(P/sub sat/)的增加,FE开关场(E/sub F/)的减小。x射线衍射结果表明,复合薄膜由明显的AFE相和FE相组成。电介质性能的模拟揭示了复合薄膜在低电场条件下的线性串联电容行为;然而,在高电场下,非线性效应明显。
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引用次数: 0
The use of applied electric fields the photorefractive tungsten bronze ferroelectrics 应用外加电场制备光折变钨青铜铁电体
N. Bei, G. Duree, G. Salamo, R. Kapoor, E. Sharp, R. Neurgaonkar
The traditional method of determining the photorefractive effective charge density is to plot the photorefractive space charge field versus the crossing angle in a two-beam coupling experiment. The difficulty with this traditional measurement technique is that the apparatus must be moved several times in order to obtain data over the sufficient number of crossing angles needed for an accurate fit with theory. Moreover, with small crossing angles the overlap between the two crossing beams can easily extend over the entire crystal, while with larger crossing angles the overlap between the two beams becomes less certain. In this paper we demonstrate an alternative method of determining the photorefractive charge density. In this approach we measure the phase shift between the optical intensity pattern in the crystal and the resulting index pattern, as a function of the magnitude of an applied d.c. field. By comparing the measured value of the d.c. field which produces a minimum phase shift with that predicted by theory the photorefractive effective charge density is found. In this case, only the magnitude of the applied field is varied and the apparatus remains fixed. The result is obtained quickly and with little error.
测定光折变有效电荷密度的传统方法是在双光束耦合实验中绘制光折变空间电荷场与交叉角的关系图。这种传统测量技术的困难在于,为了获得与理论精确拟合所需的足够数量的交叉角的数据,仪器必须移动几次。此外,当交叉角较小时,两束交叉光束之间的重叠可以很容易地扩展到整个晶体上,而当交叉角较大时,两束光束之间的重叠变得不那么确定。在本文中,我们展示了一种测定光折变电荷密度的替代方法。在这种方法中,我们测量了晶体中的光强模式和由此产生的折射率模式之间的相移,作为施加直流场大小的函数。将产生最小相移的直流电场的实测值与理论预测值进行比较,得到了光折变有效电荷密度。在这种情况下,只有外加电场的大小变化,仪器保持固定。结果得到的速度快,误差小。
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引用次数: 0
Temperature stability of resonance frequency of filter materials obtained by different techniques 不同技术获得的滤料谐振频率的温度稳定性
S. V. Gavrilyatchenko, A. Dantsiger, L. A. Reznitchenko, O. N. Razumovskaja, A. N. Klevtsov
The influence of the various techniques on the character of microstructure and temperature stability of resonance frequency for piezoelectric materials PCR-62 and PCR-63 has been considered. It is noted that temperature stability has high magnitudes at transition from hot pressing to traditional sintering. It is connected with an increase of field of bulk charge when the density of ceramics decreases.
研究了不同工艺对压电材料PCR-62和PCR-63的微观结构特征和谐振频率温度稳定性的影响。在从热压到传统烧结的转变过程中,温度稳定性具有很高的数量级。这与陶瓷密度减小时体电荷场增大有关。
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引用次数: 0
Pulsed laser deposition (PLD) of ferroelectric thin films in conjunction with superconducting oxides 铁电薄膜与超导氧化物的脉冲激光沉积(PLD)
S. Sengupta, L. Sengupta, W. E. Kosik
The possibility of combining ferroelectrics and superconductors has been of interest for use in memory storage devices. Additionally, superconductors offer crystal structures compatible to the epitaxial growth of the ferroelectric, Ba/sub 0.6/Sr/sub 0.4/TiO/sub 3/ (BSTO), which is cubic at this stoichiometry. BSTO has a lattice constant of 3.94 /spl Aring/ as compared to the superconducting Pr/sub 2-x/Ce/sub x/CuO/sub 4/ tetragonal single crystal which also has a lattice constant of a=3.94 /spl Aring/. In this study, ferroelectric thin films of BSTO were deposited on single crystals of Pr/sub 2/CuO/sub 4/ and Pr/sub 2-x/Ce/sub x/CuO/sub 4/. The optical constants of the substrates, single crystals of Pr/sub 2/CuO/sub 4/ and Pr/sub 2-x/Ce/sub x/CuO/sub 4/, were determined using Variable Angle Spectroscopic Ellipsometry (VASE) and the composition and crystal structure were examined using Rutherford Backscattering Spectrometry (RBS) with ion beam channeling. The substrate/film interfaces and the compositional variation in the films were also studied with RBS and with SEM/EDS. Glancing angle X-ray diffraction was used to verify the epitaxial nature of the films. The effect of the deposition parameters (laser repetition rate, oxygen backfill pressure, and deposition geometry) on the quality of the films was experimented with and the optimized parameters were used.
将铁电体和超导体结合在一起的可能性已引起人们对存储器存储装置的兴趣。此外,超导体提供了与铁电晶体Ba/sub 0.6/Sr/sub 0.4/TiO/sub 3/ (BSTO)外延生长相容的晶体结构,在这种化学统计下,它是立方的。与超导的Pr/sub - 2-x/Ce/sub -x/ CuO/sub - 4/四方单晶相比,BSTO的晶格常数为3.94 /spl Aring/。本研究在Pr/sub - 2/CuO/sub - 4/和Pr/sub - 2-x/Ce/sub -x/ CuO/sub - 4/单晶上沉积了BSTO铁电薄膜。利用变角椭圆偏振仪(VASE)测定了Pr/sub 2/CuO/sub 4/和Pr/sub 2-x/Ce/sub x/CuO/sub 4/单晶的光学常数,并利用离子束通道卢塞福后向散射光谱(RBS)检测了其组成和晶体结构。利用RBS和SEM/EDS研究了衬底/薄膜界面和薄膜成分的变化。用掠射角x射线衍射验证了薄膜的外延性质。实验了沉积参数(激光重复频率、氧充填压力和沉积几何形状)对薄膜质量的影响,并采用了优化后的参数。
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引用次数: 0
Increased operating temperature range in La-modified Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbTiO/sub 3/ relaxor ferroelectric-based transducers la修饰的Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbTiO/sub 3/弛豫铁电传感器工作温度范围增大
J. Fielding, T. Shrout, S. Jang
The large E-field induced strains and electromechanical coupling in PMN-based relaxors have been utilized in actuator and transducer applications. The effect of La/sup 3+/ modifications on the field-dependent dielectric and piezoelectric properties was investigated for several (1-x)PMN-(x)PT compositions with transition regions near room temperature. The effect of La/sup 3+/ modifications, increasing the width of the micro-macro polar transition range (/spl Delta/T), defined as the difference between the temperature of maximum permittivity (T/sub max/) and the depolarization temperature (T/sub d/), results in a broader temperature range for obtaining large induced electromechanical coupling factors with negligible hysteresis.
pmn型弛豫器的大电场感应应变和机电耦合特性已广泛应用于致动器和换能器中。研究了La/sup 3+/改性对几种具有室温过渡区的(1-x)PMN-(x)PT复合材料的介电和压电性能的场相关影响。La/sup 3+/修饰的作用,增加了微观-宏观极性转变范围(/spl Delta/T)的宽度(定义为最大介电常数温度(T/sub max/)与退极化温度(T/sub d/)之差),从而使获得大的感应机电耦合因子的温度范围更宽,而滞后可以忽略不计。
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引用次数: 0
Piezoelectric response of PZT thin film actuated micromachined silicon cantilever beams PZT薄膜驱动微机械硅悬臂梁的压电响应
K. Brooks, D. Damjanovic, N. Setter, P. Luginbuhl, G. Racine, N. D. de Rooij
Micromachined cantilever beams actuated by sol-gel derived lead zirconium titanate (PZT) thin films are reported. Rectangular cantilevers of sub-millimeter dimensions and several different aspect ratios were fabricated. The PZT films utilized for these structures were 0.44 /spl mu/m thick. The natural resonance frequencies of the beams were determined from impedance measurements. The resonance frequency was found to follow a L/sup -2/ dependence, where L is the cantilever length. An effective elastic constant, s/sub 11/, for the beam structures of 15.7/spl times/10/sup -12/m/sup 2/N/sup -1/ was thus calculated. The effect of bias fields on the effective electromechanical coupling factor, k/sub 31/, was also determined from the resonance data. Maximum k/sub 31/ values measured were approximately 0.15, or about half of those reported for PZT bulk ceramics.
报道了由溶胶-凝胶衍生的钛酸铅锆薄膜驱动的微机械悬臂梁。制作了亚毫米尺寸和几种不同宽高比的矩形悬臂梁。用于这些结构的PZT薄膜厚度为0.44 /spl mu/m。梁的自然共振频率由阻抗测量确定。发现共振频率遵循L/sup -2/依赖关系,其中L为悬臂长度。据此计算了15.7/spl倍/10/sup -12/m/sup 2/N/sup -1/的梁结构的有效弹性常数s/sub - 11/。根据谐振数据,确定了偏置场对有效机电耦合系数k/sub 31/的影响。测得的最大k/sub 31/值约为0.15,约为PZT体陶瓷所报告的最大值的一半。
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引用次数: 8
Flexi-distortional piezoelectric sensor results 柔性变形压电传感器结果
W. B. Carlson, S. Pilgrim, W. Schulze, Y. Kato, J. Frommelt
A longitudinal ("RIBBIE") form of a shear amplification sensor has been tested for amplified d/sub 15/ response. The mechanically amplified flexi-distortional system may improve the d/sub h/g/sub h/ figure of merit by transferring the compressional stress on the device to a lateral shear on the electroceramic element. This type of amplified system is mechanically classified as distortional and, therefore, without volume change By transforming the hydrostatic stress to transverse strain, the transverse forces can be used to develop shear strain and activate the d/sub 15/ coefficient. Electrodes are placed along the sides of the sensing element. Flexi-distortional devices are tested in order to check for the limits of sensitivity in their performance.
纵向(“RIBBIE”)形式的剪切放大传感器已经测试了放大的d/sub / 15/响应。机械放大的挠性扭曲系统可以通过将器件上的压缩应力传递到电陶瓷元件上的横向剪切来提高d/sub h/g/sub h/优值。这种类型的放大系统在机械上被归类为扭曲的,因此没有体积变化。通过将静水应力转化为横向应变,横向力可以用来产生剪切应变并激活d/sub 15/系数。电极沿传感元件的两侧放置。对挠性扭曲器件进行测试,以检查其性能中的灵敏度极限。
{"title":"Flexi-distortional piezoelectric sensor results","authors":"W. B. Carlson, S. Pilgrim, W. Schulze, Y. Kato, J. Frommelt","doi":"10.1109/ISAF.1994.522485","DOIUrl":"https://doi.org/10.1109/ISAF.1994.522485","url":null,"abstract":"A longitudinal (\"RIBBIE\") form of a shear amplification sensor has been tested for amplified d/sub 15/ response. The mechanically amplified flexi-distortional system may improve the d/sub h/g/sub h/ figure of merit by transferring the compressional stress on the device to a lateral shear on the electroceramic element. This type of amplified system is mechanically classified as distortional and, therefore, without volume change By transforming the hydrostatic stress to transverse strain, the transverse forces can be used to develop shear strain and activate the d/sub 15/ coefficient. Electrodes are placed along the sides of the sensing element. Flexi-distortional devices are tested in order to check for the limits of sensitivity in their performance.","PeriodicalId":20488,"journal":{"name":"Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics","volume":"3 1","pages":"770-771"},"PeriodicalIF":0.0,"publicationDate":"1994-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87118647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics
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