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Improved magnetoelectric effect in modified (Na0.5Bi0.5)TiO3-BaTiO3-CoFe2O4 lead-free multiferroic composites 改进的(Na0.5Bi0.5)TiO3-BaTiO3-CoFe2O4无铅多铁复合材料的磁电效应
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297834
E. Ramana, M. Graça, J. Monteiro, S. Mendiratta, M. Valente
Particulate composites of (Na0.5Bi0.5TiO3)-BaTiO3(NBBT)+(Co0.6Zn0.4)(Fe1.7Mn0.3)O4 (CZFMO) were synthesized by the conventional ceramic method to study ferroelectric, magnetic and magnetoelectric properties. Ferroelectric switching has been seen in all the ferroelectric and composite ceramics. Remanent polarization of 34 and 26μC/cm2 was obtained for the pure and 85 mol% NBT-BT ceramics, while a larger leakage current was observed for the remaining composites. The magnetoelectric coefficient (αME) of 8 mV/cm-Oe was observed in the composition with 65 mol% ferroelectric and the coupling seems to be lower for higher ferroelectric content ceramics. A change of ~10% in saturated magnetization was observed in composites of 65 mol% NBBT, which is an indication of the converse magnetoelectric effect. The results indicate that these lead-free composites are promising and can be tunable for the low-field magnetoelectric applications.
采用常规陶瓷法制备了(Na0.5Bi0.5TiO3)-BaTiO3(NBBT)+(Co0.6Zn0.4)(Fe1.7Mn0.3)O4 (CZFMO)颗粒复合材料,研究了其铁电、磁性和磁电性能。在所有的铁电陶瓷和复合陶瓷中都可以看到铁电开关。纯NBT-BT陶瓷和85 mol% NBT-BT陶瓷的剩余极化为34 μ c /cm2和26μC/cm2,剩余材料的漏电流较大。在铁电含量为65%的陶瓷中,磁电系数(αME)为8 mV/cm-Oe,铁电含量越高,耦合越小。在65 mol% NBBT的复合材料中观察到饱和磁化强度变化约10%,这表明存在逆磁电效应。结果表明,这些无铅复合材料具有良好的应用前景,可用于低场磁电应用。
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引用次数: 2
Microstructure and impedance analysis of CaBi4Ti4O15 piezoceramics with (LiCe)-modifications (LiCe)改性CaBi4Ti4O15压电陶瓷的微观结构和阻抗分析
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297791
Zhihang Peng, Fengkang Huang, Qiang Chen, Shao-Kui Bao, Xiao-Xue Wang, D. Xiao, Jianguo Zhu
(Li, Ce) doped CaBi4Ti4O15 (CBT) ceramics were prepared using the conventional solid state method. The crystal structure and microstructure of CBT-based ceramics were determined by the X-ray diffraction and scanning electron microscopy. It was found that the (Li, Ce) ions diffused into the A site of pseudo-perovskite structure and formed single Aurivillius type structure. The Curie-temperature (TC) of CBT ceramics decreased whereas the piezoelectric coefficient (d33) was improved with the increasing of (Li, Ce) dopants. Furthermore, the impedance spectrum techniques were invoked to understand the electrical properties for pure or modified-CBT compounds at high temperature region and the underlying physical mechanism were also discussed.
采用常规固相法制备了(Li, Ce)掺杂CaBi4Ti4O15 (CBT)陶瓷。采用x射线衍射和扫描电镜对陶瓷的晶体结构和微观结构进行了表征。发现(Li, Ce)离子扩散到伪钙钛矿结构的A位,形成单一的Aurivillius型结构。随着(Li, Ce)掺杂量的增加,CBT陶瓷的居里温度(TC)降低,压电系数(d33)提高。此外,利用阻抗谱技术了解了纯或改性cbt化合物在高温区的电学性质,并讨论了其潜在的物理机制。
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引用次数: 3
Direct measurements of the electrocaloric effect in lead-free K0.5Na0.5NbO3-SrTiO3 ceramics sintered in air 无铅K0.5Na0.5NbO3-SrTiO3陶瓷在空气中烧结的电热效应的直接测量
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297752
B. Rožič, J. Koruza, Z. Kutnjak, B. Malič, M. Kosec
By utilizing direct measurements of the electrocaloric effect (ECE) temperature change via high-resolution calorimeter, the ECE has been studied in bulk lead-free relaxor K0.5Na0.5NbO3-SrTiO3 (KNN-STO) ceramics. Observed magnitude of the ECE confirms existence of the large EC effect in this system near the ferroelectric phase transition.
利用高分辨率量热计直接测量电热效应(ECE)温度变化,研究了大块无铅弛豫剂K0.5Na0.5NbO3-SrTiO3 (KNN-STO)陶瓷的ECE。观察到的ECE的大小证实了在铁电相变附近存在较大的EC效应。
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引用次数: 2
Room temperature novel multiferroic single phase materials: (PbFe0.5Ta0.5O3)x-(PbZr0.53Ti0.47O3)(1−x) 新型室温多铁性单相材料:(PbFe0.5Ta0.5O3)x-(PbZr0.53Ti0.47O3)(1−x)
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297747
D. Sanchez, N. Ortega, R. Katiyar, A. Kumar, J. Scott
Solid solution of (PbFe0.5Ta0.5O3)x-(PbZr0.53Ti0.47O3)(1-x) (0.1≤ × ≤ 0.4) perovskite type structure produces a single phase materials, both in ceramic and thin films form. This novel material has low loss, possesses room temperature multiferroic properties, and has strong magnetoelectric coupling.
固溶的(PbFe0.5Ta0.5O3)x-(PbZr0.53Ti0.47O3)(1-x)(0.1≤x≤0.4)钙钛矿型结构产生的单相材料,既有陶瓷形式,也有薄膜形式。该材料具有低损耗、室温多铁性、强磁电耦合等特点。
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引用次数: 2
Anisotropy and dynamic thermal depolarization of 0.96(Bi0.5Na0.5)TiO3-0.04 BaTiO3 lead-free piezoceramics 0.96(Bi0.5Na0.5)TiO3-0.04 BaTiO3无铅压电陶瓷的各向异性和动态热退极化
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297762
L. Pardo, A. García, K. Brebøl, E. Mercadelli, C. Galassi
Undoped (Bi0.5Na0.5)0.96Ba0.04TiO3 ceramics were prepared from mixed oxides and sol-gel autocombustion powder. Similar dielectric and electromechanical properties were found for both but sol-gel derived ceramics can be obtained with a lower thermal budget, which prevent losses of volatiles. Dielectric anisotropy is observed. All the features of the thermal evolution curves of εT11 are observed at temperatures clearly displaced towards higher values with respect to those of the εT33 curves. There is also anisotropy in the depoling process. When depoling is monitored in-situ using the shear mode of thickness poled plates, resonance is observed at Td >; 150°C. Besides, hot in-situ measurements of time dependence of the resonaces of disks and plates at temperatures below Td showed that the depolarization of BNBT4 is a dynamical process.
以混合氧化物和溶胶-凝胶自燃粉末为原料制备了未掺杂的(Bi0.5Na0.5)0.96Ba0.04TiO3陶瓷。两者的介电和机电性能相似,但溶胶-凝胶衍生陶瓷可以用较低的热预算获得,这可以防止挥发物的损失。观察到介电各向异性。εT11热演化曲线的所有特征在温度上都明显地偏向于εT33曲线的高值。在脱极过程中也存在各向异性。采用厚度极化板剪切模式进行原位去极化监测时,在Td >处观察到共振;150°C。此外,在温度低于Td时,热原位测量了盘和板共振的时间依赖性,表明BNBT4的退极化是一个动态过程。
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引用次数: 5
Fabrication and evaluation of a single element lead free-based ultrasonic transducer 单元件无铅超声换能器的制造与评价
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297733
M. Hejazi, B. Jadidian, Ahmad Safari
This paper discusses the fabrication and characterization of a single element ultrasonic transducer with a lead-free piezoelectric active element. A piezoelectric ceramic with composition of 0.88Bi0.5Na0.5TiO3-0.08Bi0.5K0.5TiO3-0.04Bi0.5Li0.5TiO3 was chosen as the active element of the transducer. This composition exhibited a thickness coupling coefficient (kt) of 0.45, a dielectric constant of 440 (at 1 kHz), and a longitudinal piezoelectric coefficient (d33) of 84 pC.N-1. To make the transducer, the ceramic was sandwiched between an epoxy-tungsten backing layer and a silver epoxy matching layer. An epoxy lens was also incorporated into the transducer's design to focus the ultrasound beam. The focused transducer with a center frequency of about 23 MHz demonstrated a -6 dB bandwidth of 55% and an insertion loss of -32 dB, while the -20dB pulsed length was measured to be 150 ns. A phantom made of copper wires (30 μm in diameter) was utilized to investigate the imaging capability of the transducer. The results indicated that the fabricated transducer with a lateral resolution of 260 μm and a relatively high depolarization temperature could be considered as a candidate for replacement of lead-based ultrasonic transducers.
本文讨论了一种无铅压电有源元件单元件超声换能器的制作和性能。选用成分为0.88Bi0.5Na0.5TiO3-0.08Bi0.5K0.5TiO3-0.04Bi0.5Li0.5TiO3的压电陶瓷作为换能器的有源元件。该组合物的厚度耦合系数(kt)为0.45,介电常数为440 (1khz),纵向压电系数(d33)为84 pC.N-1。为了制造换能器,将陶瓷夹在环氧钨衬底层和银环氧匹配层之间。换能器的设计中还加入了一个环氧树脂透镜来聚焦超声波光束。中心频率约为23 MHz的聚焦换能器-6 dB带宽为55%,插入损耗为-32 dB,而-20dB脉冲长度为150 ns。利用直径为30 μm的铜线制成的模体来研究换能器的成像能力。结果表明,该换能器横向分辨率为260 μm,退极化温度较高,可作为替代铅基超声换能器的候选材料。
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引用次数: 1
Electrocaloric effect in γ-irradiated P(VDF-TrFE) relaxors γ辐照P(VDF-TrFE)松弛剂的电热效应
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297737
R. L. Moreira
Relaxor features were induced in an equimolar P(VDF-TrFE) copolymer by high doses of γ-rays. The electrocaloric responses of the samples were investigated, before and after irradiation. For the virgin copolymer, the maxima isothermal entropy change (ΔS ≈ 22.5 J/kgK) and adiabatic temperature change (ΔT ≈ 6 K) of conformational origin were observed at 90 °C and above, for a 120 MV/m applied electric field. For the γ-irradiated sample, we observed the lowering of the working temperature range by circa 15 °C, but higher external electric fields of 160 MV/m were required to recover the large level of electrocaloric response in these polymeric relaxors. The refrigerant capacity of the materials, virgin or relaxors, was evaluated as 130 J/kg, showing their high potential for applications as electrocaloric refrigerators.
高剂量γ射线诱导等摩尔P(VDF-TrFE)共聚物松弛特性。研究了辐照前后样品的电热响应。对于初生共聚物,在120 MV/m的外加电场作用下,在90℃及以上温度下,其构象源的最大等温熵变(ΔS≈22.5 J/kgK)和绝热温度变化(ΔT≈6 K)均达到最大值。对于γ辐照样品,我们观察到工作温度范围降低了约15°C,但需要更高的160 MV/m的外电场强才能恢复这些聚合物弛豫剂的大水平电热响应。这些材料的制冷剂容量,无论是原始的还是松弛的,都被评估为130 J/kg,显示出它们作为电热冰箱的巨大应用潜力。
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引用次数: 0
Flexible PVDF-BaTiO3 nanocomposites for pressure sensors 柔性PVDF-BaTiO3纳米复合材料用于压力传感器
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297828
D. Olmos, G. González‐Gaitano, R. Vela, L. Cordoba, J. González‐Benito, A. Kholkin
In this work, PVDF-BaTiO3 composites were prepared using cryogenic high-energy ball milling (HEBM). PVDF-BaTiO3 mixtures with different weight fractions of submicrometric BaTiO3 particles were subjected to 1 h of effective milling. By applying pressure at 200 °C the resulting powder was molded in the form of relatively thin discs. Morphological and structural characterization of the materials was done using conventional techniques (DSC, FTIR, XRD, SEM). Piezoelectric characterization of the specimens was also carried out. Macroscopic tapping was used to induce a voltage in the materials. It was found that the output voltage decreases with the amount of BaTiO3 particles. Finally, the piezoelectric behavior response of the samples was followed by an AFM microscope, the vertical deflection of the cantilever was obtained when an electrical signal was applied to the samples.
本文采用低温高能球磨法制备了PVDF-BaTiO3复合材料。加入不同重量分数的亚微米BaTiO3颗粒的PVDF-BaTiO3混合物进行了1 h的有效研磨。通过施加200°C的压力,得到的粉末以相对较薄的圆盘的形式成型。采用DSC、FTIR、XRD、SEM等常规技术对材料进行了形貌和结构表征。并对试样进行了压电特性分析。采用宏观攻丝在材料中感应电压。结果表明,输出电压随BaTiO3颗粒含量的增加而减小。最后,利用AFM显微镜对试样的压电行为响应进行了跟踪,得到了施加电信号时悬臂梁的垂直挠度。
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引用次数: 6
Femtosecond infrared laser annealing of ferroelectric PZT films on a metal substrate 金属基板上铁电PZT薄膜的飞秒红外激光退火
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297852
N. Y. Firsova, E. Mishina, S. Senkevich, I. P. Pronin, I. Bdikin, A. Kholkin
Ti-sapphire femtosecond laser was utilized to crystallize Pb(Zr0,54, Ti0,46)O3 (PZT) film on platinized silicon substrate. Second harmonic generation was used to in-situ monitor of the annealing process and to confirm a non-centrosymmetric perovskite ferroelectric phase of the irradiated area. Piezo-force microscopy technique allowed us to investigate local polarization properties of annealed areas.
利用钛蓝宝石飞秒激光在镀铂硅衬底上结晶Pb(Zr0,54, Ti0,46)O3 (PZT)薄膜。利用二次谐波对退火过程进行了现场监测,确认了辐照区存在非中心对称钙钛矿铁电相。压电显微镜技术使我们能够研究退火区域的局部极化特性。
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引用次数: 0
Design and optimization of secondary shock type piezoelectric system 二次冲击型压电系统的设计与优化
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297761
H. Jung, K. H. Baek, S. Hidaka, D. Song, Se Bin Kim, T. Sung
Two models for energy harvesting system imparting rotational energy to piezoelectric materials are presented in order to compare the effects of applying identical amounts of energy to a cantilever beam by strain-changing and shock application. For a piezoelectric system given a high impulse with low displacement, higher power outputs were generated at lower resistive loads. Conversely, for a system with high displacement at a low impulse, power output was higher at high resistive loads. At matched impedance, the secondary shock system generated higher power output than the hitting system did at low resistive load. Optimized response of secondary shock system was obtained at a frequency of 60 Hz with a low resistive load of 1 k Ω. The generated output power was measured 124 mW, which corresponds to power density of 140 mW/cm3 for entire cantilever beam and power density of 342 mW/cm3 for only piezoelectric material volume. For a system without a secondary impulse at low resistive loads (1 k Ω), the optimizing frequency was between 20 and 30 Hz, with an output power of 22 mW, which corresponds to a 25 mW/cm3 power density for entire cantilever beam and power density of 60 mW/ cm3 for only piezoelectric material volume.
为了比较在悬臂梁上施加相同能量时的应变变化效应和冲击效应,提出了两种传递旋转能量给压电材料的能量收集系统模型。对于给定高脉冲、低位移的压电系统,在低阻性负载下产生较高的输出功率。相反,对于一个在低脉冲下具有高位移的系统,在高电阻负载下输出功率更高。在阻抗匹配时,二次冲击系统比低阻负载下的冲击系统产生更高的功率输出。二次冲击系统在频率为60 Hz、低电阻负载为1 k Ω时的响应得到了优化。测量产生的输出功率为124 mW,对应于整个悬臂梁的功率密度为140 mW/cm3,仅压电材料体积的功率密度为342 mW/cm3。对于低阻性负载(1 k Ω)下无二次脉冲的系统,优化频率在20至30 Hz之间,输出功率为22 mW,对应于整个悬臂梁的功率密度为25 mW/cm3,仅压电材料体积的功率密度为60 mW/cm3。
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引用次数: 2
期刊
Proceedings of ISAF-ECAPD-PFM 2012
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