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Dielectric properties of K(Ta0.53Nb0.47)O3 single crystal K(Ta0.53Nb0.47)O3单晶的介电性能
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297831
P. Bednyakov, N. Setter, D. Rytz
Dielectric properties of K(Ta0,53Nb0,47)O3 [KTN] single crystals with <;100>; and <;011>; crystallographic orientation were studied. Temperature dependencies of dielectric permittivity of monodomain and polydomain crystals of these orientations are compared.
K(Ta0,53Nb0,47)O3 [KTN]单晶的介电性能和;研究了晶体取向。比较了这些取向的单畴晶体和多畴晶体介电常数的温度依赖性。
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引用次数: 0
Design and optimization of secondary shock type piezoelectric system 二次冲击型压电系统的设计与优化
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297761
H. Jung, K. H. Baek, S. Hidaka, D. Song, Se Bin Kim, T. Sung
Two models for energy harvesting system imparting rotational energy to piezoelectric materials are presented in order to compare the effects of applying identical amounts of energy to a cantilever beam by strain-changing and shock application. For a piezoelectric system given a high impulse with low displacement, higher power outputs were generated at lower resistive loads. Conversely, for a system with high displacement at a low impulse, power output was higher at high resistive loads. At matched impedance, the secondary shock system generated higher power output than the hitting system did at low resistive load. Optimized response of secondary shock system was obtained at a frequency of 60 Hz with a low resistive load of 1 k Ω. The generated output power was measured 124 mW, which corresponds to power density of 140 mW/cm3 for entire cantilever beam and power density of 342 mW/cm3 for only piezoelectric material volume. For a system without a secondary impulse at low resistive loads (1 k Ω), the optimizing frequency was between 20 and 30 Hz, with an output power of 22 mW, which corresponds to a 25 mW/cm3 power density for entire cantilever beam and power density of 60 mW/ cm3 for only piezoelectric material volume.
为了比较在悬臂梁上施加相同能量时的应变变化效应和冲击效应,提出了两种传递旋转能量给压电材料的能量收集系统模型。对于给定高脉冲、低位移的压电系统,在低阻性负载下产生较高的输出功率。相反,对于一个在低脉冲下具有高位移的系统,在高电阻负载下输出功率更高。在阻抗匹配时,二次冲击系统比低阻负载下的冲击系统产生更高的功率输出。二次冲击系统在频率为60 Hz、低电阻负载为1 k Ω时的响应得到了优化。测量产生的输出功率为124 mW,对应于整个悬臂梁的功率密度为140 mW/cm3,仅压电材料体积的功率密度为342 mW/cm3。对于低阻性负载(1 k Ω)下无二次脉冲的系统,优化频率在20至30 Hz之间,输出功率为22 mW,对应于整个悬臂梁的功率密度为25 mW/cm3,仅压电材料体积的功率密度为60 mW/cm3。
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引用次数: 2
Development of novel Pb, Li, Na and K-free piezoelectric materials for Si-based MEMS application 用于硅基MEMS的新型无铅、无锂、无钠、无钾压电材料的研制
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297769
H. Funakubo, S. Yasui, K. Yazawa, J. Nagata, T. Oikawa, T. Yamada, H. Uchida
We developed the piezoelectric materials not including Pb, Li, K and Na as constituent elements. Our concern is the composition survey of the morphotropic phase boundary between tetragonal and non-tetragonal ferroelectric materials. In this approach, we must select the tetragonal ferroelectrics other than PbTiO3 and (Bi1/2K1/2)TiO3 as a end material. BiCoO3 and Bi(Zn1/2Ti1/2)O3 are novel tetragonal candidates for this purpose. We successfully grew epitaxial tetragonal films having ferroelectricity in BiCoO3-BiFeO3 and Bi(Zn1/2Ti1/2)O3-BiFeO3 systems. Based on these system, composition having maximum piezoelectric response of d33(AFM) = 280 pm/V was discovered for epitaxial films in Bi(Zn1/2Ti1/2)O3-Bi(Mg1/2Ti1/2)O3-BiFeO3 system.
研制了不含Pb、Li、K、Na等组成元素的压电材料。我们关注的是四方和非四方铁电材料之间的相变相界的组成调查。在这种方法中,我们必须选择除PbTiO3和(Bi1/2K1/2)TiO3以外的四方铁电体作为末端材料。BiCoO3和Bi(Zn1/2Ti1/2)O3是用于此目的的新型四边形候选者。我们成功地在BiCoO3-BiFeO3和Bi(Zn1/2Ti1/2)O3-BiFeO3体系中生长出具有铁电性的外延四方薄膜。在此基础上,发现了Bi(Zn1/2Ti1/2)O3-Bi(ml1 / 2ti1 /2)O3-BiFeO3体系中外延薄膜的最大压电响应d33(AFM) = 280 pm/V。
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引用次数: 0
Ferroelectric and dielectric properties of bismuth ferrite based thin films by Pulsed Laser Deposition 脉冲激光沉积铋铁氧体基薄膜的铁电性能和介电性能
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297782
R. Rivera, M. Hejazi, A. Safari
BiFeO3 (BFO) has stimulated a great interest in recent years for its room temperature multiferroic behavior with very high remnant polarization. However, the leakage current of BFO films is very high. To lower the leakage current, we have developed thin films with following target compositions on SrRuO3 buffered on SrTiO3 substrate by Pulsed Laser Deposition (PLD): (A) BiFeO3, (B) 0.88Bi0.5Na0.5TiO3-0.08Bi0.5K0.5TiO3-0.04BaTiO3, (C) 0.6BiFeO3-0.4(Bi0.5K0.5TiO3) The phase, growth orientation, microstructural characterization and electrical properties were investigated as a function of deposition parameters. The epitaxial bi-layered 300nm BNT-BKT-BT/BFO thin films (150nm each) exhibited ferroelectric behavior as: 2Pr = 44.0 μC.cm-2, 2Ec = 200 kV.cm-1 and K = 140. Thin films with a composition of 0.6BFO-0.4BKT have also been deposited with different oxygen pressures of 300-500 mTorr. Preliminary results of 0.6BFO-0.4BKT films show that the leakage current can be suppressed by about 4 orders of magnitude which in turn improves the ferroelectric and dielectric properties of the films. It is observed that the remnant polarization increases from 8 to 19 μC.cm-2 as the oxygen pressure is changed from 500 to 300mtorr.
BiFeO3 (BFO)具有很高的残余极化率和室温多铁性,近年来引起了人们的极大兴趣。然而,BFO薄膜的泄漏电流非常大。为了降低漏电流,我们利用脉冲激光沉积(PLD)在SrRuO3衬底上制备了具有以下目标成分的薄膜:(A) BiFeO3, (B) 0.88Bi0.5Na0.5TiO3-0.08Bi0.5K0.5TiO3-0.04BaTiO3, (C) 0.6BiFeO3-0.4(Bi0.5K0.5TiO3)。研究了沉积参数对相、生长取向、微观结构表征和电学性能的影响。外延双层300nm BNT-BKT-BT/BFO薄膜(各150nm)在2Pr = 44.0 μC时表现出铁电行为。cm-2, 2Ec = 200kv。cm-1, K = 140。在300-500 mTorr不同的氧压力下,也沉积了成分为0.6BFO-0.4BKT的薄膜。对0.6BFO-0.4BKT薄膜的初步研究结果表明,泄漏电流可被抑制约4个数量级,从而提高了薄膜的铁电性能和介电性能。残余极化从8 μC增加到19 μC。当氧气压力从500到300mtorr变化时Cm-2。
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引用次数: 0
Comparison of three different topologies of driving LEDs with a piezoelectric transformer 压电变压器驱动led三种不同拓扑结构的比较
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297741
Yi-Ying Lai, Chih-Kung Lee, Wen-Jong Wu
The main purpose of this paper is to compare three different topologies of LED drivers by using a piezoelectric transformer. The advantages of LEDs lighting applications include small size, low power consumption and high efficacy. On the other hand, the merits of the piezoelectric transformer are thin profile, high power density and no electromagnetic interference radiation unlike conventional electromagnetic transformers. Therefore, piezoelectric transformers are suitable to drive LEDs. Since the output voltage of a piezoelectric transformer is highly related to the load impedance, the type of the connection between the piezoelectric transformer and LEDs is a key design parameters as it influences temperature rise and efficiency. In this paper, three different types of connections in driving LEDs are discussed in detail. They are LED self-rectifier, full-wave rectifier and current doubler. Theoretical analysis of these three various topologies are discussed. The theoretical predictions were verified by the circuit simulator PSIM. The characteristics of the three driving methods are compared and summarized.
本文的主要目的是通过使用压电变压器来比较三种不同拓扑的LED驱动器。led照明应用的优点包括体积小、功耗低、效率高。另一方面,与传统的电磁变压器相比,压电变压器具有外形薄、功率密度高、无电磁干扰辐射等优点。因此,压电变压器适合驱动led。由于压电变压器的输出电压与负载阻抗高度相关,因此压电变压器与led之间的连接方式是一个关键的设计参数,因为它影响温升和效率。本文详细讨论了驱动led的三种不同类型的连接。它们有LED自整流器、全波整流器和倍流器。对这三种不同的拓扑结构进行了理论分析。理论预测通过电路模拟器PSIM进行了验证。对比总结了三种驱动方式的特点。
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引用次数: 1
Microwave dielectric properties of novel ceramic for application in wireless communications 应用于无线通信的新型陶瓷的微波介电特性
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297728
Yih-Chien Chen, Ming-De Chen
The microwave dielectric properties of La(Mg0.5-xSrxSn0.5)O3 ceramics were examined with a view to their exploitation for wireless communications. The La(Mg0.5-xSrxSn0.5)O3 ceramics were prepared by the conventional solid-state method with various sintering temperatures. The La(Mg0.5-xSrxSn0.5)O3 ceramics contained La2O3. An apparent density of 6.56 g/cm3, a dielectric constant (ϵr) of 20.5, a quality factor (Q × f) of 107,900 GHz, and a temperature coefficient of resonant frequency (τf) of -84 ppm/°C were obtained for La(Mg0.4Sr0.1Sn0.5)O3 ceramics that were sintered at 1500 °C for 4 h.
研究了La(Mg0.5-xSrxSn0.5)O3陶瓷的微波介电性能,以期将其应用于无线通信领域。采用常规固相法在不同烧结温度下制备了La(Mg0.5-xSrxSn0.5)O3陶瓷。La(Mg0.5-xSrxSn0.5)O3陶瓷含有La2O3。在1500℃下烧结4 h的La(Mg0.4Sr0.1Sn0.5)O3陶瓷的表观密度为6.56 g/cm3,介电常数(ϵr)为20.5,品质因子(Q × f)为107900 GHz,谐振频率温度系数(τf)为-84 ppm/°C。
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引用次数: 1
Multilayer ceramic capacitors with CaCu3Ti4O12 dielectric cuu3ti4o12电介质多层陶瓷电容器
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297757
J. Kulawk, D. Szwagierczak, B. Synkiewicz
The nonferroelectric high-permittivity material CaCu3Ti4O12, being a naturally formed internal barrier layer capacitor, was utilized for preparation of slurries for tape casting and fabrication of multilayer ceramic capacitors. Screen printed silver or silver-palladium electrodes were co-fired with ceramic green sheets at 940°C. The dielectric properties of the CaCu3Ti4O12-based multilayer capacitors were studied in a wide frequency range of 0.1 Hz-2 MHz and in the temperature range from -55 to 400°C. The dominant response which is recorded at low frequency range and at temperatures above 150°C is related to grain boundaries. The dielectric response at low temperatures and/or high frequencies is attributed to grains. SEM and EDS studies showed heterogeneous microstructure and composition of ceramic layers. Large grains have composition close to stoichiometric CCTO, while smaller grains and grain boundaries regions are enriched in oxygen and depleted in copper. The fabricated multilayer capacitors exhibit low sintering temperature suitable for use of cheap electrodes, good compatibility of ceramic layers with the applied commercial conductive pastes, high specific capacitance and a relatively low temperature coefficient of capacitance.
利用非铁电性高介电常数材料CaCu3Ti4O12作为一种自然形成的内势垒层电容器,制备带铸造用浆料和制备多层陶瓷电容器。丝网印刷银或银钯电极与陶瓷绿片在940℃共烧。研究了ccu3ti4o12多层电容器在0.1 hz ~ 2 MHz宽频率和-55 ~ 400℃温度范围内的介电性能。在低频范围和150°C以上的温度下记录的主要响应与晶界有关。在低温和/或高频下的介电响应归因于晶粒。扫描电镜和能谱分析表明,陶瓷层的微观结构和组成均不均匀。大晶粒的组成接近化学计量CCTO,而小晶粒和晶界区域富氧而贫铜。制备的多层电容器具有烧结温度低、适合廉价电极使用、陶瓷层与所应用的商用导电浆料相容性好、比电容高、电容温度系数相对较低等特点。
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引用次数: 4
Intrinsic magnetoelectric coupling in PFW-PT solid solutions PFW-PT固溶体的本征磁电耦合
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297821
B. Fraygola, J. Eiras
Multiferroic solid solutions between Pb(Fe2/3W1/3)O3 (PFW) and PbTiO3 (PT) [PFW-PT] have been characterized by anelastic measurements. Anomalies in the temperature dependence of the elastic constants have been observed at TN and TC for all samples, indicating that the magnetoelectric coupling (ME) between the ferroelectric and antiferromagnetic orders occurs “via strain”. A numerical approximation for the ME coefficients was obtained from the eletroelastic and magnetoelastic coefficients and the values of electric and magnetic susceptibility. These coefficients are greater the closer the temperatures of AFM and FE orders are with each other.
用非弹性测量方法表征了Pb(Fe2/3W1/3)O3 (PFW)和PbTiO3 (PT) [PFW-PT]之间的多铁固溶体。所有样品在TN和TC处都观察到弹性常数的温度依赖性异常,表明铁电级和反铁磁级之间的磁电耦合(ME)发生了“通过应变”。从电弹性系数和磁弹性系数以及磁化率和磁化率的值得到了ME系数的数值近似。AFM和FE两阶温度越接近,这些系数越大。
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引用次数: 0
Potential barrier at the ferroelectric grain boundary due to asymmetric screening of depolarization fields 退极化场不对称筛选导致的铁电晶界势垒
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297727
Y. Genenko, O. Hirsch, P. Erhart
Electric depolarization fields generated by a stripe domain structure in ferroelectrics are considered within a semiconductor model. Field screening due to electronic band bending and due to presence of intrinsic defects leads to the building of asymmetric space charge regions near the grain boundary. This in turn results in the formation of a potential barrier between the grain surface and its interior.
在半导体模型中考虑了铁电体中由条纹畴结构产生的去极化场。由于电子能带弯曲和本征缺陷的存在而产生的场屏蔽导致在晶界附近形成不对称空间电荷区。这反过来又导致在颗粒表面和内部之间形成电位屏障。
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引用次数: 0
Growth temperature and thickness dependences of crystal and micro domain structures of BiFeO3 epitaxial films 生长温度和厚度对BiFeO3外延薄膜晶体和微畴结构的影响
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297846
K. Ujimoto, T. Yoshimura, N. Fujimura
Crystal structure and microstructure such as surface morphology and ferroelectric domain structure of 0.2- to 2.0-μm-thick BiFeO3 epitaxial films deposited between 400 and 700°C were evaluated. For the films deposited at 500°C, tetragonal BiFeO3 was grown The relaxation of the lattice strain drastically occurred by increasing the film thickness. On the other hand, rhombohedral BiFeO3 with tetragonal distortion was grown and the relaxation of the lattice strain occurred by the grain growth for the films deposited at 650°C. The grains consist of single domain for the films deposited at 500°C, while those of films deposited at 650°C consist of multi domains. It is suggested that the domain walls existing inside the grains contributes the piezoelectric response.
研究了在400 ~ 700℃温度下沉积的0.2 ~ 2.0 μm厚BiFeO3外延膜的晶体结构和微观结构,如表面形貌和铁电畴结构。在500℃沉积的薄膜中,生长出了四角形的BiFeO3,随着薄膜厚度的增加,晶格应变发生了剧烈的弛豫。另一方面,在650℃下沉积的薄膜生长出具有四方畸变的菱形BiFeO3,晶粒生长导致晶格应变的松弛。500℃沉积的薄膜晶粒为单畴结构,650℃沉积的薄膜晶粒为多畴结构。晶粒内部存在的畴壁对压电响应有贡献。
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引用次数: 0
期刊
Proceedings of ISAF-ECAPD-PFM 2012
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