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Membranes from upcycled waste plastics: current status, challenges, and future outlook 再生塑料膜:现状、挑战和未来展望
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-22 DOI: 10.1016/j.coche.2025.101106
Milad R Esfahani , Steven T Weinman
Plastic is ubiquitous across all aspects of modern life. Despite its usefulness, only 9% of all plastic waste ever produced has been recycled, leaving a tremendous amount that ends up in landfills and the environment. New strategies need to investigate using this waste plastic. This report analyzes upcycling waste plastics into membranes for water and gas separations. Polyethylene terephthalate, polystyrene, poly(vinyl chloride), polyethylene, polypropylene, and tire rubber have been studied for use as membranes. Future work needs to investigate greener solvents, health and safety aspects, costs, supply and demand, and life cycle assessments for upcycling plastic waste into membranes.
塑料在现代生活的方方面面无处不在。尽管它很有用,但只有9%的塑料垃圾被回收利用,留下了大量的垃圾填埋场和环境。需要研究使用这种废塑料的新策略。本报告分析了将废塑料升级为膜用于水和气体分离。聚对苯二甲酸乙二醇酯、聚苯乙烯、聚氯乙烯、聚乙烯、聚丙烯和轮胎橡胶已被研究用作膜。未来的工作需要研究更环保的溶剂、健康和安全方面、成本、供应和需求,以及将塑料废物升级为膜的生命周期评估。
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引用次数: 0
Using advanced X-ray spectroscopy to reveal molecular level insights into water treatment 使用先进的x射线光谱学揭示水处理分子水平的见解
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-20 DOI: 10.1016/j.coche.2025.101103
Hande Demir , Pinar Aydogan Gokturk , Ethan J Crumlin
Water treatment technologies separate relevant solutes from water resources for water reuse, valuable resource recovery, and increasing the equity and availability of clean water worldwide. Although a variety of treatment methods exist, their performance needs to be improved to enable selective separation with increased durability and fouling resistance. To achieve this, we need to gain a better understanding of how molecular-level physics and chemistry impact integrated systems. Regarding current research on water treatment techniques, there is a clear need to study such systems under realistic environmental conditions. In this review, we aim to show that X-ray spectroscopic techniques are uniquely positioned to provide such information by obtaining detailed molecular insight into phenomena relevant to water research. By doing so, we hope to accelerate the rational design of novel treatment materials and processes. Specifically, a deeper understanding of the complex and interconnected phenomena that impact multilevel water treatment processes will lead to the successful development of next-generation water purification technologies.
水处理技术将相关的溶质从水资源中分离出来,用于水的再利用,回收有价值的资源,并在全球范围内增加清洁水的公平性和可用性。虽然存在多种处理方法,但它们的性能需要改进,以实现选择性分离,增加耐用性和抗污性。为了实现这一点,我们需要更好地理解分子水平的物理和化学是如何影响集成系统的。就目前的水处理技术研究而言,显然需要在现实环境条件下研究这种系统。在这篇综述中,我们的目的是展示x射线光谱技术的独特定位,通过获得与水研究相关的现象的详细分子洞察力来提供这些信息。通过这样做,我们希望能加速新型处理材料和工艺的合理设计。具体来说,对影响多级水处理过程的复杂和相互关联的现象的更深入的理解将导致下一代水净化技术的成功发展。
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引用次数: 0
Tackling micro(nano)plastic pollution in aquaculture systems 解决水产养殖系统中的微(纳)塑料污染
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-19 DOI: 10.1016/j.coche.2025.101104
Camilla Mossotto , Alessandra Maganza , Alice Gabetti , Giuseppe Esposito , Caterina Faggio , Monia Renzi , Syed Shabi Ul Hassan Kazmi , Elena Bozzetta , Marino Prearo , Paolo Pastorino
Micro(nano)plastics (MNPs) are emerging contaminants affecting aquaculture, a key global protein source. Their presence poses significant risks to aquatic ecosystems, farmed species, and human health through consumption of contaminated products. This mini-review highlights MNP contamination in aquaculture, focusing on detection methods, mitigation strategies, and future solutions. Aquaculture-derived MNPs are significant contributors to pollution, requiring innovative countermeasures such as biodegradable materials, advanced real-time detection technologies, and strengthened filtration systems. Future perspectives emphasize the urgent need for standardized, cost-effective MNP detection methods and the adoption of bio-based materials, balancing ecological benefits and environmental impacts. Nature-based solutions, such as plant-based filters, and eco-engineered strategies offer promising avenues to improve ecosystem resilience. Policymakers must establish regulatory frameworks to limit MNP pollution, integrate microplastics into food safety protocols, and promote sustainable practices. Long-term studies on human health risks are also critical to inform actionable interventions. Addressing MNP pollution in aquaculture requires global collaboration and technological innovation to ensure seafood safety, protect ecosystems, and reduce the industry’s environmental footprint.
微(纳米)塑料(MNPs)是影响水产养殖的新兴污染物,而水产养殖是全球重要的蛋白质来源。它们的存在通过食用受污染的产品对水生生态系统、养殖物种和人类健康构成重大风险。这篇小型综述强调了水产养殖中的MNP污染,重点是检测方法、缓解策略和未来解决方案。水产养殖产生的MNPs是造成污染的重要因素,需要创新的对策,如生物可降解材料、先进的实时检测技术和强化的过滤系统。未来的观点强调迫切需要标准化,具有成本效益的MNP检测方法和采用生物基材料,平衡生态效益和环境影响。基于自然的解决方案,如基于植物的过滤器和生态工程策略,为提高生态系统的恢复能力提供了有希望的途径。决策者必须建立监管框架以限制MNP污染,将微塑料纳入食品安全协议,并促进可持续做法。关于人类健康风险的长期研究对于为可行的干预措施提供信息也至关重要。解决水产养殖中的MNP污染需要全球合作和技术创新,以确保海产品安全、保护生态系统并减少该行业的环境足迹。
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引用次数: 0
Prediction and assessment methods for sustainable solar energy systems within our planetary boundaries: how reliable are they? 地球范围内可持续太阳能系统的预测和评估方法:它们有多可靠?
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-18 DOI: 10.1016/j.coche.2025.101100
Natalia A. Cano-Londoño , Rebecca Saive , Tim Bekius , Laura Franco-García
This study presents a critical analysis of the sustainability of solar energy systems within the planetary boundaries framework, which sets the limits within which humanity can safely operate. Given the substantial contribution of the energy sector to global greenhouse gas emissions, solar energy has emerged as a crucial element in the shift toward a sustainable energy future. Nevertheless, numerous challenges impede solar energy systems reaching optimal effectiveness, encompassing technological and methodological sustainable tools constraints, environmental impacts, and socioeconomic implications. This research aims to comprehensively assess these challenges and propose strategies to surmount them through applying a Life Cycle Sustainability Assessment approach. The primary research question addressed is, "How reliable are the predictive and anticipatory assessment methods for sustainable solar energy systems within our planetary boundaries?" The study integrated circular economy principles, criticality evaluation, and advanced technological tools to enhance solar energy systems’ efficiency, environmental performance, and socioeconomic benefits. By addressing the entire life cycle of solar technologies — from material extraction to end-of-life (cradle-to-grave) — this work seeks to contribute to developing more sustainable solar energy systems that operate within the safe limits of our planet’s boundaries. The findings highlight the need for a holistic approach that not only focuses on technological advancements but also considers the broader environmental and socioeconomic impacts to ensure a truly sustainable energy transition.
本研究对地球边界框架内太阳能系统的可持续性进行了批判性分析,该框架设定了人类可以安全运行的限制。鉴于能源部门对全球温室气体排放的巨大贡献,太阳能已成为向可持续能源未来转变的关键因素。然而,许多挑战阻碍了太阳能系统达到最佳效果,包括技术和方法上的可持续工具限制、环境影响和社会经济影响。本研究旨在全面评估这些挑战,并通过应用生命周期可持续性评估方法提出克服这些挑战的策略。主要的研究问题是,“在我们的地球范围内,可持续太阳能系统的预测性和预见性评估方法有多可靠?”该研究综合了循环经济原理、临界性评估和先进的技术工具,以提高太阳能系统的效率、环境绩效和社会经济效益。通过解决太阳能技术的整个生命周期-从材料提取到寿命结束(从摇篮到坟墓)-这项工作旨在为开发更可持续的太阳能系统做出贡献,这些系统在我们地球边界的安全范围内运行。研究结果强调,需要采取全面的方法,不仅关注技术进步,还要考虑更广泛的环境和社会经济影响,以确保真正可持续的能源转型。
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引用次数: 0
Paving the way for green cross-linker substances for the fabrication of polymer membranes — a review 为绿色交联材料制备高分子膜铺平道路——综述
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-13 DOI: 10.1016/j.coche.2025.101097
Roberto Castro-Muñoz , Grzegorz Boczkaj
Chemical cross-linking in membrane fabrication aims to face limitations of polymer membranes, including poor chemical resistance, low mechanical stability, swelling, etc. Typical cross-linkers do not fit green chemistry and sustainable principles due to their toxicity. Thus, this article discusses the successful application of green cross-linkers (including organic acids — citric, gallic, ferulic, and tannic acid, calcium chloride, deep eutectic solvents, pectin) and less toxic substances in polymer membranes (including biopolymeric ones based on chitosan or cellulose) fabrication. This article also mentions how to make it ‘greener’. Important areas for these developments include food biopackaging materials, 3D printing materials, and biomedical items.
化学交联在膜制造中的应用旨在解决聚合物膜的局限性,包括耐化学性差、机械稳定性低、肿胀等。典型的交联剂由于其毒性而不符合绿色化学和可持续原则。因此,本文讨论了绿色交联剂(包括有机酸-柠檬酸、没食子酸、阿魏酸和单宁酸、氯化钙、深共晶溶剂、果胶)和低毒性物质在聚合物膜(包括基于壳聚糖或纤维素的生物聚合物膜)制造中的成功应用。这篇文章还提到了如何使它“更环保”。这些发展的重要领域包括食品生物包装材料、3D打印材料和生物医学项目。
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引用次数: 0
Editorial overview: Advances on Z-scheme and S-scheme photocatalysis for environmental application 综述:z -方案和s -方案光催化环境应用研究进展
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-12 DOI: 10.1016/j.coche.2025.101094
Fang Deng
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引用次数: 0
Lignin-based membranes for health, food safety, environmental, and energy applications: current trends and future directions 木质素基膜在健康、食品安全、环境和能源方面的应用:当前趋势和未来方向
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-07 DOI: 10.1016/j.coche.2025.101098
Karen Acurio-Cerda, Rajesh Keloth, Oghenetega Allen Obewhere, Shudipto Konika Dishari
Polymer-based membrane technologies aim to address critical needs for separation, purification, transport, wound healing, contaminant removal, and more. While robust performance from these membranes is a priority, there is also a pressing need for sustainable, cost-effective solutions for membrane materials to replace perfluorinated and petroleum-derived polymers, which pose significant environmental concerns. Lignin, the second most naturally abundant polymer and a waste by-product of pulp and paper industries and cellulosic biorefineries, offers immense potential to drive sustainable materials revolution. This largely underutilized biopolymer possesses many physical and chemical attributes, making it suitable for biomedical, environmental, and energy applications. For instance, lignin and its functionalized derivatives offer antimicrobial, antioxidant, ultraviolet (UV)-blocking, and barrier properties, which are essential for slow drug release, wound healing with reduced stress, combating antibiotic resistance, and sterile food packaging/preservation. On the other hand, lignin’s 3D, hyperbranched architecture, phenolic units, and facile functionalization opportunities enable unique physical, mechanical, thermal, chemical, and ion transport/separation characteristics, critical for clean water and clean energy technologies. Therefore, by transforming lignin-rich biomass feedstock and industrial waste into value-added, efficient products, we can potentially address global needs for clean water, safe food, affordable healthcare, and renewable energy, as outlined in the United Nations’ Sustainable Development Goals. This mini-review highlights recent advancements in lignin-based membrane designs for biomedical, environmental, and energy applications, alongside a brief discussion on rooms for improvement in this emerging field via lignin valorization.
聚合物基膜技术旨在解决分离、净化、运输、伤口愈合、污染物去除等关键需求。虽然这些膜的强大性能是一个优先事项,但也迫切需要可持续的、具有成本效益的膜材料解决方案,以取代造成重大环境问题的全氟化和石油衍生聚合物。木质素是天然含量第二高的聚合物,是纸浆和造纸工业以及纤维素生物炼制的废弃副产品,具有推动可持续材料革命的巨大潜力。这种未充分利用的生物聚合物具有许多物理和化学特性,使其适用于生物医学,环境和能源应用。例如,木质素及其功能化衍生物具有抗菌、抗氧化、紫外线(UV)阻隔和屏障特性,这些特性对于减缓药物释放、减轻压力的伤口愈合、对抗抗生素耐药性和无菌食品包装/保存至关重要。另一方面,木质素的3D、超支化结构、酚类单位和易于功能化的机会,使其具有独特的物理、机械、热、化学和离子传输/分离特性,对清洁水和清洁能源技术至关重要。因此,通过将富含木质素的生物质原料和工业废物转化为增值、高效的产品,我们有可能满足全球对清洁水、安全食品、负担得起的医疗保健和可再生能源的需求,正如联合国可持续发展目标所概述的那样。这篇小型综述强调了木质素基膜设计在生物医学、环境和能源应用方面的最新进展,并简要讨论了通过木质素增值在这一新兴领域的改进空间。
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引用次数: 0
Hydrogen production from photoelectrochemical wastewater treatment: advancing toward sustainability 光电化学废水处理制氢:向可持续性发展
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-07 DOI: 10.1016/j.coche.2025.101096
Zexiao Zheng , Juhua He , Justin HK Man , Taoran Dong , Irene MC Lo
Incorporating green hydrogen production into photoelectrochemical (PEC) wastewater treatment has been demonstrated as a promising approach to enhance the sustainability of wastewater treatment. Such a bifunctional PEC system eliminates the dependence of water splitting on pure water consumption and enables wastewater valorization. This critical review initially delves into the advances in developing photoelectrodes for bifunctional PEC systems and summarizes the involved modification approaches. Subsequently, the review provides a comprehensive analysis of strategies for optimizing the operation of bifunctional PEC systems and impacts from the wastewater matrices. Furthermore, the challenges presented in the industrialization of this technology are also pointed out. As such, further investigations are encouraged into the scale-up of the PEC reactor, the prolongation of photoelectrode lifespan, the development of downstream hydrogen storage techniques, cost-effectiveness assessment, and the strategy against external variations, thus advancing the bifunctional PEC technique toward industrialization.
在光电化学(PEC)废水处理中引入绿色制氢已被证明是提高废水处理可持续性的一种有前途的方法。这种双功能PEC系统消除了水分解对纯水消耗的依赖,并使废水增值。这篇重要的综述首先深入研究了双功能PEC系统的光电极的发展进展,并总结了所涉及的修饰方法。随后,该综述提供了优化双功能PEC系统运行的策略和废水基质的影响的综合分析。同时指出了该技术产业化过程中存在的挑战。因此,鼓励对PEC反应器的放大,光电极寿命的延长,下游储氢技术的开发,成本效益评估以及对抗外部变化的策略进行进一步的研究,从而推动双功能PEC技术走向工业化。
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引用次数: 0
Innovation through intelligent computer-aided formulation design 创新通过智能计算机辅助配方设计
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-02-06 DOI: 10.1016/j.coche.2025.101099
Thunyaras Phanusupawimol , Kris Prasopsanti , Naz P Taskiran , Venkat Venkatasubramanian , Rafiqul Gani
This perspective paper presents a focused review of a selected topic of chemical-based products, namely, formulations. As formulations cover a wide range of chemical-based products, we highlight opportunities for innovation in three types of formulations — liquid blends, which are mixtures of chemicals that are in the liquid state at standard conditions; liquid formulations, which are mixtures of chemicals that may exist in different states but the final product is a single-phase liquid; and emulsions, which are also mixtures of chemicals that may exist in different states, but the final product is in the form of an emulsion. In each case, we discuss aspects of design, analysis, and innovation together with issues and challenges that could be tackled to find better and more sustainable products. In particular, the potential of hybrid artificial intelligence augmented computer-aided techniques that can aid in the design, analysis, and innovation of formulations is highlighted.
这篇透视论文提出了一个重点审查的化学产品,即配方的选定主题。由于配方涵盖了广泛的基于化学的产品,我们强调了三种类型配方的创新机会-液体混合物,这是在标准条件下处于液态的化学品的混合物;液体制剂,即可能以不同状态存在的化学物质的混合物,但最终产品是单相液体;乳剂,也是化学物质的混合物它们可能以不同的状态存在,但最终的产物是乳剂的形式。在每个案例中,我们都会讨论设计、分析和创新的各个方面,以及可以解决的问题和挑战,以找到更好、更可持续的产品。特别强调了混合人工智能增强计算机辅助技术的潜力,这些技术可以帮助设计、分析和创新配方。
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引用次数: 0
Practicality and potential of membrane surface patterning in membrane technology 膜表面图案化在膜技术中的实用性和潜力
IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2025-01-27 DOI: 10.1016/j.coche.2025.101095
Yazan Ibrahim , Farah Ejaz Ahmed , Nidal Hilal
Surface patterning of membranes has demonstrated significant performance enhancements in various membrane-based technologies. Surface patterns can increase the effective membrane area, improve interfacial area, and enhance hydrodynamics, leading to better membrane properties. Such patterns have been successfully fabricated on a lab scale using template-based molding and direct fabrication process. However, transitioning these techniques to commercial-scale production presents challenges, including maintaining pattern fidelity, ensuring reproducibility and scalability, achieving cost-effectiveness, and avoiding pattern-induced defects. This short article focuses on the emerging field of surface patterning of membranes, exploring different techniques for pattern creation and their effects on membrane properties, structure, and performance. The practicality, sustainability, and scalability challenges of each technique are thoroughly evaluated to determine their potential for commercialization and broader application in membrane technology. The essential steps and future directions needed to address these concerns and limitations are discussed, and a framework for evaluating surface patterning techniques is proposed to stimulate future research and development, advancing the commercial viability and reliability of surface-patterned membranes in the membrane technology industry.
膜的表面图案化在各种膜基技术中表现出显著的性能增强。表面图案可以增加有效膜面积,改善界面面积,增强流体力学,从而获得更好的膜性能。这样的模式已经成功地制造在实验室规模使用基于模板的成型和直接制造工艺。然而,将这些技术转化为商业规模的产品带来了挑战,包括维护模式保真度、确保再现性和可伸缩性、实现成本效益,以及避免模式引起的缺陷。这篇短文聚焦于膜表面图案的新兴领域,探索不同的图案创造技术及其对膜性质、结构和性能的影响。对每种技术的实用性、可持续性和可扩展性挑战进行了全面评估,以确定它们在膜技术中商业化和更广泛应用的潜力。讨论了解决这些问题和限制所需的基本步骤和未来方向,并提出了一个评估表面图案技术的框架,以刺激未来的研究和发展,提高表面图案膜在膜技术工业中的商业可行性和可靠性。
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引用次数: 0
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