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2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics最新文献

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Atomic Vapor Deposition (AVD®) for High-k Dielectric and Ferroelectric films 原子气相沉积(AVD®)用于高k介电和铁电薄膜
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393159
V. Vezin, C. Isobe, O. Boissière, P. Baumann, U. Weber, G. Barbar, J. Lindner
The deposition of metal oxide thin films by metal-organic chemical vapor deposition is a good solution for the fabrication of high-k gate oxide and ferroelectric oxides for ferroelectric random access memories. The main challenges to be addressed in order to meet mass-production worthiness of this technique are reproducible and clean vaporization and transport of the precursor materials as well as process optimization for high quality thin films. The use of short pulses for the delivery of liquid precursor presents some advantages for meeting these requirements.
金属有机化学气相沉积法沉积金属氧化物薄膜是制备高钾栅极氧化物和铁电随机存取存储器用铁电氧化物的良好方法。为了满足该技术的量产价值,需要解决的主要挑战是前驱体材料的可重复性和清洁汽化和运输,以及高质量薄膜的工艺优化。使用短脉冲输送液体前驱体在满足这些要求方面具有一些优势。
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引用次数: 0
Composite Structure and Size Effect of Barium Titanate Nanoparticles 钛酸钡纳米颗粒的复合结构与尺寸效应
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393303
T. Hoshina, S. Wada, Y. Kuroiwa, H. Kakemoto, T. Tsurumi
Almost impurity and defect-free barium titanate (BaTiO3) nanoparticles with various sizes from 20 to 430 nm were prepared using 2-step thermal decomposition method. The nano-structures of these particles were analyzed using a synchrotron radiation X-ray diffraction (XRD). As a result, it was found that the BaTiO3 nanoparticles had composite structure consisted of (a) internal tetragonal layer, (b) Gradient-Lattice-Strain Layer (GLSL) and (c) surface cubic layer.
采用两步热分解法制备了尺寸在20 ~ 430 nm之间的钛酸钡纳米颗粒(BaTiO3)。利用同步辐射x射线衍射(XRD)分析了这些粒子的纳米结构。结果表明,BaTiO3纳米颗粒具有由(a)内部四方层、(b)梯度晶格应变层(GLSL)和(c)表面立方层组成的复合结构。
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引用次数: 164
MEMS-based piezoelectric micro cantilever using LaNiO3 buffered PZT thin film 基于mems的压电微悬臂梁采用LaNiO3缓冲PZT薄膜
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393381
T. Kobayashi, R. Kondo, K. Nakamura, M. Ichiki, R. Maeda
We have fabricated piezoelectric micro cantilevers using LaNiO3 (LNO) buffered PZT thin film through microelectromechanical systems (MEMS) micro fabrication process. The micro cantilevers have been fabricated from Pt/Ti/LNO/PZT/LNO/Pt/Ti/SiO2 or Pt/Ti/PZT/Pt/Ti/SiO2 multilayers deposited on SOI wafers. The PZT thin films without LNO thin films were degraded through the MEMS micro fabrication process. We have found that the LNO thin films can avoid the degradation. DC actuation of the micro cantilevers using LNO buffered PZT thin films has resulted in symmetric butterfly curve. The transverse piezoelectric constant of LNO buffered PZT thin films (-d31 = 120 pm/V) is higher than that of the PZT thin films without LNO thin films (70 pm/V).
采用微机电系统(MEMS)微加工工艺,利用LaNiO3 (LNO)缓冲PZT薄膜制备了压电微悬臂梁。采用Pt/Ti/LNO/PZT/LNO/Pt/Ti/SiO2或Pt/Ti/PZT/Pt/Ti/SiO2多层沉积在SOI晶片上制备微悬臂梁。采用MEMS微加工工艺对PZT薄膜进行了降解。我们发现LNO薄膜可以避免这种退化。利用LNO缓冲PZT薄膜对微悬臂梁进行直流驱动,形成了对称的蝴蝶曲线。LNO缓冲PZT薄膜的横向压电常数(-d31 = 120 pm/V)高于无LNO缓冲PZT薄膜的横向压电常数(70 pm/V)。
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引用次数: 2
On the vibration control using a piezoelectric actuator and a negative capacitor adjusted by a microprocessor 利用微处理器调节的压电致动器和负电容进行振动控制
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393402
P. Mokry, M. Kodejska, T. Sluka
The design and realization of an adaptive vibration isolation system based on a method to control the effective elastic stiffness of piezoelectric materials are presented in this paper. In this system, the vibration isolation effect is achieved by absorption of vibrations transmitted through a multi-stack piezoelectric actuator connected to an active analog circuit that behaves as a negative capacitor. The problem of a high sensitivity of the system to the proper adjustment of the negative capacitor and a deterioration of the vibration isolation efficiency in changing operational conditions are analyzed. A method for the self-adjustment of the system by appending an additional digital control circuit to the negative capacitor is implemented. The transmissibility of vibrations through the piezoelectric actuator was measured in different control regimes.
提出了一种基于压电材料有效弹性刚度控制方法的自适应隔振系统的设计与实现。在该系统中,隔振效果是通过吸收通过连接到有源模拟电路的多堆叠压电驱动器传输的振动来实现的,该电路充当负电容。分析了系统在运行条件变化时对负电容调整灵敏度过高和隔振效率下降的问题。通过在负电容上附加一个额外的数字控制电路,实现了一种系统自调节的方法。在不同的控制条件下,测量了振动在压电驱动器中的传递率。
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引用次数: 1
Transparent Metal-Ferroelectric nanocomposite thick films prepared by Aerosol Deposition Method 气溶胶沉积法制备透明金属-铁电纳米复合厚膜
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393421
Jaehyuk Park, J. Akedo
We prepared high transparent metal-ferroelectric nanocomposite thick films by aerosol deposition method (ADM) and report their enhanced surface plasmon resonance (SPR) properties. ADM has been attracting much attention for its ability to deposit complex composite films at a high deposition rate and a low process temperature. Composite metal-dielectric powders are prepared from submicron particles of PZT and nano particles of gold (10-40 nm) with concentrations below 1 wt%. Nanocomposite gold/PZT 3-mum-thick film acquired enhanced SPR at approximately 640 nm as a result of annealing. The SPR position in nanocomposite films deposited by ADM can be precisely controlled by adjusting the dielectric constant of the host matrix by annealing.. Moreover, we succeeded in room-tenperature-deposition of gold/alpha-Al2O3 nanocomposite films with high transparent red color for the first time.
采用气溶胶沉积法(ADM)制备了高透明金属-铁电纳米复合厚膜,并报道了其表面等离子体共振(SPR)性能的增强。ADM因其能够以高沉积速率和低工艺温度沉积复杂复合薄膜而备受关注。以亚微米级PZT颗粒和纳米级金颗粒(10-40 nm)为原料,以低于1 wt%的浓度制备复合金属介电粉末。纳米复合金/PZT薄膜在约640 nm处获得了增强的SPR。通过退火调节基体的介电常数,可以精确地控制纳米复合膜中SPR的位置。此外,我们首次成功地在室温下沉积了具有高透明红色的金/ α - al2o3纳米复合薄膜。
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引用次数: 1
Leakage Current Property of Pb(Zr0.4, Ti0.6)O3 Thin-film Capacitors with Highly Rectangular Hysteresis Property 具有高矩形迟滞特性的Pb(Zr0.4, Ti0.6)O3薄膜电容器的漏电流特性
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393176
S. Okamura, M. Tanimura, H. Shima, H. Naganuma
The Pb(Zr0.4,Ti0.6)O3 thin-film capacitors with top and bottom Pt electrodes were prepared by chemical solution deposition using the precursor solutions with Pb contents ranging from 104 to 119%. Leakage current densities of the PZT capacitors monotonically decreased with increasing Pb contents. In the Pb110%-PZT capacitor, a conduction mechanism changed from the Schottky emission to the Poole-Frenkel at an electric field of approximately 80 kV/cm at RT while the leakage current was limited only by the Poole-Frenkel in case of less Pb contents. In the Pb110%-PZT capacitor, the Schottky barrier height and a relative permittivity were estimated to be 1.1 eV and 4.8, respectively, and the activation energy of trap sites in the Poole-Frenkel conduction was estimated to be 0.5 eV.
采用铅含量为104 ~ 119%的前驱体溶液,采用化学溶液沉积法制备了顶部和底部为Pt电极的Pb(Zr0.4,Ti0.6)O3薄膜电容器。随着铅含量的增加,PZT电容器的漏电流密度单调降低。Pb110%-PZT电容器在RT下约80 kV/cm的电场下,导通机制由肖特基发射转变为普尔-弗伦克尔,而当铅含量较少时,漏电流仅受普尔-弗伦克尔限制。在Pb110%-PZT电容器中,肖特基势垒高度和相对介电常数分别为1.1 eV和4.8 eV, Poole-Frenkel传导中陷阱位点的活化能估计为0.5 eV。
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引用次数: 0
Advances in Manufacturing Relaxor Piezoelectric Single Crystals 弛豫压电单晶制造研究进展
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393328
J. Luo, S.J. Zhang, T. Shrout, W. Hackenberger
Relaxor piezoelectric single crystal, lead magnesium niobate-lead titanate (PMN-PT), has potential to greatly improve both piezoelectric actuator and transducer applications. High-quality PMN-PT single crystals with the diameter over 50 mm have been successfully grown along different crystallographic directions by the Bridgman technique at TRS. As a solid solution system, PMN-PT inevitably exhibits an inhomogeneous composition distribution along the boule in conventional Bridgman growth, which results in the variation of dielectric and piezoelectric properties along the growth direction and limits the useful portion in each crystal boule. Zone melting growth technique has been developed to further increase the composition uniformity in solid solution PMN-PT crystal. By using zone-melting growth technique, PMN-PT crystals with 22-25 mm in diameter and 150 mm long have been grown at TRS. This paper reviews the progress in Bridgman and zone-melting growth of PMN-PT with the emphasis on uniformity improvement. In addition, TRS recently developed new piezoelectric crystals with modified PMN-PT compositions, which have expanded operating temperature ranges to 120degC and coercive field to 5 kV/cm. Since these new materials were grown directly from the melt by the Bridgman technique, commercialization is achievable by applying the well established crystal growth process for PMN-PT.
弛豫压电单晶,铌镁铅-钛酸铅(PMN-PT),具有极大地改善压电致动器和换能器应用的潜力。利用Bridgman技术在TRS成功地沿不同的结晶方向生长出了直径大于50 mm的高质量PMN-PT单晶。PMN-PT作为一种固溶体体系,在传统的Bridgman生长过程中,不可避免地呈现出沿晶孔的不均匀成分分布,导致其介电和压电性能沿生长方向发生变化,限制了每个晶孔中有用的部分。为了进一步提高固溶体PMN-PT晶体的成分均匀性,研究了区域熔融生长技术。采用区域熔融生长技术,在TRS下生长出直径22 ~ 25 mm、长150 mm的PMN-PT晶体。本文综述了PMN-PT的Bridgman生长和区熔生长的研究进展,重点介绍了均匀性的改善。此外,TRS最近开发了新型压电晶体,其改性PMN-PT成分,将工作温度范围扩大到120℃,矫顽力场扩大到5 kV/cm。由于这些新材料是由Bridgman技术直接从熔体中生长出来的,因此通过应用PMN-PT成熟的晶体生长工艺,可以实现商业化。
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引用次数: 4
Preparation and Characterization of Perovskite BiFeO3-BaTiO3 Ceramics 钙钛矿BiFeO3-BaTiO3陶瓷的制备与表征
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393287
W. Sakamoto, N. Itoh, T. Shimura, T. Yogo
BiFeO3-based ceramics have been fabricated by the solid state reaction. The effect of BaTiO3 content in BiFeO3-BaTiO3 system on the crystal structure, the magnetic properties and the electrical properties were investigated. Perovskite BiFeO3 was stabilized through the formation of solid solution with BaTiO3. Rhombohedrally distorted BiFeO3-BaTiO3 showed weak ferromagnetism. Furthermore, the dielectric properties of resultant ceramics was greatly improved by a small amount of Mn doping.
采用固相反应制备了bifeo3基陶瓷。研究了BiFeO3-BaTiO3体系中BaTiO3含量对晶体结构、磁性能和电学性能的影响。通过与BaTiO3形成固溶体来稳定钙钛矿BiFeO3。菱形变形的BiFeO3-BaTiO3表现出弱铁磁性。此外,少量锰的掺杂大大提高了合成陶瓷的介电性能。
{"title":"Preparation and Characterization of Perovskite BiFeO3-BaTiO3 Ceramics","authors":"W. Sakamoto, N. Itoh, T. Shimura, T. Yogo","doi":"10.1109/ISAF.2007.4393287","DOIUrl":"https://doi.org/10.1109/ISAF.2007.4393287","url":null,"abstract":"BiFeO<sub>3</sub>-based ceramics have been fabricated by the solid state reaction. The effect of BaTiO<sub>3</sub> content in BiFeO<sub>3</sub>-BaTiO<sub>3</sub> system on the crystal structure, the magnetic properties and the electrical properties were investigated. Perovskite BiFeO<sub>3</sub> was stabilized through the formation of solid solution with BaTiO<sub>3</sub>. Rhombohedrally distorted BiFeO<sub>3</sub>-BaTiO<sub>3</sub> showed weak ferromagnetism. Furthermore, the dielectric properties of resultant ceramics was greatly improved by a small amount of Mn doping.","PeriodicalId":321007,"journal":{"name":"2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics","volume":"23 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2007-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127453665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of ZnO on Low Temperature Sintering of Pb(Mn1/3Nb2/3)O3-Pb(Ni1/3Nb2/3)O3-Pb(Zr1/2Ti1/2)O3 Ceramics ZnO对Pb(Mn1/3Nb2/3)O3-Pb(Ni1/3Nb2/3)O3-Pb(Zr1/2Ti1/2)O3陶瓷低温烧结的影响
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393348
Sang-ho Lee, J. Yoo, H. Song, Siheung Lee, Kiho Choi
In this study, in order to develop the composition ceramics for low loss multilayer ceramic actuator for ultrasonic nozzle and ultrasonic vibrator applications, Pb(Mn1/3Nb2/3)O3Pb(Ni1/3Nb2/3)O3Pb(Zr1/2Ti1/2)O3 (abbreviated as PMN-PNN-PZT) ceramics were fabricated using Li2CO3, Na2CO3 and ZnO as sintering aids. And then, their piezoelectric and dielectric properties according to the amount of ZnO addition were investigated. The addition of ZnO improved density, dielectric constant, electromechanical coupling factor, mechanical quality factor and piezoelectric d constant of PMN-PNN-PZT ceramics due to the increase of sinterability and accepter doping effect. Electromechanical coupling factor(kp) and mechanical quality factor(Qm) of PMN-PNN-PZT ceramics increased with ZnO amount up to 0.4 wt% and then decreased. At the sintering temperature of 900degC and 0.4 wt% ZnO addition, density, dielectric constant, electromechanical coupling factor(kp), mechanical quality factor(Qm) and piezoelectric d33 constant showed the optimum value of 7.876 g/cm3, 1299, 0.612, 1151 and 369 pC/N, respectively, for low loss multilayer ceramic actuator application.
本研究以Li2CO3、Na2CO3和ZnO为助烧结剂,制备了Pb(Mn1/3Nb2/3)O3Pb(Ni1/3Nb2/3)O3Pb(zt1 / 2ti1 /2)O3(简称PMN-PNN-PZT)陶瓷材料,用于超声喷嘴和超声振子的低损耗多层陶瓷致动器。然后考察了ZnO添加量对其压电和介电性能的影响。ZnO的加入提高了PMN-PNN-PZT陶瓷的密度、介电常数、机电耦合因子、机械品质因子和压电常数,这是由于烧结性和受体掺杂效应的增加。PMN-PNN-PZT陶瓷的机电耦合系数(kp)和机械品质因子(Qm)随ZnO添加量达到0.4 wt%而先升高后降低。在烧结温度为900℃,ZnO添加量为0.4 wt%的条件下,密度、介电常数、机电耦合系数(kp)、机械品质因子(Qm)和压电d33常数分别为7.876 g/cm3、1299、0.612、1151和369 pC/N为低损耗多层陶瓷致动器的最优值。
{"title":"Effect of ZnO on Low Temperature Sintering of Pb(Mn1/3Nb2/3)O3-Pb(Ni1/3Nb2/3)O3-Pb(Zr1/2Ti1/2)O3 Ceramics","authors":"Sang-ho Lee, J. Yoo, H. Song, Siheung Lee, Kiho Choi","doi":"10.1109/ISAF.2007.4393348","DOIUrl":"https://doi.org/10.1109/ISAF.2007.4393348","url":null,"abstract":"In this study, in order to develop the composition ceramics for low loss multilayer ceramic actuator for ultrasonic nozzle and ultrasonic vibrator applications, Pb(Mn<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>Pb(Ni<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>Pb(Zr<sub>1/2</sub>Ti<sub>1/2</sub>)O<sub>3</sub> (abbreviated as PMN-PNN-PZT) ceramics were fabricated using Li<sub>2</sub>CO<sub>3</sub>, Na<sub>2</sub>CO<sub>3</sub> and ZnO as sintering aids. And then, their piezoelectric and dielectric properties according to the amount of ZnO addition were investigated. The addition of ZnO improved density, dielectric constant, electromechanical coupling factor, mechanical quality factor and piezoelectric d constant of PMN-PNN-PZT ceramics due to the increase of sinterability and accepter doping effect. Electromechanical coupling factor(kp) and mechanical quality factor(Q<sub>m</sub>) of PMN-PNN-PZT ceramics increased with ZnO amount up to 0.4 wt% and then decreased. At the sintering temperature of 900degC and 0.4 wt% ZnO addition, density, dielectric constant, electromechanical coupling factor(k<sub>p</sub>), mechanical quality factor(Q<sub>m</sub>) and piezoelectric d<sub>33</sub> constant showed the optimum value of 7.876 g/cm<sup>3</sup>, 1299, 0.612, 1151 and 369 pC/N, respectively, for low loss multilayer ceramic actuator application.","PeriodicalId":321007,"journal":{"name":"2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2007-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125266545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Epitaxial Growth of PLZT Thin Films and their Electro-Optic Properties PLZT薄膜外延生长及其电光性能
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393422
T. Kosaka, D. Fukunaga, K. Uchiyama, T. Shiosaki
Epitaxially grown lanthanum-modified lead zirconate titanate (PLZT) thin films were deposited on r-cut sapphire substrates using a sol-gel method. The new deposition processes of methanol treatments brought high quality epitaxial growth of PLZT thin films. This film showed high electro-optic (EO) coefficients that were almost comparable to those of bulk PLZTs. We believe this advanced deposition technique will open the door for the future data communication systems with integrated electro-optic devices.
采用溶胶-凝胶法制备了外延生长的镧修饰锆钛酸铅(PLZT)薄膜。甲醇处理的新沉积工艺带来了高质量的PLZT薄膜外延生长。该薄膜显示出高的电光(EO)系数,几乎与大块plzt相当。我们相信这种先进的沉积技术将为未来集成电光器件的数据通信系统打开大门。
{"title":"Epitaxial Growth of PLZT Thin Films and their Electro-Optic Properties","authors":"T. Kosaka, D. Fukunaga, K. Uchiyama, T. Shiosaki","doi":"10.1109/ISAF.2007.4393422","DOIUrl":"https://doi.org/10.1109/ISAF.2007.4393422","url":null,"abstract":"Epitaxially grown lanthanum-modified lead zirconate titanate (PLZT) thin films were deposited on r-cut sapphire substrates using a sol-gel method. The new deposition processes of methanol treatments brought high quality epitaxial growth of PLZT thin films. This film showed high electro-optic (EO) coefficients that were almost comparable to those of bulk PLZTs. We believe this advanced deposition technique will open the door for the future data communication systems with integrated electro-optic devices.","PeriodicalId":321007,"journal":{"name":"2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics","volume":"58 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2007-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126140034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics
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