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2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics最新文献

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Atomic layer deposition of PbTiO3 and its component oxide films PbTiO3及其组分氧化膜的原子层沉积
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393198
Hyun Ju Lee, G. Hwang, K. Lee, G. Kim, C. Hwang
Atomic layer deposition of ferroelectric PbTiO3 (PTO) thin films and its component oxide films were attempted using the Pb(DMAMP)2 and Ti(Oi-Pr)4 or Ti(Ot-Bu)4, as the Pb-and Ti-precursors, respectively, and H2O as oxidant at a wafer temperature of 200 on Ir/IrO2/SiO2/Si substrate. The stoichiometric PTO thin films were grown by a proper control of the cycle ratio of the PbO and TiO2 cycles. The increase of the PTO film growth rate due to the cayalytic effect was observed compared to its component oxide films for both processes using Ti(Oi-Pr)4 or Ti(Ot-Bu)4. The as-deposited PTO film was amorphous so that two different post-deposition annealing method, i.e. slow and fast furnace annealing at 600 , were used to crystallize PTO film. The higher growth rate of PTO film grown using Ti(Oi-Pr)4 due to the higher growth rate of TiO2 film compared to the case using Ti(Ot-Bu)4 resulted in less dense PTO film with the higher density of micro-pores inside as well as surface of film after the fast furnace annealing. Slow furnace annealing improved the surface morphology of PTO film and reduced the micro-pore density. Post-deposition annealing transformed amorphous film to polycrystalline film of perovskite sturcure with an a-axis preferred crystallographic orientation.
以Pb(DMAMP)2和Ti(Oi-Pr)4或Ti(Ot-Bu)4分别为Pb和Ti前驱体,H2O为氧化剂,在200℃的晶圆温度下,在Ir/IrO2/SiO2/Si衬底上尝试了铁电PbTiO3 (PTO)薄膜及其组分氧化膜的原子层沉积。通过适当控制PbO和TiO2循环的循环比,制备了化学计量型PTO薄膜。采用Ti(Oi-Pr)4或Ti(Ot-Bu)4制备PTO膜时,由于催化剂的催化作用,PTO膜的生长速率比其组分氧化膜有所提高。沉积后的PTO薄膜是无定形的,因此采用两种不同的沉积后退火方法,即600℃慢速炉退火和快速炉退火来结晶PTO薄膜。与Ti(Ot-Bu)4相比,使用Ti(io - pr)4生长的PTO膜的生长速率更高,这是由于TiO2膜的生长速率更高,导致快速炉退火后的PTO膜密度更小,膜内和膜表面的微孔密度更高。慢炉退火改善了PTO薄膜的表面形貌,降低了微孔密度。沉积后退火将非晶膜转变为具有a轴优先结晶取向的钙钛矿结构的多晶膜。
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引用次数: 0
Two-Phase Driving Type Piezoelectric Gyro-Moment Motor 两相驱动型压电陀螺力矩电机
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393405
K. Kanayama, M. Hasegawa, Y. Tomikawa
This paper describes a new gyro-moment motor which utilizes two phase driving. Driving force is generated by two pairs of piezoelectric ceramic plates. They are attached to a cross-shaped vibrator plate which is made of stainless steel. As a direct torque transmission shaft is not necessary for a gyro-moment motor, it is free from a problem of mechanical friction of bearings. Accordingly, it is expected inherently to use as a high speed and low torque motor. But the former gyro-moment motor dealt with in the reference [1] has not been able to change its rotating direction and to make starting the motor. We here resolved these defects by adopting two-phase driving structure, and obtained following results. The first advantage of this motor is to be able to change its rotating direction, in other words, to rotate in CW or CCW direction. The second is to achieve starting the motor without mechanical triggering.
本文介绍了一种采用两相驱动的新型陀螺力矩电机。驱动力由两对压电陶瓷板产生。它们连接在不锈钢制成的十字形振动板上。由于直接转矩传动轴对陀螺力矩电机来说是不必要的,因此它不存在轴承的机械摩擦问题。因此,它被期望固有地用作高速和低转矩电机。但文献[1]中所处理的原陀螺力矩电机不能改变其旋转方向,不能使电机起动。本文采用两相驱动结构解决了这些缺陷,得到了以下结果:这种电机的第一个优点是能够改变其旋转方向,换句话说,可以在连续或连续方向上旋转。二是实现无机械触发起动电机。
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引用次数: 0
Sputtering (103) Oriented AlN and its SAW Properties Analysis 溅射(103)取向AlN及其SAW性能分析
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393398
Zhi-Xun Lin, Sean Wu, R. Ro, Maw-Shung Lee
In this research, the (103) oriented AIN films were successfully sputtered on silicon to be a new composite surface acoustic wave (SAW) substrate. The crystalline structure of the films was determined by grazing incident angle X-ray diffraction (XRD) and the Full-Width Half-Maximum (FWHM) value of the (103) XRD peak was 0.288deg. The SAW properties of the (103) oriented AIN films on silicon had been theoretically analyzed. The simulation results showed the maximum Rayleigh velocity was about 5626 m/s and the maximum electromechanical coupling constant (K) was about 0.61%. It was found those SAW parameters of the (103)AlN/Si structure surpassed the ones of the (002)AlN/Si structure. The (103) oriented AIN films on silicon is a promising candidate applicable for the design of SAW devices.
在本研究中,成功地将(103)取向的AIN薄膜溅射到硅上,作为一种新的复合表面声波(SAW)衬底。通过掠入射x射线衍射(XRD)测定了薄膜的晶体结构,XRD峰(103)的全宽半最大值(FWHM)值为0.288°。本文从理论上分析了(103)取向的氮化硅薄膜的SAW性能。仿真结果表明,最大瑞利速度约为5626 m/s,最大机电耦合常数K约为0.61%。结果表明,(103)AlN/Si结构的SAW参数优于(002)AlN/Si结构。在硅上制备(103)取向的AIN薄膜是一种很有前途的SAW器件设计候选材料。
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引用次数: 2
Longitudinal Displacement Measurement of Lead Zirconate Titanate Thick Films Deposited on Silicon substrates 硅衬底上锆钛酸铅厚膜的纵向位移测量
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393223
T. Iijima, H. Okino, T. Yamamoto
10-mum-thick PZT films were deposited on the Pt/Ti/SiO2/Si substrates, and 20-to 500-mum-diameter PZT thick film disks on the Si substrate were fabricated. the butterfly shape displacement curves of the top side, bottom side and subtraction of bottom side from top side were measured with twin-beam interferometer, and the effect of the disk diameter on these displacements were compared with FEM simulation. the clamping effect is eliminated when the ratio of the PZT disk diameter, d, to the PZT film thickness, t, is less than three, that is dlt < 3, for 10-mum-thick PZT film. therefore, the actual longitudinal displacement of the PZT films can be evaluated for dlt < 3.
在Pt/Ti/SiO2/Si衬底上沉积了10 μ m厚的PZT薄膜,在Si衬底上制备了20 ~ 500 μ m直径的PZT厚膜盘。利用双光束干涉仪测量了蝶形位移曲线的上、下、下与上相减,并与有限元模拟比较了圆盘直径对蝶形位移的影响。当PZT圆盘直径d与PZT薄膜厚度t之比小于3,即对于10 μ m厚的PZT薄膜,dlt < 3时,夹紧效应消除。因此,当dlt < 3时,可以评估PZT薄膜的实际纵向位移。
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引用次数: 0
Nonlinear Dielectric Bahaviour of Metal/Ferroelectric/Metal and Metal/Ferroelectric/Semiconductor-Heterostructures 金属/铁电/金属和金属/铁电/半导体异质结构的非线性介电行为
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393217
K. Barz, M. Diestelhorst, H. Beige, L. Geske, M. Alexe, D. Hesse
The influence of size effects and of the microstructure of interfaces and thin films on the linear properties of ferroelectrics is presently a widely studied topic world-wide. However, their influence on nonlinear properties of nanoscaled ferroelectrics is widely unknown. The paper is devoted to the well-defined preparation of nanoscaled ferroelectrics and to investigations into the influence of size and microstructure effects on their nonlinear properties. Different metal/ferroelectric/metal-(MFM) and metal/ferroelectric/semiconductor-(MFS) heterostructures were prepared. The ferroelectric materials used are PZT and bismuth titanate. The nonlinear dielectric properties where analyzed by inspecting the amplitude-frequency-characteristics of a nonlinear series resonance circuit, which contained the heterostructures as nonlinear capacitance.
尺寸效应以及界面和薄膜的微观结构对铁电体线性性能的影响是目前世界范围内广泛研究的课题。然而,它们对纳米铁电体非线性特性的影响却鲜为人知。本文研究了纳米铁电体的制备方法,并研究了尺寸和微观结构对其非线性性能的影响。制备了不同的金属/铁电/金属-(MFM)和金属/铁电/半导体-(MFS)异质结构。所使用的铁电材料是PZT和钛酸铋。通过检测含异质结构非线性电容的非线性串联谐振电路的幅频特性,分析了电路的非线性介电特性。
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引用次数: 0
Gradient free sol-gel Pb(Zrx, Ti1-x)O3 thin films 梯度自由溶胶-凝胶Pb(Zrx, Ti1-x)O3薄膜
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393173
F. Calame, P. Muralt
Pb(Zrx,Ti1-x)O3 thin films of homogeneous composition were synthesized by means of a modified sol-gel route on Pt(111)/TiOx/SiO2/Si substrates. The usually observed gradient in B-site composition could be reduced from plusmn12 to plusmn2.5 at% amplitude in Zr concentration fluctuations. The obtained 2 mum thick, dense and crack free films exhibited a {100}-texture index of 98.4%. Grain diameters increased at the same time by 50%. Dielectric and piezoelectric properties were remarkably improved. The relative dielectric constant epsiv33f was obtained as 1620, and the remanent transverse piezoelectric coefficient e31f-was measured as -17.7 C/m2.
采用溶胶-凝胶法在Pt(111)/TiOx/SiO2/Si衬底上合成了Pb(Zrx,Ti1-x)O3薄膜。在Zr浓度波动中,通常观察到的b位组成梯度可以在%振幅下从plusmn12降低到plusmn2.5。得到的2个厚、密、无裂纹薄膜的织构指数为98.4%。同时,晶粒直径增加了50%。介质和压电性能显著提高。得到了相对介电常数epsi33f为1620,剩余横向压电系数e31f为-17.7 C/m2。
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引用次数: 1
A Novel Technique for the Determination of Thermal Diffusivities and Conductivities and its Application to Porous PZT Samples 一种测定热扩散系数和导热系数的新技术及其在多孔PZT样品中的应用
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393409
Sidney B. Lang, E. Ringgaard
A modification of a technique for the measurement of the thermal diffusivity of thin solid materials is presented. It is based on the measurement of the phase retardation of a thermal wave passing through the test material by means of a PZT pyroelectric detector. It is not necessary to know either the pyroelectric coefficient of the detector or the intensity of the laser beam. The technique was applied to the study of several sets of Ferroperm Pz27 ceramic samples with porosities of 20, 25 and 30%. One sample set was poled and the pores were partially filled with the fluid using during poling. A second set was not poled. Scanning electron micrographs indicated that the 20 and 25% samples had 0-3 connectivity with a small amount of 3-3 connectivity. The connectivity of the 30% porosity sample was almost completely 3-3. The heat capacity of the Pz27 was determined in order that thermal conductivities could be calculated. The poled porous samples had thermal conductivities intermediate between that of a commercial dense Pz27 sample and those of unpoled materials.
提出了一种测量固体薄材料热扩散率的改进方法。它是基于用PZT热释电探测器测量通过测试材料的热波的相位延迟。不需要知道探测器的热释电系数,也不需要知道激光束的强度。应用该技术对多孔率分别为20%、25%和30%的Pz27铁陶瓷样品进行了研究。一组样品被极化,孔隙被部分填充在极化过程中使用的流体。第二局没有被淘汰。扫描电镜图显示,20%和25%样品具有0-3连通性,少量3-3连通性。30%孔隙度样品的连通性几乎完全为3-3。测定了Pz27的热容,以便计算导热系数。极化多孔样品的热导率介于商业致密Pz27样品和未极化材料之间。
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引用次数: 0
Properties of MOD-derived SrBi2Ta2O9 thin films crystallized in an electric field mod衍生SrBi2Ta2O9薄膜在电场中结晶的性质
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393186
C. Leu, Tzong-Dar Wu, F. Hsu
SrBi2Ta2O9 (SBT) films with thickness of about 200 nm were prepared on Pt/Ta/SiO2/Si substrates by metal-organic decomposition (MOD) method. A high electric field (250 kV/cm) was applied to SBT film during 750degC furnace annealing in atmosphere for 40 min. This applied electric field does some impacts on the microstructures and electrical properties of SBT regardless of the states of electric field. Under an electric field, the films exhibited stronger a/b-axis preferential orientation in Bismuth-layered structure (BLS) phase and a little higher ratio of second phase. In addition, parts of the granular grains grew into rod-like grains. As a result, the electrical properties of SBT thin films were improved by the application of electric field.
采用金属有机分解(MOD)方法在Pt/Ta/SiO2/Si衬底上制备了厚度约200 nm的SrBi2Ta2O9 (SBT)薄膜。对SBT薄膜施加250 kV/cm的高电场,在750℃的炉内气氛退火40 min,无论电场状态如何,都对SBT薄膜的组织和电学性能有一定的影响。在电场作用下,薄膜在铋层状结构(BLS)相中表现出较强的a/b轴优先取向,第二相的比例略高。另外,部分颗粒发育成棒状颗粒。结果表明,电场的作用改善了SBT薄膜的电学性能。
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引用次数: 0
Phase Transformation Sequences in As-Grown PZN-4.5%PT Single Crystals 生长PZN-4.5%PT单晶的相变序列
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393329
W. Chang, L.C. Li, P. Yang, H. Moser, F.-T. Wang, C.-T. Tseng, C. Tu
The phase transformation sequence in as-grown PZN-4.5%PT single crystal has been investigated by means of dielectric permittivity measurements and high-resolution synchrotron x-ray diffraction. The results show that the crystal undergoes the R-T(R)-Mc-C transformation path during zero-field heating from 25degC to 160degC, where R, T, Mc and C are the rhombohedral, tetragonal, Mc-type monoclinic, and cubic phases, respectively. 'T(R)" represents that dominant T domains coexist with smaller fraction of R domains. Our results indicate that both the R-T and R-Mc transformations are first-order, while the T-Mc-C transformation is second-order in nature.
采用介电常数测量和高分辨率同步加速器x射线衍射研究了生长PZN-4.5%PT单晶的相变顺序。结果表明:在25℃至160℃的零场加热过程中,晶体经历了R-T(R)-Mc-C相变过程,其中R、T、Mc和C分别为菱面体相、四方相、Mc型单斜相和立方相。“T(R)”表示优势的T域与较小比例的R域共存。我们的结果表明,R-T和R-Mc变换都是一阶的,而T-Mc-C变换本质上是二阶的。
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引用次数: 0
Design and Simulation of Ultrasonic Linear Motor using Multilayer Ceramic Actuator 多层陶瓷作动器超声直线电机的设计与仿真
Pub Date : 2007-05-27 DOI: 10.1109/ISAF.2007.4393404
J. Yoo, Sang-ho Lee, Jaeil Hong, H. Song, Durkwon Park, Eunsang Hwang
In comparison with conventional electromagnetic motors, ultrasonic motors have many advantages such as a large torque at the low velocity, good controllability, rapid response, quiet operation, simple structure and non electromagnetic field induction, etc. These features have led to the development of various ultrasonic motors in many industrial fields. Hence, in this study, ultrasonic linear motor using multilayer structured ceramic actuator was designed and simulated using ANSYS of finite element method(FEM) simulator for investigating the optimum conditions of it. The ultrasonic linear motor studied in this paper was designed using the 1st longitudinal (L1) and 4th bending (B4) vibration. The size of ceramic actuator is 15 mm long and 5 mm wide. And one-layer thickness of actuator is 60 mu m. The dimension of linear motor is 61 times 5 times 3 mm. The sectional size of projection is 1.5 times 5 mm. The driving voltage of the motor was very low as 5 Vrms. With the increase of the number of piezoelectric ceramic layers, displacement of node was increased up to 21 layered ceramic actuator and then decreased. Maximum z displacement of node was about 7.02 mum at the 21 layered ultrasonic motor.
与传统电磁电机相比,超声波电机具有低速转矩大、可控性好、响应快、运行安静、结构简单、无电磁场感应等优点。这些特点导致了各种超声波电机在许多工业领域的发展。为此,本研究对多层陶瓷作动器的超声直线电机进行了设计和仿真,并利用有限元仿真软件ANSYS对其进行了仿真,探讨了多层陶瓷作动器的最佳工作条件。本文所研究的超声波直线电机采用第一次纵向振动(L1)和第4次弯曲振动(B4)进行设计。陶瓷执行器的尺寸为长15mm,宽5mm。执行器单层厚度为60 μ m,直线电机尺寸为61 × 5 × 3mm。投影截面尺寸为1.5 × 5mm。电机的驱动电压很低,只有5 Vrms。随着压电陶瓷层数的增加,节点位移增大到21层后减小。在21层超声电机中,节点的最大z位移约为7.02 mum。
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引用次数: 2
期刊
2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics
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