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Sustainable basalt fiber reinforced polyamide 6,6 composites: Effects of fiber length and fiber content on mechanical performance 可持续玄武岩纤维增强聚酰胺 6,6 复合材料:纤维长度和纤维含量对机械性能的影响
IF 5.3 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-07-01 DOI: 10.1016/j.jcomc.2024.100495
Zavier Blackman , Kehinde Olonisakin , Hugh MacFarlane , Arturo Rodriguez-Uribe , Neelima Tripathi , Amar K. Mohanty , Manjusri Misra

The aim of this study is to explore the use of sustainable basalt fiber (BF) as compared to glass fiber and talc in injection molded engineering polyamide 6,6 (PA 6,6) plastic composite. Basalt fibers having lengths of 3 mm and 12 mm were added to PA 6,6 at 23 and 30 wt.% to fabricate the composites. The addition of basalt fiber restricts the mobility of the polymer chain in the composites, leading to its increased viscosity. Rheological results showed that the out-of-phase response to the applied stress indicated that the 3 mm basalt fiber composite could dissipate more energy, and the elastic behaviour of the composite under deformation increased with increasing basalt fiber wt.%. The fiber length had a larger effect on the mechanical properties of the composites as compared to the fiber load. The 12 mm basalt fiber composites at 23 wt.% and 30 wt.% produced higher tensile strength and modulus than the 3 mm basalt fiber composites while the 3 mm basalt fiber composite at 30 wt.% resulted in a 25 % increase in flexural strength. The experimental and the theoretical modulus predicted by the rule of mixtures showed an interaction between the matrix and the basalt fiber. Morphological analysis shows more agglomeration in composites with 3 mm fiber than the 12 mm. Glass fiber-reinforced PA 6,6 showed slightly higher performance than basalt fiber-reinforced PA 6,6. However, the basalt fiber-reinforced composites demonstrated better performance in tensile strength, flexural modulus, flexural strength, and heat deflection temperature than talc-reinforced composites.

本研究旨在探讨在注塑工程聚酰胺 6.6(PA 6.6)塑料复合材料中使用可持续玄武岩纤维(BF)与玻璃纤维和滑石粉的比较。在 PA 6,6 中加入长度为 3 毫米和 12 毫米的玄武岩纤维,重量分别为 23%和 30%,以制造复合材料。玄武岩纤维的加入限制了复合材料中聚合物链的流动性,导致其粘度增加。流变学结果表明,对外加应力的相外响应表明,3 毫米的玄武岩纤维复合材料可以耗散更多的能量,而且复合材料在变形时的弹性表现随着玄武岩纤维重量百分比的增加而增强。与纤维载荷相比,纤维长度对复合材料机械性能的影响更大。重量百分比为 23% 和 30% 的 12 毫米玄武岩纤维复合材料的拉伸强度和模量均高于 3 毫米玄武岩纤维复合材料,而重量百分比为 30% 的 3 毫米玄武岩纤维复合材料的抗弯强度提高了 25%。实验模量和根据混合物规则预测的理论模量表明,基体和玄武岩纤维之间存在相互作用。形态分析表明,3 毫米纤维的复合材料比 12 毫米纤维的复合材料更容易团聚。玻璃纤维增强 PA 6,6 的性能略高于玄武岩纤维增强 PA 6,6。不过,玄武岩纤维增强复合材料在拉伸强度、弯曲模量、弯曲强度和热变形温度方面的性能均优于滑石粉增强复合材料。
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引用次数: 0
Investigating the impact of cross-sectional area on the crushing characteristics of axially-loaded hemispherical composite shells 研究横截面积对轴向加载半球形复合材料壳体破碎特性的影响
IF 5.3 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-07-01 DOI: 10.1016/j.jcomc.2024.100479
Aamir Dean , Elsadig Mahdi

The research focus has shifted towards lightweight structures with high energy absorption capabilities due to advancements in automotive safety technology. This study specifically investigates the impact of cross-sectional area on the energy absorption characteristics of hemispherical composite shells. The experimental phase involves characterizing a glass fiber epoxy composite, followed by the manufacture of hemispherical composite shell specimens with varying cross-sectional areas. These specimens undergo quasi-static axial compressive loading, and the energy absorption parameters are analyzed. The results indicate a significant influence of the composite cross-sectional area on the crushing behavior of hemispherical shells, with a observed decrease in specific energy absorption as the cross-sectional area increases. Additionally, a 3D Finite Element (FE) model is created using ABAQUS FE code to numerically simulate the crushing process. The model’s predictions are compared and validated against experimentally measured values, demonstrating a satisfactory correlation.

由于汽车安全技术的进步,研究重点已转向具有高能量吸收能力的轻质结构。本研究专门探讨了横截面积对半球形复合材料壳体能量吸收特性的影响。实验阶段包括对玻璃纤维环氧树脂复合材料进行表征,然后制造具有不同横截面积的半球形复合材料壳体试样。对这些试样进行准静态轴向压缩加载,并对能量吸收参数进行分析。结果表明,复合材料横截面积对半球形壳体的挤压行为有显著影响,可以观察到随着横截面积的增大,比能量吸收也随之减小。此外,还使用 ABAQUS FE 代码创建了三维有限元 (FE) 模型,对挤压过程进行数值模拟。该模型的预测值与实验测量值进行了比较和验证,显示出令人满意的相关性。
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引用次数: 0
Analytical and numerical analysis of composite sandwich structures with additively manufactured lattice cores 带有添加式制造晶格芯材的复合材料夹层结构的分析和数值分析
IF 5.3 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-07-01 DOI: 10.1016/j.jcomc.2024.100484
Emre Dereli , Jordy Mbendou II , Vidhin Patel , Christian Mittelstedt

In this study, an analytical and numerical analysis of a hybrid sandwich structure with a lattice core produced by additive manufacturing with composite facesheets is carried out. This paper aims to analytically calculate the mechanical behavior of the hybrid sandwich structure under three-point bending and to verify the results by the finite element method. The analytical method used in this article for the analysis of the composite sandwich structure is the First-Order Shear Deformation Theory (FSDT). The numerical analysis of the hybrid sandwich structure was performed in ANSYS. In the analyses, homogenized models of lattice structures, which had been previously validated, were employed to reduce the number of elements and thereby save time during the solution process. As a result of the study, an extensive investigation into the deformation, shear, and normal stress values of sandwich structures with lattice cores of varying aspect ratios has been carried out. The findings suggest a potential for optimization in lightweight structures, which could lead to innovative advancements in design and manufacturing processes within the aerospace and automotive sectors.

在本研究中,我们对通过增材制造技术生产的带有复合材料面片的晶格核心的混合夹层结构进行了分析和数值分析。本文旨在分析计算混合夹层结构在三点弯曲下的力学行为,并通过有限元法对结果进行验证。本文用于分析复合材料夹层结构的分析方法是一阶剪切变形理论(FSDT)。混合夹层结构的数值分析在 ANSYS 中进行。在分析过程中,采用了之前已经验证过的均匀化晶格结构模型,以减少元素数量,从而在求解过程中节省时间。通过这项研究,我们对具有不同长宽比晶格核心的夹层结构的变形、剪切和法向应力值进行了广泛的调查。研究结果表明,轻质结构具有优化的潜力,可为航空航天和汽车行业的设计和制造工艺带来创新性的进步。
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引用次数: 0
Nano silver composite hydroxyethyl methacrylate/vinylpyrrolidone hydrogel: Tissue adhesives with antibacterial properties 纳米银复合羟乙基甲基丙烯酸酯/乙烯基吡咯烷酮水凝胶:具有抗菌性能的组织粘合剂
IF 5.3 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-07-01 DOI: 10.1016/j.jcomc.2024.100498
Junfang Cheng , Jiaxin Han , Chang Xu , Hao Zhang , Xufeng Dong , Xijing Zhuang , Min Qi

Bacterial wound infections are prevalent in daily life. However, conventional tissue adhesives lack antimicrobial properties. In this study, a redox method was employed to prepare a nano-silver solution with tannic acid as a dispersant. Subsequently, the nano-silver solution was combined with the precursor solution of the hydroxyethyl methacrylate/vinylpyrrolidone (HEMA/NVP) hydrogel. Finally, it was put under ultraviolet light to produce the hydrogel. The hydrogel exhibits remarkable extendibility (1223 %), an elastic modulus compatible with human skin tissue (3.7 ± 0.5 kPa), the strong adhesion to porcine skin tissue (24.67 ± 1.15 kPa) markedly exceeds that achieved by clinically utilized fibrin glue, low swelling ratio (75 ± 1.55 %), and demonstrates good in vitro antimicrobial properties against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Furthermore, it displays excellent biocompatibility with fibroblast cells (NIH/3T3) with cell viability above 80 %, favorable blood compatibility with goat blood, and moderate coagulation ability. It provides more possibilities for clinical wound repair.

细菌性伤口感染在日常生活中十分普遍。然而,传统的组织粘合剂缺乏抗菌性能。本研究采用氧化还原法制备了以单宁酸为分散剂的纳米银溶液。然后,将纳米银溶液与羟乙基甲基丙烯酸甲酯/乙烯基吡咯烷酮(HEMA/NVP)水凝胶的前体溶液混合。最后,将其置于紫外线下照射,制成水凝胶。该水凝胶具有显著的延展性(1223 %),弹性模量与人体皮肤组织相容(3.7 ± 0.5 kPa),与猪皮肤组织的强粘附性(24.67 ± 1.15 kPa),明显超过临床使用的纤维蛋白胶,膨胀率低(75 ± 1.55 %),对大肠杆菌(E. coli)和金黄色葡萄球菌(S. aureus)具有良好的体外抗菌特性。此外,它与成纤维细胞(NIH/3T3)的生物相容性极佳,细胞存活率超过 80%,与山羊血的血液相容性良好,凝血能力适中。它为临床伤口修复提供了更多可能性。
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引用次数: 0
Permeability and barrier layer properties of a woven carbon fibre polymer composite as battery packaging 用作电池封装的碳纤维聚合物编织复合材料的透气性和阻隔层性能
IF 5.3 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-07-01 DOI: 10.1016/j.jcomc.2024.100490
K. Pattarakunnan , J. Galos , W. Tian , A.S. Best , I.L. Kyratzis , A .P. Mouritz

Carbon fibre reinforced polymer (CFRP) laminates are used in various studies as Li-ion polymer (LiPo) battery packaging. However, their suitability as a packaging material is not well understood. The present study investigates the liquid absorption (water and lithium bis(trifluoromethanesulfonic)imide (LiTFSI) electrolyte immersion tests) and barrier layer properties (water vapour transmission rate (WVTR) and oxygen transmission rate (OTR) tests) of a 200 gsm woven CFRP laminate to assess its suitability as a battery packaging material. This is the first study to show that prolonged immersion in battery electrolyte does not change the mechanical properties of a woven CFRP laminate. Hence, the CFRP laminate may be suitable for structural battery components, such as current collectors and electrodes. However, CFRP should not be used as battery packaging, as OTR and WVTR values of the CFRP laminate were found to be five and one order of magnitudes higher than typical battery pouch materials (i.e. aluminium foil), respectively.

在多项研究中,碳纤维增强聚合物(CFRP)层压板被用作锂离子聚合物(LiPo)电池的包装材料。然而,人们对其作为包装材料的适用性还不甚了解。本研究调查了 200 克/平方米编织 CFRP 层压板的液体吸收性(水和双(三氟甲磺酸)亚胺锂(LiTFSI)电解液浸泡测试)和阻隔层特性(水蒸气透过率(WVTR)和氧气透过率(OTR)测试),以评估其作为电池包装材料的适用性。这是首次研究表明,长期浸泡在电池电解液中不会改变编织 CFRP 层压板的机械性能。因此,CFRP层压板可能适用于电池结构部件,如集流体和电极。但是,CFRP 不宜用作电池包装,因为研究发现 CFRP 层压材料的 OTR 值和 WVTR 值分别比典型的电池袋材料(即铝箔)高出五个和一个数量级。
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引用次数: 0
Investigation and calculation of the longitudinal compressive strength of unidirectional glass fiber reinforced polymer considering the fiber orientation distribution 考虑纤维取向分布的单向玻璃纤维增强聚合物纵向抗压强度的研究与计算
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-06-07 DOI: 10.1016/j.jcomc.2024.100480
Tom Blümel , Rabea Klara Sahr , Alexander Krimmer , Andreas Bardenhagen

In this study, undulations and their influence on the longitudinal compressive strength of a unidirectional glass fiber reinforced polymer (GFRP) composite are investigated theoretically and experimentally. The objective of this research is to explore the failure mechanisms in FRP and to characterize the mechanical properties of FRP as a function of fiber orientation. For this purpose, a multiscale material model is developed that considers a stochastic fiber orientation distribution (FOD) and models matrix fracture-initiated failure. The relationship between compressive strength and undulation is investigated experimentally on standardized specimens made of unidirectional GFRP. The fiber orientations are measured using X-ray computed tomography and ImageJ image analysis, resulting in a binormal distribution of fiber orientations in the series of samples tested. To examine the failure process in detail, the compression tests are simulated using finite element analysis (FEA). Both the FEA results and the measured compressive strengths confirm the model assumption of matrix fracture-initiated failure under longitudinal compressive loading. The presented analytical model realistically represents the correlation of compressive strength with the FOD.

本研究通过理论和实验研究了单向玻璃纤维增强聚合物(GFRP)复合材料的起伏及其对纵向抗压强度的影响。这项研究的目的是探索玻璃纤维增强塑料的失效机理,并描述玻璃纤维增强塑料的机械性能与纤维取向的函数关系。为此,建立了一个多尺度材料模型,该模型考虑了随机纤维取向分布 (FOD),并对基体断裂引发的失效进行了建模。通过对单向 GFRP 标准试样进行实验,研究了抗压强度与起伏之间的关系。使用 X 射线计算机断层扫描和 ImageJ 图像分析法测量了纤维取向,结果在一系列测试样品中得出了纤维取向的二正态分布。为了详细研究破坏过程,使用有限元分析(FEA)对压缩试验进行了模拟。有限元分析结果和测得的压缩强度都证实了在纵向压缩加载下基体断裂引发破坏的模型假设。所提出的分析模型真实地反映了抗压强度与 FOD 的相关性。
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引用次数: 0
Experimental method for investigating the dynamic compression behaviour of fibre-reinforced polyurethane shoe press belts under press nip conditions 在压区条件下研究纤维增强聚氨酯鞋压带动态压缩行为的实验方法
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-30 DOI: 10.1016/j.jcomc.2024.100476
Patrick Wegele , L. Daniel Söderberg

An experimental method was developed to examine the dynamic compression properties of structured polyurethane composites used as press belts within a shoe press of a paper machine. The objective was to investigate the influences of the geometrical surface structure and the matrix material composition on the compression properties. Two polyurethane formulations were tested under varying specimen conditions. The results show that the dynamic compression modulus increases with the applied load rate and that temperature and water saturation reduce the influence of dynamic effects on the compression modulus. Furthermore, it was observed that modifications of the matrix material have a more significant impact on the dynamic compression modulus than adaptions in the geometrical structure. This is addressed to the relatively small variations in possible surface designs. Finally, a rate-sensitivity index is introduced to quantify the tested specimens’ rate-sensitive behaviour.

我们开发了一种实验方法,用于研究在造纸机的压鞋机中用作压带的结构化聚氨酯复合材料的动态压缩性能。目的是研究几何表面结构和基体材料成分对压缩性能的影响。在不同的试样条件下测试了两种聚氨酯配方。结果表明,动态压缩模量随施加载荷速率的增加而增加,温度和水饱和度降低了动态效应对压缩模量的影响。此外,还观察到基体材料的改性比几何结构的改性对动态压缩模量的影响更大。这是因为可能的表面设计变化相对较小。最后,引入了速率敏感性指数来量化测试试样的速率敏感性。
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引用次数: 0
Multi-objective optimization of turning process parameters and wood sawdust contents using response surface methodology for the minimized surface roughness of recycled plastic/wood sawdust composites 利用响应面方法对车削工艺参数和木锯屑含量进行多目标优化,以最大限度降低再生塑料/木锯屑复合材料的表面粗糙度
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-27 DOI: 10.1016/j.jcomc.2024.100477
Chainarong Srivabut , Surasit Rawangwong , Salim Hiziroglu , Chatree Homkhiew

The objective of this work was to investigate the effect and optimization of turning parameters such as spindle speed, feed rate, and depth of cut as well as wood sawdust content on the roughness quality of wood-plastic composites (WPCs). The Box–Behnken design and response surface methodology were used in experiments. Three roughness parameters, namely average roughness (Ra), root mean square average of roughness (Rq), and average maximum height (Rz) were employed to evaluate the surface quality of WPC samples. Based on the findings of the experiments, the Ra, Rq, and Rz values reduced with increasing spindle speed in a range of 430 to 1030 rpm, whereas the values increased when increasing the feed rate in a range of 0.05 to 0.15 mm/min. Also, an increase in depth of cut ranging from 1 to 3 mm and WPCs with a higher amount of wood sawdust in a range of 30 to 50 wt% raised their surface roughness. Finally, optimal conditions for the turning of the WPCs were determined to comprise a spindle speed of 781 rpm, a feed rate of 0.05 mm/min, a depth of cut of 2.8 mm, and wood sawdust content of 30 wt% with the highest desirability score of 1.000. Under such conditions, the sample had Ra, Rq, and Rz values of 1.8, 2.2, and 11.3 µm, respectively. The optimal conditions for turning can be used to effectively process different WPC products into various shapes.

这项工作的目的是研究主轴转速、进给速度、切削深度以及木锯屑含量等车削参数对木塑复合材料(WPC)粗糙度质量的影响和优化。实验采用了盒式贝肯设计和响应面方法。采用三个粗糙度参数,即平均粗糙度(Ra)、粗糙度均方根平均值(Rq)和平均最大高度(Rz)来评估木塑复合材料样品的表面质量。根据实验结果,Ra、Rq 和 Rz 值随着主轴转速在 430 至 1030 转/分钟范围内的增加而降低,而当进给量在 0.05 至 0.15 毫米/分钟范围内增加时,Ra、Rq 和 Rz 值则增加。此外,切削深度增加 1 至 3 毫米,木锯末含量增加 30 至 50 wt%,都会提高木塑的表面粗糙度。最后,确定了车削木塑的最佳条件:主轴转速为 781 rpm,进给速度为 0.05 mm/min,切削深度为 2.8 mm,木锯末含量为 30 wt%,最高理想分数为 1.000。在这种条件下,样品的 Ra、Rq 和 Rz 值分别为 1.8、2.2 和 11.3 µm。车削的最佳条件可用于有效地将不同的木塑产品加工成各种形状。
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引用次数: 0
Numerical modelling of the ballistic impact response of hybrid composite structures 混合复合材料结构弹道冲击响应的数值模拟
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-23 DOI: 10.1016/j.jcomc.2024.100474
L. Peng , J. Zhou , Q.Y. Wang , X.F. Zhang , Z.W. Guan

This paper presents numerical modelling of the ballistic impact response of hybrid laminated structures, which are developed through combinations of ceramics, Ultra-High-Molecular-Weight Polyethylene (UHMWPE), Kevlar and compressed wood. It is, for the first time, to embed the compressed wood in the ballistic panel and numerically investigate the impact response of the hybrid structures made of the multiple constituent materials. Different constitutive models and the related failure criteria were employed in the modelling to capture the ballistic responses of the constituent materials and hybrid structures. The numerical simulations were compared with the corresponding experimental results with acceptable correlation. The essential features of the hybrid composite structures subjected to high velocity impact were simulated by the finite element (FE) models, such as deformation and failure modes, back-face signature and the residual velocities. The FE models developed are ready to be used to assist design lightweight composite armour with optimized ballistic resistance and self-weight.

本文对混合层压结构的弹道冲击响应进行了数值建模,该结构由陶瓷、超高分子量聚乙烯(UHMWPE)、凯夫拉尔纤维和压缩木材组合而成。这是首次在弹道板中嵌入压缩木材,并对由多种组成材料制成的混合结构的冲击响应进行数值研究。建模中采用了不同的构成模型和相关的失效标准,以捕捉组成材料和混合结构的弹道响应。数值模拟结果与相应的实验结果进行了比较,相关性可以接受。有限元(FE)模型模拟了受到高速撞击的混合复合材料结构的基本特征,如变形和破坏模式、背面特征和残余速度。所开发的有限元模型可用于协助设计具有优化抗弹性和自重的轻质复合装甲。
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引用次数: 0
Fire behaviour of biochar-based cementitious composites 生物炭水泥基复合材料的防火性能
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-20 DOI: 10.1016/j.jcomc.2024.100471
Rhoda Afriyie Mensah , Dong Wang , Vigneshwaran Shanmugam, Gabriel Sas, Michael Försth, Oisik Das

The study aimed to test the hypothesis that biochar's unique properties, such as its microporous structure, can enhance concrete's resilience to high temperatures. Despite expectations of reduced crack formation and enhanced fire resistance, the experimental results revealed a limited impact on concrete's fire behaviour. The investigation involved the use of two biochar types, fine and coarse biochar as replacements for cement and aggregates, respectively. Fine biochar exhibited higher water absorption and Young's modulus than coarse biochar, but both resisted ignition at 35 kW/m2 radiative heat flux and had peak heat release rates below 40 kW/m2. Incorporating these biochars at varying weight percentages (10, 15, and 20 wt.%) into concrete led to a gradual decline in compressive and tensile strength due to reduced binding ability with increased biochar content. Exposure to 1000 °C compromised mechanical properties across all the samples. However, the biochar concrete maintained compressive strength (compared to the control) with up to 20 wt.% biochar as a fine aggregate substitute after exposure to 600 °C, and as a cement replacement after exposure to 200 °C. This substitution also yielded a significant reduction in CO2 emissions (50 % reduction as the biochar loading amount doubled) from concrete manufacturing, showcasing biochar's potential for sustainable construction practices. Despite not fully supporting the initial hypothesis, the study demonstrated biochar's viability in reducing carbon footprint while maintaining concrete strength under certain fire conditions.

该研究旨在验证生物炭的独特特性(如微孔结构)可以增强混凝土耐高温能力的假设。尽管预期会减少裂缝的形成并增强耐火性,但实验结果表明,生物炭对混凝土的耐火性能影响有限。调查涉及使用两种生物炭,即细生物炭和粗生物炭,分别替代水泥和集料。细生物炭的吸水率和杨氏模量高于粗生物炭,但两者在 35 kW/m2 的辐射热通量下都能阻燃,且峰值热释放率低于 40 kW/m2。将这些生物炭以不同的重量百分比(10、15 和 20 wt.%)掺入混凝土中会导致抗压和抗拉强度逐渐下降,原因是随着生物炭含量的增加,结合能力降低。暴露在 1000 °C 的温度下会影响所有样品的机械性能。然而,与对照组相比,生物炭混凝土在暴露于 600 °C后仍能保持抗压强度(与对照组相比),其中生物炭作为细骨料替代物的含量最高可达 20 wt.%,而作为水泥替代物的生物炭混凝土在暴露于 200 °C后仍能保持抗压强度。这种替代品还显著减少了混凝土生产过程中的二氧化碳排放量(生物炭装载量增加一倍,二氧化碳排放量减少 50%),展示了生物炭在可持续建筑实践中的潜力。尽管这项研究没有完全支持最初的假设,但它证明了生物炭在减少碳足迹方面的可行性,同时还能在特定的火灾条件下保持混凝土强度。
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引用次数: 0
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