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Fire behaviour of biochar-based cementitious composites 生物炭水泥基复合材料的防火性能
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-20 DOI: 10.1016/j.jcomc.2024.100471
Rhoda Afriyie Mensah , Dong Wang , Vigneshwaran Shanmugam, Gabriel Sas, Michael Försth, Oisik Das

The study aimed to test the hypothesis that biochar's unique properties, such as its microporous structure, can enhance concrete's resilience to high temperatures. Despite expectations of reduced crack formation and enhanced fire resistance, the experimental results revealed a limited impact on concrete's fire behaviour. The investigation involved the use of two biochar types, fine and coarse biochar as replacements for cement and aggregates, respectively. Fine biochar exhibited higher water absorption and Young's modulus than coarse biochar, but both resisted ignition at 35 kW/m2 radiative heat flux and had peak heat release rates below 40 kW/m2. Incorporating these biochars at varying weight percentages (10, 15, and 20 wt.%) into concrete led to a gradual decline in compressive and tensile strength due to reduced binding ability with increased biochar content. Exposure to 1000 °C compromised mechanical properties across all the samples. However, the biochar concrete maintained compressive strength (compared to the control) with up to 20 wt.% biochar as a fine aggregate substitute after exposure to 600 °C, and as a cement replacement after exposure to 200 °C. This substitution also yielded a significant reduction in CO2 emissions (50 % reduction as the biochar loading amount doubled) from concrete manufacturing, showcasing biochar's potential for sustainable construction practices. Despite not fully supporting the initial hypothesis, the study demonstrated biochar's viability in reducing carbon footprint while maintaining concrete strength under certain fire conditions.

该研究旨在验证生物炭的独特特性(如微孔结构)可以增强混凝土耐高温能力的假设。尽管预期会减少裂缝的形成并增强耐火性,但实验结果表明,生物炭对混凝土的耐火性能影响有限。调查涉及使用两种生物炭,即细生物炭和粗生物炭,分别替代水泥和集料。细生物炭的吸水率和杨氏模量高于粗生物炭,但两者在 35 kW/m2 的辐射热通量下都能阻燃,且峰值热释放率低于 40 kW/m2。将这些生物炭以不同的重量百分比(10、15 和 20 wt.%)掺入混凝土中会导致抗压和抗拉强度逐渐下降,原因是随着生物炭含量的增加,结合能力降低。暴露在 1000 °C 的温度下会影响所有样品的机械性能。然而,与对照组相比,生物炭混凝土在暴露于 600 °C后仍能保持抗压强度(与对照组相比),其中生物炭作为细骨料替代物的含量最高可达 20 wt.%,而作为水泥替代物的生物炭混凝土在暴露于 200 °C后仍能保持抗压强度。这种替代品还显著减少了混凝土生产过程中的二氧化碳排放量(生物炭装载量增加一倍,二氧化碳排放量减少 50%),展示了生物炭在可持续建筑实践中的潜力。尽管这项研究没有完全支持最初的假设,但它证明了生物炭在减少碳足迹方面的可行性,同时还能在特定的火灾条件下保持混凝土强度。
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引用次数: 0
3D and 4D printing: A review of virgin polymers used in fused deposition modeling 3d 和 4d 打印:熔融沉积建模中使用的原始聚合物综述
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-20 DOI: 10.1016/j.jcomc.2024.100472
Tarig Makki , Suhail Hyder Vattathurvalappil , Rajesh Theravalappil , Aamer Nazir , Ali Alhajeri , Mohammed Abdul Azeem , Elsadig Mahdi , Aniz Chennampilly Ummer , Usman Ali

Recent advancements in additive manufacturing (AM), which includes both three-dimensional (3D) and four-dimensional (4D) printing, have revolutionized manufacturing processes across the board. Fused deposition modeling (FDM) is one of the most widespread 3D printing technique that enables the use of a wide range of virgin polymers and polymer-based composites to meet the demand for high-performance, intelligent, and self-assembling structures. Although polymer-based composites offer a variety of multifunctional properties, it is essential to comprehend the mechanical and microstructural properties of parts printed with virgin polymers to analyze and design the additives and reinforcements required to achieve the optimal desired functionalities. Overall, this review focuses on the adoption and applications of virgin FDM polymers and highlights different virgin polymers and equipment used in 3D and 4D printing. A comparative study on the mechanical and microstructural properties of various FDM polymers is also performed. In addition, this work also covers the state-of-the-art approaches and practices used for 4D printing of polymer-based systems and future directions for this field.

包括三维(3D)和四维(4D)打印在内的增材制造(AM)技术的最新进展彻底改变了整个制造流程。熔融沉积建模(FDM)是最广泛的三维打印技术之一,它可以使用多种原始聚合物和聚合物基复合材料,以满足对高性能、智能化和自组装结构的需求。虽然聚合物基复合材料具有多种多功能特性,但必须了解使用原生聚合物打印的部件的机械和微观结构特性,以便分析和设计所需的添加剂和增强剂,实现所需的最佳功能。总之,本综述侧重于原始 FDM 聚合物的采用和应用,并重点介绍了 3D 和 4D 打印中使用的不同原始聚合物和设备。还对各种 FDM 聚合物的机械和微观结构特性进行了比较研究。此外,这部著作还涵盖了聚合物基系统 4D 打印的最新方法和实践,以及该领域的未来发展方向。
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引用次数: 0
Analysis of bending vibrations of a three-layered pre-twisted sandwich beam with an exact dynamic stiffness matrix 利用精确动态刚度矩阵分析三层预扭夹层梁的弯曲振动
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-19 DOI: 10.1016/j.jcomc.2024.100473
Marziyeh Baziyar Hamzehkhani , Abdolreza Zare , Mohammad Gholami , Mojtaba Gorji Azandariani

This paper presents the novel development of the dynamic stiffness matrix for a three-layered symmetric pre-twisted sandwich beam (PTSB), aiming to investigate its free vibration characteristics. The outer layers of the beam are modeled using the Euler–Bernoulli theory, while the core is assumed to deform solely in shear. The boundary conditions and governing partial differential equations of motion are derived based on Hamilton's principle. By applying harmonic variations of displacements, the governing equations of motion are expressed as a tenth-order equation, which is solved to obtain the desired dynamic stiffness matrix. To compute the natural frequencies of in-plane and out-of-plane free vibration for both uniform and PTSBs, the Wittrick–Williams algorithm is employed. The computed frequencies are compared with the results obtained by other authors as well as those obtained from ABAQUS simulations. Various vibration modes of uniform and twisted sandwich beams are plotted and thoroughly discussed. Interestingly, contrary to straight symmetric sandwich beams, the results indicate that flexural displacements in pre-twisted symmetric sandwich beams exhibit coupling in two planes. Additionally, although there are minor changes in vibration frequencies, the mode shapes undergo significant transformations as the pre-twist angle is altered.

本文介绍了三层对称预扭夹层梁(PTSB)动态刚度矩阵的新发展,旨在研究其自由振动特性。梁的外层采用欧拉-伯努利理论建模,而梁芯则假定只发生剪切变形。根据汉密尔顿原理推导出了边界条件和支配运动的偏微分方程。通过应用位移的谐波变化,将支配运动方程表示为十阶方程,通过求解得到所需的动态刚度矩阵。为了计算均匀和 PTSB 的平面内和平面外自由振动的固有频率,采用了 Wittrick-Williams 算法。计算出的频率与其他学者以及 ABAQUS 仿真得出的结果进行了比较。绘制并深入讨论了均匀和扭曲夹层梁的各种振动模式。有趣的是,与直线对称夹层梁相反,结果表明预扭曲对称夹层梁的挠曲位移在两个平面上表现出耦合。此外,虽然振动频率变化不大,但随着预扭曲角度的改变,模态形状会发生显著变化。
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引用次数: 0
Accelerated seawater ageing and fatigue performance of glass fibre reinforced thermoplastic composites for marine and tidal energy applications 用于海洋和潮汐能应用的玻璃纤维增强热塑性复合材料的加速海水老化和疲劳性能
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-19 DOI: 10.1016/j.jcomc.2024.100470
Danijela Stankovic , Winifred Obande , Machar Devine , Ankur Bajpai , Conchúr M. Ó Brádaigh , Dipa Ray

The use of thermoplastic composites as a sustainable alternative to thermosets is gaining increasing popularity due to their improved recyclability at the end of life. The fatigue performance of glass fibre/acrylic, glass fibre/acrylic- polyphenylene ether, and glass fibre/epoxy specimens, under three distinct upper stress levels (R-ratio = 0.1; f = 5 Hz) was studied. S–N curves were established for these specimens both before and after immersing them for three months in seawater (temperature: 50 °C). The dry thermoplastic composites exhibited similar fatigue performance to the thermoset counterpart at higher stress levels, with thermosets showing greater endurance at lower stress levels. Interestingly, the aged specimens showed comparable fatigue endurance, with a slight advantage in favour of the thermoplastic composites and less variability in their data. This study offers important insights into the fatigue performance of thermoplastic composites, emphasising their potential as sustainable alternatives to conventional thermoset composites for various marine applications.

热塑性复合材料作为热固性材料的可持续替代品,因其在报废时可回收性更强而越来越受欢迎。研究了玻璃纤维/丙烯酸、玻璃纤维/丙烯酸-聚苯醚和玻璃纤维/环氧树脂试样在三种不同的上应力水平(R 比 = 0.1;f = 5 Hz)下的疲劳性能。对这些试样在海水中浸泡三个月(温度:50 °C)前后的 S-N 曲线进行了测定。在较高应力水平下,干热塑性复合材料的疲劳性能与热固性复合材料相似,而在较低应力水平下,热固性复合材料的耐久性更强。有趣的是,老化试样的疲劳耐久性与热塑性复合材料相当,热塑性复合材料略胜一筹,其数据的可变性较小。这项研究为了解热塑性复合材料的疲劳性能提供了重要依据,强调了它们作为传统热固性复合材料的可持续替代品在各种海洋应用中的潜力。
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引用次数: 0
Design and optimisation of a tipping silo semi-trailer by using innovative materials 利用创新材料设计和优化倾卸筒仓半挂车
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-18 DOI: 10.1016/j.jcomc.2024.100469
Luigi Solazzi, Nicola Danzi

This research reports the results of implementation of composite materials and the complete redesign of a tipping silo semi-trailer. The conventional semi-trailer, used for comparison, was designed based on a Feldbinder commercial model, while the innovative one has the same overall dimensions but a new geometry, while maintaining the same performance in terms of deflection and safety factor. The research involves sizing and verification of the results obtained using finite element software (Solidworks Simulation®) with different loading conditions. The main result is that the optimised solution has the lowest weight, with a reduction of about 28 % considering the same equipment and accessories mounted on the two solutions. The last part of the research concerns an estimate of economic investment containing the return on the initial investment and the reduction in fuel consumption by comparing the two solutions. Considering that the vehicle always carries the maximum (payload = 27,500 kg) and the overall weight reduction of about 1800 kg, there is a reduction in fuel consumption for the proposed solution. The return on investment for the new solution occurs between three/four years depending on the number of kilometres driven annually. Finally, the purpose of this paper is to create an example of a procedure for reducing the carbon footprint and the fuel consumption of vehicles by replace and redesign entire mechanical components, in this case industrial vehicles, that would be useful to follow and replicate for any specific case study and increase the eco-sustainability of industrial manufacturers.

本研究报告介绍了采用复合材料和重新设计翻斗筒仓半挂车的结果。用于比较的传统半挂车是根据 Feldbinder 商业模型设计的,而创新型半挂车的总体尺寸相同,但采用了新的几何形状,同时在挠度和安全系数方面保持了相同的性能。研究包括确定尺寸,并使用有限元软件(Solidworks Simulation®)验证在不同负载条件下获得的结果。主要结果是,优化方案的重量最低,在两种方案安装相同设备和附件的情况下,重量减轻了约 28%。研究的最后一部分涉及经济投资估算,包括初始投资回报率和通过比较两种解决方案减少的燃料消耗。考虑到车辆始终携带最大载荷(有效载荷 = 27 500 千克),以及总体重量减少约 1800 千克,建议的解决方案可减少燃料消耗。根据每年行驶的公里数,新解决方案的投资回报期在三到四年之间。最后,本文的目的是通过更换和重新设计整个机械部件(在本例中为工业车辆),创建一个减少碳足迹和车辆油耗的程序范例。
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引用次数: 0
Glass–Carbon–Kevlar fiber reinforced hybrid polymer composite (HPC): Part (A) mechanical and thermal characterization for high GSM laminates 玻璃-碳-凯夫拉纤维增强混合聚合物复合材料(HPC):A 部分:高 GSM 层压材料的机械和热特性分析
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-10 DOI: 10.1016/j.jcomc.2024.100468
Samina Ishtiaq , Muhammad Qaiser Saleem , Rakhshanda Naveed , Muhammad Harris , Sarmad Ali Khan

The quest for light weight hybrid polymer composites (HPC) has resulted into multiple materials and structural configurations for achieving high performance in automotive and aerospace applications. Incidentally, the past reported work has (in general) involved variable GSM while investigating reinforced fiber layers. The variable GSM may lead to a random response of each layer to the applied forces and thermal degradation, due to which attributing the role of various layers to results/properties is difficult to ascertain. This research employs a uniform/consistent approach with high GSM (400) based HPC with multiple stacking sequences of glass (G), carbon (C), and Kevlar (K) to investigate thermo-mechanical properties. The research first focuses on fabrication of eleven stacking sequences of hybrid combinations, followed by identification of an optimal sequence based on mechanical (tensile strength, flexural strength, charpy impact resistance) and thermogravimetric analysis (TGA) characterization. Additionally, scanning electron microscopy (SEM) for fracture mechanisms of hybrid composites showing fiber pull out, matrix crack, and delamination. Results show that the tertiary combination having 2 Glass, 5 Carbon and 5 Kevlar layers (G2C5K5) named H9 herein provides a good balance of tensile, flexural, impact resistance and thermal properties; its deviation from the best of each category is within approximately 5, 13.5, 9.9 and 10.9 % (for tensile, flexural, impact, TGA) respectively. The range of properties evaluated in this study is deemed suitable for lightweight aircraft structures.

对轻质混合聚合物复合材料(HPC)的追求导致了多种材料和结构配置的出现,以实现汽车和航空航天应用中的高性能。顺便提一下,在研究增强纤维层时,过去报告的工作(一般)涉及可变 GSM。可变 GSM 可能导致各层对外力和热降解的随机响应,因此很难确定各层对结果/性能的作用。本研究采用基于高 GSM(400)的 HPC(具有玻璃 (G)、碳 (C) 和凯夫拉 (K) 的多个堆叠序列)的统一/一致方法来研究热机械性能。研究首先侧重于十一种混合组合堆叠序列的制造,然后根据机械性能(拉伸强度、抗弯强度、抗夏比冲击性能)和热重分析(TGA)特性确定最佳序列。此外,通过扫描电子显微镜(SEM)观察混合复合材料的断裂机理,显示纤维拉出、基体开裂和分层。结果表明,由 2 层玻璃、5 层碳和 5 层凯夫拉纤维(G2C5K5)组成的三级组合(H9)在拉伸、弯曲、抗冲击和热性能方面达到了良好的平衡;与各类最佳组合的偏差分别约为 5%、13.5%、9.9% 和 10.9%(拉伸、弯曲、冲击和 TGA)。本研究评估的性能范围被认为适用于轻质飞机结构。
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引用次数: 0
A new method for rapidly capturing the strength and full nonlinear response of partially interacting steel–concrete composite beams 快速捕捉部分相互作用钢-混凝土复合梁强度和全非线性响应的新方法
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-03 DOI: 10.1016/j.jcomc.2024.100467
Marco Lamberti , Ghani Razaqpur

A semi-analytical procedure is presented for predicting the complete flexural response of partially interacting steel–concrete composite beams up to failure. The governing equation of the Euler–Bernoulli beam theory is solved wherein concrete, steel and the shear connectors joining the concrete slab to the steel beam are assumed to have nonlinear stress-deformation relationships. The adopted constitutive relationship for the connectors allows for partial or full composite action. The solution is applicable to beams and one-way slabs subjected to concentrated or uniform load and/or their combination. The governing equation is numerically solved by satisfying the equilibrium and compatibility requirements along the member. For the reinforced concrete part of the composite beam, a nonlinear moment–curvature relationship is developed that accounts for concrete nonlinearity in compression and for cracking and tension-stiffening in tension as well as for steel reinforcement nonlinearity. The steel profile is assumed to have a bilinear elasto–plastic strain-hardening moment–curvature relationship. Comparison of the proposed model results with the corresponding experimental load–deflection curves and interfacial shear–slip curves of several beams tested by others shows good agreement. The relative simplicity, efficiency and easy application of the present solution make it possible to accurately predict the failure load, interfacial slip and full nonlinear response of partially interacting composite beams.

本文提出了一种半分析程序,用于预测部分相互作用的钢-混凝土复合梁直至破坏的全部弯曲响应。解决了欧拉-伯努利梁理论的控制方程,其中假定混凝土、钢和连接混凝土板与钢梁的剪力连接件具有非线性应力-变形关系。采用的连接件构造关系允许部分或全部复合作用。该解决方案适用于承受集中荷载或均匀荷载和/或两者组合的梁和单向板。通过满足沿构件的平衡和兼容性要求,可以对控制方程进行数值求解。对于复合梁的钢筋混凝土部分,建立了非线性弯矩-曲率关系,考虑了混凝土受压时的非线性、受拉时的开裂和拉伸-刚度以及钢筋的非线性。假定钢筋具有双线性弹塑性应变硬化弯矩-曲率关系。将提出的模型结果与他人测试的几种梁的相应实验荷载-挠度曲线和界面剪切-滑移曲线进行比较,结果显示两者吻合良好。本解决方案相对简单、高效且易于应用,因此可以准确预测部分相互作用复合梁的破坏荷载、界面滑移和全非线性响应。
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引用次数: 0
Machine learning approach to predict the strength of concrete confined with sustainable natural FRP composites 用机器学习方法预测使用可持续天然 FRP 复合材料加固的混凝土强度
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-05-03 DOI: 10.1016/j.jcomc.2024.100466
Shabbir Ali Talpur , Phromphat Thansirichaisree , Nakhorn Poovarodom , Hisham Mohamad , Mingliang Zhou , Ali Ejaz , Qudeer Hussain , Panumas Saingam

Recent earthquakes have highlighted the need to strengthen existing structures with substandard designs. NFRPs provide a sustainable, cost-effective alternative for strengthening, but accurately predicting their performance remains a challenge. This study investigates the use of machine learning algorithms for predicting the compressive strength concrete specimens confined with various NFRPs. Four algorithms were employed: decision tree, random forest, neural network, and gradient boosting regressor. A diverse dataset encompassing various geometries, material properties, and confinement configurations was used to train and evaluate the models. Gradient boosting regressor (GBR) achieved the highest performance, with an average R-squared value of 0.94 and low mean absolute error (MAE) and root mean squared error (RMSE) during training and k-fold cross-validation. Neural network and random forest also demonstrated satisfactory performance, with average R-squared values of 0.88 and 0.86, respectively, during cross-validation. These results suggest that machine learning holds promise for predicting the compressive strength of concrete confined with NFRPs. GBR offers the most accurate predictions, making it a valuable tool for engineers seeking to optimize the design and performance of strengthened structures using sustainable materials.

最近发生的地震凸显了加固设计不合标准的现有结构的必要性。NFRP 为加固提供了一种可持续的、具有成本效益的替代方案,但准确预测其性能仍是一项挑战。本研究调查了机器学习算法在预测使用各种 NFRP 加固的混凝土试件抗压强度方面的应用。研究采用了四种算法:决策树、随机森林、神经网络和梯度提升回归器。模型的训练和评估使用了一个包含各种几何形状、材料特性和约束配置的多样化数据集。梯度提升回归器(GBR)的性能最高,平均 R 平方值为 0.94,在训练和 k 倍交叉验证期间的平均绝对误差(MAE)和均方根误差(RMSE)都很低。神经网络和随机森林的表现也令人满意,在交叉验证期间的平均 R 平方值分别为 0.88 和 0.86。这些结果表明,机器学习有望预测使用非弹性体加固混凝土的抗压强度。GBR 提供了最准确的预测,使其成为工程师优化使用可持续材料的加固结构设计和性能的重要工具。
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引用次数: 0
Agricultural by-product filled poly(lactic acid) biocomposites with enhanced biodegradability: The effect of flax seed meal and rapeseed straw 生物降解性更强的农副产品填充聚乳酸生物复合材料:亚麻籽粉和油菜籽秸秆的影响
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-04-29 DOI: 10.1016/j.jcomc.2024.100464
Sándor Kálmán Jakab , Tej Singh , Imre Fekete , László Lendvai

The purpose of this research was to develop “green” materials by combining poly(lactic acid) (PLA) with two agricultural by-products, namely flax seed meal (FSM) and rapeseed straw (RSS). The natural fillers (0–20 wt.%) were mixed with PLA through extrusion and then injection molded into specimens. The samples were analyzed for their thermal, morphological, mechanical, and physical features and biodegradability. Thermal properties and crystallinity were analyzed using Differential Scanning Calorimetry (DSC), while the morphology was investigated by Scanning Electron Microscopy (SEM). Mechanical properties were characterized through tensile, flexural, and impact measurements, while surface hardness was evaluated by Shore D tests. Water absorption and biodegradability of the samples were also examined. DSC measurements revealed a nucleating effect of both bio-fillers. Based on the tensile tests, major improvement in stiffness was found with the biocomposites having up to ∼16 % higher Young's modulus than neat PLA (2.5 GPa). It came, however, at the cost of tensile strength, which decreased from 56 to 51 MPa even in the presence of the lowest amount (2.5 wt.%) of FSM. Loss in strength was due to the limited adhesion between the components, as also supported by SEM images. The hardness slightly (1–2 %) improved in the presence of even 2.5 wt.% bio-filler and it remained at that level at higher filler loading as well. Laboratory-scale composting revealed that both fillers facilitated biodegradation with FSM being superior. In the presence of 10–20 wt.% FSM, the rate of decomposition was found to be twice as fast compared to neat PLA.

这项研究的目的是将聚乳酸(PLA)与亚麻籽粉(FSM)和油菜籽秸秆(RSS)这两种农副产品结合起来,开发 "绿色 "材料。天然填料(0-20 wt.%)通过挤压与聚乳酸混合,然后注塑成试样。对样品的热性能、形态、机械性能、物理特性和生物降解性进行了分析。使用差示扫描量热法(DSC)分析了热性能和结晶度,使用扫描电子显微镜(SEM)研究了形态。机械性能通过拉伸、弯曲和冲击测量进行表征,表面硬度则通过邵氏硬度测试进行评估。此外,还检测了样品的吸水性和生物降解性。DSC 测量显示了两种生物填料的成核效应。根据拉伸试验,发现生物复合材料的刚度有了很大提高,其杨氏模量比纯聚乳酸(2.5 GPa)高出 16%。然而,这是以拉伸强度为代价的,即使在含有最低量(2.5 wt.%)FSM 的情况下,拉伸强度也从 56 兆帕下降到 51 兆帕。强度下降的原因是成分之间的粘附力有限,这一点也得到了 SEM 图像的证实。即使含有 2.5 wt.%的生物填料,硬度也会略有提高(1-2%),而且在填料含量较高时,硬度也会保持在这一水平。实验室规模的堆肥试验表明,两种填料都能促进生物降解,而 FSM 更胜一筹。在含有 10-20 wt.% FSM 的情况下,分解速度是纯聚乳酸的两倍。
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引用次数: 0
Additive manufacturing for sustainability, circularity and zero-waste: 3DP products from waste plastic bottles 促进可持续性、循环性和零废弃的快速成型制造:利用废塑料瓶制造 3DP 产品
IF 4.2 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-04-23 DOI: 10.1016/j.jcomc.2024.100463
Ans Al Rashid, Muammer Koç

Polymers and their composites are now widely used in several industrial sectors, owing to their flexibility in developing customized products. The significant surge in plastic usage has led to a severe challenge in managing end-of-life plastic waste. Millions of tons of plastic waste produced annually mainly end up in landfills, leaking into the environment and posing severe threats to ecosystems. Innovative solutions to reuse/recycle/repurpose plastic waste are desired to address these global challenges. Therefore, in this study, a sustainable route to converting plastic waste into additive manufacturing (AM) feedstock is presented, where waste plastic bottles (mainly Polyethylene Terephthalate, PET) are recycled using an in-house 3D-printed filament extrusion system to produce filaments for fused filament fabrication (FFF) process. In addition to the recycled PET (rPET), virgin carbon fiber reinforced polyamide-6 (PA6-CF) polymer composites were also used to produce hybrid feedstock filaments. The rPET and rPET/PA6-CF composite filaments were extruded using an in-house filament extruder setup. The produced rPET-based filaments were characterized for their chemical and thermal properties. Subsequently, mechanical characterization was performed on 3D-printed specimens. The mechanical analysis revealed better tensile strength for rPET/PA6-CF than rPET; however, the rPET demonstrated better failure strain and young modulus, demonstrating their potential as viable materials for industrial and consumer applications. The outcomes of this study revealed promising results to promote sustainable production and consumption, complementing the circular economy practices with a straightforward production route to convert plastic waste into AM feedstock.

聚合物及其复合材料因其在开发定制产品方面的灵活性,现已广泛应用于多个工业领域。塑料用量的激增给报废塑料垃圾的管理带来了严峻挑战。每年产生的数百万吨塑料废弃物主要被填埋,渗漏到环境中,对生态系统造成严重威胁。为应对这些全球性挑战,我们需要创新的解决方案,对塑料废物进行再利用/再循环/再利用。因此,本研究提出了一条将塑料废弃物转化为增材制造(AM)原料的可持续途径,即利用内部 3D 打印长丝挤出系统回收废旧塑料瓶(主要是聚对苯二甲酸乙二醇酯,PET),为熔融长丝制造(FFF)工艺生产长丝。除回收的 PET(rPET)外,还使用原始碳纤维增强聚酰胺-6(PA6-CF)聚合物复合材料生产混合原料长丝。rPET 和 rPET/PA6-CF 复合长丝是使用内部长丝挤出机装置挤出的。对生产出的 rPET 长丝进行了化学和热性能表征。随后,对 3D 打印试样进行了力学表征。机械分析表明,rPET/PA6-CF 的拉伸强度优于 rPET;然而,rPET 的破坏应变和年轻模量更好,这表明它们具有作为工业和消费应用材料的潜力。这项研究的结果表明,在促进可持续生产和消费方面取得了可喜的成果,通过将塑料废弃物转化为 AM 原料的直接生产路线,补充了循环经济实践。
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Composites Part C Open Access
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