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Total cost of ownership of vehicle electrification and fuel switching options for light-duty and heavy-duty vehicles 轻型和重型车辆电气化和燃料转换选项的总拥有成本
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-13 DOI: 10.1016/j.etran.2025.100512
Kwang Hoon Baek , Xinyi Wu , Yan Zhou , Ram Vijayagopal , Namdoo Kim , Amgad Elgowainy
Projecting the transition from combustion engines to battery-based powertrains is complex becuase it involves numerous interdependent decisions. This study estimates total cost of ownership (TCO) to assess the economic viability of powertrain electrification, focusing exclusively on advances in vehicle and fuel technologies. Under two bounding technology-progress scenarios, we develop vehicle designs and fuel cost trajectories, which serve as inputs to TCO projections for selected classes from 2021 to 2050.
We analyzed a small sport utility vehicle (SUV) to represent the light-duty vehicle (LDV) sector, and four medium- and heavy-duty vehicle (MHDV) classes: Class 6 box delivery, Class 8 drayage, Class 8 long-haul, and Class 8 transit bus. For each class, we compared the TCO of battery electric vehicles (BEVs) and fuel cell hybrid electric vehicles (FCHEVs) against conventional internal combustion engine vehicles (ICEVs).
The results show that modern ICEVs generally have lower TCO; however, BEVs and FCHEVs could match or have lower TCOs than ICEVs over time, depending on technological progress. In LDVs, BEV300 is projected to deliver the lowest TCO by 2050, particularly under the high-progress scenario. In MHDVs, both BEVs and FCHEVs could become more cost-competitive than ICEVs by 2050 in the high-progress case.
Beyond these results, the findings suggest further investigation is warranted for BEV charging infrastructure, FCHEV hydrogen refueling infrastructure, and MHDV charging strategies. These factors could reduce the fuel-cost share of TCO and enhance the competitiveness of BEVs and FCHEVs relative to ICEVs.
规划从内燃机向电池动力系统的过渡是复杂的,因为它涉及许多相互依存的决策。本研究通过估算总拥有成本(TCO)来评估动力总成电气化的经济可行性,重点关注车辆和燃料技术的进步。在两种边界技术进步情景下,我们开发了车辆设计和燃料成本轨迹,作为2021年至2050年选定类别的TCO预测的输入。我们分析了代表轻型车辆(LDV)领域的小型运动型多用途车(SUV),以及四种中型和重型车辆(MHDV)类别:第6类箱子运输,第8类运输,第8类长途和第8类运输巴士。对于每个类别,我们比较了纯电动汽车(bev)和燃料电池混合动力汽车(FCHEVs)与传统内燃机汽车(icev)的总拥有成本(TCO)。结果表明,现代icev总体上具有较低的TCO;然而,随着时间的推移,纯电动汽车和电动汽车的tco可能会与电动汽车相当,或者低于电动汽车,这取决于技术进步。在ldv中,BEV300预计到2050年将提供最低的总拥有成本,特别是在高进度情景下。在高速发展的情况下,到2050年,纯电动汽车和氢燃料电池汽车都将比电动汽车更具成本竞争力。除了这些结果之外,研究结果还表明,有必要对纯电动汽车充电基础设施、FCHEV氢燃料补给基础设施和MHDV充电策略进行进一步调查。这些因素可以降低总成本的燃料成本份额,提高纯电动汽车和氢燃料汽车相对于内燃机汽车的竞争力。
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引用次数: 0
Machine-learning integrated multi-domain co-optimization for electrified heavy duty fleets 电气化重型车队机器学习集成多域协同优化
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-10 DOI: 10.1016/j.etran.2025.100511
Christoph Wellmann , Pekka Rahkola , Sai Santhosh Tota , Mikko Pihlatie , Abdul Rahman Khaleel , Christopher Marx , Akshay Sharma , Markus Eisenbarth , Jakob Andert
Driven by global regulations and the urgent need for a sustainable transition to zero-emission fleets in the transport sector, revolutionizing powertrain systems and their respective development processes have become more and more prevalent. Ambitious goals have been established for the latest public-funded research projects, such as ESCALATE (Powering European Union Net Zero Future by Escalating Zero Emission Heavy Duty Vehicles (HDV) and Logistic Intelligence), to increase the efficiency of the powertrain by up to 10% and thus maximize the operational range above 750 km. All of this will be achieved by introducing cost-effective, modular, and scalable electric powertrain components combined with advanced system control algorithms, targeting a broad market coverage with flexible vehicle architectures. In this context, the paper presents a completely virtual frontloading strategy to create a modular and highly integrated e-Axle system, leveraging a dual permanent magnet synchronous machine configuration to improve multiple performance indicators. These are the performance output, in terms of power and torque, system efficiency, and noise-vibration-harshness (NVH) criteria. To allow for an holistic system parametrization, a combined electric machine and transmission synthesis, using an active learning-based, multi-layer nested optimization approach together with a model predictive control strategy for motion and thermal domain has been employed. This development framework is integrating electric machine dimensions and transmission gear ratios as design parameters, as well as thermal actuation and torque as control parameters, to ensure a system right-sizing in a given use-case environment. By including monetary considerations with genetic algorithms, an extension for a powertrain family identification to a complete HDV fleet is facilitated. To demonstrate the feasibility of this framework, a concept assessment and validation has been carried out. The key achievements include a close matching of the defined KPIs, namely the peak wheel torque of 56150 Nm and continuous power of 381 kW – about 2%, respectively 0.2% above the target – and an enhanced peak power capability of 536 kW. In terms of energy efficiency, the multi-stage gear boxes support a well optimized operation in the VECTO long haul cycle, indicating a 40-ton vehicle energy consumption of around 109.7 kWh per 100 km, while the 76-ton variant consumes approximately 204.6 kWh per 100 km. Further the predictive cruise control strategy led to a consumption reduction of about 2.6%–3.4%.
在全球法规和运输行业向零排放车队可持续过渡的迫切需求的推动下,革命性的动力总成系统及其各自的开发过程变得越来越普遍。为最新的公共资助研究项目制定了雄心勃勃的目标,例如“升级”(通过升级零排放重型车辆(HDV)和物流智能为欧盟净零未来提供动力),将动力系统的效率提高10%,从而最大限度地提高750公里以上的运行范围。所有这些都将通过引入具有成本效益、模块化和可扩展的电动动力总成组件,结合先进的系统控制算法,以灵活的车辆架构为目标,覆盖广泛的市场。在此背景下,本文提出了一个完全虚拟的前置加载策略,以创建一个模块化和高度集成的e-Axle系统,利用双永磁同步电机配置来提高多个性能指标。这些是性能输出,包括功率和扭矩、系统效率和噪声-振动粗糙度(NVH)标准。为了实现整体系统参数化,采用基于主动学习的多层嵌套优化方法以及运动和热域的模型预测控制策略,结合电机和传动综合。该开发框架将电机尺寸和传动齿轮比作为设计参数,将热致动和扭矩作为控制参数,以确保系统在给定的用例环境中具有合适的尺寸。通过将金钱考虑与遗传算法相结合,可以将动力总成家族识别扩展到完整的HDV车队。为了证明该框架的可行性,进行了概念评估和验证。关键成果包括与既定kpi的紧密匹配,即峰值车轮扭矩为56150 Nm,连续功率为381 kW,分别比目标高出约2%,分别为0.2%,以及增强的峰值功率能力536 kW。在能源效率方面,多级齿轮箱支持VECTO长途循环的良好优化操作,表明40吨车辆每100公里能耗约为109.7千瓦时,而76吨版本每100公里能耗约为204.6千瓦时。此外,预测巡航控制策略使油耗降低了约2.6%-3.4%。
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引用次数: 0
Hierarchical porous transport layers for enhancing mass transport in proton exchange membrane electrolyzer cells 提高质子交换膜电解槽质量传输的分层多孔传输层
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-05 DOI: 10.1016/j.etran.2025.100510
Jiexin Zou , Yuanbin Sun , Xiuyue Wang , Juntao Chen , Jingke Mo , Siguang Wu , Qiren Chen , Cenkai Zhao , Haijiang Wang , Min Wang
The performance of proton exchange membrane electrolyzer cells (PEMECs) at high current density is constrained by mass transport limitation in conventional porous transport layer (PTL), which is the critical barrier to their large-scale adoption for green hydrogen production. In this paper, a laser-ablated non-penetrating-hole PTL (NP-PTL) with architected pores demonstrates an over 50 % reduction in mass transport overpotential compared to commercial Ti-felt PTL. Through a synergistic combination of in-situ optical diagnostics and two-phase flow modeling, we elucidate the mechanism by which the laser-engineered NP-PTL structure reduces mass transport resistance under high current density operation. Unlike fully perforated designs, the non-penetrating hole architecture maintains optimal contact between the PTL and catalyst layer (CL), minimizing the increase in high-frequency resistance (HFR) and further improving overall electrolyzer efficiency. The NP-PTL not only enhances performance but also exhibits promising initial operational stability, maintaining steady performance during 100-h testing. The laser ablation strategy for fabricating PTL with non-perforated structures offer a novel approach to enhance the performance of PEMECs, thereby accelerating the commercialization of PEMECs.
质子交换膜电解槽(PEMECs)在高电流密度下的性能受到传统多孔输运层(PTL)中质量输运的限制,这是其大规模应用于绿色制氢的关键障碍。在本文中,一种具有结构孔的激光烧蚀非穿透孔PTL (NP-PTL)与商用ti毡PTL相比,其质量输运过电位降低了50%以上。通过原位光学诊断和两相流建模的协同结合,我们阐明了激光工程NP-PTL结构在高电流密度操作下降低质量输运阻力的机制。与全穿孔设计不同,非穿透孔结构保持了PTL和催化剂层(CL)之间的最佳接触,最大限度地减少了高频电阻(HFR)的增加,进一步提高了电解槽的整体效率。NP-PTL不仅提高了性能,而且表现出良好的初始操作稳定性,在100小时的测试中保持稳定的性能。采用激光烧蚀技术制造无孔PTL为提高pemec的性能提供了一种新方法,从而加速了pemec的商业化。
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引用次数: 0
Towards real-world battery health intelligence: A review of machine learning advances and challenges in SOH estimation 面向现实世界的电池健康智能:SOH估计中机器学习的进展和挑战的综述
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-04 DOI: 10.1016/j.etran.2025.100509
Xing Shu , Jiangwei Shen , Fengxiang Guo , Yonggang Liu , Yuanjian Zhang , Zheng Chen , Hongqian Zhao
Lithium-ion batteries have become the dominant power source in electric transportation due to their high energy density and long cycle life. Nevertheless, prolonged operation leads to irreversible degradation, and results in capacity fade and safety risks. Accurate estimation of state of health (SOH) is therefore critical for ensuring reliable electric vehicle operation and for guiding maintenance strategies. In recent years, extensive research has been devoted to SOH estimation, supported by both laboratory investigations and field applications. Unlike previous reviews that mainly focus on either laboratory data or algorithmic modeling, this review uniquely bridges the gap between lab-based methods and practical applications using real vehicle operational data by providing a comparative analysis of datasets, estimation methods, and application challenges. A systematic survey of recent advances is provided in lithium-ion battery SOH estimation. First, accelerated aging experiments under laboratory conditions and operational data acquisition in real-world scenarios are reviewed and compared. The extraction of health features, feature optimization, and dimensionality reduction techniques are elaborated. Second, the progress in modeling methods is summarized, including shallow neural networks, convolutional neural networks, recurrent neural networks, attention-based networks, and physics-informed networks. Third, SOH label acquisition methods and estimation approaches for real-world datasets are analyzed. Finally, three major challenges are discussed for improving SOH estimation accuracy in practice, including bridging the gap between laboratory and real-world conditions, achieving more reliable SOH labeling, and reducing the dependence on large-scale training data.
锂离子电池因其能量密度高、循环寿命长等优点,已成为电动交通领域的主导电源。然而,长时间的运行会导致不可逆的老化,并导致产能衰退和安全风险。因此,准确估计健康状态(SOH)对于确保电动汽车可靠运行和指导维护策略至关重要。近年来,在实验室研究和现场应用的支持下,对SOH估算进行了广泛的研究。与以往主要关注实验室数据或算法建模的综述不同,本综述通过对数据集、估计方法和应用挑战的比较分析,独特地弥合了基于实验室的方法与使用真实车辆运行数据的实际应用之间的差距。对锂离子电池SOH估算的最新进展进行了系统的综述。首先,对实验室条件下的加速老化实验和现实场景下的操作数据采集进行了回顾和比较。阐述了健康特征的提取、特征优化和降维技术。其次,总结了建模方法的进展,包括浅神经网络、卷积神经网络、循环神经网络、基于注意力的网络和物理信息网络。第三,分析了真实数据集的SOH标签获取方法和估计方法。最后,讨论了在实践中提高SOH估计精度的三个主要挑战,包括弥合实验室和现实条件之间的差距,实现更可靠的SOH标记,以及减少对大规模训练数据的依赖。
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引用次数: 0
Modeling study on fire propagation behavior and analysis of energy flow paths in double-layer LFP battery module 双层LFP电池模块火焰传播特性建模研究及能量流路径分析
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-04 DOI: 10.1016/j.etran.2025.100508
Yan Wang , Yu Wang , Chengshan Xu , Feng Dai , Xilong Zhang , Hewu Wang , Xuning Feng
With the global transformation of energy structure and rapid development of energy storage technologies, battery energy storage stations (BESS) have been widely applied. However, vertically stacked lithium iron phosphate (LFP) battery modules in BESS are highly susceptible to thermal runaway (TR) jet combustion, leading to collective violent battery combustion under the influence of vertical flames. Extensive experimental investigations have been conducted on the failure process involving heat generation - jet combustion - (thermal runaway propagation)TRP in double - layer LFP battery modules. However, experimental methods struggle to clarify the influence mechanisms of vertical flames on battery TRP and energy flow pathways. This paper establishes a chain-type failure model for heat generation - jet combustion - TRP in double-layer battery modules based on non-premixed combustion theory. After calibrating critical parameters such as battery temperature and heat release rate (HRR), the model predicts battery TRP patterns and energy flow pathways in double-layer quadruple-battery modules under vertical flame influence. Results revealed that 71.2 % of flame-released heat radiates to the lateral surface of the upper battery module, while only 28.8 % radiates to the battery bottom. At 2133 s, the battery module has a group deflagration with a maximum HRR of 336.5 kW. The outermost upper-layer battery absorbs heat most rapidly, leading to earliest valve venting and TR. This creates an “inverse sequence” TRP pattern in the upper battery layer. The findings provide theoretical references for fire propagation protection and safety design in BESS.
随着全球能源结构的转型和储能技术的快速发展,电池储能站(BESS)得到了广泛应用。然而,BESS中垂直堆叠的磷酸铁锂(LFP)电池模块极易发生热失控(TR)射流燃烧,导致电池在垂直火焰的影响下发生集体剧烈燃烧。对双层LFP电池模块热生成-射流燃烧-(热失控传播)TRP失效过程进行了广泛的实验研究。然而,实验方法很难阐明垂直火焰对电池TRP和能量流动路径的影响机制。基于非预混燃烧理论,建立了双层电池模块发热-射流燃烧- TRP链式失效模型。在标定电池温度和热释放率(HRR)等关键参数后,该模型预测了垂直火焰影响下双层四层电池模块的电池TRP模式和能量流动路径。结果表明,71.2%的火焰释放热量辐射到电池上部模块的侧面,而只有28.8%的热量辐射到电池底部。2133秒时,电池模块群发爆燃,最大HRR为336.5 kW。最外层的上层电池吸收热量最快,导致最早的阀门排气和TR。这在上层电池层形成了“逆序列”TRP模式。研究结果可为BESS的火灾传播防护和安全设计提供理论参考。
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引用次数: 0
Design parameter optimization for sulfide-based all-solid-state batteries with high energy density 高能量密度硫化物基全固态电池设计参数优化
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-10-31 DOI: 10.1016/j.etran.2025.100507
Jiyoung Kim , Charles Mish , Alexandre T.R. Guibert , Filippo Agnelli , Marta Vicencio , So-Yeon Ham , Min-Sang Song , Ying Shirley Meng , Jeong Beom Lee , H. Alicia Kim
Sulfide-based all-solid-state batteries (ASSBs) are promising candidates for applications requiring high energy density and enhanced safety, with the potential to replace conventional Li-ion batteries. Despite significant advances in material design and engineering, the impact of material properties and process variables on cell energy density remains poorly understood. In this study, we employed a validated pseudo-two-dimensional (P2D) model to investigate how volumetric and gravimetric energy densities of ASSBs change as function of various cell design parameters and to perform mathematical optimization to maximize energy densities. Model parameters were derived from pellet cell experiments, incorporating a cathode composite with high-capacity NCM811 and densely packed fine argyrodite, alongside a bulk solid electrolyte separator with high ionic conductivity. The model's accuracy was confirmed by comparing simulation results with experimental voltage profiles, resulting in a root mean square error of 0.028 mV and an energy discrepancy of 0.7 %. Using the validated P2D model, we set energy densities as objective functions and scaled the pellet cell structure to automotive pouch cell dimensions to assess practical energy densities. A comprehensive sensitivity study was conducted on design parameters within the solid electrolyte separator and cathode composite. The weight percentage of the cathode active material was identified as a highly sensitive parameter, with other cathode composite parameters showing strong dependence on it. Employing a gradient-free direct search optimization method, we identified optimal design parameters that improved the volumetric and gravimetric energy densities by 62.5 % and 66.3 %, respectively, relative to reference values based on experimental parameters for a single cell.
硫化物基全固态电池(assb)在高能量密度和安全性要求较高的应用中具有很好的前景,有可能取代传统的锂离子电池。尽管在材料设计和工程方面取得了重大进展,但材料特性和工艺变量对电池能量密度的影响仍然知之甚少。在这项研究中,我们采用了一个经过验证的伪二维(P2D)模型来研究assb的体积和重量能量密度随不同细胞设计参数的变化,并进行数学优化以最大化能量密度。模型参数来源于颗粒电池实验,包括高容量NCM811和密集堆积的细银柱石阴极复合材料,以及具有高离子电导率的大块固体电解质分离器。通过仿真结果与实验电压曲线的比较,验证了该模型的准确性,得到的均方根误差为0.028 mV,能量差为0.7%。利用验证的P2D模型,我们将能量密度设置为目标函数,并将颗粒电池结构缩放到汽车袋状电池尺寸,以评估实际能量密度。对固体电解质分离器和阴极复合材料的设计参数进行了综合敏感性研究。阴极活性物质的重量百分比是一个高度敏感的参数,其他阴极复合材料参数对其有很强的依赖性。采用无梯度直接搜索优化方法,我们确定了最优设计参数,相对于基于单个细胞实验参数的参考值,体积和重量能量密度分别提高了62.5%和66.3%。
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引用次数: 0
Dynamic flight challenges in PEMFC-powered UAVs: Towards intelligent management and sustainable propulsion pemfc动力无人机的动态飞行挑战:迈向智能管理和可持续推进
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-10-29 DOI: 10.1016/j.etran.2025.100506
Xikai Tu , Jin Wu , Zhiming Tao , Chang Wen , Zhengkai Tu
Proton exchange membrane fuel cell (PEMFC)-powered unmanned aerial vehicles (UAVs) exhibit nonlinear and coupled behavior under dynamic flight conditions. To enable intelligent management, this study proposes an adaptive air stoichiometric ratio (ASR) strategy that dynamically responds to real-time variations in payload and acceleration. Although ASR optimization has been studied under steady-state conditions, its regulation under realistic UAV dynamics remains underexplored and experimentally unverified. We develop a coupled framework integrating UAV flight dynamics, an air-cooled PEMFC model, and mass–heat transfer multiphysics, and validate it through dynamic flight tests. Results show that optimal ASR varies significantly with operating conditions: with a 40 kg payload, ASR increases from 52 to 81 as acceleration changes from −0.6 to 0.6 m/s2; at 0.6 m/s2, raising the payload from 25 to 40 kg increases ASR from 24 to 81. Optimal ASR regulation improves stack voltage by 0.170 V, reduces hydrogen consumption by 2.05 mg per 100 m of flight, lowers temperature by 18.32 %, and enhances efficiency, voltage uniformity, and temperature uniformity. Notably, ASR exhibits a nonlinear influence on performance: it improves markedly from 25 to 28 kg, remains stable between 28 and 31 kg, and rises again at 40 kg. Experimental validation (error <1.1 %) confirms model accuracy and demonstrates the effectiveness of ASR optimization in PEMFC-powered UAVs. Beyond UAV applications, the proposed adaptive ASR strategy offers a pathway toward intelligent air management in fuel-cell propulsion systems, with direct relevance to emerging electric transportation modes such as urban air mobility vehicles, cargo drones, and hybrid-electric aircraft.
以质子交换膜燃料电池(PEMFC)为动力的无人机在动态飞行条件下表现出非线性和耦合行为。为了实现智能管理,本研究提出了一种自适应空气化学计量比(ASR)策略,该策略可以动态响应有效载荷和加速度的实时变化。虽然ASR优化已经在稳态条件下进行了研究,但其在实际无人机动力学下的调节仍未得到充分探索和实验验证。建立了集成无人机飞行动力学、风冷PEMFC模型和传质传热多物理场的耦合框架,并通过动态飞行试验对其进行了验证。结果表明,最佳ASR随工况变化显著:当载荷为40 kg时,当加速度从- 0.6 m/s2增加到0.6 m/s2时,ASR从52增加到81;在0.6 m/s2的速度下,将有效载荷从25 kg提高到40 kg, ASR从24增加到81。优化后的ASR调节使堆叠电压提高0.170 V,每100 m飞行氢耗降低2.05 mg,温度降低18.32%,并提高了效率、电压均匀性和温度均匀性。值得注意的是,ASR对性能表现出非线性影响:在25至28 kg期间,ASR显著提高,在28至31 kg之间保持稳定,在40 kg时再次上升。实验验证(误差<; 1.1%)证实了模型的准确性,并证明了在pemfc驱动的无人机中ASR优化的有效性。除了无人机应用之外,提出的自适应ASR策略还为燃料电池推进系统的智能空气管理提供了一条途径,与新兴的电动交通方式(如城市空中交通工具、货运无人机和混合动力飞机)直接相关。
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引用次数: 0
Multi-parameter degradation of PEMFCs in freeze/thaw cycles: Impacts of assembly force and initial membrane water content on cold start durability for transportation applications 冻融循环中pemfc的多参数退化:装配力和初始膜含水量对运输应用冷启动耐久性的影响
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-10-24 DOI: 10.1016/j.etran.2025.100505
Lei Shi , Ruitao Li , Chang Du , Julong Zhou , Yahui Yi , Ze Liu , Jianbin Su , Liqin Qian , Tiancai Ma , Shijia Yang , Chengyu Xia , Xingwang Tang
The adaptability of fuel cell vehicles in extreme low-temperature environments remains a critical challenge urgently requiring breakthroughs in the transportation sector. As a core factor influencing low-temperature operational reliability, freeze/thaw cycles directly impact the performance stability and service life of fuel cells, and hold decisive significance for advancing the popularization and application of fuel cell vehicles in cold regions. This study investigates the degradation mechanisms of fuel cells subjected to freeze/thaw cycles under varying initial membrane dissolved water content and assembly force conditions. Building on three preliminary experiments-initial water content calibration, freezing time retardation analysis, and initial microstructure characterization of the catalytic layer and gas diffusion layer-a 100-h freeze/thaw test was conducted. Electrochemical impedance spectroscopy, cyclic voltammetry, and other characterization techniques were employed to assess the fuel cell degradation process. The degradation rate during freeze/thaw cycles was quantified using the distribution of relaxation times method and electrochemical active surface area. High-magnification optical microscopy and scanning electron microscopy were utilized to examine the microstructure of disassembled gas diffusion layers post-freeze/thaw cycles, offering insights into structural damage to both the catalytic layer and gas diffusion layer. Results reveal that higher assembly forces exacerbate gas diffusion layer degradation, leading to slower mass transport and increased mass transport resistance-with the distribution of relaxation times low-frequency peak rising by 202 % under a 13 N m assembly force after 5 cycles. Additionally, higher initial membrane dissolved water content slightly accelerates GDL degradation and significantly contributes to catalytic layer degradation, as evidenced by a 29 % reduction in electrochemical active surface area for 100 % initial water content after 5 cycles. The degradation mechanisms of fuel cells under freeze-thaw cycles revealed in this study provide crucial support for improving the low-temperature reliability of fuel cell vehicles in the transportation sector and promoting their commercialization and application in cold regions.
燃料电池汽车在极端低温环境下的适应性仍然是交通运输领域急需突破的关键挑战。冻融循环作为影响燃料电池低温运行可靠性的核心因素,直接影响燃料电池的性能稳定性和使用寿命,对推进燃料电池汽车在寒冷地区的推广应用具有决定性意义。本研究探讨了不同初始膜溶解水含量和组装力条件下燃料电池在冻融循环下的降解机理。在初始含水量标定、冻结时间延迟分析、催化层和气体扩散层初始微观结构表征三个初步实验的基础上,进行了100 h冻融试验。利用电化学阻抗谱、循环伏安法和其他表征技术对燃料电池的降解过程进行了评价。利用弛豫时间分布法和电化学活性表面积对冻融循环过程中的降解速率进行了量化。利用高倍光学显微镜和扫描电子显微镜对冻融循环后分解的气体扩散层的微观结构进行了观察,从而深入了解了催化层和气体扩散层的结构破坏情况。结果表明,较高的装配力加剧了气体扩散层的降解,导致质量输运变慢和质量输运阻力增加,在13 N m装配力下,5次循环后,低频峰的弛豫次数分布增加了202%。此外,较高的初始膜溶解水含量会略微加速GDL的降解,并显著促进催化层的降解。5个循环后,当初始水含量达到100%时,电化学活性表面积减少29%。本研究揭示的燃料电池在冻融循环下的降解机理,为提高燃料电池汽车在交通运输领域的低温可靠性,促进其在寒冷地区的商业化应用提供了重要支持。
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引用次数: 0
Fast reconstruction of non-uniform temperature fields in large-scale blade battery enabled by partitioned equivalent heat generation resistance modeling 基于分段等效热阻模型的大型叶片电池非均匀温度场快速重构
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-10-21 DOI: 10.1016/j.etran.2025.100496
Kai Shen , Jiaqi Yuan , Peng Ding , Bin He , Gan Song , Xing Pang , Yufang Lu , Xin Lai , Xiangqi Meng , Xuning Feng , Yuejiu Zheng
With the increasingly trend toward the large-scale batteries, a multitude of new and diverse-shaped large batteries, such as blade battery and 4680 cell, have been applied. Temperature inhomogeneity is a new critical issue that arises during the operation of large-size blade batteries, it can have adverse effects on the performance, life, and safety of both individual cell and battery packs. But the temperature distribution estimation is difficult to be estimated because of uneven electro-thermal coupling effects and heat transfer induced during the Li-ion transport and deintercalation process between the planar electrodes. A new equivalent heat generation internal resistance method was used to construct the thermal model for the blade battery, which includes the pole and body regions. And the heat balance method is employed to establish the differential equation for the temperature distribution in the battery body region. To validate the accuracy and efficiency of the model, tests were conducted under different environmental conditions spanning steady-state and dynamic operating regimes. The results show that blade battery temperature inhomogeneity cannot be ignored. The proposed model can estimate the inhomogeneous temperature distribution of a large-size blade battery in less than 1 s. Under normal temperature steady-state and dynamic operating conditions, the maximum real-time error is controlled within 0.8 °C. Under low-temperature or high-current conditions, the maximum real-time errors are kept within 1.88 °C and 1.35 °C, respectively. This model can quickly and accurately predict the real-time evolution of the temperature distribution for blade batteries. And this approach provides innovative insights into real-time temperature monitoring and management for large-scale battery applications.
随着电池大型化的趋势日益明显,叶片电池、4680电池等多种新型、形状各异的大型电池得到了广泛的应用。温度不均匀性是大尺寸叶片电池运行过程中出现的一个新的关键问题,它会对单个电池和电池组的性能、寿命和安全性产生不利影响。但由于锂离子在平面电极间的输运和脱嵌过程中存在不均匀的电热耦合效应和热传递,使得温度分布难以估计。采用一种新的等效产热内阻法,建立了叶片电池的等效产热内阻模型。采用热平衡法建立了电池体区域温度分布的微分方程。为了验证模型的准确性和有效性,在不同的环境条件下进行了测试,包括稳态和动态运行机制。结果表明,叶片电池温度的不均匀性不容忽视。该模型可以在不到1 s的时间内估计出大尺寸叶片电池的非均匀温度分布。在常温稳态和动态工况下,最大实时误差控制在0.8℃以内。在低温和大电流条件下,最大实时误差分别保持在1.88°C和1.35°C。该模型能够快速准确地预测叶片电池温度分布的实时演变。这种方法为大规模电池应用的实时温度监测和管理提供了创新的见解。
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引用次数: 0
Lightweight fault diagnosis for EV battery packs via SpikingFormer and frequency slice wavelet transform 基于SpikingFormer和频率切片小波变换的电动汽车电池组轻量化故障诊断
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-10-20 DOI: 10.1016/j.etran.2025.100503
Qian Huo , Zhikai Ma , Tao Zhang , Zepeng Gao
Accurate fault diagnosis of power batteries is crucial for ensuring the safe and reliable operation of electric vehicles (EVs). Existing fault diagnosis methods have increasingly adopted deep neural networks due to their powerful learning and feature extraction capabilities. However, two significant limitations remain. Firstly, these methods fail to exploit the time–frequency coupling characteristics from multiple battery operational signals, leading to suboptimal feature representation. Secondly, the employed deep network models, such as Transformers, often require substantial computational resources, making them unsuitable for real-time deployment. To address these challenges, this paper proposes a novel fault diagnosis framework that integrates frequency slice wavelet transform (FSWT) with a lightweight SpikingFormer architecture. FSWT is employed to decompose and analyze multiple raw battery signals, capturing comprehensive time–frequency domain features that enhance fault representation. SpikingFormer, inspired by spiking neural networks, serves as an efficient alternative to the Transformer model, reducing computational complexity through event-driven processing while maintaining its capability to capture long-term dependencies. The proposed method, validated using real-world EV battery datasets collected from 100 EVs over a period of 6 to 12 months, demonstrates superior performance compared to state-of-the-art (SOTA) techniques. Specifically, it achieves a 4%–6.8% increase in mean fault-diagnosis accuracy and reduces the time-to-fault error by 1.2–3.2 min. Moreover, its inference time accounts for only 2.8%–28.4% of that required by SOTA methods, while its energy consumption is limited to 13.3%–14.4% of their levels.
动力电池的准确故障诊断是保证电动汽车安全可靠运行的关键。由于深度神经网络具有强大的学习和特征提取能力,现有的故障诊断方法越来越多地采用深度神经网络。然而,仍然存在两个重要的限制。首先,这些方法无法利用多个电池运行信号的时频耦合特性,导致特征表示不理想。其次,所采用的深度网络模型,如Transformers,往往需要大量的计算资源,使其不适合实时部署。为了解决这些问题,本文提出了一种新的故障诊断框架,该框架将频片小波变换(FSWT)与轻量级SpikingFormer架构相结合。采用FSWT对多个电池原始信号进行分解和分析,捕获全面的时频域特征,增强故障表征。SpikingFormer的灵感来自于脉冲神经网络,它可以作为Transformer模型的有效替代方案,通过事件驱动处理降低计算复杂性,同时保持其捕获长期依赖关系的能力。通过在6至12个月内从100辆电动汽车中收集的真实电动汽车电池数据集进行验证,与最先进的(SOTA)技术相比,该方法表现出了卓越的性能。具体而言,它实现了4%-6.8%的平均故障诊断精度提高,并减少了1.2-3.2分钟的故障时间误差。其推理时间仅占SOTA方法所需时间的2.8% ~ 28.4%,能耗仅为SOTA方法的13.3% ~ 14.4%。
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引用次数: 0
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Etransportation
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