In recent years, the development of electric vehicles (EVs) thermal management systems has underscored the crucial role in ensuring driving safety and optimizing driving range has become increasingly prominent. However, the inherent dynamic complexity of EV operation coupled with automatic control systems, can sometimes lead to unstable behavior, resulting in performance degradation and safety risks for compressors and batteries. To effectively address this issue, an evaluation was conducted on the dynamic control characteristics of an EV thermal management system utilizing CO2 as the refrigerant in this study. Through mathematical modeling and experimental analysis, the erratic nature of the dynamic thermal process was first identified. The underlying reasons were elucidated, focusing on system control characteristics and intrinsic mechanisms. It was found that control disorder could induce abnormal actions in thermal management system components like compressors and expansion valve, leading to significant performance decline and issues such as liquid carryover in compressor suction. Furthermore, specific control disorder regions of CO2 heat pumps for EVs were delineated, providing a framework for assessing the likelihood of system control disorder. Notably, control disorder was more likely to occur under conditions of low indoor air flow rate, high ambient temperature, and low supply air temperature. Given the widespread nature of this issue and the lack of suitable solutions, two control disorder suppression schemes were developed using V2X technology and validated through simulation. Results showed that adoption of V2X communication technology prevented an average of 70.1 % COP degradation, ensuring stability and safety of compressors and batteries under various operating conditions. The research provides useful information for exploring the dynamic characteristics of CO2 thermal management systems, offering a novel approach to enhance the system stability and efficiency.