首页 > 最新文献

Etransportation最新文献

英文 中文
Enhancing control disorder and implementing V2X-Based suppression methods for electric vehicle CO2 thermal management systems 增强电动汽车二氧化碳热管理系统的控制紊乱和实施基于 V2X 的抑制方法
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-05-11 DOI: 10.1016/j.etran.2024.100336
Fan Jia , Xiang Yin , Feng Cao , Ce Cui , Jianmin Fang , Xiaolin Wang

In recent years, the development of electric vehicles (EVs) thermal management systems has underscored the crucial role in ensuring driving safety and optimizing driving range has become increasingly prominent. However, the inherent dynamic complexity of EV operation coupled with automatic control systems, can sometimes lead to unstable behavior, resulting in performance degradation and safety risks for compressors and batteries. To effectively address this issue, an evaluation was conducted on the dynamic control characteristics of an EV thermal management system utilizing CO2 as the refrigerant in this study. Through mathematical modeling and experimental analysis, the erratic nature of the dynamic thermal process was first identified. The underlying reasons were elucidated, focusing on system control characteristics and intrinsic mechanisms. It was found that control disorder could induce abnormal actions in thermal management system components like compressors and expansion valve, leading to significant performance decline and issues such as liquid carryover in compressor suction. Furthermore, specific control disorder regions of CO2 heat pumps for EVs were delineated, providing a framework for assessing the likelihood of system control disorder. Notably, control disorder was more likely to occur under conditions of low indoor air flow rate, high ambient temperature, and low supply air temperature. Given the widespread nature of this issue and the lack of suitable solutions, two control disorder suppression schemes were developed using V2X technology and validated through simulation. Results showed that adoption of V2X communication technology prevented an average of 70.1 % COP degradation, ensuring stability and safety of compressors and batteries under various operating conditions. The research provides useful information for exploring the dynamic characteristics of CO2 thermal management systems, offering a novel approach to enhance the system stability and efficiency.

近年来,电动汽车(EV)热管理系统的发展凸显了其在确保驾驶安全和优化行驶里程方面的重要作用。然而,电动汽车运行固有的动态复杂性加上自动控制系统,有时会导致行为不稳定,从而造成压缩机和电池性能下降并带来安全风险。为了有效解决这一问题,本研究对使用二氧化碳作为制冷剂的电动汽车热管理系统的动态控制特性进行了评估。通过数学建模和实验分析,首先确定了动态热过程的不稳定性。研究重点从系统控制特性和内在机制入手,阐明了其根本原因。研究发现,控制失调会诱发压缩机和膨胀阀等热管理系统组件的异常动作,从而导致性能显著下降,并引发压缩机吸入液体携带等问题。此外,还划定了电动汽车二氧化碳热泵的特定控制失调区域,为评估系统控制失调的可能性提供了一个框架。值得注意的是,在室内空气流速低、环境温度高和供气温度低的条件下,更容易出现控制失调。鉴于这一问题的普遍性和缺乏合适的解决方案,我们利用 V2X 技术开发了两种控制失调抑制方案,并通过模拟进行了验证。结果表明,采用 V2X 通信技术平均防止了 70.1% 的 COP 下降,确保了压缩机和电池在各种运行条件下的稳定性和安全性。这项研究为探索二氧化碳热管理系统的动态特性提供了有用信息,为提高系统稳定性和效率提供了一种新方法。
{"title":"Enhancing control disorder and implementing V2X-Based suppression methods for electric vehicle CO2 thermal management systems","authors":"Fan Jia ,&nbsp;Xiang Yin ,&nbsp;Feng Cao ,&nbsp;Ce Cui ,&nbsp;Jianmin Fang ,&nbsp;Xiaolin Wang","doi":"10.1016/j.etran.2024.100336","DOIUrl":"10.1016/j.etran.2024.100336","url":null,"abstract":"<div><p>In recent years, the development of electric vehicles (EVs) thermal management systems has underscored the crucial role in ensuring driving safety and optimizing driving range has become increasingly prominent. However, the inherent dynamic complexity of EV operation coupled with automatic control systems, can sometimes lead to unstable behavior, resulting in performance degradation and safety risks for compressors and batteries. To effectively address this issue, an evaluation was conducted on the dynamic control characteristics of an EV thermal management system utilizing CO<sub>2</sub> as the refrigerant in this study. Through mathematical modeling and experimental analysis, the erratic nature of the dynamic thermal process was first identified. The underlying reasons were elucidated, focusing on system control characteristics and intrinsic mechanisms. It was found that control disorder could induce abnormal actions in thermal management system components like compressors and expansion valve, leading to significant performance decline and issues such as liquid carryover in compressor suction. Furthermore, specific control disorder regions of CO<sub>2</sub> heat pumps for EVs were delineated, providing a framework for assessing the likelihood of system control disorder. Notably, control disorder was more likely to occur under conditions of low indoor air flow rate, high ambient temperature, and low supply air temperature. Given the widespread nature of this issue and the lack of suitable solutions, two control disorder suppression schemes were developed using V2X technology and validated through simulation. Results showed that adoption of V2X communication technology prevented an average of 70.1 % COP degradation, ensuring stability and safety of compressors and batteries under various operating conditions. The research provides useful information for exploring the dynamic characteristics of CO<sub>2</sub> thermal management systems, offering a novel approach to enhance the system stability and efficiency.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"21 ","pages":"Article 100336"},"PeriodicalIF":11.9,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141025476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Prediction of thermal runaway for a lithium-ion battery through multiphysics-informed DeepONet with virtual data 通过虚拟数据的多物理信息 DeepONet 预测锂离子电池的热失控现象
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-05-09 DOI: 10.1016/j.etran.2024.100337
Jinho Jeong , Eunji Kwak , Jun-hyeong Kim , Ki-Yong Oh

A surrogate model that predicts thermal runaway (TR) of lithium-ion batteries (LIBs) fast and accurately is essential, yet complex phenomena of TR present significant challenges to achieving adequate performance in both aspects, particularly as traditional finite element models (FEMs) incur significant time and cost. This study proposes a multiphysics-informed deep operator network (MPI-DeepONet) with encoders to address these issues. This proposed neural network aims to predict TR under various thermal abuse conditions, offering a fast and accurate TR prediction surrogate model. In this study, MPI-DeepONet with encoders is trained with virtual data from a multiphysics FEM to overcome the scarcity of actual TR data. The architecture of DeepONet solves interpolation and extrapolation problems, allowing predictions across multiple thermal abuse conditions once trained. The neural network is further enhanced by the supervision of energy balance and chemical reaction equations, ensuring accurate and robust predictions despite limited data by effectively capturing the complex phenomena of TR. Quantitative analysis, compared against actual experiments and ablation studies, confirms the effectiveness of the proposed neural network. Notably, MPI-DeepONet achieves a mean RMSE of 13.2 °C for temperature predictions in the test set, significantly outperforming the 25.4 °C RMSE of purely data-driven DeepONet. This improvement highlights the importance of integrating multiphysics constraints into the neural network. The generality of the proposed neural network is further evidenced by accurate TR prediction in both LFP and NMC cells. The features deployed on the proposed neural network enable real-time quantification of internal temperature distribution and dimensionless concentration of the key components in LIBs, which are challenging to measure directly, achieving speeds at least 10,000 times faster than FEM. The proposed neural network provides comprehensive information for advanced battery management systems to ensure safety and reliability in LIBs, accelerating the digital twin of electric transportation systems through artificial intelligence transformation.

快速准确地预测锂离子电池(LIB)热失控(TR)的替代模型至关重要,然而复杂的热失控现象给实现这两方面的充分性能带来了巨大挑战,尤其是传统的有限元模型(FEM)需要耗费大量的时间和成本。本研究提出了一种带有编码器的多物理信息深度算子网络(MPI-DeepONet)来解决这些问题。该建议的神经网络旨在预测各种热滥用条件下的 TR,提供快速准确的 TR 预测替代模型。在本研究中,带有编码器的 MPI-DeepONet 使用多物理场有限元的虚拟数据进行训练,以克服实际 TR 数据稀缺的问题。DeepONet 的结构可以解决内插法和外推法问题,一旦训练完成,就可以对多种热滥用条件进行预测。能量平衡和化学反应方程的监督进一步增强了神经网络,通过有效捕捉 TR 的复杂现象,确保在数据有限的情况下仍能进行准确、稳健的预测。根据实际实验和烧蚀研究进行的定量分析证实了所建议的神经网络的有效性。值得注意的是,MPI-DeepONet 对测试集中温度预测的平均 RMSE 为 13.2 °C,明显优于纯数据驱动 DeepONet 的 25.4 °C。这一改进凸显了将多物理约束整合到神经网络中的重要性。对 LFP 和 NMC 电池的 TR 预测准确,进一步证明了所提出的神经网络的通用性。所提出的神经网络所具有的特征能够实时量化锂电池中关键成分的内部温度分布和无量纲浓度,而直接测量这些成分是具有挑战性的,其速度比有限元分析至少快 10,000 倍。拟议的神经网络为先进的电池管理系统提供了全面的信息,以确保锂电池组的安全性和可靠性,通过人工智能转型加速电动交通系统的数字孪生。
{"title":"Prediction of thermal runaway for a lithium-ion battery through multiphysics-informed DeepONet with virtual data","authors":"Jinho Jeong ,&nbsp;Eunji Kwak ,&nbsp;Jun-hyeong Kim ,&nbsp;Ki-Yong Oh","doi":"10.1016/j.etran.2024.100337","DOIUrl":"10.1016/j.etran.2024.100337","url":null,"abstract":"<div><p>A surrogate model that predicts thermal runaway (TR) of lithium-ion batteries (LIBs) fast and accurately is essential, yet complex phenomena of TR present significant challenges to achieving adequate performance in both aspects, particularly as traditional finite element models (FEMs) incur significant time and cost. This study proposes a multiphysics-informed deep operator network (MPI-DeepONet) with encoders to address these issues. This proposed neural network aims to predict TR under various thermal abuse conditions, offering a fast and accurate TR prediction surrogate model. In this study, MPI-DeepONet with encoders is trained with virtual data from a multiphysics FEM to overcome the scarcity of actual TR data. The architecture of DeepONet solves interpolation and extrapolation problems, allowing predictions across multiple thermal abuse conditions once trained. The neural network is further enhanced by the supervision of energy balance and chemical reaction equations, ensuring accurate and robust predictions despite limited data by effectively capturing the complex phenomena of TR. Quantitative analysis, compared against actual experiments and ablation studies, confirms the effectiveness of the proposed neural network. Notably, MPI-DeepONet achieves a mean RMSE of 13.2 °C for temperature predictions in the test set, significantly outperforming the 25.4 °C RMSE of purely data-driven DeepONet. This improvement highlights the importance of integrating multiphysics constraints into the neural network. The generality of the proposed neural network is further evidenced by accurate TR prediction in both LFP and NMC cells. The features deployed on the proposed neural network enable real-time quantification of internal temperature distribution and dimensionless concentration of the key components in LIBs, which are challenging to measure directly, achieving speeds at least 10,000 times faster than FEM. The proposed neural network provides comprehensive information for advanced battery management systems to ensure safety and reliability in LIBs, accelerating the digital twin of electric transportation systems through artificial intelligence transformation.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"21 ","pages":"Article 100337"},"PeriodicalIF":11.9,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141030454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamic mechanical behaviors of load-bearing battery structure upon low-velocity impact loading in electric vehicles 电动汽车低速冲击加载时承重电池结构的动态力学行为
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-29 DOI: 10.1016/j.etran.2024.100334
Ruiqi Hu , Dian Zhou , Yikai Jia , Yang Chen , Chao Zhang

As the electrification trend of vehicles continues, new energy vehicles such as electric vehicles (EVs) and plug-in hybrid electric vehicles (PHEVs) are being equipped with new functional energy storage devices demanding a trade-off between electrical and mechanical property. Accordingly, composite-battery integrated structures which simultaneously carry mechanical resistance and energy-storage capacity, are being explored to offer great potential for the next generation of EVs or PHEVs. Herein, the dynamic responses and failure mechanisms of the integrated structure under the commonly occurring low-velocity impact events are studied both experimentally and numerically. A macro-scale finite element (FE) model was developed by implementing constitutive models of component materials, including lithium‐ion polymer (LiPo) battery cells, polymer foams, and carbon fiber-reinforced polymers (CFRP). The numerical method demonstrates good feasibility and accurately predicts impact behaviors, with the maximum error of the peak impact load not exceeding 8 %. The integrated structures are proven to reduce mechanical damage while maintaining mechanical and electrochemical performance within a range of impacts. The electrical and mechanical behaviors and their correlations were revealed. Sensitivity of the mechanical behaviors and electrical failure to battery arrangement were discussed as well as the structure design on energy absorption capacity. These results hold significant potential for the safety and lightweight design of energy storage composite structures incorporating lithium-ion batteries.

随着汽车电气化趋势的不断发展,电动汽车(EV)和插电式混合动力汽车(PHEV)等新能源汽车正在配备新的功能性储能装置,这些装置需要在电气性能和机械性能之间进行权衡。因此,同时具有机械阻力和储能能力的复合材料电池集成结构正在被探索之中,为下一代电动汽车或混合动力电动汽车(PHEV)提供了巨大潜力。本文通过实验和数值方法研究了集成结构在常见的低速冲击事件下的动态响应和失效机制。通过实施包括锂离子聚合物(LiPo)电池芯、聚合物泡沫和碳纤维增强聚合物(CFRP)在内的组件材料构成模型,建立了宏观尺度的有限元(FE)模型。该数值方法具有良好的可行性,能准确预测冲击行为,冲击载荷峰值的最大误差不超过 8%。经证明,集成结构可减少机械损伤,同时在一定冲击范围内保持机械和电化学性能。研究揭示了电气和机械行为及其相关性。还讨论了机械行为和电气故障对电池布置的敏感性,以及结构设计对能量吸收能力的影响。这些结果为结合锂离子电池的储能复合结构的安全性和轻量化设计提供了巨大的潜力。
{"title":"Dynamic mechanical behaviors of load-bearing battery structure upon low-velocity impact loading in electric vehicles","authors":"Ruiqi Hu ,&nbsp;Dian Zhou ,&nbsp;Yikai Jia ,&nbsp;Yang Chen ,&nbsp;Chao Zhang","doi":"10.1016/j.etran.2024.100334","DOIUrl":"https://doi.org/10.1016/j.etran.2024.100334","url":null,"abstract":"<div><p>As the electrification trend of vehicles continues, new energy vehicles such as electric vehicles (EVs) and plug-in hybrid electric vehicles (PHEVs) are being equipped with new functional energy storage devices demanding a trade-off between electrical and mechanical property. Accordingly, composite-battery integrated structures which simultaneously carry mechanical resistance and energy-storage capacity, are being explored to offer great potential for the next generation of EVs or PHEVs. Herein, the dynamic responses and failure mechanisms of the integrated structure under the commonly occurring low-velocity impact events are studied both experimentally and numerically. A macro-scale finite element (FE) model was developed by implementing constitutive models of component materials, including lithium‐ion polymer (LiPo) battery cells, polymer foams, and carbon fiber-reinforced polymers (CFRP). The numerical method demonstrates good feasibility and accurately predicts impact behaviors, with the maximum error of the peak impact load not exceeding 8 %. The integrated structures are proven to reduce mechanical damage while maintaining mechanical and electrochemical performance within a range of impacts. The electrical and mechanical behaviors and their correlations were revealed. Sensitivity of the mechanical behaviors and electrical failure to battery arrangement were discussed as well as the structure design on energy absorption capacity. These results hold significant potential for the safety and lightweight design of energy storage composite structures incorporating lithium-ion batteries.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"21 ","pages":"Article 100334"},"PeriodicalIF":11.9,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140825599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Revealing the mechanism of pack ceiling failure induced by thermal runaway in NCM batteries: A coupled multiphase fluid-structure interaction model for electric vehicles 揭示 NCM 电池热失控导致电池组顶盖失效的机理:电动汽车多相流体-结构-相互作用耦合模型
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-24 DOI: 10.1016/j.etran.2024.100335
Junyuan Li , Peng Gao , Bang Tong , Zhixiang Cheng , Mingwei Cao , Wenxin Mei , Qingsong Wang , Jinhua Sun , Peng Qin

Structure failure of lithium-ion battery (LIB) pack ceiling leads to the unintended release of combustible and poisonous substances during thermal runaway (TR), resulting in personnel injuries and financial losses. However, limited research has been conducted on the mechanism behind pack ceiling failures. In this study, we developed a coupled multiphase fluid-structure interaction (FSI) model to simulate the evolution of up-cover baffle under the TR impact of a 52 Ah NCM battery. Our findings reveal several important insights:1) the maximum force and temperature on the baffle are 13.01 N and 598.5 °C in experiment; 2) the simulation shows that particles exert higher temperature and greater force on the baffle compared to the gas phase; 3) the overall equivalent stress in the stainless-steel baffle surpasses the tensile strength that incurs crack on the baffles. According to the validated model, we find that the baffle structure failure is caused by the thermal stress from particle-structure heat conduction. Furthermore, this observation is applicable to the structure failure problems associated to the thermal runaway of high-density battery that involves enormous particles. In addition, the insulation layer is found to be more effective than the gap distance in protecting the pack ceiling. These findings offer a valuable insight into the structure design of LIB pack, and provide the guidance toward future battery integration technologies.

锂离子电池组(LIB)顶盖结构失效会导致热失控(TR)过程中可燃和有毒物质的意外释放,造成人员伤亡和经济损失。然而,对电池组天花板失效背后机理的研究还很有限。在本研究中,我们开发了一种多相流固耦合(FSI)模型,用于模拟 52 Ah NCM 电池在 TR 冲击下上盖挡板的演变过程。我们的研究结果揭示了几个重要的观点:1)实验中,挡板上的最大力和温度分别为 13.01 N 和 598.5 °C;2)模拟结果表明,与气相相比,颗粒对挡板施加了更高的温度和更大的力;3)不锈钢挡板上的整体等效应力超过了在挡板上产生裂纹的拉伸强度。根据验证模型,我们发现障板结构失效是由粒子-结构热传导产生的热应力引起的。此外,这一观点也适用于涉及巨大颗粒的高密度电池热失控相关的结构破坏问题。此外,在保护电池组顶盖方面,绝缘层比间隙距离更有效。这些发现为锂电池组的结构设计提供了宝贵的见解,并为未来的电池集成技术提供了指导。
{"title":"Revealing the mechanism of pack ceiling failure induced by thermal runaway in NCM batteries: A coupled multiphase fluid-structure interaction model for electric vehicles","authors":"Junyuan Li ,&nbsp;Peng Gao ,&nbsp;Bang Tong ,&nbsp;Zhixiang Cheng ,&nbsp;Mingwei Cao ,&nbsp;Wenxin Mei ,&nbsp;Qingsong Wang ,&nbsp;Jinhua Sun ,&nbsp;Peng Qin","doi":"10.1016/j.etran.2024.100335","DOIUrl":"10.1016/j.etran.2024.100335","url":null,"abstract":"<div><p>Structure failure of lithium-ion battery (LIB) pack ceiling leads to the unintended release of combustible and poisonous substances during thermal runaway (TR), resulting in personnel injuries and financial losses. However, limited research has been conducted on the mechanism behind pack ceiling failures. In this study, we developed a coupled multiphase fluid-structure interaction (FSI) model to simulate the evolution of up-cover baffle under the TR impact of a 52 Ah NCM battery. Our findings reveal several important insights:1) the maximum force and temperature on the baffle are 13.01 N and 598.5 °C in experiment; 2) the simulation shows that particles exert higher temperature and greater force on the baffle compared to the gas phase; 3) the overall equivalent stress in the stainless-steel baffle surpasses the tensile strength that incurs crack on the baffles. According to the validated model, we find that the baffle structure failure is caused by the thermal stress from particle-structure heat conduction. Furthermore, this observation is applicable to the structure failure problems associated to the thermal runaway of high-density battery that involves enormous particles. In addition, the insulation layer is found to be more effective than the gap distance in protecting the pack ceiling. These findings offer a valuable insight into the structure design of LIB pack, and provide the guidance toward future battery integration technologies.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"20 ","pages":"Article 100335"},"PeriodicalIF":11.9,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140782912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lithium-ion battery sudden death: Safety degradation and failure mechanism 锂离子电池猝死:安全退化和失效机制
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-16 DOI: 10.1016/j.etran.2024.100333
Guangxu Zhang , Xuezhe Wei , Xueyuan Wang , Jiangong Zhu , Siqi Chen , Gang Wei , Xiaopeng Tang , Xin Lai , Haifeng Dai

Environmental pollution and energy scarcity have acted as catalysts for the energy revolution, particularly driving the rapid progression of vehicle electrification. Lithium-ion batteries play a fundamental role as the pivotal components in electric vehicles. Nevertheless, battery sudden death poses substantial challenges to battery design and management. This work comprehensively investigates the failure mechanism of cell sudden death under different degradation paths and its impact on cell performances. Multi-angle characterization analysis shows that lithium plating is the primary failure mechanism of battery sudden death under different degradation paths. However, the formation mechanisms of lithium plating differ in various degradation paths. In the path-L and path-F, the limited lithium intercalation rate in graphite leads to lithium plating, while localized anode drying and uneven potential distribution are the causes in the path-H and path-R. Furthermore, sudden death significantly reduces the cell electrochemical performances and thermal safety, but the cell performance evolution varies under different degradation paths. Sudden death primarily affects the anode interface polarization process in the path-L and path-F, with a more severe impact on cell thermal safety. However, sudden death mainly affects the charge transfer process, with a relatively milder impact on cell thermal safety. These findings can provide valuable insights for optimizing battery design and management.

环境污染和能源短缺是能源革命的催化剂,尤其推动了汽车电气化的快速发展。锂离子电池作为电动汽车的关键部件发挥着重要作用。然而,电池猝死给电池设计和管理带来了巨大挑战。这项研究全面探讨了不同降解路径下电池猝死的失效机理及其对电池性能的影响。多角度表征分析表明,镀锂是不同降解路径下电池猝死的主要失效机制。然而,在不同的降解路径下,锂镀层的形成机制也不尽相同。在路径-L 和路径-F 中,石墨中有限的锂插层速率导致镀锂,而在路径-H 和路径-R 中,局部负极干燥和电位分布不均是镀锂的原因。此外,猝死会大大降低电池的电化学性能和热安全性,但在不同的降解路径下,电池的性能演变也各不相同。在路径-L 和路径-F 中,猝死主要影响阳极界面极化过程,对电池热安全性的影响更为严重。然而,猝死主要影响电荷转移过程,对电池热安全性的影响相对较小。这些发现可为优化电池设计和管理提供有价值的见解。
{"title":"Lithium-ion battery sudden death: Safety degradation and failure mechanism","authors":"Guangxu Zhang ,&nbsp;Xuezhe Wei ,&nbsp;Xueyuan Wang ,&nbsp;Jiangong Zhu ,&nbsp;Siqi Chen ,&nbsp;Gang Wei ,&nbsp;Xiaopeng Tang ,&nbsp;Xin Lai ,&nbsp;Haifeng Dai","doi":"10.1016/j.etran.2024.100333","DOIUrl":"https://doi.org/10.1016/j.etran.2024.100333","url":null,"abstract":"<div><p>Environmental pollution and energy scarcity have acted as catalysts for the energy revolution, particularly driving the rapid progression of vehicle electrification. Lithium-ion batteries play a fundamental role as the pivotal components in electric vehicles. Nevertheless, battery sudden death poses substantial challenges to battery design and management. This work comprehensively investigates the failure mechanism of cell sudden death under different degradation paths and its impact on cell performances. Multi-angle characterization analysis shows that lithium plating is the primary failure mechanism of battery sudden death under different degradation paths. However, the formation mechanisms of lithium plating differ in various degradation paths. In the path-L and path-F, the limited lithium intercalation rate in graphite leads to lithium plating, while localized anode drying and uneven potential distribution are the causes in the path-H and path-R. Furthermore, sudden death significantly reduces the cell electrochemical performances and thermal safety, but the cell performance evolution varies under different degradation paths. Sudden death primarily affects the anode interface polarization process in the path-L and path-F, with a more severe impact on cell thermal safety. However, sudden death mainly affects the charge transfer process, with a relatively milder impact on cell thermal safety. These findings can provide valuable insights for optimizing battery design and management.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"20 ","pages":"Article 100333"},"PeriodicalIF":11.9,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140606626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
How does room temperature cycling ageing affect lithium-ion battery behaviors under extreme indentation? 室温循环老化如何影响锂离子电池在极端压痕下的行为?
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-16 DOI: 10.1016/j.etran.2024.100331
Yunlong Qu, Bobin Xing, Yong Xia, Qing Zhou

Safety of lithium-ion battery (LIB) cells throughout the whole lifecycle has drawn enormous research interest. Understanding how cycling ageing affects the mechanical-electrical-thermal responses of LIB cells under mechanical abuse is meaningful for more considerate safety design. In the present study, impact of room temperature ageing on morphology of lithium-ion pouch cell was experimentally explored at first, which clearly identified the deposition phenomenon on electrodes induced by electrolyte consumption. Spherical indentation along out-of-plane direction was carried out on both pristine and aged cells, in which the mechanical-electrical-thermal responses were all monitored. Test results indicate that the mechanical response of the aged cells is quite distinct from the pristine ones, characterized by a rightward shift of the force-displacement curve. Electrical and thermal responses of the aged cells were comparatively less severe. It is inferred that those deposits generated during the ageing process postpone the failure of cells. The short circuit of aged cells behaves relatively tenderly as short contact is alleviated by deposits on the surface of electrodes. By combining the present results with previous researches, correlation between the ageing mechanism and the mechanical abuse failure was sorted for different cells subjected to different ageing processes. It is recognized that changes in mechanical, electrical, and thermal responses of aged cells are highly dependent on both ageing condition and battery configuration.

锂离子电池(LIB)在整个生命周期中的安全性引起了人们极大的研究兴趣。了解循环老化如何影响锂离子电池在机械滥用情况下的机械、电气和热响应,对于更周全的安全设计非常有意义。本研究首先通过实验探讨了室温老化对锂离子袋式电池形貌的影响,明确了电解液消耗引起的电极沉积现象。在原始电池和老化电池上沿平面外方向进行球形压痕试验,监测其机械、电气和热响应。测试结果表明,老化电池的机械响应与原始电池截然不同,其特征是力-位移曲线右移。老化电池的电反应和热反应则相对较轻。由此推断,老化过程中产生的沉积物会推迟电池的失效时间。由于电极表面的沉积物缓解了短路接触,因此老化电池的短路表现相对较轻。通过将目前的研究结果与之前的研究结果相结合,对不同老化过程中的不同电池的老化机制和机械滥用失效之间的相关性进行了分类。我们认识到,老化电池的机械、电气和热反应变化与老化条件和电池配置密切相关。
{"title":"How does room temperature cycling ageing affect lithium-ion battery behaviors under extreme indentation?","authors":"Yunlong Qu,&nbsp;Bobin Xing,&nbsp;Yong Xia,&nbsp;Qing Zhou","doi":"10.1016/j.etran.2024.100331","DOIUrl":"https://doi.org/10.1016/j.etran.2024.100331","url":null,"abstract":"<div><p>Safety of lithium-ion battery (LIB) cells throughout the whole lifecycle has drawn enormous research interest. Understanding how cycling ageing affects the mechanical-electrical-thermal responses of LIB cells under mechanical abuse is meaningful for more considerate safety design. In the present study, impact of room temperature ageing on morphology of lithium-ion pouch cell was experimentally explored at first, which clearly identified the deposition phenomenon on electrodes induced by electrolyte consumption. Spherical indentation along out-of-plane direction was carried out on both pristine and aged cells, in which the mechanical-electrical-thermal responses were all monitored. Test results indicate that the mechanical response of the aged cells is quite distinct from the pristine ones, characterized by a rightward shift of the force-displacement curve. Electrical and thermal responses of the aged cells were comparatively less severe. It is inferred that those deposits generated during the ageing process postpone the failure of cells. The short circuit of aged cells behaves relatively tenderly as short contact is alleviated by deposits on the surface of electrodes. By combining the present results with previous researches, correlation between the ageing mechanism and the mechanical abuse failure was sorted for different cells subjected to different ageing processes. It is recognized that changes in mechanical, electrical, and thermal responses of aged cells are highly dependent on both ageing condition and battery configuration.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"20 ","pages":"Article 100331"},"PeriodicalIF":11.9,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140558477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive study of various carbon-free vehicle propulsion systems utilizing ammonia-hydrogen synergy fuel 利用氨氢协同燃料的各种无碳车辆推进系统的综合研究
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-15 DOI: 10.1016/j.etran.2024.100332
Nuo Lei, Hao Zhang, Hu Chen, Zhi Wang

Ammonia and hydrogen, as carbon-free clean energy, can be converted and applied in various scenarios. They can also be mixed to achieve synergistic efficiency. To promote the carbon-neutral development of heavy-duty vehicles, this paper studies an ammonia-hydrogen powertrain equipped with both a fuel cell and an engine (FCEAP). This powertrain efficiently allocates energy between multiple power sources and exploits the potential of ammonia-hydrogen synergy fuel. The modeling of FCEAP is based on experimental data obtained from engine bench tests, and the control strategy enables real-time control. Additionally, FCEAP undergoes multi-objective co-optimization using the non-dominated sorting algorithm-III (NSGA-III). By optimizing ammonia consumption, acceleration time, and manufacturing cost, Pareto solutions for the configuration and control strategy parameters are obtained. Furthermore, FCEAP is compared to ammonia-hydrogen powertrains equipped with either a fuel cell (FCAP) or an engine (EAP). The trade-off solutions indicate that FCEAP effectively balances energy consumption and manufacturing cost compared with FCAP and EAP. A comprehensive analysis of the energy flow distribution within various ammonia-hydrogen powertrains is conducted, revealing the operational processes and details of each component. The proposed ammonia-hydrogen powertrain represents an important technological pathway for achieving carbon neutrality in the future heavy-duty long-haul trucks industry.

氨和氢作为无碳清洁能源,可以在各种情况下进行转换和应用。它们还可以混合使用,实现协同增效。为促进重型汽车的碳中和发展,本文研究了一种同时配备燃料电池和发动机的氨氢动力系统(FCEAP)。该动力系统可在多种动力源之间有效分配能量,并挖掘氨氢协同燃料的潜力。FCEAP 的建模基于发动机台架试验获得的实验数据,控制策略可实现实时控制。此外,FCEAP 利用非支配排序算法-III(NSGA-III)进行了多目标协同优化。通过优化氨气消耗、加速时间和制造成本,获得了配置和控制策略参数的帕累托解决方案。此外,还将 FCEAP 与配备燃料电池(FCAP)或发动机(EAP)的氨氢动力系统进行了比较。权衡解决方案表明,与 FCAP 和 EAP 相比,FCEAP 能有效平衡能耗和制造成本。对各种氨氢动力系统内部的能量流分布进行了全面分析,揭示了每个组件的运行过程和细节。所提出的氨氢动力系统是未来重型长途卡车行业实现碳中和的重要技术途径。
{"title":"A comprehensive study of various carbon-free vehicle propulsion systems utilizing ammonia-hydrogen synergy fuel","authors":"Nuo Lei,&nbsp;Hao Zhang,&nbsp;Hu Chen,&nbsp;Zhi Wang","doi":"10.1016/j.etran.2024.100332","DOIUrl":"https://doi.org/10.1016/j.etran.2024.100332","url":null,"abstract":"<div><p>Ammonia and hydrogen, as carbon-free clean energy, can be converted and applied in various scenarios. They can also be mixed to achieve synergistic efficiency. To promote the carbon-neutral development of heavy-duty vehicles, this paper studies an ammonia-hydrogen powertrain equipped with both a fuel cell and an engine (FCEAP). This powertrain efficiently allocates energy between multiple power sources and exploits the potential of ammonia-hydrogen synergy fuel. The modeling of FCEAP is based on experimental data obtained from engine bench tests, and the control strategy enables real-time control. Additionally, FCEAP undergoes multi-objective co-optimization using the non-dominated sorting algorithm-III (NSGA-III). By optimizing ammonia consumption, acceleration time, and manufacturing cost, Pareto solutions for the configuration and control strategy parameters are obtained. Furthermore, FCEAP is compared to ammonia-hydrogen powertrains equipped with either a fuel cell (FCAP) or an engine (EAP). The trade-off solutions indicate that FCEAP effectively balances energy consumption and manufacturing cost compared with FCAP and EAP. A comprehensive analysis of the energy flow distribution within various ammonia-hydrogen powertrains is conducted, revealing the operational processes and details of each component. The proposed ammonia-hydrogen powertrain represents an important technological pathway for achieving carbon neutrality in the future heavy-duty long-haul trucks industry.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"20 ","pages":"Article 100332"},"PeriodicalIF":11.9,"publicationDate":"2024-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140552384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in separator design for lithium metal batteries without dendrite formation: Implications for electric vehicles 无枝晶形成的锂金属电池隔膜设计的最新进展:对电动汽车的影响
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-10 DOI: 10.1016/j.etran.2024.100330
Yu Lei , Lulu Xu , Qing Nian Chan , Ao Li , Anthony Chun Yin Yuen , Yao Yuan , Guan Heng Yeoh , Wei Wang

Electric vehicle (EV) technology addresses the challenge of reducing carbon and greenhouse gas emissions. The power battery, which serves as the energy source for EVs, directly impacts their driving range, maximum speed, and service life. Considering the high energy density requirements for future EVs, lithium metal anodes possess several advantages such as high theoretical capacity, high energy and power density, and low electrochemical reduction potential which enable them to be a promising material for next-generation batteries. However, lithium metal anodes suffer from short cycle life and safety concerns due to the formation of dendritic and moss-like metal deposits that impede battery performance and reliability. This review will feature the recent advancement of functional separators to tackle these challenges. Firstly, this review presents a comprehensive review of the growth mechanism of lithium dendrites and delineates the underlying processes leading to battery failure. This aims to deepen understanding, which serves as a fundamental basis for classifying separators. Then, according to the growth of lithium dendrites and the failure process of lithium metal batteries, namely lithium-ion nucleation, growth of lithium dendrites, penetration of lithium dendrites into the separator, thermal runaway and even failure of the battery, four types of functional separators for different stages are proposed. The functions of these types of separators are to prevent the nucleation of lithium ions and regulate the uniform deposition of lithium ions, detect and eliminate dendrites, increase the mechanical strength of the separator and enhance the thermal stability and flame-retardancy of the separators, respectively. Finally, the recent advances of the above strategies are reviewed and discussed, existing critical problems are identified, and the future perspective of functional separators for the safety of lithium metal batteries is also discussed.

电动汽车(EV)技术解决了减少碳和温室气体排放的难题。作为电动汽车能源的动力电池直接影响着电动汽车的行驶里程、最高车速和使用寿命。考虑到未来电动汽车对高能量密度的要求,锂金属阳极具有理论容量大、能量和功率密度高、电化学还原电位低等优点,是下一代电池的理想材料。然而,锂金属阳极由于会形成树枝状和苔藓状金属沉积物,从而影响电池的性能和可靠性,因此存在循环寿命短和安全问题。本综述将介绍功能性隔膜的最新进展,以应对这些挑战。首先,本综述全面回顾了锂枝晶的生长机制,并描述了导致电池失效的基本过程。这样做的目的是加深理解,为隔膜分类提供基本依据。然后,根据锂枝晶的生长和锂金属电池的失效过程,即锂离子成核、锂枝晶生长、锂枝晶渗入隔膜、热失控乃至电池失效,提出了针对不同阶段的四种功能隔膜。这些隔膜的功能分别是防止锂离子成核和调节锂离子的均匀沉积、检测和消除枝晶、提高隔膜的机械强度以及增强隔膜的热稳定性和阻燃性。最后,对上述策略的最新进展进行了回顾和讨论,指出了存在的关键问题,并展望了功能性隔膜在锂金属电池安全方面的未来前景。
{"title":"Recent advances in separator design for lithium metal batteries without dendrite formation: Implications for electric vehicles","authors":"Yu Lei ,&nbsp;Lulu Xu ,&nbsp;Qing Nian Chan ,&nbsp;Ao Li ,&nbsp;Anthony Chun Yin Yuen ,&nbsp;Yao Yuan ,&nbsp;Guan Heng Yeoh ,&nbsp;Wei Wang","doi":"10.1016/j.etran.2024.100330","DOIUrl":"https://doi.org/10.1016/j.etran.2024.100330","url":null,"abstract":"<div><p>Electric vehicle (EV) technology addresses the challenge of reducing carbon and greenhouse gas emissions. The power battery, which serves as the energy source for EVs, directly impacts their driving range, maximum speed, and service life. Considering the high energy density requirements for future EVs, lithium metal anodes possess several advantages such as high theoretical capacity, high energy and power density, and low electrochemical reduction potential which enable them to be a promising material for next-generation batteries. However, lithium metal anodes suffer from short cycle life and safety concerns due to the formation of dendritic and moss-like metal deposits that impede battery performance and reliability. This review will feature the recent advancement of functional separators to tackle these challenges. Firstly, this review presents a comprehensive review of the growth mechanism of lithium dendrites and delineates the underlying processes leading to battery failure. This aims to deepen understanding, which serves as a fundamental basis for classifying separators. Then, according to the growth of lithium dendrites and the failure process of lithium metal batteries, namely lithium-ion nucleation, growth of lithium dendrites, penetration of lithium dendrites into the separator, thermal runaway and even failure of the battery, four types of functional separators for different stages are proposed. The functions of these types of separators are to prevent the nucleation of lithium ions and regulate the uniform deposition of lithium ions, detect and eliminate dendrites, increase the mechanical strength of the separator and enhance the thermal stability and flame-retardancy of the separators, respectively. Finally, the recent advances of the above strategies are reviewed and discussed, existing critical problems are identified, and the future perspective of functional separators for the safety of lithium metal batteries is also discussed.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"20 ","pages":"Article 100330"},"PeriodicalIF":11.9,"publicationDate":"2024-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590116824000201/pdfft?md5=3539b65fc39a5d7928a0176ed21acf0f&pid=1-s2.0-S2590116824000201-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140552383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Decoding range variability in electric vehicles: Unravelling the influence of cell-to-cell parameter variation and pack configuration 解码电动汽车的续航里程变化:解读电池间参数变化和电池组配置的影响
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-03 DOI: 10.1016/j.etran.2024.100329
Sourabh Singh , Sarbani Mandal , Sai Krishna Mulpuri , Bikash Sah , Praveen Kumar

This study addresses the common occurrence of cell-to-cell variations arising from manufacturing tolerances and their implications during battery production. The focus is on assessing the impact of these inherent differences in cells and exploring diverse cell and module connection methods on battery pack performance and their subsequent influence on the driving range of electric vehicles (EVs). The analysis spans three battery pack sizes, encompassing various constant discharge rates and nine distinct drive cycles representative of driving behaviours across different regions of India. Two interconnection topologies, categorised as “string” and “cross”, are examined. The findings reveal that cross-connected packs exhibit reduced energy output compared to string-connected configurations, which is reflected in the driving range outcomes observed during drive cycle simulations. Additionally, the study investigates the effects of standard deviation in cell parameters, concluding that an increased standard deviation (SD) leads to decreased energy output from the packs. Notably, string-connected packs demonstrate superior performance in terms of extractable energy under such conditions.

本研究探讨了电池生产过程中常见的因制造公差引起的电池间差异及其影响。重点是评估电池中这些固有差异的影响,并探讨不同电池和模块连接方法对电池组性能的影响,以及随后对电动汽车(EV)行驶里程的影响。分析涵盖三种电池组尺寸,包括各种恒定放电率和九种不同的驱动循环,代表了印度不同地区的驾驶行为。研究了 "串联 "和 "交叉 "两种互连拓扑结构。研究结果表明,与串联配置相比,交叉连接的电池组显示出较低的能量输出,这反映在驱动循环模拟中观察到的行驶里程结果上。此外,研究还调查了电池参数中标准偏差的影响,得出的结论是标准偏差(SD)的增加会导致电池组输出的能量减少。值得注意的是,在这种条件下,串联式电池组在可提取能量方面表现出更优越的性能。
{"title":"Decoding range variability in electric vehicles: Unravelling the influence of cell-to-cell parameter variation and pack configuration","authors":"Sourabh Singh ,&nbsp;Sarbani Mandal ,&nbsp;Sai Krishna Mulpuri ,&nbsp;Bikash Sah ,&nbsp;Praveen Kumar","doi":"10.1016/j.etran.2024.100329","DOIUrl":"https://doi.org/10.1016/j.etran.2024.100329","url":null,"abstract":"<div><p>This study addresses the common occurrence of cell-to-cell variations arising from manufacturing tolerances and their implications during battery production. The focus is on assessing the impact of these inherent differences in cells and exploring diverse cell and module connection methods on battery pack performance and their subsequent influence on the driving range of electric vehicles (EVs). The analysis spans three battery pack sizes, encompassing various constant discharge rates and nine distinct drive cycles representative of driving behaviours across different regions of India. Two interconnection topologies, categorised as “string” and “cross”, are examined. The findings reveal that cross-connected packs exhibit reduced energy output compared to string-connected configurations, which is reflected in the driving range outcomes observed during drive cycle simulations. Additionally, the study investigates the effects of standard deviation in cell parameters, concluding that an increased standard deviation (SD) leads to decreased energy output from the packs. Notably, string-connected packs demonstrate superior performance in terms of extractable energy under such conditions.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"20 ","pages":"Article 100329"},"PeriodicalIF":11.9,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590116824000195/pdfft?md5=95f9f4099b650810285e13132b2d7ba7&pid=1-s2.0-S2590116824000195-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140540281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multidimensional fire propagation of lithium-ion phosphate batteries for energy storage 用于储能的磷酸锂离子电池的多维火势传播
IF 11.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-04-03 DOI: 10.1016/j.etran.2024.100328
Qinzheng Wang , Huaibin Wang , Chengshan Xu , Changyong Jin , Shilin Wang , Lejun Xu , Jiting Ouyang , Xuning Feng

In electrochemical energy storage stations, battery modules are stacked layer by layer on the racks. During the thermal runaway process of the battery, combustible mixture gases are vented. Once ignited by high-temperature surfaces or arcing, the resulting intense jet fire can cause the spread of both the same-layer and upper-layer battery modules. The direction of thermal runaway propagation of the battery involves both horizontal and vertical dimensions. Currently, there is a lack of quantitative research on the multidimensional fire propagation mechanism and heat flow patterns of the “thermal runaway-spontaneous heating-flaming” process in lithium-ion phosphate batteries. This paper conducts multidimensional fire propagation experiments on lithium-ion phosphate batteries in a realistic electrochemical energy storage station scenario. It investigates the propagation characteristics of lithium-ion phosphate batteries in both horizontal and vertical directions, the heat flow patterns during multidimensional propagation, and elucidates the influence mechanism of flame radiation heat transfer on thermal runaway propagation. Research indicates that when the heat transfer reaches 56.6 kJ, it triggers the fire propagation of cell. The heat required to trigger the fire propagation of a battery module is 35.99 kJ. In vertical fire propagation, the thermal runaway propagation time of the upper module is shorter (reduced from 122.3 s to 62.3 s), the temperature is higher (increased from 610.6 °C to 645 °C), the heat release is greater (increased from 205.69 kJ to 221.05 kJ), and the combustion is more intense. The research results of this paper can provide a theoretical basis and technical guidance for the fire safety design of energy storage stations.

在电化学储能站中,电池模块逐层堆叠在支架上。在电池的热失控过程中,可燃混合气体被排出。一旦被高温表面或电弧点燃,由此产生的强烈喷射火会导致同层和上层电池模块蔓延。电池热失控的传播方向涉及水平和垂直两个维度。目前,对磷酸锂离子电池 "热失控-自燃-起火 "过程的多维火势传播机理和热流模式缺乏定量研究。本文在真实的电化学储能站场景下,对磷酸锂离子电池进行了多维火灾传播实验。研究了磷酸锂离子电池在水平和垂直方向上的传播特性、多维传播过程中的热流模式,并阐明了火焰辐射传热对热失控传播的影响机理。研究表明,当热传导达到 56.6 kJ 时,就会引发电池的火势传播。引发电池组件火势蔓延所需的热量为 35.99 kJ。在垂直火势传播过程中,上部模块的热失控传播时间更短(从 122.3 秒缩短至 62.3 秒),温度更高(从 610.6 ℃升至 645 ℃),放热量更大(从 205.69 kJ 升至 221.05 kJ),燃烧更剧烈。本文的研究成果可为储能站的消防安全设计提供理论依据和技术指导。
{"title":"Multidimensional fire propagation of lithium-ion phosphate batteries for energy storage","authors":"Qinzheng Wang ,&nbsp;Huaibin Wang ,&nbsp;Chengshan Xu ,&nbsp;Changyong Jin ,&nbsp;Shilin Wang ,&nbsp;Lejun Xu ,&nbsp;Jiting Ouyang ,&nbsp;Xuning Feng","doi":"10.1016/j.etran.2024.100328","DOIUrl":"https://doi.org/10.1016/j.etran.2024.100328","url":null,"abstract":"<div><p>In electrochemical energy storage stations, battery modules are stacked layer by layer on the racks. During the thermal runaway process of the battery, combustible mixture gases are vented. Once ignited by high-temperature surfaces or arcing, the resulting intense jet fire can cause the spread of both the same-layer and upper-layer battery modules. The direction of thermal runaway propagation of the battery involves both horizontal and vertical dimensions. Currently, there is a lack of quantitative research on the multidimensional fire propagation mechanism and heat flow patterns of the “thermal runaway-spontaneous heating-flaming” process in lithium-ion phosphate batteries. This paper conducts multidimensional fire propagation experiments on lithium-ion phosphate batteries in a realistic electrochemical energy storage station scenario. It investigates the propagation characteristics of lithium-ion phosphate batteries in both horizontal and vertical directions, the heat flow patterns during multidimensional propagation, and elucidates the influence mechanism of flame radiation heat transfer on thermal runaway propagation. Research indicates that when the heat transfer reaches 56.6 kJ, it triggers the fire propagation of cell. The heat required to trigger the fire propagation of a battery module is 35.99 kJ. In vertical fire propagation, the thermal runaway propagation time of the upper module is shorter (reduced from 122.3 s to 62.3 s), the temperature is higher (increased from 610.6 °C to 645 °C), the heat release is greater (increased from 205.69 kJ to 221.05 kJ), and the combustion is more intense. The research results of this paper can provide a theoretical basis and technical guidance for the fire safety design of energy storage stations.</p></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":"20 ","pages":"Article 100328"},"PeriodicalIF":11.9,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140350845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Etransportation
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1