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The role of EV fast charging in the urban context: An agent-based model approach 电动汽车快速充电在城市环境中的作用:基于代理模型的方法
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-10-22 DOI: 10.1016/j.etran.2024.100369
F. Hipolito , J. Rich , Peter Bach Andersen
Using an agent-based simulation approach, this paper investigates the role of fast-charging infrastructure in urban environments. The simulation model tracks the spatial and temporal behaviours of electric vehicles (EVs), facilitating a comprehensive analysis of the deployment of charging infrastructure. Notably, the model incorporates non-parametric queuing dynamics, information-sharing regarding waiting times, and diverse agent characteristics, deepening insights into the subject matter. Drawing on a large-scale implementation in the municipalities of Frederiksberg and Copenhagen, the study advocates for adopting fast chargers by demonstrating several key points. Firstly, information-sharing significantly reduces waiting times, particularly within the fast-charging network, with potential reductions of up to 30% during peak demand periods. Secondly, larger fast-charging clusters comprising 10–14 outlets outperform smaller clusters, primarily due to reduced waiting times and enhanced prediction accuracy of waiting times, which is a consequence of the information-sharing. Thirdly, placement strategies based on unserved demand metrics yield superior outcomes than those solely driven by observed demand patterns. By effectively monitoring both observed and unmet demand, these strategies tend to better optimize charging infrastructure placement. These insights, which emerge from the sophisticated and heterogeneous nature of the simulation framework, highlight the value of information and unserved demand in this field.
本文采用基于代理的模拟方法,研究了快速充电基础设施在城市环境中的作用。仿真模型跟踪电动汽车(EV)的空间和时间行为,有助于对充电基础设施的部署进行全面分析。值得注意的是,该模型纳入了非参数排队动态、等待时间信息共享和不同的代理特征,从而加深了对主题的理解。该研究以腓特烈斯贝格市和哥本哈根市的大规模实施为基础,通过证明几个关键点来倡导采用快速充电器。首先,信息共享可显著减少等待时间,尤其是在快速充电网络内,在需求高峰期可减少多达 30% 的等待时间。其次,由 10-14 个网点组成的大型快充集群优于小型集群,这主要是由于信息共享缩短了等待时间并提高了等待时间预测的准确性。第三,基于未满足需求指标的投放策略比仅由观察到的需求模式驱动的投放策略效果更好。通过有效监控观察到的需求和未满足的需求,这些策略往往能更好地优化充电基础设施的布局。这些见解来自于模拟框架的复杂性和异质性,凸显了信息和未满足需求在这一领域的价值。
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引用次数: 0
Improving energy efficiency for suburban railways: A two-stage scheduling optimization in a rail-EV smart hub 提高市郊铁路的能源效率:铁路-电动汽车智能枢纽的两阶段调度优化
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-10-20 DOI: 10.1016/j.etran.2024.100366
Yinyu Chen , Minwu Chen , Wenjie Lu , Agustí Egea-Àlvarez , Lie Xu
As the scale of suburban rail and electric vehicles (EVs) continues to expand with the revolution of electrification of transportation, park and ride (P&R) facilities are increasingly recognized as critical energy coupling points between suburban rail traction transformers and EV charging stations. However, flexible coordination of the energy distribution among the bidirectional power flow of multiple trains and EVs’ charging demand becomes an urgent issue. In this paper, we establish a rail-EV Smart Energy Hub (SEH) framework integrating trains, ultra-capacitors (UC), and battery-based EVs. An emendable two-stage optimization model is proposed, enabling railways to provide R2X (railway-to-anything) services. The first stage determines the optimal train trajectory and adjusts timetables to minimize the energy consumption of multiple trains. In the second stage, the charging strategy of the EV is coordinated with the charging/discharging scheme of the UC, which takes the train power flow determined in the first stage as input. Meanwhile, the voltage unbalance caused by the railway is constrained to comply with the limits set by IEC/TR 61000-3-13. Case studies based on actual suburban railway lines in China demonstrate that the proposed scheduling optimization approach can significantly reduce the energy consumption of both railways and EVs.
随着交通电气化革命的推进,市郊铁路和电动汽车(EV)的规模不断扩大,停车和乘车(P&R)设施作为市郊铁路牵引变压器和电动汽车充电站之间的关键能源耦合点,越来越受到重视。然而,如何灵活协调多列列车双向电力流与电动汽车充电需求之间的能量分配成为一个亟待解决的问题。本文建立了一个铁路-电动汽车智能能源枢纽(SEH)框架,将列车、超级电容器(UC)和基于电池的电动汽车整合在一起。本文提出了一个可修正的两阶段优化模型,使铁路能够提供 R2X(铁路到任何地方)服务。第一阶段确定最佳列车轨迹并调整时刻表,使多列列车的能耗最小化。在第二阶段,以第一阶段确定的列车功率流为输入,协调电动汽车的充电策略和 UC 的充放电方案。同时,铁路造成的电压不平衡将受到限制,以符合 IEC/TR 61000-3-13 规定的限制。基于中国实际市郊铁路线路的案例研究表明,所提出的调度优化方法可以显著降低铁路和电动汽车的能耗。
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引用次数: 0
On safety of swelled commercial lithium-ion batteries: A study on aging, swelling, and abuse tests 关于膨胀商用锂离子电池的安全性:老化、膨胀和滥用测试研究
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-10-16 DOI: 10.1016/j.etran.2024.100368
Yiding Li , Shicong Ding , Li Wang , Wenwei Wang , Cheng Lin , Xiangming He
Lithium-ion battery technology has advanced significantly, making these power sources essential for portable electronic devices such as smartphones. In 2023, global smartphone shipments reached nearly 1.2 billion units, underscoring the widespread reliance on these batteries. However, as batteries age, they may swell and potentially pose explosion risks. To investigate the safety of swollen batteries, this study conducts accelerated aging and swelling tests on lithium-ion batteries from five leading brands, which together represent over half of the global smartphone market share. The research involves a series of comprehensive tests, including Accelerated Rate Calorimeters (ARC) test, mechanical, electrical, and thermal abuse tests in accordance with Chinese national standards, as well as gas composition and theoretical flammability analyses on both new and swollen batteries. The findings indicate that swollen batteries generally exhibit safer behavior under floating charging conditions, and both new and swollen batteries pass the abuse tests within the standard framework. This study suggests that the safety of swollen lithium-ion batteries cannot be categorically labeled as dangerous or safe and should be assessed within the context of specific environments.
锂离子电池技术取得了长足的进步,使其成为智能手机等便携式电子设备的重要电源。2023 年,全球智能手机出货量将近 12 亿部,凸显了对这些电池的广泛依赖。然而,随着电池老化,它们可能会膨胀,并可能带来爆炸风险。为了研究膨胀电池的安全性,本研究对五大领先品牌的锂离子电池进行了加速老化和膨胀测试,这五大品牌共占全球智能手机市场份额的一半以上。研究涉及一系列综合测试,包括加速速率量热仪(ARC)测试,符合中国国家标准的机械、电气和热滥用测试,以及新电池和膨胀电池的气体成分和理论可燃性分析。研究结果表明,膨胀电池在浮充条件下通常表现得更安全,新电池和膨胀电池都能通过标准框架内的滥用测试。这项研究表明,膨胀锂离子电池的安全性不能一概而论地归结为危险或安全,而应根据具体环境进行评估。
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引用次数: 0
Microstructure-based digital twin thermo-electrochemical modeling of LIBs at the cell-to-module scale 基于微观结构的电池到模块级锂离子电池数字孪生热电化学建模
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-10-16 DOI: 10.1016/j.etran.2024.100370
Siyoung Park , Hyobin Lee , Seungyeop Choi , Jaejin Lim , Suhwan Kim , Jihun Song , Mukarram Ali , Tae-Soon Kwon , Chilhoon Doh , Yong Min Lee
As the application of lithium-ion batteries (LIBs) expands beyond conventional electric vehicles (EVs) to heavy vehicles such as electric trucks or trams, the importance of thermal management in LIB systems is increasing, even at the module or pack level. In particular, because monitoring the thermal behaviors of each cell is not feasible, thermo-electrochemical modeling and simulations in the module or pack level are essential for analyzing and ensuring thermal stability. However, because the conventional lumped thermo-electrochemical models cannot reflect the actual structure of LIB cells, there might be considerable differences may exist between simulation and experimental results. To fill these gaps, we have newly developed a 3D microstructure-based digital twin model of a battery module (8.8 Ah/18.5 V, five LIB pouch cells in series) for an unmanned railway vehicle. Unlike traditional lumped models, our digital twin model accurately well reflects the internal structure of cells and can calculate the heat generation of each component inside a cell. As a result, contrary to a lumped model, the digital twin model can not only simulate the inhomogeneous temperature gradient inside a cell, but also estimates higher local maximum temperatures (TDT, max/TL, max = 137.2 °C/123.9 °C @ 10C discharge) in cells which can trigger thermal runaway. Therefore, microstructure-based digital twin modeling can alleviate concerns regarding the thermal runaway of LIB cells, modules, and packs, and provide safe operating conditions.
随着锂离子电池(LIB)的应用范围从传统的电动汽车(EV)扩展到电动卡车或有轨电车等重型车辆,锂离子电池系统中热管理的重要性与日俱增,甚至在模块或电池组层面也是如此。特别是,由于监控每个电池的热行为并不可行,因此模块或电池组级的热电化学建模和模拟对于分析和确保热稳定性至关重要。然而,由于传统的块状热电化学模型无法反映 LIB 电池的实际结构,因此模拟结果与实验结果之间可能存在相当大的差异。为了填补这些空白,我们新开发了一种基于三维微观结构的数字孪生模型,用于无人轨道车辆的电池模块(8.8 Ah/18.5 V,5 个串联的锂电池袋电池)。与传统的块状模型不同,我们的数字孪生模型能准确反映电池的内部结构,并能计算出电池内部每个组件的发热量。因此,与块状模型相反,数字孪生模型不仅能模拟电池内部不均匀的温度梯度,还能估算出电池中可能引发热失控的较高局部最高温度(TDT, max/TL, max = 137.2 °C/123.9 °C @ 10C 放电)。因此,基于微观结构的数字孪生建模可减轻对锂电池、模块和电池组热失控的担忧,并提供安全的运行条件。
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引用次数: 0
Battery engineering safety technologies (BEST): M5 framework of mechanisms, modes, metrics, modeling, and mitigation 电池工程安全技术(BEST):机制、模式、度量、建模和缓解的 M5 框架
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-09-23 DOI: 10.1016/j.etran.2024.100364
Jingyuan Zhao , Zhilong Lv , Di Li , Xuning Feng , Zhenghong Wang , Yuyan Wu , Dapai Shi , Michael Fowler , Andrew F. Burke
The increasing adoption of electric vehicles (EVs) has underscored the importance of lithium-ion batteries (LIBs), which, however, pose inherent safety risks. These issues can escalate from moderate faults to critical failures, potentially leading to thermal runaway—a dangerous chain reaction that can result in fires and explosions. Therefore, addressing and mitigating these safety hazards is crucial. This review introduces the concept of Battery Engineering Safety Technologies (BEST), summarizing recent advancements and aiming to outline a holistic and hierarchical framework for addressing real-world battery safety issues step by step: mechanisms, modes, metrics, modelling, and mitigation. Specifically, the M5 framework includes: (a) identification of mechanisms and causes, (b) failure mode and effects analysis, (c) metrics for evaluation, (d) modelling and forecasting, and (e) mitigation through material optimization, cell, and system design. Applications of the M5 hierarchical assessment, stemming from observational, empirical, statistical, and physical understanding of batteries at the materials, cell, and pack levels, not only have the potential to produce new insights but also contribute to dramatic efficiencies, more accurate predictions, and better interpretability for the evolution of electrochemical systems. It concludes with an overview of current challenges and future directions in battery safety research, emphasizing data-centered, AI-based digital solutions.
电动汽车(EV)的日益普及凸显了锂离子电池(LIB)的重要性,但锂离子电池也存在固有的安全风险。这些问题可能从中级故障升级为严重故障,有可能导致热失控--一种可能导致火灾和爆炸的危险连锁反应。因此,解决和减轻这些安全隐患至关重要。本综述介绍了电池工程安全技术(BEST)的概念,总结了最新进展,旨在勾勒出一个整体的分层框架,逐步解决现实世界中的电池安全问题:机制、模式、度量、建模和缓解。具体来说,M5 框架包括(a) 机制和原因识别,(b) 失效模式和影响分析,(c) 评估指标,(d) 建模和预测,以及 (e) 通过材料优化、电池和系统设计减轻影响。M5 分层评估的应用源于对电池在材料、电池芯和电池组层面的观察、经验、统计和物理理解,不仅有可能产生新的见解,还有助于显著提高效率、更准确地预测和更好地解释电化学系统的演变。报告最后概述了电池安全研究的当前挑战和未来方向,强调了以数据为中心、以人工智能为基础的数字化解决方案。
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引用次数: 0
Synergies of variable renewable energy and electric vehicle battery swapping stations: Case study for Beijing 可变可再生能源与电动汽车电池交换站的协同效应:北京案例研究
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-09-19 DOI: 10.1016/j.etran.2024.100363
Chongyu Zhang , Xi Lu , Shi Chen , Mai Shi , Yisheng Sun , Shuxiao Wang , Shaojun Zhang , Yujuan Fang , Ning Zhang , Aoife M. Foley , Kebin He
Battery swapping technology has emerged as a promising option for simultaneously addressing electric vehicle (EV) range anxiety and uncoordinated charging impacts, thereby enabling a renewable-powered future at the city scale. This study aims to explore the potential synergies between variable renewable energy (VRE), including wind and solar power, and the city-scale operation of battery swapping stations (BSSs) under varying levels of VRE penetration. To this end, an integrated modeling framework that combines multisource traffic data with node-based BSS deployment optimization and hourly power system dispatch simulations was developed. Beijing in 2025 was selected as the case study due to its ambitious EV development goals and the substantial need for VRE integration. The simulation results reveal that system-optimized BSS operations, particularly through bidirectional charging (V2G), can significantly enhance VRE integration, reduce net load fluctuations, and mitigate carbon emissions. Specifically, increasing VRE penetration from 30 % to 70 % reduces VRE curtailment by 1.1 TWh to 6.4 TWh and avoids 3.0 t to 6.3 t of carbon emissions per vehicle annually. The economic analysis further indicates that while current time-of-use electricity pricing leads to higher costs for BSS operations, a real-time pricing mechanism offers a more economically viable solution, benefiting both power system operators and BSS operators. The integrated modeling framework developed in this study not only advances the understanding of city-scale BSS operations but also provides a valuable tool for analyzing the complex interactions between EV infrastructure, VRE integration, and urban power grids.
电池交换技术已成为同时解决电动汽车(EV)续航焦虑和不协调充电影响的一种有前途的选择,从而在城市范围内实现可再生能源供电的未来。本研究旨在探索可再生能源(VRE)(包括风能和太阳能)与电池交换站(BSS)在不同可再生能源渗透水平下的城市规模运营之间的潜在协同效应。为此,我们开发了一个综合建模框架,该框架结合了多源交通数据、基于节点的 BSS 部署优化和每小时电力系统调度模拟。由于北京雄心勃勃的电动汽车发展目标和对可再生能源整合的巨大需求,2025 年的北京被选为案例研究对象。模拟结果表明,经过系统优化的 BSS 运行,特别是通过双向充电(V2G),可以显著提高可再生能源的集成度,减少净负荷波动,并减少碳排放。具体而言,将可再生能源的渗透率从 30% 提高到 70%,可减少 1.1 太瓦时至 6.4 太瓦时的可再生能源削减,并避免每辆车每年 3.0 吨至 6.3 吨的碳排放。经济分析进一步表明,虽然目前的分时电价会导致 BSS 运营成本上升,但实时定价机制提供了更经济可行的解决方案,使电力系统运营商和 BSS 运营商都能从中受益。本研究开发的综合建模框架不仅加深了人们对城市规模 BSS 运营的理解,还为分析电动汽车基础设施、可再生能源集成和城市电网之间复杂的相互作用提供了宝贵的工具。
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引用次数: 0
Enhancing capacity estimation of retired electric vehicle lithium-ion batteries through transfer learning from electrochemical impedance spectroscopy 通过从电化学阻抗谱转移学习,加强退役电动汽车锂离子电池的容量估算
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.etran.2024.100362
Wenjun Fan , Bo Jiang , Xueyuan Wang , Yongjun Yuan , Jiangong Zhu , Xuezhe Wei , Haifeng Dai

The low economic feasibility caused by inefficient testing and inaccurate performance estimation is one of the main bottlenecks in the echelon utilization of large-scale retired batteries. This study proposes a fast and accurate capacity estimation method for retired batteries based on electrochemical impedance spectroscopy (EIS). Firstly, the EIS of the batteries that experience multi-condition aging in the laboratory are collected. EIS characteristic parameter sequences highly related to battery performance, including real part and magnitude, are directly extracted to establish a base bi-directional long short-term memory model. Secondly, a transfer learning method based on feature matching is designed, which applies a linear transformation layer to map the features between the source and target domains. The proposed transfer learning method has been effectively validated on laboratory battery data measured at different temperatures and retired battery datasets of different material types. The improvements are especially notable for retired batteries. The detection time has been reduced, with each cell requiring only 1.67 min. And using only a small amount of data as input for transfer learning can achieve an accuracy improvement of over 90 %, indicating an effective transfer channel from the base model established on laboratory small-capacity battery aging data to large-capacity retired battery data is successfully established for the first time. For retired nickel-cobalt-manganese batteries, the mean absolute percentage error (MAPE) and the root mean square percentage error (RMSPE) are 2.33 % and 2.75 %, respectively, while for retired lithium-iron-phosphate batteries, the MAPE and RMSPE reached 4.12 % and 5.04 %, respectively. The results demonstrate the proposed method reduces the cost of repeated testing, modeling, and training for specific retired batteries while maintaining the accuracy of capacity estimation. This advancement helps to improve the efficiency of large-scale retired battery grading, and injects new momentum into facilitating more effective decision-making processes.

测试效率低下和性能估算不准确导致的经济可行性低是大规模退役电池梯次利用的主要瓶颈之一。本研究提出了一种基于电化学阻抗谱(EIS)的快速、准确的退役电池容量估算方法。首先,收集实验室中经历多条件老化的电池的电化学阻抗谱。直接提取与电池性能高度相关的 EIS 特征参数序列,包括实部和幅度,从而建立基础双向长短期记忆模型。其次,设计了一种基于特征匹配的迁移学习方法,该方法应用线性变换层在源域和目标域之间映射特征。所提出的迁移学习方法在不同温度下测量的实验室电池数据和不同材料类型的退役电池数据集上得到了有效验证。退役电池的改进尤为显著。检测时间缩短了,每个电池仅需 1.67 分钟。而且仅使用少量数据作为迁移学习的输入,准确率就能提高 90% 以上,这表明首次成功建立了从实验室小容量电池老化数据建立的基础模型到大容量退役电池数据的有效迁移通道。对于退役镍钴锰电池,平均绝对百分比误差(MAPE)和均方根百分比误差(RMSPE)分别为 2.33 % 和 2.75 %,而对于退役磷酸铁锂电池,MAPE 和 RMSPE 分别达到 4.12 % 和 5.04 %。结果表明,所提出的方法降低了针对特定报废电池的重复测试、建模和训练成本,同时保持了容量估算的准确性。这一进步有助于提高大规模退役电池分级的效率,为促进更有效的决策过程注入了新的动力。
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引用次数: 0
Enhancing lithium-ion battery monitoring: A critical review of diverse sensing approaches 加强锂离子电池监测:对各种传感方法的严格审查
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.etran.2024.100360
Jun Peng , Xuan Zhao , Jian Ma , Dean Meng , Jiangong Zhu , Jufan Zhang , Siqian Yan , Kai Zhang , Zexiu Han

Lithium-ion batteries (LIBs) play a pivotal role in promoting transportation electrification and clean energy storage. The safe and efficient operation is the biggest challenge for LIBs. Smart batteries and intelligent management systems are one of the effective solutions to address this issue. Multiparameter monitoring is regarded as a promising tool to achieve the goal. This paper provides an overview of the state of the art in multiparameter monitoring approaches for LIBs. Further, the sensing principle, experimental configuration, and sensor performance are elaborated and discussed. The results show that internal parameter monitoring of cells is more attractive and challenging than external parameter monitoring. Temperature, deformation, and gas are the most concerned parameters inside batteries. Finally, the outlooks and challenges for the implementation and application of LIB multiparameter monitoring are investigated from two aspects: internal parameters monitoring and application of the monitored multivariate data. Compact, precise, and stable sensors compatible with the internal environment of batteries as well as efficient and intelligent algorithms for battery management are still awaiting breakthroughs.

锂离子电池(LIB)在促进交通电气化和清洁能源存储方面发挥着举足轻重的作用。安全高效地运行是锂离子电池面临的最大挑战。智能电池和智能管理系统是解决这一问题的有效方案之一。多参数监测被认为是实现这一目标的有效工具。本文概述了锂电池多参数监测方法的最新进展。此外,还对传感原理、实验配置和传感器性能进行了阐述和讨论。结果表明,与外部参数监测相比,电池内部参数监测更具吸引力和挑战性。温度、变形和气体是电池内部最受关注的参数。最后,从内部参数监测和监测到的多变量数据的应用这两个方面探讨了 LIB 多参数监测的实施和应用前景与挑战。与电池内部环境相适应的紧凑、精确、稳定的传感器以及高效、智能的电池管理算法仍有待突破。
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引用次数: 0
Towards real-world state of health estimation: Part 2, system level method using electric vehicle field data 实现真实世界的健康状况评估:第 2 部分:使用电动汽车现场数据的系统级方法
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-08-24 DOI: 10.1016/j.etran.2024.100361
Yufang Lu , Dongxu Guo , Gengang Xiong , Yian Wei , Jingzhao Zhang , Yu Wang , Minggao Ouyang

Accurate battery health estimation is pivotal for ensuring the safety and performance of electric vehicles (EVs). While predominant research has centered on laboratory-level single cells, the accurate estimation of battery system capacity using real-world data remains a challenge, due to the vast diversity in battery types, operating conditions, data recordings, etc. To this end, we release three large-scale field datasets of 464 EVs from three manufacturers, comprising over 1.2 million charging snippets. The EVs’ capacity and State of Health (SOH) are effectively labeled using K-means to cluster and concatenate charging snippets. A robust data-driven framework integrating a Gated Convolutional Neural Network (GCNN) for estimating battery capacity is proposed, and the results outperform other machine learning models. In addition, a fine-tuning technique is employed to further enhance model efficacy on new datasets and with limited training data. This research not only advances battery health estimations but also paves the way for broader applications in battery management systems (BMSs), offering a scalable solution to real-world challenges in battery technology.

准确估算电池健康状况对于确保电动汽车(EV)的安全和性能至关重要。虽然主要的研究都集中在实验室级别的单体电池上,但由于电池类型、运行条件、数据记录等方面的巨大差异,利用真实世界的数据准确估算电池系统容量仍然是一项挑战。为此,我们发布了三个大规模现场数据集,包括来自三个制造商的 464 辆电动汽车,总计超过 120 万个充电片段。使用 K-means 方法对电动汽车的容量和健康状况(SOH)进行有效标记,以聚类和串联充电片段。该研究提出了一个稳健的数据驱动框架,其中集成了一个用于估算电池容量的门控卷积神经网络(GCNN),其结果优于其他机器学习模型。此外,还采用了微调技术,以进一步提高模型在新数据集和有限训练数据上的功效。这项研究不仅推动了电池健康状况的估算,还为电池管理系统(BMS)的更广泛应用铺平了道路,为电池技术领域的现实挑战提供了可扩展的解决方案。
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引用次数: 0
A comparative study on mechanical-electrical-thermal characteristics and failure mechanism of LFP/NMC/LTO batteries under mechanical abuse 机械滥用条件下 LFP/NMC/LTO 电池机械-电气-热特性和失效机理的比较研究
IF 15 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-08-12 DOI: 10.1016/j.etran.2024.100359
Renjie Wang, Guofeng Liu, Can Wang, Zhaoqi Ji, Quanqing Yu

Understanding the failure behaviors and failure mechanisms of lithium-ion batteries under mechanical abuse is essential for numerical reconstruction of abuse scenarios for different types of cells. This study investigates the mechanical-electrical-thermal characteristics, components tensile properties and failure mechanisms of LiFePO4 (LFP), Li(Ni0.5Mn0.3Co0.2)O2 (NMC), and Li2TiO3 (LTO) cells through indentation experiments, including ball intrusion, cylindrical intrusion, and out-of-plane compression modes at quasi-static loading rates. Additional ball intrusion experiments were conducted at varying loading rates. This study compares the effects of different material systems on battery performance under standardized mechanical abuse conditions. Post-test examinations analyze surface damage and internal component fracture morphology. Two distinct fracture modes were observed: ductile fracture and brittle fracture. The findings suggest that, under the same loading mode, LTO cells exhibit distinct failure behavior compared to NMC and LFP cells, attributed to differing material properties and resulting fracture modes during intrusion. Based on the analysis of the tensile results of the battery components, the cell fracture mode may be related to the tensile strength of the separator. The loading rate significantly impacts the mechanical-electrical-thermal performance of pouch cells, resulting in increased cell stiffness and shorter internal short circuit duration at higher loading speeds. However, the effect of loading rate is consistent across cells with different material systems.

了解锂离子电池在机械滥用情况下的失效行为和失效机理,对于数值重建不同类型电池的滥用情景至关重要。本研究通过压入实验,包括球形压入、圆柱形压入和准静态加载速率下的平面外压缩模式,研究了磷酸铁锂(LFP)、镍钴锰酸锂(NMC)和氧化钛锂(LTO)电池的机械-电气-热特性、组件拉伸性能和失效机制。此外,还进行了不同加载速率下的球侵入实验。这项研究比较了不同材料系统在标准化机械滥用条件下对电池性能的影响。测试后检查分析了表面损伤和内部组件断裂形态。观察到两种截然不同的断裂模式:韧性断裂和脆性断裂。研究结果表明,在相同的加载模式下,与 NMC 和 LFP 电池相比,LTO 电池表现出不同的失效行为,这归因于不同的材料特性以及在侵入过程中产生的断裂模式。根据对电池组件拉伸结果的分析,电池的断裂模式可能与隔膜的拉伸强度有关。加载速度对袋装电池的机械-电气-热性能有重大影响,在加载速度较高时,电池刚度增加,内部短路持续时间缩短。不过,加载速度对不同材料系统电池的影响是一致的。
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