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The value of solar forecasts and the cost of their errors: A review 太阳预报的价值及其误差的代价:综述
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-08 DOI: 10.1016/j.rser.2023.113915
Oktoviano Gandhi , Wenjie Zhang , Dhivya Sampath Kumar , Carlos D. Rodríguez-Gallegos , Gokhan Mert Yagli , Dazhi Yang , Thomas Reindl , Dipti Srinivasan

Despite the advances in solar forecasting methods, and their ever-increasing accuracy, little is known about their value for real applications, e.g., bidding in the electricity market, power system operations, and household electricity bill reduction. This work comprehensively reviews the value of solar forecasts and the cost of their errors across the different applications available in the literature. Most works analysed the economics of solar forecast at the transmission level, either from the electricity market perspective or the system operations perspective. When compared with the levelised cost of electricity of photovoltaic (PV) systems, the value of solar forecasts and the cost of their errors are considerable. Recommendations on how to minimise and adapt to solar uncertainty and variability are also discussed. The measures will not only help mitigate the cost of forecast errors but also enable better integration of PV and other variable generation. Different system/market operators and regulators can consider the different suggestions based on their unique circumstances.

尽管太阳能预测方法取得了进步,其准确性也在不断提高,但人们对其实际应用的价值知之甚少,例如,在电力市场投标、电力系统运行和减少家庭电费。这项工作全面回顾了太阳预报的价值及其在文献中可用的不同应用中的误差成本。大多数研究从电力市场或系统运行的角度分析了输电层太阳能预测的经济性。与光伏发电系统的平均电力成本相比,太阳能预测的价值及其误差的成本是相当可观的。还讨论了如何尽量减少和适应太阳的不确定性和可变性的建议。这些措施不仅有助于降低预测误差的成本,还有助于更好地整合光伏发电和其他变量发电。不同的系统/市场经营者和监管机构可以根据其独特的情况考虑不同的建议。
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引用次数: 0
A comprehensive analysis of time-dependent performance of a solar chimney power plant equipped with a thermal energy storage system 装有蓄热系统的太阳能烟囱电厂时间特性综合分析
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-08 DOI: 10.1016/j.rser.2023.114051
Amir Arefian , Reza Hosseini-Abardeh , Mohsen Rahimi-Larki , Arman Torkfar , Hamid Sarlak

Solar Chimney Power Plants (SCPP) are among the promising solar thermal electricity generation technologies. Equipped with a Thermal Energy Storage (TES) system, such technologies can overcome variations in the main driving factors such as solar radiation and ambient air temperature. This article presents a comprehensive semi-analytical model of a TES to predict the time-dependent performance of an SCPP. By introducing a Quality Factor of power generation (QF) that includes energy conversion efficiency and capacity factor, the effects of 15 TES materials have been studied on the plant performance. Results indicate no significant difference between water TES and clay or soil type, and water-filled bags or tubes are relatively ineffective in improving performance compared to them. Among the various TES materials analyzed, a type of wet soil, i.e., the specific wet mixture of clay, sand, and silt in closed and dark-colored bags, show excellent performance in both QF enhancement and having low Heat Penetration Depth (HPD) simultaneously. The QF and HPD are directly affected by thermal effusivity and thermal diffusivity, respectively. Implementing wet soil TES for the studied power plant (Manzanares) enhances the QF from 7.46 % (for limestone soil) to 10.95 %. Water-filled bags demonstrate a heat penetration depth of 0.4 m, while wet soil exhibits a slightly greater depth of 0.5 m. Furthermore, water-filled bags experience a broader temperature range of 40 °C, whereas wet soil undergoes a comparatively smaller temperature variation of 26 °C. Furthermore, the capacity factor raises from 41.18 % to 61.07 % when utilizing wet soil TES compared to water-filled bags.

太阳能烟囱发电厂(SCPP)是最有前途的太阳能热发电技术之一。这些技术配备了热能储存(TES)系统,可以克服太阳辐射和环境空气温度等主要驱动因素的变化。本文提出了一个全面的半解析模型的TES来预测一个SCPP的时间相关性能。通过引入发电质量因子(QF),包括能量转换效率和容量因子,研究了15种TES材料对电厂性能的影响。结果表明,水TES与粘土或土壤类型无显著差异,充水袋或充水管在提高性能方面相对无效。在所分析的各种TES材料中,一种湿土,即封闭的深色袋中粘土、沙子和淤泥的特定湿混合物,在增强QF方面表现优异,同时具有较低的热穿透深度(HPD)。QF和HPD分别直接受到热渗出率和热扩散率的影响。对所研究的发电厂(Manzanares)实施湿土TES将QF从7.46%(石灰石土壤)提高到10.95%。充水袋的热渗透深度为0.4 m,而湿土的热渗透深度略大,为0.5 m。此外,充水袋的温度变化范围更广,为40°C,而湿土的温度变化范围相对较小,为26°C。此外,与充水袋相比,使用湿土TES的容量系数从41.18%提高到61.07%。
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引用次数: 0
Biomass to biofuels using hydrothermal liquefaction: A comprehensive review 热液液化生物质制生物燃料综述
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-08 DOI: 10.1016/j.rser.2023.113976
Hossein Shahbeik , Hamed Kazemi Shariat Panahi , Mona Dehhaghi , Gilles J. Guillemin , Alireza Fallahi , Homa Hosseinzadeh-Bandbafha , Hamid Amiri , Mohammad Rehan , Deepak Raikwar , Hannes Latine , Bruno Pandalone , Benyamin Khoshnevisan , Christian Sonne , Luigi Vaccaro , Abdul-Sattar Nizami , Vijai Kumar Gupta , Su Shiung Lam , Junting Pan , Rafael Luque , Bert Sels , Mortaza Aghbashlo

The utilization of renewable fuel alternatives holds promise for reducing the financial burden of regulatory compliance and the social responsibility associated with greenhouse gas emissions. Hydrothermal liquefaction (HTL) is one of the most versatile technologies for converting renewable biomass feedstocks (especially in the wet state) into biofuel (biocrude oil) in a compact plant. Therefore, this review is devoted to thoroughly reviewing and critically discussing biocrude oil production from biomass feedstocks through the HTL process. This review starts by discussing the principles of biomass HTL processing and product upgrading, aiming to provide a grounded and broad understanding of current developments in this domain. The data reported in the published literature are analyzed and visualized in order to scrutinize the effects of the main process parameters on the quantity, quality, cost, and environmental impacts of resultant biofuels. Higher biocrude oil yields are obtained at temperatures, pressures, and residual times between 300 and 350 °C, 24–27 MPa, and 15–25 min, respectively. Concerning yield and calorific value, biocrude oil derived from homogeneous catalysts demonstrates figures of 23.6 % and 32.1 MJ/kg, whereas that from heterogeneous catalysts exhibits percentages of 66.8 % and 40 MJ/kg, respectively. The challenges and prospects for the future development of biocrude oil are also discussed. HTL has a long way to go before being used for biofuel production on a large scale. Future studies appear to be directed towards the use of HTL technology under the biorefinery framework to maximize the exploitation of biomass into value-added products, while minimizing waste generation.

利用可再生燃料替代品有望减轻监管合规的经济负担和与温室气体排放相关的社会责任。水热液化(HTL)是将可再生生物质原料(特别是在湿态)转化为生物燃料(生物原油)的最通用的技术之一。因此,本文致力于全面回顾和批判性地讨论通过HTL工艺从生物质原料生产生物原油。本文首先讨论了生物质HTL加工和产品升级的原理,旨在为该领域的当前发展提供一个接地和广泛的理解。对已发表文献中报告的数据进行分析和可视化,以便仔细检查主要工艺参数对所得生物燃料的数量、质量、成本和环境影响的影响。在300 ~ 350°C、24 ~ 27 MPa和15 ~ 25 min的温度、压力和剩余时间下,生物原油产量更高。在产率和热值方面,均相催化剂制备的生物原油的产率和热值分别为23.6%和32.1 MJ/kg,而多相催化剂制备的生物原油的产率和热值分别为66.8%和40 MJ/kg。讨论了生物原油未来发展面临的挑战和前景。HTL在大规模用于生物燃料生产之前还有很长的路要走。未来的研究似乎是针对在生物炼制框架下使用HTL技术,以最大限度地将生物质开发成增值产品,同时最大限度地减少废物产生。
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引用次数: 0
Distribution network expansion planning: An updated review of current methods and new challenges 配电网扩张计划:对当前方法和新挑战的最新回顾
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-08 DOI: 10.1016/j.rser.2023.114062
Abdollah Rastgou

Many studies have been conducted on the distribution network expansion planning (DNEP) problem in recent years. The primary goal of this issue is to satisfy electric load demand, taking into account economic and technical considerations. In the past, this planning was done in a centralized manner with all the information available. The restructuring of power networks and the emergence of renewable energy sources (RESs), energy storage systems (ESSs), and new market players with different interests have led to extensive changes in the DNEP issue. Subsequently, the solving methods of the DNEP problem will be important because many new goals, constraints, and other factors have caused the problem to become non-linear and non-convex. This paper prepares a comprehensive study on the DNEP problem from different aspects such as objective functions and constraints, design variables, planning horizon and phases, planning and system types, uncertainty, distributed generations (DGs) and storage units, planning level, solving methods, load models, and environmental issues. Finally, future research trends such as handling the conflicts, solving approaches, and other points facing the DNEP problem are suggested.

近年来,对配电网扩容规划(DNEP)问题进行了大量研究。本课题的主要目标是满足电力负荷需求,同时兼顾经济和技术方面的考虑。在过去,这种规划是用所有可用的信息以集中的方式完成的。随着电网结构的调整,可再生能源、储能系统的出现,以及具有不同利益的新市场参与者的出现,导致了DNEP问题的广泛变化。随后,DNEP问题的求解方法将变得非常重要,因为许多新的目标、约束和其他因素使问题变得非线性和非凸。本文从目标函数与约束、设计变量、规划视界与阶段、规划与系统类型、不确定性、分布式发电机组与存储单元、规划层次、求解方法、负荷模型、环境问题等方面对DNEP问题进行了全面研究。最后,提出了未来的研究趋势,如处理冲突、解决方法以及DNEP问题面临的其他问题。
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引用次数: 0
Political economy of low-carbon electricity: Governance effects across 198 countries 低碳电力的政治经济学:198个国家的治理效应
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-08 DOI: 10.1016/j.rser.2023.114016
Darrick Evensen , Benjamin K. Sovacool

Which countries best foster low-carbon electricity transitions – authoritarian regimes or democratic societies? Crucial for understanding how transitions unfold is identifying contextual factors conditioning propensity to adopt specific forms of energy production. This research assesses the relationship between quality of governance within 198 countries and domestic electricity production from all major energy sources, across the years 2002–2020. Governance quality is measured via a range of comprehensive, internationally recognised metrics, focusing predominantly on the World Bank's worldwide governance indicators. The data reveal that a future, decarbonised electricity system via wind, solar, and/or nuclear appears most likely in countries where the traditions and institutions by which authority is exercised support good governance. Over the last two decades, the association between electricity from solar and wind and good governance has progressively strengthened globally. Beyond governance, national measures of economic (in)equality are strongly related to electricity production from nuclear and hydropower. These findings offer a point of departure for assessing how governance systems might predispose countries to particular energy choices.

哪个国家最能促进低碳电力转型——专制政权还是民主社会?理解转型如何展开的关键是确定影响采用特定能源生产形式倾向的环境因素。本研究评估了2002-2020年间198个国家的治理质量与所有主要能源的国内发电量之间的关系。治理质量是通过一系列全面的、国际公认的指标来衡量的,主要集中在世界银行的全球治理指标上。数据显示,未来通过风能、太阳能和/或核能实现的脱碳电力系统最有可能出现在那些行使权力的传统和机构支持良好治理的国家。在过去二十年中,太阳能和风能发电与良好治理之间的联系在全球范围内逐步加强。除了治理之外,国家经济平等的衡量标准与核能和水力发电密切相关。这些发现为评估治理体系如何使国家倾向于特定的能源选择提供了一个出发点。
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引用次数: 0
Deep learning based on Transformer architecture for power system short-term voltage stability assessment with class imbalance 基于变压器结构的深度学习在类不平衡情况下电力系统短期电压稳定评估中的应用
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-08 DOI: 10.1016/j.rser.2023.113913
Yang Li , Jiting Cao , Yan Xu , Lipeng Zhu , Zhao Yang Dong

Most existing data-driven power system short-term voltage stability assessment (STVSA) approaches presume class-balanced input data. However, in practical applications, the occurrence of short-term voltage instability following a disturbance is minimal, leading to a significant class imbalance problem and a consequent decline in classifier performance. This work proposes a Transformer-based STVSA method to address this challenge. By utilizing the basic Transformer architecture, a stability assessment Transformer (StaaT) is developed as a classification model to reflect the correlation between the operational states of the system and the resulting stability outcomes. To combat the negative impact of imbalanced datasets, this work employs a conditional Wasserstein generative adversarial network with gradient penalty (CWGAN-GP) for synthetic data generation, aiding in the creation of a balanced, representative training set for the classifier. Semi-supervised clustering learning is implemented to enhance clustering quality, addressing the lack of a unified quantitative criterion for short-term voltage stability. Numerical tests on the IEEE 39-bus test system extensively demonstrate that the proposed method exhibits robust performance under class imbalances up to 100:1 and noisy environments, and maintains consistent effectiveness even with an increased penetration of renewable energy. Comparative results reveal that the CWGAN-GP generates more balanced datasets than traditional oversampling methods and that the StaaT outperforms other deep learning algorithms. This study presents a compelling solution for real-world STVSA applications that often face class imbalance and data noise challenges.

现有的数据驱动电力系统短期电压稳定评估(STVSA)方法大多假设输入数据是类平衡的。然而,在实际应用中,干扰后短期电压不稳定的发生是最小的,导致显著的类不平衡问题和分类器性能的下降。这项工作提出了一种基于变压器的STVSA方法来解决这一挑战。利用变压器的基本体系结构,开发了一个稳定性评估变压器(StaaT)作为一个分类模型来反映系统运行状态与稳定性结果之间的相关性。为了对抗不平衡数据集的负面影响,这项工作采用了一个带梯度惩罚的条件Wasserstein生成对抗网络(CWGAN-GP)来生成合成数据,帮助为分类器创建一个平衡的、有代表性的训练集。采用半监督聚类学习来提高聚类质量,解决短期电压稳定性缺乏统一定量标准的问题。在IEEE 39总线测试系统上的数值测试广泛表明,该方法在高达100:1的类不平衡和噪声环境下表现出稳健的性能,即使在可再生能源渗透率增加的情况下也保持一致的有效性。对比结果表明,CWGAN-GP比传统的过采样方法生成更平衡的数据集,并且statat优于其他深度学习算法。这项研究为现实世界中经常面临类不平衡和数据噪声挑战的STVSA应用提供了一个引人注目的解决方案。
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引用次数: 0
Bupleurum chinense and Medicago sativa sustain their growth in agrophotovoltaic systems by regulating photosynthetic mechanisms 柴胡和紫花苜蓿在农业光伏系统中通过调节光合机制维持生长
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-08 DOI: 10.1016/j.rser.2023.114024
Siqi Zhang, Jirui Gong, Cunde Xiao, Xiaofan Yang, Xiaobing Li, Zihe Zhang, Liangyuan Song, Weiyuan Zhang, Xuede Dong, Yuxia Hu

The three-dimensional nature of agrophotovoltaic systems (APV) accounts for the needs of photovoltaic power generation and agricultural production. The combination can solve conflicts among utilization of resources, ecological protection, and agricultural production to achieve low-carbon economic development. However, the economically respond (crop yield and quality) of different species under the decreased light available system is still unclear. To provide insights, we compared agrophotovoltaic and traditional ecosystems to explore the economic feasibility of planting Bupleurum chinense (B. chinense) and Medicago sativa (M. sativa) from the perspectives of light utilization, photosynthetic responses, and land use. The combined system improved the land equivalent ratio, net income and species quality of B. chinense and M. sativa. Both species showed high plasticity, and maintained growth and development by regulating their morphology and photosynthetic parameters. B. chinense in the APV increased its light use efficiency, photosynthetic rate, and root biomass by increasing its height, electron transfer flux, and up-regulating a photosystem I protein (PsaA). M. sativa in the APV allocated more energy to photochemical reactions to improve photosynthetic capacity. It captured and utilized the limited light by reducing leaf mass per unit area and dark respiration, increasing the chlorophyll content, and down-regulating a photosystem II protein (PsbD). Our results showed the importance of species selection based on morphological and photosynthetic responses and provide insights into the selection of appropriate species, efficient resource utilization, and sustainable economic development based on APV.

农业光伏系统(APV)的立体化特性满足了光伏发电和农业生产的需要。这种结合可以解决资源利用、生态保护和农业生产之间的矛盾,实现低碳经济发展。然而,不同树种在光效降低系统下的经济响应(作物产量和品质)尚不清楚。本研究通过对比农业光伏生态系统和传统生态系统,从光能利用、光合响应和土地利用等方面探讨种植柴胡和紫花苜蓿的经济可行性。复合系统提高了羊草和苜蓿的土地当量比、净收入和种属质量。这两种植物都表现出高度的可塑性,通过调节形态和光合参数来维持生长发育。在APV中,黄芪通过增加其高度、电子传递通量和上调光系统I蛋白(PsaA)来提高其光能利用效率、光合速率和根系生物量。在APV中,苜蓿将更多的能量分配给光化学反应,以提高光合能力。它通过降低单位面积叶质量和暗呼吸,增加叶绿素含量和下调光系统II蛋白(PsbD)来捕获和利用有限的光。本研究结果揭示了基于形态和光合响应的物种选择的重要性,并为基于APV的适宜物种选择、资源高效利用和经济可持续发展提供了新的思路。
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引用次数: 0
Critical review: ‘Green’ ethylene production through emerging technologies, with a focus on plasma catalysis 关键评论:通过新兴技术生产“绿色”乙烯,重点是等离子体催化
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-07 DOI: 10.1016/j.rser.2023.114044
Pradeep Lamichhane , Nima Pourali , Lauren Scott , Nam N. Tran , Liangliang Lin , Marc Escribà Gelonch , Evgeny V. Rebrov , Volker Hessel

Over the years, numerous studies have explored the green synthesis of ethylene. Within this context, the focus of this perspective shifts toward plasma technology, which has demonstrated the capability to convert methane into ethylene. Plasma catalysis creates distinctive physical and chemical environments, particularly at normal temperature and pressure, distinguishing it from alternative methods. Nevertheless, the utilization of atmospheric pressure plasma is intricate, posing scientific challenges in the realms of physics and chemistry. In this viewpoint, various key performance aspects are evaluated, encompassing methane conversion efficiency, ethylene selectivity, and specific energy input. These scientific pros and cons are then assessed for their readiness for industrial-scale implementation. Initially, the potential for small-scale ethylene production is examined, leveraging existing robust process technologies to unlock fresh market and supply chain opportunities. Subsequently, the sustainability of plasma technology for green ethylene production is compared to conventional ethylene production and alternative green ethylene production methods, including biomass-based approaches. Contrary to perhaps optimistic expectations, current literature evidence does not uniformly favor the latter, indicating the potential for plasma-based green ethylene processes. Additionally, this paper underscores the importance of considering Environmental, Social, and Governance factors that influence business decisions. Finally, this review underscores plasma technology as a potentially promising approach for green ethylene synthesis from methane, offering unique advantages under normal conditions while simultaneously presenting scientific challenges. It assesses its viability for small-scale production and benchmarks its sustainability against conventional and alternative methods, emphasizing the importance of a sustainable future for the green petrochemical industry.

多年来,许多研究探索了乙烯的绿色合成。在此背景下,这一观点的焦点转向了等离子体技术,该技术已经证明了将甲烷转化为乙烯的能力。等离子体催化创造了独特的物理和化学环境,特别是在常温常压下,使其与其他方法区别开来。然而,大气压等离子体的利用是复杂的,在物理和化学领域提出了科学挑战。在这种观点下,评估了各种关键性能方面,包括甲烷转化效率、乙烯选择性和比能量输入。然后评估这些科学上的利弊,以确定它们是否准备好进行工业规模的实施。首先,研究小规模乙烯生产的潜力,利用现有的强大工艺技术来打开新的市场和供应链机会。随后,将等离子体技术用于绿色乙烯生产的可持续性与传统乙烯生产和替代绿色乙烯生产方法(包括基于生物质的方法)进行了比较。与乐观的预期相反,目前的文献证据并不一致地支持后者,表明基于等离子体的绿色乙烯过程的潜力。此外,本文强调了考虑影响商业决策的环境、社会和治理因素的重要性。最后,本综述强调了等离子体技术作为一种潜在的有前途的甲烷绿色乙烯合成方法,在正常条件下具有独特的优势,同时也提出了科学挑战。它评估了其小规模生产的可行性,并将其可持续性与传统方法和替代方法进行比较,强调了绿色石化工业可持续未来的重要性。
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引用次数: 0
Multiscale wettability characterization under CO2 geological storage conditions: A review CO2地质储存条件下多尺度润湿性表征研究进展
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-07 DOI: 10.1016/j.rser.2023.113956
Xin Wang , Shaohua Li , Baocai Tong , Lanlan Jiang , Pengfei Lv , Yi Zhang , Yu Liu , Yongchen Song

The wettability of porous media strongly affects the trapping mechanism and storage capacity during CO2 geological storage. Various novel measuring methods have been proposed recently with the development of imaging techniques. This review describes the state-of-the-art wettability characterization at different scales in three aspects: conventional laboratory-based contact angle characterization to analyze the porous external surface properties, pore-scale contact angle analysis to summarize the wettability of the porous inner surface based on micromodels and X-ray microtomography, and overall wettability evaluation through nuclear magnetic resonance and thermodynamic contact angle and topology analysis. The impact of the pore structure, mineral composition, and surface roughness on pore-scale wettability is described, including contact angle hysteresis and mixed wettability. The wettability in various pore events and wettability alternation with various storage conditions and fluid displacement patterns provide a description of reservoir properties. This review also illustrates the feasibility of multiscale wettability descriptions. Future studies should focus on the interrelation among the contact angles at different scales. How the contact angle of a porous surface, especially at the pore scale, changes under reservoir conditions and the mechanism of wettability alternation still need to be further investigated. Additionally, the impact of rock wettability on storage capacity in practical applications is concluded. Future research will focus on methods to control wettability in actual storage sites to enhance economic benefits and ensure safety.

在CO2地质封存过程中,多孔介质的润湿性对CO2的捕集机制和封存能力有重要影响。随着成像技术的发展,近年来提出了各种新的测量方法。本文从三个方面综述了目前不同尺度下的润湿性表征:基于实验室的常规接触角表征分析多孔外表面性质;基于微模型和x射线微层析成像的孔尺度接触角分析总结多孔内表面的润湿性;通过核磁共振、热力学接触角和拓扑分析进行整体润湿性评价。描述了孔隙结构、矿物组成和表面粗糙度对孔隙尺度润湿性的影响,包括接触角滞后和混合润湿性。不同孔隙事件下的润湿性以及不同储层条件和流体驱替模式下的润湿性变化为储层性质提供了描述。这也说明了多尺度润湿性描述的可行性。未来的研究应关注不同尺度接触角之间的相互关系。在储层条件下,多孔表面(尤其是孔隙尺度上)的接触角如何变化,以及润湿性变化的机理还有待进一步研究。并总结了实际应用中岩石润湿性对储水能力的影响。未来的研究将集中在如何控制实际储存地点的润湿性,以提高经济效益和确保安全。
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引用次数: 0
Influence of pre-treatment of straw biomass and additives on the release of nitrogen species during combustion and gasification 秸秆生物质预处理及添加剂对燃烧和气化过程中氮素释放的影响
IF 15.9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2023-11-07 DOI: 10.1016/j.rser.2023.114033
Florian Lebendig , Daniel Schmid , Oskar Karlström , Patrik Yrjas , Michael Müller

The aim of this study is to investigate how pre-treatment of herbaceous straw biomass for ash control affects the release of nitrogen species during combustion and gasification. To comprehend the formation of NO and its precursors, NH3 and HCN, the release of these species was investigated and compared under both combustion and gasification-like conditions at 950 °C. The effects of various upgrading methods, such as torrefaction, water-leaching, a combination of leaching and torrefaction, and CaCO3 addition, were studied. The assessment of nitrogen release was divided into two consecutive conversion steps – devolatilization/pyrolysis and ash/char reactions. The release of nitrogen is highly dependent on the reaction conditions. For instance, the emissions of NO from the combustion conditions (3 vol% O2) for all fuel samples were, on average, six times higher than under gasification conditions (14.5 vol% H2O and 5 vol% CO2). The emissions of NO from the combustion and gasification of torrefied biomass were, on average, 20 % higher than those from raw biomass. Water-leaching had a suppressing effect on NO formation during char conversion. Approximately 62 % of the char-N formed NO for raw and torrefied material, whereas only 26 %–35 % was formed for pre- or postwashed samples. The effect of the applied pre-treatment approaches on the release of nitrogen was particularly significant during char conversion. Increasing calcium and decreasing potassium content had catalytic effects, mainly on the conversion of volatile-N to NH3. The Ca-doped biomass feedstock showed approximate 10 % increase in volatile-N to NH3 conversion compared to the source material.

本研究的目的是研究草本秸秆生物质的灰控制预处理如何影响燃烧和气化过程中氮的释放。为了了解NO及其前体NH3和HCN的形成,研究了950°C下燃烧和类似气化条件下这些物质的释放并进行了比较。研究了焙烧、水浸、浸出与焙烧相结合、CaCO3添加等不同提质方法的效果。氮释放的评估分为两个连续的转化步骤-脱挥发/热解和灰分/焦反应。氮的释放高度依赖于反应条件。例如,所有燃料样品在燃烧条件下(3 vol% O2)排放的NO平均比在气化条件下(14.5 vol% H2O和5 vol% CO2)高6倍。碳化生物质燃烧和气化产生的NO排放量平均比原料生物质高出20%。水浸对炭转化过程中NO的生成有抑制作用。大约62%的炭- n在原料和固化材料中形成NO,而在洗前或洗后样品中只有26% - 35%形成NO。应用的预处理方法对炭转化过程中氮释放的影响尤为显著。增加钙含量和减少钾含量有催化作用,主要是对挥发性氮转化为NH3有促进作用。与原料相比,掺钙生物质原料的挥发性n到NH3的转化率提高了约10%。
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Renewable and Sustainable Energy Reviews
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