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Evaluation of the possibility to use organic acids solutions for production of fertilizers based on horticultural mineral wool waste 利用有机酸溶液生产以园艺矿棉废料为基础的肥料的可能性评价
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ecea.2015.22(2)17
K. Hoffmann, K. Chęcińska, M. Huculak-Mączka, J. Hoffmann
The aim of the research was evaluation of the possibility to use organic acids solutions for production of fertilizers based on mineral wool waste. This substrate thanks to inert character and good air-water relationship is commonly used in greenhouse industry. Increased production of vegetable in soilless culture due to world’s population growth. However mineral wool after full crop cycle is non-biodegradable – dangerous waste. Possibility of extraction nutrients from this kind of substrate could be solution of that important environmental problem. Before analyses mineral wool waste was grinded on 0.40 mm sieve. Then the extraction process was conducted using 2 % m/m and 10 % m/m citric acid, 2 % m/m and 10 % m/m formic acid, 0.2 % m/m and 2 % m/m acetic acid for 3 and 6 hours at temperature 25 C. Solid phase before analyses was mineralized. Iron, phosphorus was analyzed using spectrophotometer methods. Iron analysis is based on formation of a coloured ferric ion complex with 2,2’-bipyridyl. Phosphorus analysis is based on formation of molybdenum blue complex. Calcium and magnesium was examined by complexometric titration with EDTA and using Eriochrome Black T as an indicator, while calcium ions concentration was analyzed using calconcarboxylic acid as an indicator. Content of nutrients after extraction from mineral wool waste allows to conclude that obtained liquid phase can be used as a fertilizer component while solid phase can be used in mixed substrate production.
该研究的目的是评估使用有机酸溶液生产基于矿棉废料的肥料的可能性。该基材具有惰性和良好的气水关系,在温室工业中得到广泛应用。由于世界人口增长,无土栽培蔬菜产量增加。然而,矿棉在整个作物周期后是不可生物降解的危险废物。从这种基质中提取营养物质的可能性可以解决这一重要的环境问题。分析前,矿棉废料在0.40 mm筛上研磨。然后用2% m/m和10% m/m的柠檬酸、2% m/m和10% m/m的甲酸、0.2% m/m和2% m/m的乙酸在温度25℃下分别提取3和6小时。用分光光度法对铁、磷进行了分析。铁分析是基于与2,2 ' -联吡啶形成有色铁离子络合物。磷的分析是基于钼蓝络合物的形成。以EDTA络合滴定法测定钙、镁,以Eriochrome Black T为指示剂,以钙羧酸为指示剂测定钙离子浓度。从矿棉废料提取后的营养成分含量可以得出结论,所得的液相可以用作肥料成分,而固相可以用于混合基质生产。
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引用次数: 0
Modeling studies of hydraulic efficiency of compacted waste landfill clay liner 垃圾填埋场粘土衬垫压实水力效率模型研究
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)31
M. Widomski, W. Stepniewski, R. Horn
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引用次数: 0
Statistical approach to the determination of the index of soil suppleness on reduction 测定土壤还原性指数的统计方法
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)25
S. Labuda, A. Vetchinnikov
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引用次数: 0
Examination of thermal stability of waste rockwool and ammonium nitrate mixtures 废岩棉和硝酸铵混合物的热稳定性检验
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)28
M. Huculak-Mączka, D. Popławski, M. Kaniewski, E. Klem, J. Hoffmann
Results of research carried out on a waste rockwool and ammonium nitrate mixtures to examine the possibility of using them in fertilization of plants were presented. Reactions occurring between compounds were analyzed to determine the possibility of an uncontrolled exothermic decomposition of nitrogen fertilizer additive. Results obtained from the analysis of prepared mixtures in various proportions and separate samples of individual compounds were compared. Ammonium nitrate used in the research was supplied by one of the domestic fertilizers producer and waste rockwool was collected after a completed crop cycle of a tomato plant. Each sample was dried and ground before examination. Analysis was carried out using differential thermal analysis coupled with thermogravimetry and mass spectrometry (DTA-TG-MS). Obtained results indicate a possibility of use of rockwool mixed with ammonium nitrate in agriculture. However, it is important to choose optimal proportions of compounds to ensure the thermal stability of the mixture.
介绍了一种废岩棉与硝酸铵混合物的研究结果,探讨了它们在植物施肥中的可能性。分析了化合物之间发生的反应,以确定氮肥添加剂不受控制的放热分解的可能性。对不同比例的配制混合物和个别化合物的单独样品的分析结果进行了比较。研究中使用的硝酸铵由国内某肥料生产商提供,废岩棉是在番茄植株完成一个作物周期后收集的。每个样品在检测前都被干燥和研磨。采用差热分析结合热重质谱法(DTA-TG-MS)进行分析。结果表明,岩棉与硝酸铵混合使用在农业上是可行的。然而,重要的是选择最佳比例的化合物,以确保混合物的热稳定性。
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引用次数: 0
Pesticide residues and acute dietary risk assessment in Polish raw food (2005–2013) 2005-2013年波兰生食品农药残留及急性膳食风险评估
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(3)30
B. Łozowicka, I. Hrynko, M. Jankowska, E. Rutkowska, P. Kaczyński, P. Mojsak
Abstract: Food safety is very important for consumers. Fruits, vegetables and cereals are not only the major source of vitamins, minerals, fibre and energy, but can also be a source of many pollutants posing health hazards. Pesticides found in food are just examples of harmful substances affecting food safety. The objective of this paper was to assess short-term health risks assessment based on the concentration of pesticide residues found in agricultural products collected from national food control systems during the period 2005–2013 at the Official Pesticide Residue Laboratory in Bialystok in frame of RASFF (Rapid Alert System for Food and Feed) system. During nine-year testing, totally 2021 fruits, vegetables and cereals were sampled from the north-eastern and central part of Poland and analyzed by gas and liquid chromatography and spectroscopic technique for the presence of 188 active substances of pesticides. Contaminations were not detected in 65.3 % of samples, 31.9 % samples contained residues below the maximum residue levels (MRLs), while 2.8 % of tested samples exceeded MRLs. Among 81 RASFF notifications noted, the greatest number of irregularities concerned exceeding the values of MRL – 41, in 27 cases it was found that a pesticide was not used in accordance with the registration of plant protection product. The highest estimated values for short-term exposure were obtained for plum for the dimethoate, and in the group of toddlers it was 94.6 % ARfD (Acute Reference Dose), and in the adult group it was 23.3 % ARfD.
摘要:食品安全对消费者来说非常重要。水果、蔬菜和谷物不仅是维生素、矿物质、纤维和能量的主要来源,而且也是危害健康的许多污染物的来源。在食品中发现的农药只是影响食品安全的有害物质的例子。本文的目的是在RASFF(食品和饲料快速警报系统)系统框架下,基于Bialystok官方农药残留实验室2005-2013年期间从国家食品控制系统收集的农产品中发现的农药残留浓度,评估短期健康风险评估。在为期9年的测试中,从波兰东北部和中部地区共取样了2021种水果、蔬菜和谷物,并通过气相色谱和液相色谱及光谱技术分析了188种农药活性物质的存在。65.3%的样品未检测到污染,31.9%的样品含有低于最大残留限量(MRLs)的残留物,而2.8%的测试样品超过了最大残留限量。在81份RASFF通报中,最多的违规行为涉及超过MRL - 41的值,其中27例被发现没有按照植物保护产品的注册使用农药。短期暴露的最高估计值是梅子对乐果的暴露,在幼儿组中为94.6%的ARfD(急性参考剂量),在成人组中为23.3%的ARfD。
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引用次数: 1
The effect of manganese treatment on pathogenic fungi isolated from barley kernels 锰处理对大麦籽粒病原菌的影响
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(4)39
K. Gleń-Karolczyk, E. Boligłowa
Teprosyn Mn manganese seed treatment, manufactured by a British firm Phosyn Chemicals Ltd., which was tested in the experiment, has been available on the Polish market for several years. Applied as a seed treatment it results in more intensive development of root system and improves general plant condition. However, in the available literature lacks information on Teprosyn Mn effect on plant healthiness or pathogenic organisms. The aim of the paper was to compare the effect of Teprosyn Mn fertilizer and Raxil Gel 206 chemical seed treatment on pathogenic fungi species: Fusarium culmorum (W.G. Smith) Sacc., Fusarium poae (Peck) Wollen., Fusarium avenaceum (Fr.) Sacc., Bipolaris sorokiniana (Sacc. in Sorok.) Shoem. and Botrytis cinerea Pers. In laboratory conditions the dynamics of growth and sporulation of the above mentioned fungi were assessed on PDA medium with a supplement of 0.1; 0.5 and 1.0 mm cm of Teprosyn Mn and 0.005; 0.05 and 0.5 mm cm of Raxil Gel 206. In vitro Teprosyn Mn manganese fertilizer reveals weak and diversified effect on linear growth of the studied phytopathogens. In the highest concentration (1.0 mm cm) it reduces the growth of Fusarium avenaceum, Botrytis cinerea and Fusarium poae colonies on the level of 7.3–10.1 %, whereas all its concentrations inhibit the sporulation process in B. cinerea i F. avenaceum from 35.3 % to 66 %. Along with increasing concentration in the medium its stimulating effect on linear growth of Bipolaris sorokiniana raises (5.7–18.3 %) and the spore number increases from 40 to 271.5 %.
泰普罗辛锰种子处理剂是由英国Phosyn化学有限公司生产的,在实验中进行了测试,已经在波兰市场上销售了好几年。作为种子处理,可使根系发育更紧密,改善植株的一般状况。然而,在现有的文献中,缺乏关于替普罗辛锰对植物健康或致病生物的影响的信息。比较了泰普罗辛锰肥和罗辛凝胶206化学种子处理对病原菌镰刀菌(Fusarium culmorum) Sacc的影响。,镰刀菌poae (Peck) Wollen。镰刀菌(Fusarium avenaceum);;双极莲;Sorok)。Shoem。和灰葡萄孢。在实验室条件下,对上述真菌在添加0.1的PDA培养基上的生长和产孢动态进行了评估;0.5和1.0 mm cm的Teprosyn Mn和0.005;0.05和0.5 mm cm的Raxil凝胶206。在体外试验中,替普罗辛锰肥对所研究植物病原菌的线性生长表现出微弱而多样的影响。在最高浓度(1.0 mm cm)下,对灰霉变菌、灰霉病菌和灰霉变菌菌落生长的抑制作用为7.3% ~ 10.1%,对灰霉变菌和灰霉变菌产孢的抑制作用为35.3% ~ 66%。随着培养基浓度的增加,其对双极莲线性生长的刺激作用增强(5.7% ~ 18.3%),孢子数从40%增加到271.5%。
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引用次数: 1
Using ash from incineration of municipal sewage sludge to fertilize Virginia Fanpetals 利用城市污水污泥焚烧产生的灰给维吉尼亚花瓣瓣施肥
Q4 Environmental Science Pub Date : 2015-01-01 DOI: 10.2428/ECEA.2015.22(4)40
J. Wierzbowska, S. Sienkiewicz, P. Sternik, M. K. Busse
: The purpose of this paper was to determine the effect of ash from a sewage sludge incinerating facility on yields and mineral composition of Virginia fanpetals, and on the content of heavy metals in soil. The study was based on a pot experiment in which ash obtained from sewage sludge incineration at the Lyna Wastewater Treatment Plant was used as a substitute of mineral fertilizers. The dominant fertilizing ingredients found in the analyzed ash were phosphorus and calcium. The content of cadmium and lead was lower than the allowable concentrations of these metals in mineral fertilizers. Ash from incinerated sewage sludge did not have any substantial effect on the soil content of the mobile forms of cadmium, copper, lead and chromium. With respect to three metals, namely nickel, zinc and manganese, the medium and high doses of ash raised significantly their concentrations in soil. The rate of ash had no influence on the content of sodium and magnesium in the plants but when the highest dose of ash had been applied, the concentration of calcium in plants rose significantly. Ash modified the content of heavy metals in the plant material only very slightly.
本文的目的是确定从一个污水污泥焚烧设施的灰对产量和弗吉尼亚扇形花瓣的矿物组成,并对土壤中的重金属含量的影响。这项研究是基于一项盆栽试验,在该试验中,从Lyna废水处理厂的污水污泥焚烧中获得的灰被用作矿物肥料的替代品。在分析的灰分中发现的主要施肥成分是磷和钙。镉和铅的含量低于矿质肥料中镉和铅的允许浓度。焚烧后的污泥灰对土壤中镉、铜、铅和铬的流动形态含量没有实质性影响。对于三种金属,即镍、锌和锰,中剂量和高剂量的灰大大提高了它们在土壤中的浓度。施灰量对植株中钠、镁的含量没有影响,但施灰量最大时,植株中钙的浓度显著升高。灰分对植物材料中重金属含量的改变作用非常微弱。
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引用次数: 5
Migration of pahs in the arable layer of flooded soil – model experiment 淹水土壤耕层中多环芳烃的迁移——模型试验
Q4 Environmental Science Pub Date : 2014-01-01 DOI: 10.2428/ECEA.2014.21(1)4
T. Ciesielczuk, C. Rosik-Dulewska, Joanna Poluszyńska
Soils periodically, or permanently, waterlogged and soils exposed to flood waters are heavily imperilled to pollution of inorganic and organic compounds. They are primarily compounds that are brought with the inflowing (highly loaded) floodwater and indigenously produced within the soil profile by anaerobic metabolism of the organic matter. PAHs compounds are adsorbed by the soil from the floodwaters and move in the soil profile posing a threat to groundwater. In addition, when the flood recedes, these compounds may be taken up by the crops. In this study soil pollution with polycyclic aromatic hydrocarbons (PAHs) derived from the decomposition of organic matter and silt and their migration in the arable layer of soil.
土壤周期性或永久性涝渍和暴露于洪水中的土壤受到无机和有机化合物污染的严重危害。它们主要是随着流入的(高负荷)洪水带来的化合物,并通过有机物的厌氧代谢在土壤剖面中本地产生。多环芳烃化合物从洪水中被土壤吸附,并在土壤剖面中移动,对地下水构成威胁。此外,当洪水退去时,这些化合物可能被农作物吸收。本文研究了土壤有机质和淤泥分解产生的多环芳烃(PAHs)对土壤的污染及其在耕地土壤中的迁移。
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引用次数: 0
Car cabin atmosphere quatilty: vehicle interior toxicity assesment based on In vitro tests 汽车舱内空气质量:基于体外试验的汽车内部毒性评价
Q4 Environmental Science Pub Date : 2014-01-01 DOI: 10.2428/ECEA.2014.21(1)11
A. Janicka
In the article the problem of vehicle interior as an important environment of human life hase been discussed. The problem is very important in aspect of indoor air quality. A vehicle interior is a specific environment where levels of volatile toxic organic compounds concentrations are particularly high. In the article the results of statistical analysis of human resistance time in vehicle interior are presented. A method of gaseous mixtures toxicity estimation based on in vitro tests has been proposed in application for vehicle cabin interior and compared to the popular toxicity indicators (relative toxicity coefficients). The results of the method application in brand new passenger vehicles (in parking conditions) are presented. The results was correlated with volatile organic compounds concentration in vehicles interior (method: gas chromatography).
本文就汽车内部作为人类生活的重要环境问题进行了探讨。这个问题在室内空气质量方面是非常重要的。车辆内部是挥发性有毒有机化合物浓度特别高的特定环境。本文介绍了人在汽车内部阻力时间的统计分析结果。提出了一种基于体外试验的气体混合物毒性评估方法,并将其应用于汽车舱室内部,并与常用的毒性指标(相对毒性系数)进行了比较。给出了该方法在全新乘用车(停车工况)中的应用结果。结果与车辆内部挥发性有机物浓度(气相色谱法)相关。
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引用次数: 0
Analysis and evaluation of sewage treatment plant operation 污水处理厂运行分析与评价
Q4 Environmental Science Pub Date : 2014-01-01 DOI: 10.2428/ECEA.2014.21(2)16
J. Gawdzik, J. Długosz
{"title":"Analysis and evaluation of sewage treatment plant operation","authors":"J. Gawdzik, J. Długosz","doi":"10.2428/ECEA.2014.21(2)16","DOIUrl":"https://doi.org/10.2428/ECEA.2014.21(2)16","url":null,"abstract":"","PeriodicalId":44472,"journal":{"name":"ECOLOGICAL CHEMISTRY AND ENGINEERING A-CHEMIA I INZYNIERIA EKOLOGICZNA A","volume":"21 1","pages":"199-209"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68904109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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