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A self-powered spring-based triboelectric vibration sensor 自供电弹簧式三电振动传感器
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012068
V. Ganesan, P. S. Chee, Q. L. Goh, E. H. Lim, Y. J. King, L. H. Chong
Self-powered vibration sensors have gained attention due to their versatility. However, a limitation of many existing self-powered sensors is their single-direction functionality, which hinders their effectiveness in capturing multidirectional human movement’s swinging motions. To address this, this study introduces an innovative self-powered vibration sensor based on the triboelectrification effect of an inverted pendulum metal ball. This novel sensor excels at detecting micro-vibrations through the freestanding sliding electrification of a metal ball using Kapton tape. The generated charge is transferred through interdigital electrodes arranged in a spiral pattern. To ensure adaptability to various motion types, the metal ball is affixed to a spring and configured as an inverted pendulum. This setup allows the sensor to detect both linear and rotary motions across a range of acceleration levels. The fabricated sensor exhibits remarkable sensitivity, measuring 0.203 V/mm. It was affixed to the human body to detect low-frequency vibrations, particularly those below 20 Hz. Impressively, it can detect millimeter-scale vibrations, even up to 3 mm, at different rotational angles (0°, 30°, 60°, and 90°). This outcome highlights the promising performance of our vibration sensor in the field of human motion monitoring, making it a significant advancement in the realm of self-powered vibration sensors.
自供电振动传感器因其多功能性而备受关注。然而,许多现有自供电传感器的局限性在于其单一方向功能,这妨碍了它们捕捉人体运动多方向摆动动作的有效性。针对这一问题,本研究基于倒立摆金属球的三电化效应,推出了一种创新的自供电振动传感器。这种新型传感器通过使用 Kapton 胶带对金属球进行独立滑动通电,从而出色地检测微振动。产生的电荷通过呈螺旋状排列的数字间电极转移。为确保适应各种运动类型,金属球被固定在一个弹簧上,并被配置成一个倒立摆。这种设置使传感器能够在一定加速度范围内检测线性和旋转运动。制作的传感器灵敏度极高,测量值为 0.203 V/mm。它被固定在人体上,用于检测低频振动,尤其是低于 20 赫兹的振动。令人印象深刻的是,在不同的旋转角度(0°、30°、60°和 90°)下,它都能检测到毫米级的振动,甚至可达 3 毫米。这一成果凸显了我们的振动传感器在人体运动监测领域的良好性能,使其在自供电振动传感器领域取得了重大进展。
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引用次数: 0
Life Cycle Assessment of Large-Scale Solar Photovoltaic Plant based in Malaysia 马来西亚大型太阳能光伏发电厂的生命周期评估
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012055
A. Quek, A. R. Abbas, N. Z. I. S. Zaman, W. N. S. W. Ata, M. F. Zainal, F. K. M. Yapandi, Z. F. Ibrahim, A. Suhardi
A cradle-to-grave life cycle assessment (LCA) has been performed on a Large Scale Solar Photovoltaic (LSSPV) plant based in Peninsular Malaysia to study the detailed environmental impact of its life cycle. The LSSPV, with a capacity of 78 MWdc, is currently one of Malaysia’s largest solar power plants. The different life cycle phases of the LSSPV, starting from resource manufacturing and transportation, through plant construction and electricity generation, and to decommissioning of the plant, were assessed using the SimaPro software with the Ecoinvent v3.8 database. Results show that the overall emission rate for the LSSPV is 0.0309 kgCO2eq/kWh. It is estimated that the construction phase of the power plant, which includes activities such as infrastructure works and production of PV modules and Balance of System, yields the largest amount of kgCO2eq/kWh emission at 85.7% and imposes the highest environmental impact as compared to the other phases. The second biggest contributor is attributed to the transportation phase, contributing to 14.0% of the total kgCO2eq/kWh emission, of which most of the emission is emitted during the sea freight transportation of PV components from China port to Malaysia port (12.4%). A sensitivity analysis was performed to compare the environmental impact between open ground installation and the slanted roof installation mounting system of LSSPV. The findings from LCA proposed that open-ground installation has a greater negative impact on the environment because it involves additional land clearing and infrastructure transformation. The findings from this study serve as a benchmark for the LSSPV system in Malaysia and present technical perspectives for the future development of PV projects considering environmental impacts across the project lifetime.
对位于马来西亚半岛的大型太阳能光伏电站进行了 "从摇篮到坟墓 "生命周期评估(LCA),以研究其生命周期对环境的详细影响。LSSPV 容量为 78 MWdc,是目前马来西亚最大的太阳能发电厂之一。使用 SimaPro 软件和 Ecoinvent v3.8 数据库对 LSSPV 的不同生命周期阶段进行了评估,从资源制造和运输开始,到电站建设和发电,直至电站退役。结果显示,LSSPV 的总排放率为 0.0309 kgCO2eq/kWh。据估计,与其他阶段相比,电站的建设阶段(包括基础设施工程、光伏组件生产和系统平衡等活动)产生的 kgCO2eq/kWh 排放量最大,为 85.7%,对环境的影响也最大。其次是运输阶段,占总 kgCO2eq/kWh 排放量的 14.0%,其中大部分排放量是在光伏组件从中国港口到马来西亚港口的海运过程中排放的(12.4%)。通过敏感性分析,比较了露天安装和斜屋顶安装 LSSPV 安装系统对环境的影响。生命周期分析结果表明,露天安装对环境的负面影响更大,因为它涉及额外的土地清理和基础设施改造。本研究的结果可作为马来西亚 LSSPV 系统的基准,并为光伏项目的未来发展提供了考虑整个项目生命周期内环境影响的技术视角。
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引用次数: 0
Generating synthetic building electrical load profiles using machine learning based on the CRISP-ML(Q) framework 利用基于 CRISP-ML(Q)框架的机器学习生成合成建筑物电力负荷曲线
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012082
J. B. Magdaong, A. Culaba, A. Ubando, N. S. Lopez
This study presents a machine learning application for generating synthetic building electrical load profiles. The implementation followed the Cross Industry Standard Process for the development of Machine Learning Applications with Quality assurance methodology, or CRISP-ML(Q) framework, to ensure a systematic machine learning development process. The model training performance was evaluated using the mean absolute error (MAE), root mean squared error (RSME), and coefficient of determination (R2) which were observed to be 0.0739, 0.1119, and 0.5728, respectively. These metrics remained consistent during the model testing phase, suggesting robust model performance. During the initial simulation experiment, the MAE and RMSE of the generated synthetic load profile were found to be 0.014 and 0.016, respectively, underscoring high model accuracy. Additional evaluation experiments showed that the developed machine learning application can generate realistic building load profiles using high-level parameters such as building type, average daily load, and peak demand. This study can aid in the development of demand-side management strategies and building energy management systems by providing realistic building electrical load profiles especially when real-world data is limited. For future work, researchers can consider integrating additional model features, refining data processing methods, and developing an agile version of the CRISP-ML(Q) framework.
本研究介绍了一种用于生成合成建筑物电力负荷曲线的机器学习应用。该应用的实施遵循了具有质量保证方法的机器学习应用开发跨行业标准流程(或 CRISP-ML(Q)框架),以确保机器学习开发流程的系统性。使用平均绝对误差(MAE)、均方根误差(RSME)和判定系数(R2)对模型训练性能进行了评估,结果分别为 0.0739、0.1119 和 0.5728。这些指标在模型测试阶段保持一致,表明模型性能稳定。在初始模拟实验中,生成的合成负载曲线的 MAE 和 RMSE 分别为 0.014 和 0.016,表明模型的准确性很高。其他评估实验表明,所开发的机器学习应用软件可以利用建筑物类型、日均负荷和峰值需求等高级参数生成真实的建筑物负荷曲线。这项研究通过提供真实的建筑电力负荷曲线,尤其是在真实世界数据有限的情况下,有助于需求侧管理策略和建筑能源管理系统的开发。在未来的工作中,研究人员可以考虑集成更多的模型功能,改进数据处理方法,并开发一个敏捷版的 CRISP-ML(Q) 框架。
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引用次数: 0
Decision support system for urban river water quality as a source of clean water using the SMART method 利用 SMART 方法对作为清洁水源的城市河流水质进行决策支持系统研究
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012038
Yumarlin Mz, Sri Rahayu
Rivers play an essential role as vital water sources with roles spanning sanitation, hygiene, drinking, and agriculture, particularly in rural areas. However, Kabupaten Sleman’s river water quality, including its Kabupaten Sleman region in Yogyakarta, has severely degraded due to pollution from solid and liquid sources. Chemical contaminants have rendered the water unsafe, posing health risks. The primary objective of this study is to evaluate the water quality in the rivers of Bedog and Sembung located in Kabupaten Sleman. This evaluation utilizes Water Quality Criteria from the Republic of Indonesia Government Regulations Number 82 of 2001, alongside assigned weights. The research employs a diverse range of methodologies, including in-depth literature analysis, meticulous field observation, interviews, and comprehensive water quality assessment. A Decision Support System is adeptly employed as a strategic tool to grapple with the intricate facets inherent in the issue, thereby formulating pragmatic resolutions that facilitate judicious decision-making across diverse contexts. In addressing the dimension of water quality for communities along the Bedog and Sembung rivers, the study seamlessly integrates the SMART (Simple Multi-Attribute Rating Technique) approach. SMART’s agility in steering multi-attribute decisions expedites the decision-making process. SMART’s computational outcomes yield values of 0.304 and 0.395 for the Bedog and Sembung Rivers, respectively, both falling within the 0 to 0.49 range. This collective conclusion indicates that neither river meets the criteria for clean water quality, making it unsuitable for activities like sanitation, hygiene, drinking, and agriculture. The study underscores the urgency of rectifying river water quality, particularly in urban settings, to ensure safe and sustainable water sources for communities. The seamless integration of SMART as a decision-making tool amplifies the potential for effective interventions in navigating water quality management complexities.
河流作为重要的水源,在卫生、个人卫生、饮用和农业方面发挥着不可或缺的作用,尤其是在农村地区。然而,由于受到固体和液体污染源的影响,日惹苏莱曼区(Kabupaten Sleman)的河流水质严重恶化。化学污染物导致水质不安全,对健康构成威胁。本研究的主要目的是评估位于斯勒曼省的贝多格河和森蓬河的水质。本次评估采用了印度尼西亚共和国政府 2001 年第 82 号法规中的水质标准以及指定的权重。研究采用了多种方法,包括深入的文献分析、细致的实地观察、访谈和全面的水质评估。决策支持系统作为一种战略工具,被巧妙地用于处理问题中固有的错综复杂的方面,从而制定出务实的解决方案,促进在不同背景下做出明智的决策。在解决勿洛河和胜榜河沿岸社区的水质问题时,本研究采用了 SMART(简单多属性评级技术)方法。SMART 在指导多属性决策方面的灵活性加快了决策过程。根据 SMART 的计算结果,勿洛河和胜榜河的价值分别为 0.304 和 0.395,均在 0 至 0.49 的范围内。这一综合结论表明,这两条河流都不符合清洁水质标准,因此不适合开展环境卫生、个人卫生、饮用和农业等活动。这项研究强调了纠正河流水质的紧迫性,尤其是在城市环境中,以确保社区的安全和可持续水源。作为一种决策工具,SMART 系统的无缝集成扩大了在水质管理复杂性方面进行有效干预的潜力。
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引用次数: 0
Biochar and syngas from wet torrefaction of oil palm empty fruit bunches and palm oil mill effluent: A renewable energy approach 油棕空果串和棕榈油厂废水湿法热解产生的生物炭和合成气:可再生能源方法
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012032
Nur Atiqah Mohamad Aziz, Yu Kai Ling, H. Mohamed, B. S. Zainal, H. Zaman, A. G. Alsultan
Palm oil mill effluent (POME) and oil palm empty fruit bunches (EFB) constitute the highest waste generated in the mill. This study investigates thermochemical approaches, specifically wet torrefaction and gasification, aiming to transform these wastes into higher-value products such as biochar. Wet torrefaction was initially applied to EFB and POME at 200 °C, with a heating rate of 5 °C/min for 30-min residence time under nitrogen-inert conditions, resulting in a solid yield of 82%. This process led to a notable increase in the heating value of raw EFB by 30.6%, from 17.3 to 22.6 MJ/kg. Subsequently, the product underwent gasification at various temperatures ranging from 600 to 800 °C, with a constant heating rate of 10 °C/min, gas flow rate of 20 ml/min, and a retention time of 30 min. The gasification reaction improved the solid yield and resulted in the generation of liquid products and syngas. The results indicated that 45-59% of biochar, 12-17% of bio-oil, and 30-39% of syngas were produced. The syngas composition, determined using gas chromatography, revealed the presence of CO2, H2, CH4, and CO. The solid product, characterised by a higher heating value, is a viable alternative for solid fuel. The findings suggested that both wet torrefaction and the gasification process have the potential to address the abundance of palm mill waste issues and offer an alternative approach for utilising and generating energy within the mill.
棕榈油厂废水(POME)和油棕空果串(EFB)是棕榈油厂产生的最大废物。本研究调查了热化学方法,特别是湿法高温分解和气化,旨在将这些废物转化为生物炭等高价值产品。最初对 EFB 和 POME 采用湿法高温分解,温度为 200 °C,加热速度为 5 °C/分钟,氮惰性条件下停留时间为 30 分钟,固体产量为 82%。这一工艺使原料 EFB 的热值显著提高了 30.6%,从 17.3 兆焦耳/千克提高到 22.6 兆焦耳/千克。随后,该产品在 600 至 800 °C 的不同温度下进行气化,恒定加热速率为 10 °C/分钟,气体流速为 20 毫升/分钟,停留时间为 30 分钟。气化反应提高了固体产量,并产生了液体产品和合成气。结果表明,生成的生物炭占 45-59%,生物油占 12-17%,合成气占 30-39%。使用气相色谱法测定的合成气成分显示,其中含有 CO2、H2、CH4 和 CO。固体产品的特点是热值较高,是一种可行的固体燃料替代品。研究结果表明,湿法高温分解和气化工艺都有可能解决棕榈种植园的大量废弃物问题,并为种植园内能源的利用和生产提供了一种替代方法。
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引用次数: 0
MFIX–DEM simulation of gas-solid flow dynamics in a dual fluidized bed system MFIX-DEM 模拟双流化床系统中的气固流动动力学
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012100
R. K. Banik, H. J. Das
To overcome the operational difficulties associated with bubbling and circulating fluidized bed gasifiers, a new gasification technology termed dual fluidized bed gasification (DFBG) has evolved. To strengthen the understanding of the gasification and combustion processes in the DFBG system, a thorough analysis of bed hydrodynamics is of paramount importance. Furthermore, the complexity of the hydrodynamics escalates while incorporating diverse fuels like biomass and coal, along with bed materials fluidized in a single reactor due to its nonlinearity and transience. As a result, the study of hydrodynamics in such a system is indispensable. The present study focuses on the discrete element model (DEM) simulation of the bed hydrodynamic behaviour within the gasifier of a DFBG system. The simulation was conducted using Multiphase Flow with Interphase eXchanges (MFiX) software. The influence of superficial velocity on the number of particles in a gasifier was analyzed using the 2-D discrete element model (DEM). In this numerical investigation, transient variation of pressure drop, axial and radial solid volume fraction, and particle velocity was evaluated, and the data were analyzed using the ParaView software. The simulation results of the gasifier indicated an increase in the bed pressure drop with the rise in inlet air velocity. The effective height of solid volume fraction also increased with the surge in superficial velocity. The solid velocity profile and streamlines were also investigated to understand its variation pertaining to the location within the fluidized bed.
为了克服鼓泡流化床气化炉和循环流化床气化炉在操作上的困难,一种被称为双流化床气化(DFBG)的新型气化技术应运而生。为了加强对 DFBG 系统中气化和燃烧过程的了解,对床流体力学进行全面分析至关重要。此外,由于流体力学的非线性和瞬时性,在将生物质和煤炭等不同燃料以及床层材料流化在一个反应器中时,流体力学的复杂性也会增加。因此,对这种系统中的流体力学进行研究是必不可少的。本研究的重点是离散元素模型(DEM)模拟 DFBG 系统气化炉内的床层流体力学行为。模拟使用多相流与相间交换(MFiX)软件进行。利用二维离散元素模型(DEM)分析了表层速度对气化炉中颗粒数量的影响。在这项数值研究中,评估了压降、轴向和径向固体体积分数以及颗粒速度的瞬态变化,并使用 ParaView 软件对数据进行了分析。气化炉的模拟结果表明,床层压降随着进气速度的增加而增大。固体体积分数的有效高度也随着表面速度的增加而增加。还对固体速度曲线和流线进行了研究,以了解其与流化床内位置有关的变化。
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引用次数: 0
A study of the temperature distribution in the OTEC cold water pipe using a heat and mass transfer approach 利用传热和传质方法研究 OTEC 冷水管中的温度分布
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012018
A. I. Firmansyah, Mukthasor, D. Satrio, S. Rahmawati, H. Ikhwani, W. A. Pratikto
The difference between sea water temperature at a depth of around 1000 m and sea water temperature at sea level is generally used as a parameter in the design of Ocean Thermal Energy Conversion (OTEC). In practice, electricity generation is determined by the difference between the temperature of the cold seawater coming out of the Cold Water Pipe (CWP) and the temperature of the seawater at the surface. The temperature of cold sea water increases due to heat transfer experienced by cold sea water flowing through the CWP, which comes into contact with surrounding sea water which has a higher temperature. This in turn provides a lower actual temperature difference, and therefore reduces the design power capacity. However, many previous studies did not consider these lower temperature differences. This may be acceptable for cases with practically small heat transfer such as CWP with low thermal conductivity combined with good insulation used in 1000 m CWP vertical floating systems. Unfortunately, this may not be the case for many of OTEC’s proposed alternative sites, which are located on land systems that require CWP lengths of five km or more. This raises the need for careful investigation to determine the temperature of the sea water coming out of the CWP, where it is necessary to calculate the temperature distribution of the cold sea water flowing through the CWP. This paper aims to estimate the temperature distribution of cold sea water flowing through the CWP and the increase in temperature of cold sea water leaving the CWP. Analysis based on the principles of mass and heat transfer was carried out in this research, where modelling was carried out numerically using a finite volume approach. For the case considered, the change in sea water temperature at CWP from depth to the surface occurs 1-3°C, which is the accumulation of each change in sea water depth. The results of this research illustrate that designing an OTEC system with a long CWP must consider the temperature distribution of cold sea water flowing through the CWP to produce a more realistic design.
在海洋热能转换(OTEC)的设计中,通常采用 1000 米左右深度的海水温度与海平面海水温度之差作为参数。实际上,发电量取决于从冷水管道(CWP)流出的冷海水温度与海面海水温度之差。流经冷水管道的冷海水与周围温度较高的海水接触后会发生热传递,从而导致冷海水温度升高。这反过来又降低了实际温差,从而降低了设计功率容量。然而,之前的许多研究并未考虑这些较低的温差。对于热传导实际上较小的情况,如 1000 米 CWP 垂直漂浮系统中使用的导热系数低且隔热性能良好的 CWP,这种情况可能是可以接受的。遗憾的是,对于 OTEC 提议的许多替代场址来说,情况可能并非如此,这些场址位于陆地系统上,需要 5 千米或更长的 CWP。这就需要进行仔细调查,以确定从 CWP 流出的海水温度,其中有必要计算流经 CWP 的冷海水的温度分布。本文旨在估算流经化武生产厂的冷海水的温度分布以及离开化武生产厂的冷海水的温度升高情况。本研究根据传质和传热原理进行分析,并采用有限体积法进行数值模拟。在所考虑的情况下,CWP 海水温度从深度到表面的变化为 1-3°C,即海水深度每次变化的累积值。研究结果表明,在设计具有较长 CWP 的 OTEC 系统时,必须考虑流经 CWP 的冷海水的温度分布,以便设计出更切合实际的系统。
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引用次数: 0
Ion- and surface-sensitive interactions during oxygen evolution reaction in alkaline media 碱性介质中氧进化反应的离子和表面敏感相互作用
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012101
P. D. Angeles, A. R. I. Bustamante, H. A. S. Sasil, D. E. D. Loresca, J. A. Paraggua
Clean and sustainable energy has turned towards electrochemical water splitting as a viable solution in minimizing carbon emissions. Electrolysis of water converts electrical energy to chemical energy, through the production of hydrogen and oxygen gases, which can be harnessed for potential applications without contributing to greenhouse emissions. While this energy storage process shows great potential, its efficiency is hindered by the sluggish kinetics of the oxygen evolution reaction (OER). As a result, its widespread application in green electrolytic technologies is limited hence investigations on improving OER kinetics are of utmost importance. Recent research breakthroughs indicate that alkali metal cations are more than passive observers. They play complex roles in the electric double layer (EDL), which positively influences the OER kinetics. The presence of numerous ions and their combinations presents a challenge of complexity. This study aims to delve into the impact of alkali metal cations on OER activity due to the variance in their hydration energies. Specific investigations focusing on different alkali metal cations in solution, such as Li+, Na+, and K+, was conducted on RuO2 to gain a deeper understanding of how these ions interact with both reactants and intermediate species in the reaction kinetics. Traditional electrochemical tests, including cyclic voltammetry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), and accelerated degradation test (ADT) measurements were employed to elucidate critical aspects such as surface activation, electric double layer interactions, catalytic activity and stability, ohmic resistance, and mass and charge transport.
清洁和可持续能源已转向电化学水分离,将其作为尽量减少碳排放的可行解决方案。电解水通过产生氢气和氧气,将电能转化为化学能。虽然这一储能过程显示出巨大的潜力,但其效率却受到氧进化反应(OER)缓慢动力学的阻碍。因此,它在绿色电解技术中的广泛应用受到了限制,而改善氧进化反应动力学的研究就显得尤为重要。最近的研究突破表明,碱金属阳离子不仅仅是被动的观察者。它们在电双层(EDL)中扮演着复杂的角色,对 OER 动力学产生了积极影响。众多离子的存在及其组合带来了复杂性的挑战。本研究旨在深入探讨碱金属阳离子的水合能量差异对 OER 活性的影响。针对溶液中不同的碱金属阳离子,如 Li+、Na+ 和 K+,在 RuO2 上进行了具体研究,以深入了解这些离子在反应动力学中如何与反应物和中间物种相互作用。研究采用了传统的电化学测试方法,包括循环伏安法 (CV)、线性扫描伏安法 (LSV)、电化学阻抗谱 (EIS) 和加速降解测试 (ADT),以阐明表面活化、电双层相互作用、催化活性和稳定性、欧姆电阻以及质量和电荷传输等关键问题。
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引用次数: 0
Seawater source heat pump system based on capillary heat exchanger for seepage in submarine tunnel: a case study 基于毛细管换热器的海底隧道渗流海水源热泵系统:案例研究
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012074
F J Zhang, L Zhang, C Li, S J Gao
The discharge of seepage water from undersea tunnel structures, often treated as wastewater, inherently carries a substantial reservoir of untapped low-grade thermal energy. Unfortunately, comprehensive investigations into harnessing this latent potential remain notably limited. This study introduced an innovative strategy through the design of an undersea tunnel seepage seawater source heat pump system. Distinguished by the integration of a capillary front-end heat exchanger, this system aimed to effectively exploit the frequently disregarded low-grade thermal energy present in the seepage water of undersea tunnel structures. The seawater seepage from the tunnel is transported to the car park at the tunnel entrance, and a seawater energy pool is constructed by storing seawater in its underground space. The use of capillary network placed in the energy pool in the front heat exchanger, water source heat pump units, circulating water pumps and fan coil end device composed of underground undersea tunnel seepage seawater source heat pump system for the building heating and cooling. Furthermore, a comparative assessment was conducted, contrasting this novel system with the traditional air-conditioning setup that utilizes chillers and gas boilers as cooling and heating sources. The aim was to evaluate its capacity for energy conservation and emission reduction. The findings from the study strongly affirmed the viability of the proposed seepage seawater source heat pump system within undersea tunnels. It boasted the potential to achieve annual savings of 53.55 tce, highlighting a noteworthy energy-saving rate of 21.2%. Concurrently, reductions in CO2, SO2, and particulate emissions amounted to 132.28 t/a, 1.07 t/a, and 0.54 t/a, respectively. This study not only stands as a reference for the strategic utilization of seepage seawater from undersea tunnel structures, prioritizing energy conservation and emission reduction, but also pioneers innovative approaches toward resource optimization and environmental sustainability, meeting the inherent needs of carbon peaking and carbon neutrality goals.
海底隧道结构排放的渗水通常作为废水处理,本身就蕴藏着大量尚未开发的低品位热能。遗憾的是,对利用这一潜在能量的全面研究仍然十分有限。本研究通过设计海底隧道渗流海水源热泵系统,引入了一种创新策略。该系统集成了毛细管前端热交换器,旨在有效利用海底隧道结构渗水中经常被忽视的低品位热能。隧道渗出的海水被输送到隧道入口处的停车场,并通过在其地下空间储存海水来构建海水能源池。利用放置在能量池中的毛细管网前端换热器、水源热泵机组、循环水泵和风机盘管末端装置组成海底隧道地下渗流海水源热泵系统,为建筑物供热制冷。此外,还进行了比较评估,将这种新型系统与利用冷水机组和燃气锅炉作为冷热源的传统空调装置进行了对比。目的是评估其节能减排能力。研究结果有力地证实了拟议的海底隧道渗海水源热泵系统的可行性。该系统每年可节约能源 53.55 吨,节能率高达 21.2%。同时,二氧化碳、二氧化硫和颗粒物排放量分别减少了 132.28 吨/年、1.07 吨/年和 0.54 吨/年。这项研究不仅为海底隧道结构渗漏海水的战略利用、节能减排优先提供了参考,而且开创了资源优化和环境可持续发展的创新方法,满足了碳调峰和碳中和目标的内在需求。
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引用次数: 0
Development of zwitterion-functionalized graphene oxide/polyethersulfone nanocomposite membrane and fouling evaluation using solutes of varying charges 开发齐聚物功能化氧化石墨烯/聚醚砜纳米复合膜并利用不同电荷的溶质进行污垢评估
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012030
C.Z. Soh, Z. Chang, J.Y. Sum, S. P. Yeap, P.V Chai, Z. A. Jawad
This study explores the functionalization of polyethersulfone (PES) ultrafiltration (UF) membranes using zwitterion-functionalized graphene oxide (GO) and assesses their interactions with solutes of different charges, both neutral and anionic. Initially, PES nanocomposite membranes were synthesized, incorporating varying dosages (ranging from 0-1 % (w/w)) of glycine-functionalized graphene oxide (Gly/GO) and diglycine-functionalized graphene oxide (diGly/GO) through a direct blending method. The physicochemical properties, including hydrophilicity, surface morphology, and porosity of these membranes were characterized using sessile-drop contact angle, tabletop scanning electron microscopy (SEM), and gravimetric methods, respectively. Subsequently, the antifouling performance of these synthesized membranes was assessed by exposing them to a solution containing sucrose as a neutral model foulant and humic acid as an anionic foulant. The incorporation of zwitterion-functionalized graphene oxide nanoparticles improved the surface wettability of the nanocomposite membrane, enhancing its resistance to sucrose fouling. This was supported by a reduction in flux declination ratio (e.g., 40.6 % for pristine PES, 29.7 % for 1.0 % (w/w) Gly/GO PES, and 33.1 % for 1.0 % (w/w) diGly/GO PES) and an increase in flux recovery ratio (67.2 % for pristine PES, 79.7 % for 1.0 % (w/w) Gly/GO PES, and 80.0% for 1.0 % (w/w) diGly/GO PES). The improvement in antifouling characteristics is attributed to the formation of a hydration layer on the membrane surface, which inhibits sucrose deposition. However, zwitterion-functionalized PES nanocomposite membranes displayed a higher affinity for anionic humic acid, resulting in a substantial flux decline and a lower flux recovery ratio. Overall, this research provides insights into the roles of surface wettability and the charge interactions between solutes and the membrane surface, both of which are crucial factors in determining fouling severity and the restorability of spent membranes.
本研究探讨了使用齐聚物功能化氧化石墨烯(GO)对聚醚砜(PES)超滤膜进行功能化的问题,并评估了它们与不同电荷(包括中性电荷和阴离子电荷)的溶质之间的相互作用。首先,通过直接混合法合成了聚醚砜纳米复合膜,其中加入了不同剂量(0-1%(w/w)不等)的甘氨酸功能化氧化石墨烯(Gly/GO)和二甘氨酸功能化氧化石墨烯(diGly/GO)。采用无梗水滴接触角、台式扫描电子显微镜(SEM)和重量法分别对这些膜的亲水性、表面形貌和孔隙率等理化性质进行了表征。随后,将这些合成膜暴露在含有蔗糖(中性污垢模型)和腐植酸(阴离子污垢)的溶液中,对其防污性能进行了评估。加入齐聚物功能化的氧化石墨烯纳米颗粒改善了纳米复合膜的表面润湿性,提高了其抗蔗糖污垢的能力。通量衰减率的降低(例如,原生石墨烯膜的通量衰减率为 40.6%)证明了这一点、原始 PES 为 40.6%,1.0%(重量比)Gly/GO PES 为 29.7%,1.0%(重量比)diGly/GO PES 为 33.1%),通量恢复比增加(原始 PES 为 67.2%,1.0%(重量比)Gly/GO PES 为 79.7%,1.0%(重量比)diGly/GO PES 为 80.0%)。防污特性的改善归功于膜表面水合层的形成,它抑制了蔗糖的沉积。然而,齐聚物功能化的 PES 纳米复合膜对阴离子腐植酸的亲和力更高,导致通量大幅下降,通量回收率降低。总之,这项研究深入揭示了表面润湿性和溶质与膜表面之间电荷相互作用的作用,这两者都是决定污垢严重程度和废膜可恢复性的关键因素。
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引用次数: 0
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IOP Conference Series: Earth and Environmental Science
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