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2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)最新文献

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Interface stoichiometry control in ZnO/Cu2O photovoltaic devices ZnO/Cu2O光伏器件的界面化学计量控制
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744960
S. Wilson, Y. Tolstova, H. Atwater
Cu2O is a potential earth-abundant alternative to established thin photovoltaic materials (CIGS, CdTe, etc.) because of its low cost, high availability, and inexpensive processing, but Cu2O has seen limited development as a photovoltaic device material owing to challenges in measurement and control of interface stoichiometry and doping. We report measurements of Cu2O interface stoichiometry and the effect of interface composition on heterojunction device performance. ZnO/Cu2O interface stoichiometry was varied by adjusting the ZnO window layer deposition conditions and stoichiometry was measured by X-ray photoelectron spectroscopy. Current-voltage characteristics of ZnO/Cu2O heterojunctions indicate open circuit voltages of Voc ~ 530 mV for devices where the Cu2O layer is stoichiometric at the interface and Voc ~ 100 mV for devices where Cu2O is nonstoichiometric at the interface.
Cu2O具有低成本、高可用性和廉价的加工成本,是现有薄光伏材料(CIGS、CdTe等)的潜在替代品,但由于界面化学计量学和掺杂的测量和控制方面的挑战,Cu2O作为光伏器件材料的发展有限。我们报道了Cu2O界面化学计量的测量和界面组成对异质结器件性能的影响。通过调整ZnO窗口层沉积条件改变了ZnO/Cu2O界面化学计量,并用x射线光电子能谱测量了化学计量。ZnO/Cu2O异质结的电流电压特性表明,Cu2O层在界面处为化学计量的器件开路电压为Voc ~ 530 mV, Cu2O层在界面处为非化学计量的器件开路电压为Voc ~ 100 mV。
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引用次数: 1
Towards the origin of photochemical EVA discoloration 光化学EVA变色的成因探讨
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744447
C. Peike, Lea Purschke, K. Weiß, Michael Kohl, M. Kempe
The root cause of the photochemical ethylene vinyl acetate (EVA) discoloration in photovoltaic (PV) modules was investigated. Laminates containing EVA foils with a systematic variation of the additive formulation, i.e. the crosslinking agents, ultraviolet (UV) absorber, hindered amine light stabilizers and antioxidants, were subjected to UV aging. The influence of the additive combination on the photochemical aging of EVA was investigated by Raman spectroscopy, Fourier transform infrared spectroscopy and UV/visible spectroscopy. The amount of EVA discoloration was found to be strongly depending on the additive formation. An important impact of the antioxidant in terms of chromophore formation inhibition could be found. Surprisingly, the highly stabilized EVA foils showed higher discoloration rates as well as a more intense fluorescence background in the Raman spectra.
研究了光伏(PV)组件光化学醋酸乙烯酯(EVA)变色的根本原因。层压板含有EVA箔与系统变化的添加剂配方,即交联剂,紫外线(UV)吸收剂,受阻胺光稳定剂和抗氧化剂,进行紫外线老化。采用拉曼光谱、傅里叶变换红外光谱和紫外/可见光谱研究了添加剂组合对EVA光化学老化的影响。EVA的变色量与添加剂的形成有很大的关系。发现抗氧化剂在抑制发色团形成方面具有重要影响。令人惊讶的是,高度稳定的EVA箔在拉曼光谱中显示出更高的变色率以及更强的荧光背景。
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引用次数: 36
Thermodynamic limits of solar cells with non-ideal optical response 具有非理想光学响应的太阳能电池热力学极限
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744318
M. Khan, P. Bermel, M. Alam
The Shockley-Queisser (S-Q) theory defines the thermodynamic upper limits for Jsc, Voc, FF, and efficiency of a solar cell. The classical calculation assumes an abrupt onset of absorption at the band-edge, perfect absorption for all energies above the bandgap, and absence of non-radiative recombination. These assumptions are never satisfied for any practical solar cell. In this paper, we explain how the S-Q limits are redefined in the presence of the non-ideal optical effects, and we provide closed-form analytical expressions for the new limits for Jsc, Voc, and FF. Remarkably, these new limits can be achieved to a very high degree, even with significantly imperfect materials.
Shockley-Queisser (S-Q)理论定义了太阳能电池的Jsc、Voc、FF和效率的热力学上限。经典计算假设在带边缘处突然开始吸收,带隙以上的所有能量都完全吸收,并且没有非辐射复合。这些假设对于任何实际的太阳能电池来说都是不满足的。在本文中,我们解释了如何在存在非理想光学效应的情况下重新定义S-Q极限,并为Jsc, Voc和FF的新极限提供了封闭形式的解析表达式。值得注意的是,这些新的极限可以达到非常高的程度,即使材料明显不完美。
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引用次数: 4
Simulation and development of sub-wavelength grated dielectric ARCs for CPV applications 用于CPV应用的亚波长光栅介电电弧的仿真与开发
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6745104
Wei Wang, A. Freundlich
Here, and in an attempt to identify a better alternative to the conventional dual layer ARCs for III-V multi-junction concentrator cells operating with or without protective cover glass in conjunction with wide acceptance angles, we have undertaken a systematic analysis of design parameters and angular dependent antireflective properties of dielectric grating formed, through the implementation of sub-wavelength arrays of 2D pyramidal gratings of ZnS and TiO2. Though the study indicated no or limited improvement for devices operating with a SiO2 like cover glass, in the absence of a cover the evaluation indicates that through a careful selection of the design these dielectric gratings can reduce reflection-loss related current losses by 2-3 fold by comparison to their planar double layer ARC counterparts. i.e. for a 3J metamorphic device this lead to a current improvement of 0.7 mA/cm2 for a 60 degree acceptance angles.
在这里,为了找到一种更好的替代传统双层电弧的III-V型多结聚光电池,在有或没有保护罩玻璃的情况下,结合宽接受角,我们通过实现ZnS和TiO2的二维锥体光栅的亚波长阵列,对设计参数和角度相关的介电光栅抗反射特性进行了系统分析。虽然研究表明,对于使用SiO2等覆盖玻璃的设备没有或有限的改进,但在没有覆盖玻璃的情况下,评估表明,通过仔细选择设计,这些介质光栅可以将反射损耗相关的电流损失减少2-3倍,与平面双层ARC相比。也就是说,对于一个3J的变质器件,在60度接受角下,这将导致0.7 mA/cm2的电流改进。
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引用次数: 1
Commercial size multicrytalline silicon solar cell with ion implant emitter 具有离子植入发射极的商业尺寸多晶硅太阳能电池
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744910
A. Ebong, Yizhe Wang, Guangyao Jin, T. Zhou
This paper reports on the preliminary results of the first manufacturable ion implanted multicrystalline silicon solar cells with mean efficiency of 16.60%. The best efficiency of 16.83% is demonstrated, which is the highest reported ion implanted 243.4 cm2 multicrystalline silicon solar cell with Al back surface field. A dose of 2.8E15 atom.cm2 at 15-keV was used and annealed at implant anneal similar to the mono crystalline solar cell counterparts. The open circuit voltage of ~621 mV and the measured internal quantum efficiency (IQE) were similar to multicrystalline cells using POCl3 emitter. This results is very promising and confirms that the bulk lifetime does not degrade during the implant anneal.
本文报道了第一个可制造的离子注入多晶硅太阳能电池的初步结果,其平均效率为16.60%。结果表明,离子注入243.4 cm2铝背表面场的多晶硅太阳电池效率最高,达到16.83%。2.8E15原子的剂量。在15 kev下使用cm2,并在类似单晶太阳能电池的植入退火下进行退火。开路电压为~621 mV,测得的内部量子效率(IQE)与使用POCl3发射极的多晶硅电池相似。这一结果是非常有希望的,并证实了种植体在退火过程中不会降低整体寿命。
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引用次数: 0
Feasibility study of homojunction CIGS solar cells 均匀结CIGS太阳能电池的可行性研究
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744869
N. Nakagawa, S. Shibasaki, H. Hiraga, M. Yamazaki, Kazushige Yamamoto, S. Sakurada
The potential for high conversion efficiency of the homojunction Cu(In, Ga)Se2 (CIGS) solar cells was examined by device simulations and experimental approaches. The simulation results showed that many electrons in n-CIGS layers could compensate to some extent for the existence of interface states at i-ZnO/n-CIGS interfaces in the homojunction structure. In the case of using the partial electrolyte treatments of CIGS films to produce the n-type doping, the concentrations of the Cd dopants in the n-CIGS layer were 1016 cm-2. The conversion efficiency of 17.2% for this homojunction CIGS solar cell was obtained.
通过器件模拟和实验方法研究了Cu(In, Ga)Se2 (CIGS)太阳能电池的高转换效率潜力。仿真结果表明,n-CIGS层中的大量电子可以在一定程度上补偿同质结结构中i-ZnO/n-CIGS界面态的存在。采用部分电解质处理CIGS膜制备n型掺杂时,n-CIGS膜中Cd掺杂物的浓度为1016 cm-2。该电池的转换效率为17.2%。
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引用次数: 2
Influence of the Schottky barrier height on the silicon solar cells 肖特基势垒高度对硅太阳能电池的影响
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6745023
S. Thibert, J. Jourdan, B. Bechevet, D. Chaussy, N. Reverdy-Bruas, D. Beneventi
With the recent introduction of ion implantation in the photovoltaic industry, it is now easier to carefully tailor the emitter doping profile. However the metallization layout should be optimized in the same time, as they are closely linked via the metal/silicon contact resistivity. In this work, an advanced co-optimization procedure allows finding out the influence of the Schottky barrier height on the metal grid design and the optimal doping profile. The theoretical electrical properties of a 2 × 2 cm2 ideal silicon solar cell are also computed for each optimal combination. According to this work, the maximal achievable efficiency decreases from 26.2 % to 25.3 % if the Schottky barrier height increases from 0.5 eV to 0.9 e V.
随着最近在光伏工业中引入离子注入,现在更容易仔细地定制发射极掺杂轮廓。然而,由于金属/硅的接触电阻率将金属化布局紧密联系在一起,因此应同时优化金属化布局。在这项工作中,一种先进的协同优化程序可以找出肖特基势垒高度对金属栅格设计和最佳掺杂谱的影响。计算了2 × 2 cm2理想硅太阳电池的理论电学性能。根据这项工作,当肖特基势垒高度从0.5 eV增加到0.9 eV时,最大可达到效率从26.2%下降到25.3%。
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引用次数: 1
Optical cell temperature measurements of multiple CPV technologies in outdoor conditions 多种CPV技术在室外条件下的光学电池温度测量
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6745184
M. Muller, T. Silverman, M. Deceglie, S. Kurtz, E. Menard, S. Burroughs
It is well known that photovoltaic performance is dependent on cell temperature. Although various methods have been explored to determine outdoor concentrating photovoltaic (CPV) cell temperature, no method has proven to work across all module technologies and result in desirable uncertainties. Menard (2012) has recently published results claiming accurate measurements of cell temperature using the wavelength shift of light emitted from the sub-cells of a Semprius CPV module. This work focuses on efforts to verify Menard's results using additional CPV technologies that are on-sun at NREL. Baseline electro-luminescence emission is recorded for modules under a low level forward bias and under isothermal conditions using thermal chambers. The same modules or sister modules are then placed on NREL's high accuracy two-axis tracker for outdoor measurements. Photo-luminescence emission peaks are measured for multiple modules at stable wind and irradiance conditions. Emission results from the sub-cells are compared to what is documented in the literature for the given semiconductor material. The signal to background ratio is analyzed and the possible broad applicability of this procedure is discussed.
众所周知,光伏电池的性能取决于电池的温度。尽管已经探索了各种方法来确定室外聚光光伏(CPV)电池温度,但没有一种方法被证明适用于所有模块技术并产生理想的不确定性。Menard(2012)最近发表的研究结果声称,利用Semprius CPV模块的子电池发出的光的波长位移,可以精确测量电池温度。这项工作的重点是使用NREL的附加CPV技术来验证Menard的结果。使用热室在低水平正向偏置和等温条件下记录模块的基线电致发光发射。然后将相同的模块或姊妹模块放置在NREL的高精度双轴跟踪器上进行室外测量。在稳定的风和辐照条件下,测量了多个模块的光致发光发射峰。从亚电池的发射结果是比较什么是在文献中记录的给定的半导体材料。对信本比进行了分析,并讨论了该方法的广泛适用性。
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引用次数: 4
Analysis, design, and evaluation of a high frequency inductor to reduce manufacturing cost, and improve the efficiency of a PV inverter 分析,设计和评估高频电感,以降低制造成本,提高光伏逆变器的效率
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6745064
A. Alabakhshizadeh, O. Midtgård, K. Boysen
Photovoltaic inverters are the major functional units of the photovoltaic systems. Therefore, efficiency and cost are vitally important in the design, and operation of the PV system. Magnetic components are the bulkiest component and highly affect the efficiency of the galvanically isolated PV inverter and design of such component generally involves a compromise between the reduction of core loss at the expense of increased winding loss or vice versa. The loss characteristics of the magnetic material itself present a fundamental limitation on core loss reduction, implying that the intrinsic reduction of core loss density depends on magnetic material improvements. Hence, the essential tradeoff between cost, performance and physical size must be done by designers to make the most optimal inductor for their design. A high frequency magnetic powder core inductor used in galvanically isolated PV inverter is analyzed with commercially available finite element analysis software, Maxwell - Ansoft. Results obtained from simulation studies are compared with built prototype show good agreement.
光伏逆变器是光伏发电系统的主要功能部件。因此,在光伏发电系统的设计和运行中,效率和成本是至关重要的。磁性元件是体积最大的元件,对电隔离式PV逆变器的效率影响很大,此类元件的设计通常涉及以增加绕组损耗为代价降低铁芯损耗或反之亦然之间的折衷。磁性材料本身的损耗特性对磁芯损耗的降低产生了根本性的限制,这意味着磁芯损耗密度的内在降低取决于磁性材料的改进。因此,设计人员必须在成本,性能和物理尺寸之间进行必要的权衡,以使其设计最优的电感。采用Maxwell - Ansoft有限元分析软件,对电隔离式光伏逆变器中高频磁粉铁芯电感进行了分析。仿真研究结果与实际样机进行了比较,结果吻合较好。
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引用次数: 2
Metalorganic vapor phase epitaxy growth of dual junction solar cell with InGaAs/GaAsP superlattice on Ge 锗上InGaAs/GaAsP超晶格双结太阳能电池的金属有机气相外延生长
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744157
H. Sodabanlu, Yunpeng Wang, Shaojun Ma, Kentaroh Watanabe, M. Sugiyama, Y. Nakano
The impact of growth temperature was investigated on the quality and interface abruptness of InGaAs/GaAsP multiple quantum wells (MQWs) grown on various misoriented substrates. The growth of MQWs on substrates with a larger misoriented angle required a lower temperature. Non-radiative carrier lifetimes in MQWs strongly depended on the quality and abruptness of MQWs. On the basis of this understanding, a dual junction cell consisting of InGaAs/GaAsP superlattice top cell and Ge bottom cell was successfully fabricated. The result encourages the application of InGaAs/GaAsP superlattice for better current balancing and higher efficiency by III-V/Ge multiple junction solar cells.
研究了生长温度对生长在不同取向基底上的InGaAs/GaAsP多量子阱质量和界面粗糙度的影响。在取向角较大的衬底上生长MQWs需要较低的温度。小波的非辐射载流子寿命与小波的质量和突发性密切相关。在此基础上,成功制备了由InGaAs/GaAsP超晶格顶电池和Ge底电池组成的双结电池。该结果鼓励了InGaAs/GaAsP超晶格在III-V/Ge多结太阳能电池中更好的电流平衡和更高的效率的应用。
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引用次数: 0
期刊
2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)
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