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Performance Analysis of Fabricated ‘Hastelloy C-276–AISI 409’ Stirrer for Application in Petrochemical Industry 石化工业用“哈氏合金C-276-AISI 409”搅拌器性能分析
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-20 DOI: 10.1007/s11665-025-11771-9
Kalinga Simant Bal

The performance study of the fabricated stirrer was based on tensile, fatigue, flexural, and corrosion tests. The tensile specimen fractured at the base metal showed a higher value of ultimate tensile stress (≈ 12%) and extension (≈ twice) as compared to that of the specimen fractured at the weld zone (WZ) which was due to the difference in the fracture modes with the former being more plastic and the latter being restrained by precipitate decohesion–fragmentation phenomena. No fracture was visible for the specimens subjected to 105 fatigue cycles, and the force–displacement behavior was observed to follow a closed-loop hysteresis curve. Implementation of the numerical method showed a logarithmic increase in the maximum deflection at the midspan, where the angular variable factor plays an important role in controlling the flexural deformation. The slower cooling rate of the WZ (= 44.97 °C/s) during solidification led to the Mo segregation and caused corrosion at the nanoscale level due to the formation of localized concentration cells. The introduction of ‘weld shield glass–camera’ assembly and ‘neutral density filter–infrared pyrometer’ combination helped in capturing the five stages of free-mode droplet transfer and the weld pool thermal cycle, respectively.

Graphical Abstract

所制搅拌器的性能研究是基于拉伸、疲劳、弯曲和腐蚀试验。与焊缝区(WZ)断裂相比,在母材处断裂的拉伸试样的极限拉应力值(≈12%)和延伸值(≈2倍)更高,这是由于试样的断裂模式不同,母材处断裂的塑性更强,而焊缝处断裂的析出散裂现象抑制了试样的断裂模式。105次疲劳循环后试样未见断裂,力-位移行为服从闭环迟滞曲线。数值方法的实现表明,跨中最大挠度呈对数增长,其中角变因子对控制弯折变形起着重要作用。WZ在凝固过程中较慢的冷却速度(= 44.97℃/s)导致Mo偏析,并在纳米尺度上形成局部浓度细胞导致腐蚀。“焊接屏蔽玻璃相机”组件和“中性密度过滤器-红外高温计”组合的引入有助于分别捕捉自由模式液滴转移和焊接池热循环的五个阶段。图形抽象
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引用次数: 0
Effect of TiO2 Content on Coefficient of Thermal Expansion, Crystallization Behavior, and Optical Properties of La2O3-Y2O3-Al2O3-B2O3-SiO2 Glass TiO2含量对La2O3-Y2O3-Al2O3-B2O3-SiO2玻璃热膨胀系数、结晶行为和光学性能的影响
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-20 DOI: 10.1007/s11665-025-11809-y
Junyu Yao, Weiwei Zhu, Haohao Zou, Ying Han, Xu Ran

In this study, the coefficient of thermal expansion (CTE), crystallization behavior, refractive index, and in-line transmittance of La2O3-Y2O3-Al2O3-B2O3-SiO2 glasses with different TiO2 contents were studied. With the increased in TiO2 content, the CTE value could be adjusted in the range of 6.0 × 10−6/°C-6.5 × 10−6/°C. And the refractive index gradually increased from 1.6935 to 1.8010 due to the high refractive factor of TiO2. Glass has an excellent in-line transmittance of more than 79%. This provides good conditions for brazing transparent ceramics to obtain joints with excellent in-line transmittance and high strength. Additionally, the increase in TiO2 content decreased the crystallization characteristic temperature of the glasses. After crystallization treatment, the type of crystals changed and the crystal content gradually increased.

本研究研究了不同TiO2含量的La2O3-Y2O3-Al2O3-B2O3-SiO2玻璃的热膨胀系数(CTE)、结晶行为、折射率和在线透射率。随着TiO2含量的增加,CTE值可以在6.0 × 10−6/°C ~ 6.5 × 10−6/°C范围内调节。由于TiO2的高折射率,其折射率从1.6935逐渐增加到1.8010。玻璃具有优异的在线透光率,超过79%。这为钎焊透明陶瓷提供了良好的条件,获得了良好的在线透光率和高强度的接头。此外,TiO2含量的增加降低了玻璃的结晶特征温度。结晶处理后,晶体类型发生变化,晶体含量逐渐增加。
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引用次数: 0
The Performance of AA6082 Aluminum in Simulated Marine Environments after Blast-Cleaning with Recycled Glass Grit 回收玻璃砂喷砂清洗后AA6082铝在模拟海洋环境中的性能研究
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-20 DOI: 10.1007/s11665-025-11735-z
Andreas W. Momber, Maria Serdechnova, Carsten Blawert

Recycled glass grit was applied to the blast-cleaning of AA6082 aluminum alloys. Effects on morphology, chemistry and corrosion of the substrates were studied and compared with garnet blast-cleaning. The substrates were inspected by means of scanning electron microscopy, energy-dispersive x-ray spectroscopy, x-ray diffraction and scanning confocal microscopy. Electrochemical impedance spectroscopy and cyclic corrosion tests in artificial seawater were applied. Glass grit generated irregular isotropic surface morphologies and promoted the embedment of glass debris into the substrate. The surfaces met the profile roughness requirements for offshore applications. The corrosion performance of glass grit blast-cleaned AA6082 was excellent in cyclic testing using artificial seawater. Specific energy consumptions and CO2 footprints for all process steps were calculated and compared with garnet blast-cleaning. Influence classes were estimated for all working steps. Compressed-air-based working steps contributed critically to specific energy consumption and to CO2 footprint.

采用再生玻璃砂对AA6082铝合金进行喷砂清洗。研究了石榴石喷砂清洗对基体形貌、化学性质和腐蚀性能的影响,并进行了比较。采用扫描电子显微镜、能量色散x射线能谱、x射线衍射和扫描共聚焦显微镜对基材进行了检测。应用电化学阻抗谱法和人工海水循环腐蚀试验。玻璃砂产生不规则的各向同性表面形态,促进玻璃碎片嵌入基片。表面满足海上应用的轮廓粗糙度要求。在人工海水循环试验中,喷砂净化AA6082的腐蚀性能良好。计算了所有工艺步骤的比能耗和二氧化碳足迹,并与石榴石喷砂清洗进行了比较。对所有工作步骤估计了影响等级。以压缩空气为基础的工作步骤对特定能源消耗和二氧化碳足迹产生了重大影响。
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引用次数: 0
Effect of Potential and pH on Passive Behavior of Nickel-Based Alloy Under High Hydrostatic Pressure 电位和pH对高静水压力下镍基合金钝化行为的影响
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-20 DOI: 10.1007/s11665-025-11824-z
Bisheng Gong, Sifan Wen, Xiuqi Hu, Ke Gong, Feixiong Mao

This study provides new insights into the passivation behavior and growth mechanism of nickel-based alloy in a simulated deep-sea environment, with a focus on the effects of applied potentials and solution pH. To comprehensively elucidate the influence mechanisms of the experimental variables on the passive film formed on the nickel-based alloy surface, in situ electrochemical tests, x-ray photoelectron spectroscopy, and transmission electron microscopy were employed. The results obtained from these analyses demonstrate that the passive film exhibits characteristics of an n-type semiconductor and possesses an amorphous structure, where the film thickness decreases with increasing potential, leading to enhanced ionic transport through the film. A novel finding is that the increase in potential not only raises the CrO3/Cr2O3 ratio but also significantly increases the oxygen vacancy diffusion rate, which accelerates the cation transport and reduces the corrosion resistance. Furthermore, the oxygen vacancies increase with pH due to enhanced hydroxyl ion adsorption, while the Cr2O3 content decreases, resulting in a less protective passive film.

本研究为镍基合金在模拟深海环境中的钝化行为和生长机制提供了新的见解,重点研究了施加电位和溶液ph的影响。为了全面阐明实验变量对镍基合金表面钝化膜形成的影响机制,采用了原位电化学测试、x射线光电子能谱和透射电镜等方法。分析结果表明,该钝化膜具有n型半导体的特性,具有非晶结构,薄膜厚度随电位的增加而减小,导致离子在薄膜中的输运增强。新发现是电势的增加不仅提高了CrO3/Cr2O3比,而且显著提高了氧空位扩散速率,从而加速了阳离子的传递,降低了材料的耐蚀性。此外,由于羟基离子吸附增强,氧空位随着pH值的增加而增加,而Cr2O3含量减少,导致钝化膜的保护性减弱。
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引用次数: 0
Mechanism of Molded Fiber Products in Plastic Strain and the Construction of a Model of Moisture Content 模压纤维制品塑性应变机理及含水率模型的建立
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-20 DOI: 10.1007/s11665-025-11816-z
Zhiqiang Fu, Hongsong Wang, Liying Duan, Tong Zhao, Liqiang Huang, Hesong Liu, Zhiyong Zhao, Xiaoyu Jia

The change in moisture content (MC) will lead to a change in the mechanical properties of molded fiber products (MFP). Therefore, for predicting the mechanical properties of MFP, it is necessary to construct a mechanical constitutive model with the MC term. In this study, quasi-static uniaxial tensile tests of sugarcane bagasse-molded fiber products (SBMFP) were conducted at different MCs (0 ~ 17%), and the stress-strain curves were obtained. The maximum failure strength of SBMFP was achieved at 6% MC. The phenomenon of MFP, the fiber moisture swelling-induced damage, was observed by SEM of the mesoscopic fiber structure of SBMFP. To accurately predict the SBMFP’s mechanical properties at different MCs, based on the test results, a plastic constitutive model containing the MC term of SBMFP was constructed using the Geometric Linear Mapping method. Based on the constitutive model, the tensile process was simulated in Abaqus. The maximum error between the simulation results and the test data was 5.91%. The influence mechanism and the new constitutive model were validated by wheat straw-molded fiber products (WSMFP) and waste paper-molded fiber products (WPMFP). This study provides theoretical support for predicting the mechanical properties of fiber products.

含水率(MC)的变化会导致模塑纤维制品(MFP)力学性能的变化。因此,为了预测MFP的力学性能,有必要建立带有MC项的力学本构模型。本研究对甘蔗渣模塑纤维制品(SBMFP)进行了不同MCs(0 ~ 17%)下的准静态单轴拉伸试验,得到了应力-应变曲线。在6% MC时,SBMFP达到了最大破坏强度。通过扫描电镜观察了SBMFP细观纤维结构的MFP现象,即纤维湿胀损伤。为了准确预测SBMFP在不同MCs下的力学性能,在试验结果的基础上,采用几何线性映射法建立了包含MCs项的SBMFP塑性本构模型。基于本构模型,在Abaqus中对拉伸过程进行了数值模拟。仿真结果与试验数据的最大误差为5.91%。通过麦秸模塑纤维制品(WSMFP)和废纸模塑纤维制品(WPMFP)验证了影响机理和新的本构模型。该研究为预测纤维制品的力学性能提供了理论支持。
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引用次数: 0
Effects of Raster Angle, Printing Speed, and Layer Height on Mechanical Properties of Fused Deposition Modeling-Printed Polylactic Acid Samples for Biomedical Applications 光栅角度、打印速度和层高对生物医学用熔融沉积建模打印聚乳酸样品力学性能的影响
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-20 DOI: 10.1007/s11665-025-11812-3
Rakesh Kumar, Santosh Kumar

In this investigation, the taguchi methodology was employed to examine the effects of fused deposition modeling parameters on printed polylactic acid (PLA) material. The fabricated samples were tested for the tensile and flexural strengrh using a universal testing machine. Finally, the signal-to-noise ratio and analysis of variance were applied to choose the best possible combinations of the parameters. The optimal results were obtained at optimal process parameters (angle was 0°, printing speed was 30 mm/sec, and layer height was 0.10 mm). At these optimal parameters, maximum tensile strength (44.56 MPa) and flexural strength (110.25 MPa) were achieved. In addition, a differential scanning calorimetry (DSC) test on the highest tensile strength sample was conducted to examine the thermal characteristics of polymer materials. The plot between temperature vs. heat flow shows reactions at a particular temperature. This indicates that a high-strength PLA sample absorbs a significant quantity of energy. In addition, a surface roughness test was also performed using Mitutoyo SJ-301 roughness tester on the lowest and highest tensile strength samples to examine the effect of printing parameters. The average surface roughness of lowest and highest tensile strength samples was 15.24 µm and 10.233 µm, respectively. Thus, the surface roughness study demonstrates that printing parameters (printing speed, layer height, etc.) play the major role in achieving the desired surface roughness.

在本研究中,采用田口方法研究了熔融沉积建模参数对打印聚乳酸(PLA)材料的影响。利用万能试验机对制备的试样进行了拉伸和弯曲强度测试。最后,应用信噪比和方差分析来选择参数的最佳可能组合。在最佳工艺参数(打印角度为0°,打印速度为30 mm/sec,层高为0.10 mm)下获得最佳效果。在此优化参数下,材料的最大抗拉强度为44.56 MPa,最大抗折强度为110.25 MPa。此外,对拉伸强度最高的样品进行了差示扫描量热(DSC)测试,以检查聚合物材料的热特性。温度与热流的关系图显示了在特定温度下的反应。这表明高强度PLA样品吸收了大量的能量。此外,还使用Mitutoyo SJ-301粗糙度测试仪对最低和最高拉伸强度样品进行表面粗糙度测试,以检查打印参数的影响。拉伸强度最低和最高样品的平均表面粗糙度分别为15.24µm和10.233µm。因此,表面粗糙度研究表明,打印参数(打印速度,层高等)在实现所需表面粗糙度方面起主要作用。
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引用次数: 0
Analytical Estimation of Build Profile in Gas Metal Arc Directed Energy Deposition Process 气体金属电弧定向能沉积过程中构建轮廓的分析估计
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-20 DOI: 10.1007/s11665-025-11749-7
Pratyush Jyoti Roy, Aritra Karar, Atanu Das

Process parameters, such as wire feed rate, deposition travel speed and energy input per unit length, have a direct impact on controlling the dimensional consistency of the multi-layer components in the gas metal arc directed energy deposition (GMA-DED) process. The present investigation proposes a novel analytical methodology to estimate the build profile of single-track-multi-layer builds following mechanistic principles of energy balance and thermo-physical properties of the materials. The analytically estimated and the corresponding experimentally measured results for a range of process conditions considered in the present study have shown a fair agreement with a deviation of around 0.87%, 3.9% and 4% for build height, net build width and surface waviness, respectively. The present methodology can be employed to design the optimum process parameters for enhancing the reliability of GMA-DED components.

在气体金属电弧定向能沉积(GMA-DED)工艺中,送丝速度、沉积行程速度和单位长度能量输入等工艺参数对多层构件尺寸一致性的控制有直接影响。本研究提出了一种新的分析方法,根据材料的能量平衡和热物理性质的机理原理来估计单轨多层结构的结构轮廓。在本研究中考虑的一系列工艺条件下的分析估计和相应的实验测量结果表明,在构建高度,净构建宽度和表面波浪度方面,偏差分别约为0.87%,3.9%和4%。该方法可用于设计最佳工艺参数,以提高GMA-DED部件的可靠性。
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引用次数: 0
Optimizing Mechanical Properties of Selective Laser Sintering-Printed Nylon-Glass Fiber Composites through Controlled Annealing Parameters 通过控制退火参数优化激光烧结印刷尼龙-玻璃纤维复合材料的力学性能
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-19 DOI: 10.1007/s11665-025-11788-0
Abhinav Mukundan, Abraham Shine, V. M. Adhil, Geo G Vithayathil, Juby Joseph, Vipin Vijayan, V. V. Manikandan

This research explores the optimization of mechanical properties of the Nylon-Glass Fiber composites manufactured by Selective Laser Sintering (SLS) under varying annealing conditions. Nylon 12, which is reinforced with glass fibers, was fabricated by SLS process, after which annealing at room temperature, 110, 130, and 150 °C was done. The effects of these thermal treatments had made changes on the composite’s mechanical properties like tensile, flexural, and impact properties which were then evaluated. Metallurgical tests such as Fourier transform infrared spectroscopy (FTIR) and field emission scanning electron microscopy (FE-SEM) were employed to understand the microstructural changes that had happened due to annealing and to identify the reasons for the property enhancements. Results revealed a significant improvement in mechanical performance, particularly at 150 °C, where the composites exhibited superior tensile, flexural, and impact strength due to its lesser structural defects, improved polymer chain alignment, and upgraded fiber-matrix bonding. However, further increases in temperature led to poor performance, bringing into view the critical importance of precise annealing parameters to get the best results. FTIR analysis confirmed the rearrangement of the polymer chains and reduced chemical degradation after annealing, while FE-SEM images showed improved inter-molecular bonding and a more homogeneous microstructure. These findings bring into a conclusion the potential of controlled annealing processes to significantly enhance the durability, strength, and resilience of SLS-printed composites, making them particularly suitable for demanding applications in the aerospace, automotive, and industrial manufacturing sectors. This study provides a comprehensive framework for tailoring composite properties through post-processing, thereby advancing the capabilities and industrial relevance of additive manufacturing technologies.

研究了不同退火条件下选择性激光烧结法制备的尼龙-玻璃纤维复合材料的力学性能。采用SLS法制备了玻璃纤维增强尼龙12,分别在室温、110℃、130℃和150℃下退火。这些热处理的效果改变了复合材料的力学性能,如拉伸、弯曲和冲击性能,然后对这些性能进行了评估。采用傅里叶变换红外光谱(FTIR)和场发射扫描电镜(FE-SEM)等冶金测试来了解由于退火而发生的微观结构变化,并确定性能增强的原因。结果表明,复合材料的机械性能有了显著的提高,特别是在150°C时,由于其较少的结构缺陷、改善的聚合物链排列和升级的纤维-基质结合,复合材料表现出优异的拉伸、弯曲和冲击强度。然而,温度的进一步升高导致性能变差,这表明精确的退火参数对于获得最佳结果至关重要。FTIR分析证实了聚合物链的重排和退火后化学降解的减少,而FE-SEM图像显示了分子间键的改善和更均匀的微观结构。这些发现得出结论,受控退火工艺有可能显著提高sls打印复合材料的耐久性、强度和弹性,使其特别适用于航空航天、汽车和工业制造领域的苛刻应用。本研究为通过后处理定制复合材料性能提供了一个全面的框架,从而提高了增材制造技术的能力和工业相关性。
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引用次数: 0
A Research on AC Corrosion of B30 Alloy in Simulated Seawater B30合金在模拟海水中的交流腐蚀研究
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-19 DOI: 10.1007/s11665-025-11792-4
S. T. Guo, M. Zhu, Y. F. Yuan, S. Y. Guo

This resarch systematically investigated the alternating current (AC) interference corrosion of B30 alloy in simulated ocean environment. The results exhibit that the imposed AC apparently facilitates the dissolution of surface passive film, augments the level of internal flaws in the film, diminishes its protective effect, and reduces the anti-corrosion performance of the alloy. As AC density rises, the adsorption of H+/Cl at the flaws of passivation film is promoted, causing the film integrity and stability to decrease and deteriorating the local corrosion degree. The pits produced on the alloy result from the selective dissolution of the Cu element.

本研究系统研究了模拟海洋环境中B30合金的交流干扰腐蚀。结果表明:施加的交流电明显促进了表面钝化膜的溶解,增加了钝化膜内部缺陷的程度,降低了钝化膜的保护作用,降低了合金的防腐性能;随着交流浓度的升高,促进了H+/Cl−在钝化膜缺陷处的吸附,导致钝化膜的完整性和稳定性降低,局部腐蚀程度恶化。合金上产生的凹坑是铜元素选择性溶解的结果。
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引用次数: 0
Modeling of Magnetocaloric Effect in A2B′BO6 Transition Metal Double Perovskite-Based Oxides for Cooling Applications Using Random Forest and Hybrid Support Vector Regression Intelligent Methods 基于随机森林和混合支持向量回归智能方法的A2B 'BO6过渡金属双钙钛矿基氧化物的磁热效应建模
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-08-19 DOI: 10.1007/s11665-025-11783-5
Sami M. Ibn Shamsah

A2BBO6 (where A is the rare-earth metal, B is a transition metal, and B is any metal) double perovskite-based oxides exhibit novel and interesting features such as exchange bias, multiferroic and magnetocaloric effect, which promote their candidature for magnetic cooling applications. The double exchange interaction (existing between B′-O-B) that influences the observed magnetocaloric effect for cooling applications becomes strengthened by the proper combination of electronic configuration and ionic radii of rare-earth and B and B ions. In this contribution, the magnetocaloric effect of the A2B′BO6 system, a double perovskite, is modeled using random forest regression (RFR) and hybrid genetically optimized support vector regression (GSVR) algorithms, which employ crystal lattice parameters and ionic radii as predictors at various applied magnetic fields. Using assessment parameters such as correlation coefficient (CC), root mean square error (RMSE), and mean absolute error (MAE), the performances of the developed GSVR-ionic and RFR-ionic models with ionic radii descriptors are compared with those of the GSVR-latt and RFR-latt models, which employ crystal structural parameters as predictors. In the case of the RFR-based model, the values of assessment parameters computed for training samples of double perovskite magnetocaloric oxides using RFR-IONIC were 0.9873, 1.3750, and 1.1069 J/Kg K corresponding to CC, RMSE, and MAE, respectively. For the same assessment parameters using the RFR-latt model, 0.9096, 2.6041, and 1.7635 J/Kg K were, respectively, computed. The GSVR-ionic model outperforms the GSVR-latt, RFR-ionic, and RFR-latt models, achieving improvements of 8.18, 57.63, and 47.85%, respectively, as measured by the RMSE metric. Performance superiorities of 4.89, 60.13, and 40.95% were obtained using the MAE performance metric with double perovskite magnetocaloric oxide testing samples. The outstanding performance demonstrated by the models developed would strengthen the exploration of the magnetocaloric effect in the A2B′BO6 system of double perovskite for addressing energy crises in cooling applications.

A2B ‘ bo6(其中A是稀土金属,B是过渡金属,B ’是任何金属)双钙钛矿基氧化物表现出新颖有趣的特性,如交换偏置、多铁性和磁热效应,这促进了它们在磁冷却应用中的候选性。双交换相互作用(存在于B′-O-B之间)影响冷却应用中观测到的磁热效应,通过稀土与B′和B离子的电子构型和离子半径的适当组合而得到加强。在本文中,采用随机森林回归(RFR)和混合遗传优化支持向量回归(GSVR)算法对双钙钛矿A2B 'BO6体系的磁热效应进行了建模,这两种算法采用晶格参数和离子半径作为不同外加磁场下的预测因子。利用相关系数(CC)、均方根误差(RMSE)和平均绝对误差(MAE)等评价参数,比较了采用离子半径描述符的GSVR-ionic和RFR-ionic模型与采用晶体结构参数作为预测因子的GSVR-latt和RFR-latt模型的性能。在基于rfr的模型中,利用RFR-IONIC对双钙钛矿磁热氧化物训练样品计算的评估参数值分别为0.9873、1.3750和1.1069 J/Kg K,对应于CC、RMSE和MAE。对于相同的评价参数,采用RFR-latt模型分别计算得到0.9096、2.6041和1.7635 J/Kg K。gsvr -离子模型优于GSVR-latt、rfr -离子模型和RFR-latt模型,通过RMSE度量分别实现了8.18%、57.63%和47.85%的改进。采用双钙钛矿磁热氧化物测试样品的MAE性能指标,其性能优势分别为4.89、60.13和40.95%。所建立的模型所显示的优异性能将加强对双钙钛矿A2B 'BO6体系磁热效应的探索,以解决冷却应用中的能源危机。
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引用次数: 0
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