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Influence of environment, temperature and time of the thermal modification of ash wood (Fraxinus excelsior L.) on the cellulose weight average degree of polymerization 白蜡木热改性环境、温度和时间对纤维素质量、平均聚合度的影响
Pub Date : 2021-12-30 DOI: 10.5604/01.3001.0015.6642
J. Gawron
Influence of environment, temperature and time of the thermal modification of ash wood (Fraxinus excelsior L.) on the cellulose weight average degree of polymerization . Using the size-exclusion chromatography (HPLC SEC) method, the weight average degree of cellulose polymerization was determined. The polymer was isolated by the Kürschner-Hoffer method from ash wood (Fraxinus excelsior L.). The wood was thermally modified in different environments (nitrogen, steam and air) at 190°C and modification times of 2, 6 and 10 hours. Depending on the anaerobic atmosphere used, the highest values of the weight average degree of cellulose polymerization were obtained for the nitrogen environment, followed by steam and air. The effect of modification time on the weight average degree of polymerization was observed. The highest values were obtained for wood modified at 2 hours, then 6 and 10 hours of modification. The native wood showed the highest degree of polymerization. On the basis of the results obtained, it can be concluded that for the material studied the oxidation and degradation reactions occurring depend on the environment and time for a given temperature of wood modification.
白蜡木热改性环境、温度和时间对纤维素质量、平均聚合度的影响采用排粒径色谱法(HPLC)测定了纤维素的重量平均聚合度。该聚合物采用k rschner- hoffer法从白蜡木(Fraxinus excelsior L.)中分离得到。木材在不同的环境(氮气,蒸汽和空气)中进行热改性,温度为190°C,改性时间为2,6和10小时。根据所使用的厌氧气氛,在氮气环境中获得的纤维素重量平均聚合度最高,其次是蒸汽和空气。观察了改性时间对质量平均聚合度的影响。木材在改性2小时、6小时和10小时时获得最高值。原生木材的聚合程度最高。根据得到的结果,可以得出结论,对于所研究的材料,在给定的木材改性温度下,氧化和降解反应的发生取决于环境和时间。
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引用次数: 0
Classics of Polish Design. Post-War Polish Furniture Design. 波兰设计经典。战后波兰家具设计。
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.6370
A. Różańska
Classics of Polish Design. Post-War Polish Furniture Design the paper presents a review of Polish post-war design in the times of Polish People's Republic: in the 1950s and 1960s. It is the first paper in the series of "Classical Polish Design", presenting the results of research on Polish furniture and the icons of Polish design, carried out within the framework of dissertations in the Department of Wood Technology in the Warsaw University of Life Sciences (SGGW). The paper presents two main trends in Polish post-war design, together with their background. We analysed the development of industrial design and of mass production dedicated for mass users, as well as the education system for industrial designers. We present the concept of furniture for small living spaces and the impact of global trends, availability of new materials and technological solutions on Polish furniture design.
波兰设计经典。战后波兰家具设计本文回顾了波兰人民共和国时期的战后波兰设计:在20世纪50年代和60年代。这是“经典波兰设计”系列的第一篇论文,介绍了华沙生命科学大学(SGGW)木材技术系在论文框架内对波兰家具和波兰设计标志的研究结果。本文介绍了波兰战后设计的两个主要趋势及其背景。我们分析了工业设计和面向大众用户的大规模生产的发展,以及工业设计师的教育体系。我们提出了小生活空间家具的概念,以及全球趋势的影响,新材料的可用性和波兰家具设计的技术解决方案。
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引用次数: 1
Selected techniques of soil contaminated phytoremediation with the use of hyperaccumulative plants and trees 利用超蓄积性植物和树木修复土壤污染植物的技术选择
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.6332
M. Niedbała
Selected techniques of soil phytoremediation with the use of hyperaccumulative plants and trees are intended to outline the possibilities of using various hyperaccumulative plants, including trees, in the phytoremediation process of contaminated soil matrix. The potential of plants that belong to the group of hyperaccumulators is huge, especially in the case of pollution of large areas of agricultural, forest and urban soil. They can be used in the process of cleaning contaminated, industrially degraded areas and supplement the physical and physicochemical methods of remediation of contaminated areas.
利用超积累植物和树木的土壤植物修复技术的选择旨在概述在污染土壤基质的植物修复过程中使用各种超积累植物(包括树木)的可能性。超蓄积体植物的潜力是巨大的,特别是在大面积的农业、森林和城市土壤污染的情况下。它们可用于污染、工业退化地区的清洁过程中,并补充污染地区修复的物理和物理化学方法。
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引用次数: 1
Moisture swelling and shrinkage of pine wood versus susceptibility to robotic assembly of furniture elements 松木的潮气膨胀和收缩与机器人组装家具元件的敏感性
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.5274
Wojciech Turbański, M. Sydor, Łukasz Matwiej, K. Wiaderek
Moisture swelling and shrinkage of pine wood and susceptibility to robotic assembly of furniture elements. Background and Objectives. Processing technology, storage conditions and wood properties affect the actual dimensions of wooden elements. It was decided to experimentally check how the dimensions of samples, made of the selected wood species, will change under the influence of different storage conditions, typical for industrial environments. And especially how these changes will affect the susceptibility to assembly of upholstery frame rails that form a box joint. Materials and Methods. The tests were performed on three series of rails made of Scotch pine wood. Each tested series consisted of 12 elements. First, the five dimensions forming the box joint were measured. Then, each series was exposed to different conditions: in the industrial hall (air of RH = 29-48% and t = 16-24°C), in the compressor room (RH = 24-51%, t = 13-27°C) and outside in a covered shed (RH = 20-50%, t = 3-23°C). After 35 days the dimensions were measured again. Results. It was found that the average moisture content decreased and the dimensional deviations increased in the samples stored in the production hall and in the compressor room. In samples stored outside, the mean moisture content did not change, but the dimensional deviations increased significantly. Discussion. The storage of wooden elements increases the deviations from assigned dimensions. Exposure to repeated changes in moisture content and ambient temperature, even without changing the final moisture content of the elements, results in greater dimensional changes than storage under more stabilized conditions that reduce wood moisture content. Conclusions. The shrinkage and swelling of wood due to changes in its moisture content are not fully reversible, therefore, apart from maintaining the appropriate temperature and air humidity during storage, it is important to keep these conditions unchanged.
松木的潮气膨胀和收缩以及对家具元件机器人装配的敏感性。背景和目标。加工工艺、储存条件和木材性能影响木件的实际尺寸。他们决定通过实验来检查由所选木材制成的样品的尺寸在不同的储存条件(典型的工业环境)的影响下是如何变化的。特别是这些变化将如何影响易组装的内饰框架轨道,形成一个盒子接头。材料与方法。测试是在苏格兰松木制成的三个系列轨道上进行的。每个测试系列由12个元素组成。首先,测量了箱体接头的5个尺寸;然后,将每个系列暴露在不同的条件下:在工业大厅(RH = 29-48%, t = 16-24℃),在压缩室内(RH = 24-51%, t = 13-27℃)和室外(RH = 20-50%, t = 3-23℃)。35天后,再次测量这些尺寸。结果。结果发现,在生产车间和压缩机房存放的样品,其平均含水率降低,尺寸偏差增大。在室外贮存时,样品的平均含水率没有变化,但尺寸偏差明显增加。讨论。木质元素的储存增加了与指定尺寸的偏差。暴露于水分含量和环境温度的反复变化中,即使没有改变元素的最终水分含量,也会导致比在更稳定的条件下储存更大的尺寸变化,从而降低木材的水分含量。结论。木材的收缩和膨胀由于其水分含量的变化是不完全可逆的,因此,除了在储存期间保持适当的温度和空气湿度外,重要的是保持这些条件不变。
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引用次数: 1
The influence of particleboard resination on their internal bond strength 刨花板树脂对其内部粘结强度的影响
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.5273
Stella Rzyska-Pruchnik, G. Kowaluk
The influence of particleboard resination on their internal bond strength. The aim of the project was to investigate the main mechanical and physical properties of particleboards, especially focused on internal bond, in terms of their resination. For the tests, the particleboards have been produced in laboratory conditions with the following glue content: 7, 10, 15, 30 and 50%. Particular attention was paid for examining the mechanical property – tensile strength perpendicular to surfaces (Internal Bond – IB). In addition, there were investigated modulus of elasticity (MOE), modulus of rupture (MOR) density and density profile. In the light of above mentioned tests, there is no positive effect of improvement of tested parameters when raise resination over 30% when producing particleboards. With the resination increase from 7 to 50% a significant change (densification) of panels’ structure, as well as differences between face and core layers density have been found.
刨花板树脂对其内部粘结强度的影响。该项目的目的是研究 刨花板的主要机械和物理特性,特别是在其树脂方面的内部粘合。为了进行测试,刨花板在实验室条件下生产,胶水含量为:7,10,15,30和50%。特别注意的是检查机械性能-垂直于表面的拉伸强度(内部键合- IB)。此外,还研究了 弹性模量(MOE)、断裂模量(MOR)密度和密度剖面。从上述试验来看,在生产刨花板时,当树脂含量超过30%时,对试验参数的改善没有积极作用。当树脂含量从7%增加到50%时,发现了面板结构的显著变化(致密化),以及面板和芯层密度之间的差异。
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引用次数: 2
Impact of annual growth pattern on swelling of selected wood species 年生长模式对选定树种膨胀的影响
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.7302
E. Dobrowolska, Joanna Macińska
Impact of annual growth pattern on swelling of selected wood species. Unit swelling was investigated in radial and tangential directions as well as in the intermediate directions for wood of density ranging from 300÷500 kg/m3 and 500÷700 kg/m3 and above 700 kg/m3. Species selected included pine – PNSY (Pinus sylvestris L.), oak – QCXE (Quercus. robur L.) and bangkirai – SHBL (Shorea spp.), teak – TEGR (Tectona grandis), merbau – INXX (Intsia bijuga), jatoba – HYCB (Hymenaea courbaril L). For all the studied wood species, the lowest swelling in the radial direction (0°) was found after both 2 h and 24 h of wetting in water, which increased with the angle of inclination of the annual growth and, after reaching 90°, corresponded to the maximum swelling in the tangential direction. For pine (PNSY) sapwood and heartwood and for oak (QCXE), a high swelling unit was obtained after a wetting time of 2 h, with little change after 24 h of wetting. Swelling increments for the other wood species were lower, ranging from 1% to over 2% after a wetting time of 2 h, showing slight differences between radial and tangential directions. For these wood species, after 24 h of wetting the swelling was higher and varied from more than 2% to nearly 5% in the radial direction and from more than 4% to 10% in the tangential direction. The study showed that, for high-density wood species, it becomes necessary to extend the wetting time in order to determine the actual maximum swelling per unit. The swelling anisotropy coefficients ε of the studied wood species corresponded to the values found in the literature. Higher coefficients were found for oak (QCXE) and teak (TEGR), bangkirai (SHBL) and jatoba (INXX), and were related to the characteristic features of the density structure and anatomical structure. The unit swelling values calculated with the Krzysik (1974) and Vorreiter (1949) equations may be used to assess changes in the dimensions of elements in intermediate directions. The discrepancies between the experimental and theoretical values are smaller for the unit swelling values calculated with the Vorreiter (1949) equation compared to the Krzysik (1974) equation.
年生长模式对选定树种膨胀的影响。对密度为300÷500 kg/m3和500÷700 kg/m3及700 kg/m3以上的木材进行了径向和切向以及中间方向的单元膨胀研究。选择的树种包括pine - PNSY (Pinus sylvestris L.), oak - QCXE (Quercus.)。所有树种在水分湿润2 h和24 h后,径向膨胀最小(0°),随年生长倾斜角增大而增大,在90°后,切向膨胀最大。对于松材(PNSY)、心材和橡木(QCXE),润湿2 h后膨胀系数较高,润湿24 h后变化不大。其他树种的溶胀增量较低,在浸湿2 h后,溶胀增量在1% ~ 2%之间,径向和切向略有差异。润湿24 h后,这些树种的溶胀率较高,径向溶胀率在2%以上至近5%之间,切向溶胀率在4%以上至10%之间。研究表明,对于高密度木材品种,有必要延长润湿时间,以确定每单位的实际最大膨胀。所研究树种的膨胀各向异性系数ε与文献中发现的值相符。栎木(QCXE)、柚木(TEGR)、竹木(SHBL)和竹叶(INXX)的系数较高,且与密度结构和解剖结构的特征有关。用Krzysik(1974)和Vorreiter(1949)方程计算的单位膨胀值可以用来评估元素在中间方向上的尺寸变化。与Krzysik(1974)方程相比,Vorreiter(1949)方程计算的单位膨胀值的实验值与理论值之间的差异较小。
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引用次数: 0
Testing of the fatigue strength along wood fibres at different moisture contents 不同含水率下沿木纤维的疲劳强度试验
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.5133
E. Dobrowolska, M. Niedbała, Daniel Tabaczyński
Testing of the fatigue strength along wood fibres at different moisture contents. The paper determines the effect of wood moisture content on the fatigue strength in compression along fibres. The method of determining the maximum stress at the proportional limit was used for the measurements. Fatigue strength was investigated for three wood species: pedunculate oak (Quercus robur L.), bearded birch (Betula pendula Roth.) and Norway spruce (Picea abies L.), with two moisture contents: close to the absolutely dry state and above the fibre saturation point. The ratio of fatigue strength to short term strength depends on moisture content and is similar for birch (70.3% in the dry state and 72.1% in the wet state), for oak (67.4% and 69.5% in both states) and for spruce (66.6% in the dry state and 68.1% in the wet state). The moisture content of the wood clearly influences the fatigue strength of the wood. On average, the fatigue strength of wood with moisture contents above the fibre saturation point constitutes about 0.20 of the fatigue strength of wood with moisture contents close to 0%. This tendency was found regardless of the tested species. The simplified method for testing fatigue strength at the limit of proportionality has shown its limited usefulness, requiring further analysis and comparison with other methods in order to be thoroughly tested and possibly improved.
不同含水率下沿木纤维的疲劳强度试验。测定了木材含水率对沿纤维压缩疲劳强度的影响。测量采用了在比例极限处确定最大应力的方法。研究了三种木材的疲劳强度:有柄栎(Quercus robur L.)、胡子桦(Betula pendula Roth.)和挪威云杉(Picea abies L.),两种木材的水分含量:接近绝对干燥状态和高于纤维饱和点。疲劳强度与短期强度之比取决于含水率,桦木(干燥状态为70.3%,潮湿状态为72.1%)、橡树(两种状态分别为67.4%和69.5%)和云杉(干燥状态为66.6%,潮湿状态为68.1%)的含水率相似。木材的含水率明显影响木材的疲劳强度。平均而言,含水率高于纤维饱和点的木材的疲劳强度约为含水率接近0%的木材疲劳强度的0.20。无论测试的物种是什么,都发现了这种趋势。比例极限疲劳强度的简化测试方法已经显示出其有限的实用性,需要进一步的分析和与其他方法的比较,以便进行彻底的测试和可能的改进。
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引用次数: 0
The review of the financial strategies of Polish wood-industry companies listed on the Warsaw Stock Exchange 在华沙证券交易所上市的波兰木材工业公司的财务战略回顾
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.5025
J. Biernacka
The review of the financial strategies of Polish wood-industry companies listed on the Warsaw Stock Exchange. The paper focuses on the analysis of the financing strategies of wood industry enterprises listed on Warsaw Stock Exchange in 2018 - 2020. This paper examines three main values characterising company's financing strategy: equity capital share in total capital, equity capital share in fixed assets and long-term debt share in total debt. The data for calculations was taken from publicly available quarterly financial statements of analysed entities from 1st quarter of 2018 to 3rd quarter of 2020. The analysis showed that moderate financing strategy was used by Biofactory and KLON companies and an aggressive strategy was used by Standrew. KPPD financing strategy was not possible to clearly define due to the high volatility of values of examined ratios and depend on the considered period. The highest variability in the structure of foreign capital was observed in KLON - in this company the highest level of long-term debt was observed (above 70% of total debt).
在华沙证券交易所上市的波兰木材工业公司的财务战略回顾。本文重点分析了华沙证券交易所上市木材行业企业2018 - 2020年的融资策略。本文考察了表征公司融资策略的三个主要价值:股权资本占总资本的比例、股权资本占固定资产的比例和长期债务占总债务的比例。用于计算的数据取自2018年第一季度至2020年第三季度被分析实体的公开季度财务报表。分析表明,Biofactory和KLON公司采用了温和的融资策略,Standrew公司采用了激进的融资策略。由于所审查比率的价值高度波动,并取决于所考虑的时期,因此不可能明确界定KPPD融资战略。外资结构的最大变异性出现在KLON——该公司长期债务水平最高(占总债务的70%以上)。
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引用次数: 1
The effect of the time process of enzymatic hydrolysis on nanocellulose properties 酶解时间过程对纳米纤维素性能的影响
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.6629
M. Babicka, M. Woźniak, K. Szentner, S. Borysiak, K. Dwiecki, I. Ratajczak
The effect of the time process of enzymatic hydrolysis on nanocellulose properties - the aim of the study was to evaluate the effect of enzymatic hydrolysis time on the properties of obtained nanocellulose. Two cellulose materials were tested as a raw material for nanocellulose production in the experiment: Avicel and Whatman. The cellulolytic enzyme obtained from the fungus Trichoderma reesei was used to carry out the enzymatic hydrolysis reaction. Enzymatic hydrolysis was performed on cellulose using the reaction times of 0.5, 1, 2 and 4 hours. In order to characterize the obtained materials, the following analyses were used: infrared spectroscopy, X-ray diffraction and dynamic light scattering. The recorded results showed that cellulose after enzymatic hydrolysis showed similar parameters (particle size, XRD patterns and degree of crystallinity) after all the applied reaction times.
酶解时间过程对纳米纤维素性能的影响——本研究的目的是评价酶解时间对所得纳米纤维素性能的影响。在实验中测试了两种纤维素材料作为纳米纤维素生产的原料:Avicel和Whatman。从里氏木霉中提取纤维素水解酶进行酶解反应。对纤维素进行酶解,反应时间分别为0.5、1、2和4小时。为了表征所获得的材料,使用了以下分析:红外光谱,x射线衍射和动态光散射。记录结果表明,酶解后的纤维素在不同的反应时间内具有相似的参数(粒度、XRD谱图和结晶度)。
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引用次数: 0
Bent chairs as poster inspiration 弯曲的椅子作为海报的灵感
Pub Date : 2021-09-26 DOI: 10.5604/01.3001.0015.6635
G. Wieloch
Bent chairs as poster inspiration. In 2020, an exhibition of posters based on seating equipment was presented at the National Museum in Poznań. The exhibition referred to the chair and the metamorphosis it underwent, that apart from the function of utility furniture, it became a part of art, Equipment basically used for sitting - to which we are used to everyday practice of its use, it is an indispensable element of the interior design of apartments, offices, waiting rooms, schools, stadiums, health clinics, shopping malls, cinemas, theatres and other public places. The posters on display showed chairs with a structure based on bent beech elements. Some of them accurately represented the types of bent chairs currently in production. A number of other chairs had bent elements in their design, e.g. backrests, legs or armrests, allowing for economical serial production of elements. The exhibition included works advertising films, theatre and opera performances, exhibition and party posters. They are mostly works by Polish designers.
弯曲的椅子作为海报的灵感。2020年,波兹纳斯国家博物馆举办了一场以座椅设备为基础的海报展览。展览提到了椅子和它所经历的蜕变,除了实用家具的功能,它成为了艺术的一部分,基本上是用来坐的设备——我们习惯了它的日常使用,它是公寓、办公室、候车室、学校、体育场馆、诊所、商场、电影院、剧院和其他公共场所的室内设计中不可或缺的元素。展出的海报展示了基于弯曲山毛榉元素的椅子结构。其中一些准确地代表了目前生产的弯曲椅的类型。许多其他椅子在设计中有弯曲的元素,例如靠背、腿或扶手,允许经济的批量生产元素。展览包括电影广告、戏剧表演、展览和晚会海报。它们大多是波兰设计师的作品。
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引用次数: 0
期刊
Annals of WULS, Forestry and Wood Technology
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