首页 > 最新文献

Environmental Nanotechnology, Monitoring and Management最新文献

英文 中文
Development of flexible SERS substrates based on silver nanoparticles and graphene quantum dots on fiberglass for enhanced dye detection 基于银纳米粒子和石墨烯量子点的玻璃纤维柔性SERS衬底的开发用于增强染料检测
Q1 Environmental Science Pub Date : 2025-08-15 DOI: 10.1016/j.enmm.2025.101094
Nurul Mutmainnah Ramlan , Isnaeni Isnaeni , Adnan Fatahillah Afiff , Maria M. Suliyanti , Dahlang Tahir
This study presents the development of a flexible Surface Enhanced Raman Spectroscopy (SERS) substrate by combining Silver Nanoparticles (Ag NPs) and Graphene Quantum Dots (GQD) on fiberglass (FG) substrates. GQD is synthesized using an electrolysis method, and Ag NPs are deposited onto the substrate via microwave-assisted hydrothermal synthesis. The resulting substrates, GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG, were used to detect Raman signals from three different dyes: Malachite Green (MG), Methylene Blue (MB), and Eriochrome Black T (EBT). The SERS results indicate that the GQD0.78 % + Ag NPs @FG substrate exhibits higher sensitivity than GQD25% + Ag NPs @FG. The SERS signal is enhanced by 1.98–2.26 times and 2.54–3.53 times on the GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG substrates, respectively, due to the presence of GQD, indicating the significant role of GQD concentration in enhancing the Raman signal. This research highlights the potential of flexible SERS substrates for cost-effective, high-sensitivity detection, particularly in environmental and industrial applications.
本研究提出了在玻璃纤维(FG)衬底上结合银纳米粒子(Ag NPs)和石墨烯量子点(GQD)的柔性表面增强拉曼光谱(SERS)衬底的开发。采用电解法合成了GQD,并通过微波辅助水热合成将银纳米粒子沉积在衬底上。所得底物GQD25% + Ag NPs @FG和gqd0.78% + Ag NPs @FG分别用于检测孔雀石绿(MG)、亚甲基蓝(MB)和Eriochrome Black T (EBT)三种不同染料的拉曼信号。SERS结果表明,gqd0.78% + Ag NPs @FG底物的灵敏度高于GQD25% + Ag NPs @FG底物。GQD的存在使GQD25% + Ag NPs @FG和gqd0.78% + Ag NPs @FG底物的SERS信号分别增强1.98 ~ 2.26倍和2.54 ~ 3.53倍,表明GQD浓度对拉曼信号的增强作用显著。这项研究强调了柔性SERS基板具有成本效益,高灵敏度检测的潜力,特别是在环境和工业应用中。
{"title":"Development of flexible SERS substrates based on silver nanoparticles and graphene quantum dots on fiberglass for enhanced dye detection","authors":"Nurul Mutmainnah Ramlan ,&nbsp;Isnaeni Isnaeni ,&nbsp;Adnan Fatahillah Afiff ,&nbsp;Maria M. Suliyanti ,&nbsp;Dahlang Tahir","doi":"10.1016/j.enmm.2025.101094","DOIUrl":"10.1016/j.enmm.2025.101094","url":null,"abstract":"<div><div>This study presents the development of a flexible Surface Enhanced Raman Spectroscopy (SERS) substrate by combining Silver Nanoparticles (Ag NPs) and Graphene Quantum Dots (GQD) on fiberglass (FG) substrates. GQD is synthesized using an electrolysis method, and Ag NPs are deposited onto the substrate via microwave-assisted hydrothermal synthesis. The resulting substrates, GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG, were used to detect Raman signals from three different dyes: Malachite Green (MG), Methylene Blue (MB), and Eriochrome Black T (EBT). The SERS results indicate that the GQD0.78 % + Ag NPs @FG substrate exhibits higher sensitivity than GQD25% + Ag NPs @FG. The SERS signal is enhanced by 1.98–2.26 times and 2.54–3.53 times on the GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG substrates, respectively, due to the presence of GQD, indicating the significant role of GQD concentration in enhancing the Raman signal. This research highlights the potential of flexible SERS substrates for cost-effective, high-sensitivity detection, particularly in environmental and industrial applications.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101094"},"PeriodicalIF":0.0,"publicationDate":"2025-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144878922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eggshell waste as a sustainable resource for nanoparticle preparation; synthesis, characterization and applications 蛋壳废料作为纳米颗粒制备的可持续资源合成、表征及应用
Q1 Environmental Science Pub Date : 2025-08-05 DOI: 10.1016/j.enmm.2025.101092
Eman Ayman Nada , Mallak Eyad Abu Kaddorah , Mazen El Jamal , Amal Hamad , Fotouh R. Mansour
There has been substantial interest in using eggshell waste for the creation of environmentally-friendly products. This review discusses on the synthesis and examination of nanoparticles obtained from eggshells, with a particular focus on their suitability for usage in environmental and catalytic settings. Calcination and mechanical grinding are acknowledged as effective techniques for generating eggshell nanoparticles. Calcination is a high-temperature process that converts calcium carbonate (CaCO3) into calcium oxide (CaO). On the other hand, mechanical grinding is a method used to decrease the size of particles to the nanoscale. The text examines different methods employed for characterization, such as thermogravimetric analysis (TGA) for evaluating thermal stability, zeta potential for assessing surface charge and stability, X-ray diffraction (XRD) for identifying crystal structure, Fourier transform infrared (FTIR) spectroscopy for detecting functional groups, energy-dispersive X-ray (EDX) spectroscopy for determining elemental composition, dynamic light scattering (DLS) for analyzing particle size distribution, and atomic force microscopy (AFM) for visualizing surface morphology. The produced nano-hydroxyapatite shows promise as an adsorbent for effectively eliminating arsenic and heavy metals from water systems, hence contributing to sustainable waste management and advancements in materials. This work offers a thorough comprehension of the procedure involved in producing and examining eggshell nanoparticles. Acquiring this information is crucial for effectively utilizing them in environmental remediation and catalytic processes.
人们对利用蛋壳废料制造环保产品非常感兴趣。这篇综述讨论了从蛋壳中获得的纳米颗粒的合成和检测,特别关注了它们在环境和催化环境中的适用性。煅烧和机械研磨是制备蛋壳纳米颗粒的有效技术。煅烧是将碳酸钙(CaCO3)转化为氧化钙(CaO)的高温过程。另一方面,机械研磨是一种用于将颗粒尺寸减小到纳米级的方法。本文考察了用于表征的不同方法,例如用于评估热稳定性的热重分析(TGA),用于评估表面电荷和稳定性的zeta电位,用于识别晶体结构的x射线衍射(XRD),用于检测官能团的傅里叶变换红外(FTIR)光谱,用于确定元素组成的能量色散x射线(EDX)光谱,用于分析粒度分布的动态光散射(DLS),原子力显微镜(AFM)用于表面形貌的可视化。制备的纳米羟基磷灰石有望作为一种吸附剂,有效地消除水系统中的砷和重金属,从而有助于可持续废物管理和材料的进步。这项工作提供了生产和检查蛋壳纳米粒子所涉及的程序的透彻理解。获取这些信息对于在环境修复和催化过程中有效利用它们至关重要。
{"title":"Eggshell waste as a sustainable resource for nanoparticle preparation; synthesis, characterization and applications","authors":"Eman Ayman Nada ,&nbsp;Mallak Eyad Abu Kaddorah ,&nbsp;Mazen El Jamal ,&nbsp;Amal Hamad ,&nbsp;Fotouh R. Mansour","doi":"10.1016/j.enmm.2025.101092","DOIUrl":"10.1016/j.enmm.2025.101092","url":null,"abstract":"<div><div>There has been substantial interest in using eggshell waste for the creation of environmentally-friendly products. This review discusses on the synthesis and examination of nanoparticles obtained from eggshells, with a particular focus on their suitability for usage in environmental and catalytic settings. Calcination and mechanical grinding are acknowledged as effective techniques for generating eggshell nanoparticles. Calcination is a high-temperature process that converts calcium carbonate (CaCO<sub>3</sub>) into calcium oxide (CaO). On the other hand, mechanical grinding is a method used to decrease the size of particles to the nanoscale. The text examines different methods employed for characterization, such as thermogravimetric analysis (TGA) for evaluating thermal stability, zeta potential for assessing surface charge and stability, X-ray diffraction (XRD) for identifying crystal structure, Fourier transform infrared (FTIR) spectroscopy for detecting functional groups, energy-dispersive X-ray (EDX) spectroscopy for determining elemental composition, dynamic light scattering (DLS) for analyzing particle size distribution, and atomic force microscopy (AFM) for visualizing surface morphology. The produced nano-hydroxyapatite shows promise as an adsorbent for effectively eliminating arsenic and heavy metals from water systems, hence contributing to sustainable waste management and advancements in materials. This work offers a thorough comprehension of the procedure involved in producing and examining eggshell nanoparticles. Acquiring this information is crucial for effectively utilizing them in environmental remediation and catalytic processes.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101092"},"PeriodicalIF":0.0,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144771071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rationale of AgNPsmodified 3-dimensional grapheneas electrochemical sensor for the ultra-tracedetermination of mercury ions agnp改性三维石墨烯电化学传感器超痕量测定汞离子的基本原理
Q1 Environmental Science Pub Date : 2025-07-31 DOI: 10.1016/j.enmm.2025.101089
Prasanta Kumar Sahoo , Srikant Sahoo , Rajendra Prasad Pandey , Ashis Kumar Satpati
Mercury (Hg) is a globally accepted highly toxic heavy metal pollutant and despite several important developments in the field, the determination of Hg2+ ions attrace levels in real-world samples is a challenge. Herein, the silver nanoparticles modified with three-dimensional graphene (AgNPs/3D-graphene) nanocomposite has been synthesised through a simple, cost-efficient, one-step freeze-casting routethat has been applied for highlysensitive determination of Hg2+. The 3D cellular network structure with continuous micrometersize open pores and uniformly decorated Ag nanoparticles with an average size of 30 nm has been suggested by the morphologies and structures of the as-prepared AgNPs/3D-Graphene nanocomposite. The AgNPs/3D-graphene nanocomposite-modifiedGCE (AgNPs/3D-graphene/GCE) exhibited a good linear relationship with Hg2+ concentrations ranging from 0.1 to 40 μg L−1. The results showed that the limit of detection (LOD) of 0.08 μg L−1 (S/N = 3), which is significantly less than the World Health Organization’s (WHO) recommended threshold. The method validation has been carried out using certified reference material (CRM). The sensitivity and stability from the composite has been achieved from the well scaffolded AgNPs all along the 3D-graphene network, which has made the method novel and stand out from othere reported. The suggested electrochemical sensor performed well in detecting Hg2+ in soil and borewell water samples as well as in clinical samples, which is crucial in safeguarding human health.
汞(Hg)是全球公认的高毒性重金属污染物,尽管在该领域取得了一些重要进展,但实际样品中Hg2+离子吸引水平的测定仍然是一个挑战。本文通过一种简单、经济、一步的冷冻铸造方法合成了三维石墨烯修饰的银纳米颗粒(AgNPs/ 3d -石墨烯),该方法已被用于高灵敏度的Hg2+测定。制备的AgNPs/3D-石墨烯纳米复合材料的形貌和结构表明其具有连续微米大小的开放孔和均匀装饰的平均尺寸为30 nm的银纳米颗粒的三维细胞网络结构。AgNPs/ 3d -石墨烯纳米复合材料修饰的GCE (AgNPs/ 3d -石墨烯/GCE)与Hg2+浓度在0.1 ~ 40 μg L−1范围内呈良好的线性关系。结果表明,该方法的检出限(LOD)为0.08 μ L−1 (S/N = 3),显著低于世界卫生组织(WHO)推荐阈值。采用标准物质(CRM)对方法进行了验证。这种复合材料的灵敏度和稳定性是通过3d -石墨烯网络上支架良好的AgNPs实现的,这使得该方法新颖,从其他报道中脱颖而出。该电化学传感器能很好地检测土壤和井水样品以及临床样品中的Hg2+,对保障人体健康具有重要意义。
{"title":"Rationale of AgNPsmodified 3-dimensional grapheneas electrochemical sensor for the ultra-tracedetermination of mercury ions","authors":"Prasanta Kumar Sahoo ,&nbsp;Srikant Sahoo ,&nbsp;Rajendra Prasad Pandey ,&nbsp;Ashis Kumar Satpati","doi":"10.1016/j.enmm.2025.101089","DOIUrl":"10.1016/j.enmm.2025.101089","url":null,"abstract":"<div><div>Mercury (Hg) is a globally accepted highly toxic heavy metal pollutant and despite several important developments in the field, the determination of Hg<sup>2+</sup> ions attrace levels in real-world samples is a challenge. Herein, the silver nanoparticles modified with three-dimensional graphene (AgNPs/3D-graphene) nanocomposite has been synthesised through a simple, cost-efficient, one-step freeze-casting routethat has been applied for highlysensitive determination of Hg<sup>2+</sup>. The 3D cellular network structure with continuous micrometersize open pores and uniformly decorated Ag nanoparticles with an average size of 30 nm has been suggested by the morphologies and structures of the as-prepared AgNPs/3D-Graphene nanocomposite. The AgNPs/3D-graphene nanocomposite-modifiedGCE (AgNPs/3D-graphene/GCE) exhibited a good linear relationship with Hg<sup>2+</sup> concentrations ranging from 0.1 to 40 μg L<sup>−1</sup>. The results showed that the limit of detection (LOD) of 0.08 μg L<sup>−1</sup> (S/N = 3), which is significantly less than the World Health Organization’s (WHO) recommended threshold. The method validation has been carried out using certified reference material (CRM). The sensitivity and stability from the composite has been achieved from the well scaffolded AgNPs all along the 3D-graphene network, which has made the method novel and stand out from othere reported. The suggested electrochemical sensor performed well in detecting Hg<sup>2+</sup> in soil and borewell water samples as well as in clinical samples, which is crucial in safeguarding human health.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101089"},"PeriodicalIF":0.0,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144781269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating the sonophotocatalytic activity of Fe(III) doped cobalt oxide nanoparticles prepared by planetary ball milling method in the degradation of amoxicillin as a pollutant 评价行星球磨法制备的Fe(III)掺杂氧化钴纳米颗粒降解污染物阿莫西林的声光催化活性
Q1 Environmental Science Pub Date : 2025-07-30 DOI: 10.1016/j.enmm.2025.101091
Masih Darbandi, Hadis Asadi, At-har Najafi
The world’s waters threatened by the dual forces of demographic growth and industrial expansion. Advanced oxidation techniques, particularly photocatalytic processes, offer a practical and eco-friendly solution to this problem by decomposing organic contaminants, providing a cleaner and safer aquatic environment. Doping of iron(III) ions through the ball milling method was applied to study the activity of nanoparticles (NPs) in the visible spectrum. Advanced techniques were employed to characterize synthesized NPs, utilizing Transmission Electron Microscopy (TEM), X-ray Diffraction (XRD), and Brunauer-Emmett-Teller (BET). The synthesized NPs exhibit a consistent mesoporous structure, as demonstrated by the experimental findings. Research findings indicate that the application of sonocatalytic, photocatalytic, and sonophotocatalytic techniques significantly reduced amoxicillin (AMX), a pharmaceutical pollutant, levels by 46.26%, 60.34%, and 83.14%, respectively, within the one-hour timeframe when utilizing Co3O4/Fe3+ NPs. The 40.37% synergistic effect demonstrated the doped NPs’ efficiency. Additionally, the experimental data strongly aligns with the pseudo-second-order equation, confirming the reaction’s adherence to second-order kinetics. Scavengers like formic acid, disodium oxalate, and isopropanol demonstrated a reduction impact, slowing down the degradation rate by 29.44%, 36.62%, and 74%, respectively. Furthermore, across all four cycles, the negligible decline in the degradation rate confirmed the Co3O4/Fe3+ NPs’ reusability and performance.
世界水资源受到人口增长和工业扩张双重力量的威胁。先进的氧化技术,特别是光催化工艺,通过分解有机污染物,为这一问题提供了一个实用而环保的解决方案,提供了一个更清洁、更安全的水生环境。采用球磨法掺杂铁(III)离子,研究了纳米颗粒(NPs)的可见光谱活性。利用透射电镜(TEM)、x射线衍射(XRD)和布鲁诺尔-埃米特-泰勒(BET)等先进技术对合成的NPs进行了表征。实验结果表明,合成的NPs具有一致的介孔结构。研究结果表明,使用Co3O4/Fe3+ NPs时,声催化、光催化和声光催化技术在1小时内可显著降低药物污染物阿莫西林(AMX)的含量,分别降低46.26%、60.34%和83.14%。40.37%的协同效应证明了掺杂NPs的效率。此外,实验数据与伪二阶方程非常吻合,证实了反应符合二阶动力学。清除剂如甲酸、草酸二钠和异丙醇表现出减少作用,分别使降解率降低29.44%、36.62%和74%。此外,在所有四个循环中,降解率的可忽略不计的下降证实了Co3O4/Fe3+ NPs的可重用性和性能。
{"title":"Evaluating the sonophotocatalytic activity of Fe(III) doped cobalt oxide nanoparticles prepared by planetary ball milling method in the degradation of amoxicillin as a pollutant","authors":"Masih Darbandi,&nbsp;Hadis Asadi,&nbsp;At-har Najafi","doi":"10.1016/j.enmm.2025.101091","DOIUrl":"10.1016/j.enmm.2025.101091","url":null,"abstract":"<div><div>The world’s waters threatened by the dual forces of demographic growth and industrial expansion. Advanced oxidation techniques, particularly photocatalytic processes, offer a practical and eco-friendly solution to this problem by decomposing organic contaminants, providing a cleaner and safer aquatic environment. Doping of iron(III) ions through the ball milling method was applied to study the activity of nanoparticles (NPs) in the visible spectrum. Advanced techniques were employed to characterize synthesized NPs, utilizing Transmission Electron Microscopy (TEM), X-ray Diffraction (XRD), and Brunauer-Emmett-Teller (BET). The synthesized NPs exhibit a consistent mesoporous structure, as demonstrated by the experimental findings. Research findings indicate that the application of sonocatalytic, photocatalytic, and sonophotocatalytic techniques significantly reduced amoxicillin (AMX), a pharmaceutical pollutant, levels by 46.26%, 60.34%, and 83.14%, respectively, within the one-hour timeframe when utilizing Co<sub>3</sub>O<sub>4</sub>/Fe<sup>3+</sup> NPs. The 40.37% synergistic effect demonstrated the doped NPs’ efficiency. Additionally, the experimental data strongly aligns with the pseudo-second-order equation, confirming the reaction’s adherence to second-order kinetics. Scavengers like formic acid, disodium oxalate, and isopropanol demonstrated a reduction impact, slowing down the degradation rate by 29.44%, 36.62%, and 74%, respectively. Furthermore, across all four cycles, the negligible decline in the degradation rate confirmed the Co<sub>3</sub>O<sub>4</sub>/Fe<sup>3+</sup> NPs’ reusability and performance.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101091"},"PeriodicalIF":0.0,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144771072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green conductive paper derived from sago pulp of Southeast Sulawesi based on magnetic nanocomposite of Fe3O4/carbon nanofibers for phenol adsorption 基于Fe3O4/纳米碳纤维磁性复合材料的苏拉威西东南部西米浆绿色导电纸对苯酚的吸附
Q1 Environmental Science Pub Date : 2025-07-25 DOI: 10.1016/j.enmm.2025.101090
Alimin Alimin , Sri Juari Santosa , Akrajas Ali Umar , Rahmayanti Rahmayanti , Alham Alham
A green conductive magnetic nanocomposite paper that has been synthesized by decorating carbon nanofibers (CNFs) with Fe3O4 nanoparticles (Fe3O4/CNFs) and mixed with sago pulp as phenol adsorbents has been investigated. The paper was synthesized using sago pulp waste from the sago farmer’s community. To produce cellulose paper, Sago pulp was treated mechanically and chemically through dehemicellulose and delignification techniques. Fe3O4 was synthesized by ultrasonication of iron sand in NaOH solution (8 M) for 120 min at 70 °C. The nanocomposite of Fe3O4/CNFs was prepared by ultrasonication Fe3O4 and CNFs in water. The nanocomposite paper was finally prepared by mixing sago’s cellulose and polyvinyl alcohol (PVA) with ultrasonication, followed by solvent casting drying. The phase crystallinity of the paper was evaluated via X-ray Diffraction (XRD) and Fourier Transform infrared (FTIR) spectroscopy. The phenol’s sensing and adsorption kinetic properties over the magnetic paper were examined using a UV–Vis spectrophotometer at a maximum wavelength of 269 nm. The result showed that the phenol was efficiently adsorbed on magnetic paper under an optimum pH of 7 at a contact time of 90 min. The adsorption followed Ho-McKay pseudo-second-order kinetics with adsorption capacity at an equilibrium of 3.15 mg/g. The magnetic and conductive paper of Fe3O4/CNFs should be extensively used in the adsorption of phenolic compounds in the environment.
研究了用Fe3O4纳米粒子(Fe3O4/CNFs)修饰碳纳米纤维(CNFs),以西米浆为吸附剂制备绿色导电磁性纳米复合纸。该纸是利用西米农民社区的西米纸浆废料合成的。为了生产纤维素纸,对西米纸浆进行了机械和化学处理,采用脱半纤维素和脱木质素技术。采用超声法将铁砂在8 M NaOH溶液中,在70℃条件下反应120 min合成Fe3O4。采用超声法在水中制备了Fe3O4/CNFs纳米复合材料。以西米纤维素和聚乙烯醇(PVA)为原料,经超声混合,再经溶剂铸造干燥制备纳米复合纸。通过x射线衍射(XRD)和傅里叶变换红外光谱(FTIR)对纸的相结晶度进行了评价。用紫外可见分光光度计在最大波长269 nm处考察了苯酚在磁性纸上的传感和吸附动力学性质。结果表明,在最佳pH = 7、接触时间为90 min的条件下,苯酚在磁性纸上的吸附符合Ho-McKay准二级吸附动力学,吸附量为3.15 mg/g。Fe3O4/CNFs磁性导电纸在吸附环境中酚类化合物方面具有广泛的应用前景。
{"title":"Green conductive paper derived from sago pulp of Southeast Sulawesi based on magnetic nanocomposite of Fe3O4/carbon nanofibers for phenol adsorption","authors":"Alimin Alimin ,&nbsp;Sri Juari Santosa ,&nbsp;Akrajas Ali Umar ,&nbsp;Rahmayanti Rahmayanti ,&nbsp;Alham Alham","doi":"10.1016/j.enmm.2025.101090","DOIUrl":"10.1016/j.enmm.2025.101090","url":null,"abstract":"<div><div>A green conductive magnetic nanocomposite paper that has been synthesized by decorating carbon nanofibers (CNFs) with Fe<sub>3</sub>O<sub>4</sub> nanoparticles (Fe<sub>3</sub>O<sub>4</sub>/CNFs) and mixed with sago pulp as phenol adsorbents has been investigated. The paper was synthesized using sago pulp waste from the sago farmer’s community. To produce cellulose paper, Sago pulp was treated mechanically and chemically through dehemicellulose and delignification techniques. Fe<sub>3</sub>O<sub>4</sub> was synthesized by ultrasonication of iron sand in NaOH solution (8 M) for 120 min at 70 °C. The nanocomposite of Fe<sub>3</sub>O<sub>4</sub>/CNFs was prepared by ultrasonication Fe<sub>3</sub>O<sub>4</sub> and CNFs in water. The nanocomposite paper was finally prepared by mixing sago’s cellulose and polyvinyl alcohol (PVA) with ultrasonication, followed by solvent casting drying. The phase crystallinity of the paper was evaluated via X-ray Diffraction (XRD) and Fourier Transform infrared (FTIR) spectroscopy. The phenol’s sensing and adsorption kinetic properties over the magnetic paper were examined using a UV–Vis spectrophotometer at a maximum wavelength of 269 nm. The result showed that the phenol was efficiently adsorbed on magnetic paper under an optimum pH of 7 at a contact time of 90 min. The adsorption followed Ho-McKay pseudo-second-order kinetics with adsorption capacity at an equilibrium of 3.15 mg/g. The magnetic and conductive paper of Fe<sub>3</sub>O<sub>4</sub>/CNFs should be extensively used in the adsorption of phenolic compounds in the environment.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101090"},"PeriodicalIF":0.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144723920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Environmentally-friendly activated carbon for the removal of antibiotic-resistant bacteria removal from hospital wastewater 环保型活性炭去除医院废水中的耐药菌
Q1 Environmental Science Pub Date : 2025-07-16 DOI: 10.1016/j.enmm.2025.101088
Ederaldo Luiz Beline , Alexandre Amado de Moura , Alexandre Diório , Anna Carla Ribeiro , Benício Alves de Abreu Filho , Daniel Tait Vareschini , Débora Federici dos Santos , Leidiane Silva Vasconcelos , Rosângela Bergamasco , Maria Angélica Simões Dornellas de Barros
The rise of antibiotic-resistant bacteria has driven research into natural antimicrobial alternatives. Allicin, a compound formed in freshly crushed garlic cloves, exhibits antibacterial properties but suffers from poor stability in aqueous environments. That is why this study aimed to explore the synthesis and characterization of allicin-modified activated carbon (AMAC) and evaluate its potential application removing Escherichia coli from synthetic hospital wastewater (HWW). Sugarcane bagasse (SB) provided by a local Brazilian alcohol mill was transformed into activated carbon (SBAC) through a hydrothermal process (heating at 200 °C for 24 h followed by activation at 450 °C for 10 min). Allicin extract was obtained from fresh garlic and impregnated onto the SBAC surface, resulting in AMAC with 105 µm mean diameter. The materials were characterized (FT-IR, Raman and N2-physisorption), revealing significant structural and surface modifications. The antibacterial activity of allicin against E. coli was assessed through minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC) trials and disk diffusion, demonstrating effective bacterial growth inhibition, as expected. Adsorption assays showed that AMAC enhanced E. coli removal efficiency in synthetic HWW by 3 %, compared to the AMAC in deionized and sterile water. This improvement was attributed to the positive interactions and synergistic effects between AMAC and the wastewater constituents. In other words, it means that AMAC can be used in the E. coli removal even in presence of organic and inorganic molecules without any loss of efficiency. The study also highlights the environmentally friendly synthesis process of AMAC and its potential as a sustainable solution for treating HWWs without the use of antibiotics, thus avoiding the potential release of pharmaceutical compounds into the environment. The results suggest that AMAC could be a viable alternative for enhancing the removal of antibiotic-resistant bacteria from contaminated water sources, contributing to public health and environmental protection.
耐抗生素细菌的增加推动了对天然抗菌替代品的研究。大蒜素是一种在新鲜碾碎的蒜瓣中形成的化合物,具有抗菌性能,但在水环境中稳定性差。因此,本研究旨在探索大蒜素修饰活性炭(AMAC)的合成和表征,并评估其在去除医院合成废水(HWW)中大肠杆菌的潜在应用。通过水热法(在200℃下加热24 h,然后在450℃下活化10 min)将巴西当地一家酒精厂提供的甘蔗渣(SB)转化为活性炭(SBAC)。从新鲜大蒜中提取大蒜素,并将其浸渍在SBAC表面,得到平均直径为105µm的AMAC。对材料进行了表征(FT-IR, Raman和n2 -物理吸附),揭示了明显的结构和表面修饰。通过最小抑菌浓度(MIC)试验、最小杀菌浓度(MBC)试验和圆盘扩散试验,对大蒜素对大肠杆菌的抑菌活性进行了评价,结果表明,大蒜素对大肠杆菌的生长具有抑制作用。吸附实验表明,与AMAC在去离子水和无菌水中相比,AMAC在合成水中对大肠杆菌的去除效率提高了3%。这种改善归因于AMAC与废水成分之间的积极相互作用和协同效应。换句话说,这意味着即使存在有机和无机分子,AMAC也可以用于去除大肠杆菌,而不会损失任何效率。该研究还强调了AMAC的环境友好型合成工艺及其作为不使用抗生素治疗hww的可持续解决方案的潜力,从而避免了药物化合物可能释放到环境中。结果表明,AMAC可能是一种可行的替代方法,可以加强对受污染水源中抗生素耐药细菌的去除,有助于公共卫生和环境保护。
{"title":"Environmentally-friendly activated carbon for the removal of antibiotic-resistant bacteria removal from hospital wastewater","authors":"Ederaldo Luiz Beline ,&nbsp;Alexandre Amado de Moura ,&nbsp;Alexandre Diório ,&nbsp;Anna Carla Ribeiro ,&nbsp;Benício Alves de Abreu Filho ,&nbsp;Daniel Tait Vareschini ,&nbsp;Débora Federici dos Santos ,&nbsp;Leidiane Silva Vasconcelos ,&nbsp;Rosângela Bergamasco ,&nbsp;Maria Angélica Simões Dornellas de Barros","doi":"10.1016/j.enmm.2025.101088","DOIUrl":"10.1016/j.enmm.2025.101088","url":null,"abstract":"<div><div>The rise of antibiotic-resistant bacteria has driven research into natural antimicrobial alternatives. Allicin, a compound formed in freshly crushed garlic cloves, exhibits antibacterial properties but suffers from poor stability in aqueous environments. That is why this study aimed to explore the synthesis and characterization of allicin-modified activated carbon (AMAC) and evaluate its potential application removing <em>Escherichia coli</em> from synthetic hospital wastewater (HWW). Sugarcane bagasse (SB) provided by a local Brazilian alcohol mill was transformed into activated carbon (SBAC) through a hydrothermal process (heating at 200 °C for 24 h followed by activation at 450 °C for 10 min). Allicin extract was obtained from fresh garlic and impregnated onto the SBAC surface, resulting in AMAC with 105 µm mean diameter. The materials were characterized (FT-IR, Raman and N<sub>2</sub>-physisorption), revealing significant structural and surface modifications. The antibacterial activity of allicin against <em>E. coli</em> was assessed through minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC) trials and disk diffusion, demonstrating effective bacterial growth inhibition, as expected. Adsorption assays showed that AMAC enhanced <em>E. coli</em> removal efficiency in synthetic HWW by 3 %, compared to the AMAC in deionized and sterile water. This improvement was attributed to the positive interactions and synergistic effects between AMAC and the wastewater constituents. In other words, it means that AMAC can be used in the <em>E. coli</em> removal even in presence of organic and inorganic molecules without any loss of efficiency. The study also highlights the environmentally friendly synthesis process of AMAC and its potential as a sustainable solution for treating HWWs without the use of antibiotics, thus avoiding the potential release of pharmaceutical compounds into the environment. The results suggest that AMAC could be a viable alternative for enhancing the removal of antibiotic-resistant bacteria from contaminated water sources, contributing to public health and environmental protection.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101088"},"PeriodicalIF":0.0,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144661988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Detoxification of wastewater with toxic cyanide substance using TiO2-based photocatalysts 二氧化钛基光催化剂对含有毒氰化物废水的解毒研究
Q1 Environmental Science Pub Date : 2025-07-11 DOI: 10.1016/j.enmm.2025.101087
Erkan Cakiroglu , Suleyman Demir , Erdal Celik
Industrial, agricultural, and domestic chemicals increasingly pollute the environment, affecting water, air, and soil even at low concentrations. This pollution, especially from waste, is a serious global problem. Using renewable energy like sunlight with photocatalysts offers an environmentally friendly way to remove pollutants. The focus of the innovation is the use of V, Er, and Ce-doped, multilayer mosaic-structured TiO2 thin films coated on glass substrates with their suitable band gap values to enhance the performance and sustainability of traditional TiO2 photocatalysts for the effective treatment of cyanide-containing wastewater under sunlight/UV light. In this study, it was aimed to produce V, Er, Ce pure/doped TiO2 thin coatings on glass substrates with sol–gel technique and photocatalytic degradation of cyanide in wastewater by using these substrates. The structural, microstructural and electrical properties of the produced films were investigated and thin films coated on glass substrates were used as photocatalysts in the photocatalytic degradation of cyanide in wastewater under UV/sun light source. As an innovative approach, laboratory and industrial scale TiO2, V-TiO2, Er-TiO2, and Ce-TiO2 coatings with the anatase phase on glass substrates exhibit a multilayered mosaic architecture. The coatings’ refractive index, film thickness, and energy bandgap were observed to vary within the ranges of 1.6028–1.6075 nD, 2.408–2.750 μm, and 3.08–3.73 eV, respectively. Notably, a 95 % efficiency was achieved in cyanide degradation from wastewater using these modified TiO2 films, indicating their significant potential for high-performance photocatalytic applications in environmental remediation. Photocatalytic samples demonstrated effective cyanide degradation over 10 industrial-scale cycles, with efficiency declining due to impurity buildup from real wastewater. Cleaning the surface restored activity, highlighting the material’s potential for recyclability. As a result, this innovation offers up to 95 % cyanide removal efficiency, reusability and sustainability through surface cleaning, and applicability at industrial scale.
工业、农业和家用化学品日益污染环境,即使浓度很低也会影响水、空气和土壤。这种污染,特别是来自废物的污染,是一个严重的全球性问题。使用可再生能源,如阳光和光催化剂,提供了一种环保的方式来去除污染物。创新的重点是使用V, Er和ce掺杂的多层马赛克结构TiO2薄膜涂覆在合适的带隙值的玻璃基板上,以提高传统TiO2光催化剂的性能和可持续性,从而在日光/紫外光下有效处理含氰废水。本研究旨在利用溶胶-凝胶技术在玻璃基板上制备V, Er, Ce纯/掺杂TiO2薄膜,并利用这些基板光催化降解废水中的氰化物。研究了所制备薄膜的结构、微观结构和电学性能,并将其涂覆在玻璃基板上作为光催化剂,在紫外/太阳光源下光催化降解废水中的氰化物。作为一种创新的方法,实验室和工业规模的TiO2, V-TiO2, Er-TiO2和Ce-TiO2涂层具有锐钛矿相在玻璃基板上呈现多层马赛克结构。涂层的折射率、膜厚和能带分别在1.6028 ~ 1.6075 nD、2.408 ~ 2.750 μm和3.08 ~ 3.73 eV范围内变化。值得注意的是,使用这些改性TiO2薄膜降解废水氰化物的效率达到95%,这表明它们在环境修复中的高性能光催化应用潜力巨大。光催化样品在10个工业规模循环中证明了有效的氰化物降解,由于实际废水中的杂质堆积,效率下降。清洁表面恢复了活性,突出了材料的可回收性潜力。因此,这一创新提供了高达95%的氰化物去除效率,通过表面清洁可重复使用和可持续性,并具有工业规模的适用性。
{"title":"Detoxification of wastewater with toxic cyanide substance using TiO2-based photocatalysts","authors":"Erkan Cakiroglu ,&nbsp;Suleyman Demir ,&nbsp;Erdal Celik","doi":"10.1016/j.enmm.2025.101087","DOIUrl":"10.1016/j.enmm.2025.101087","url":null,"abstract":"<div><div>Industrial, agricultural, and domestic chemicals increasingly pollute the environment, affecting water, air, and soil even at low concentrations. This pollution, especially from waste, is a serious global problem. Using renewable energy like sunlight with photocatalysts offers an environmentally friendly way to remove pollutants. The focus of the innovation is the use of V, Er, and Ce-doped, multilayer mosaic-structured TiO<sub>2</sub> thin films coated on glass substrates with their suitable band gap values to enhance the performance and sustainability of traditional TiO<sub>2</sub> photocatalysts for the effective treatment of cyanide-containing wastewater under sunlight/UV light. In this study, it was aimed to produce V, Er, Ce pure/doped TiO<sub>2</sub> thin coatings on glass substrates with sol–gel technique and photocatalytic degradation of cyanide in wastewater by using these substrates. The structural, microstructural and electrical properties of the produced films were investigated and thin films coated on glass substrates were used as photocatalysts in the photocatalytic degradation of cyanide in wastewater under UV/sun light source. As an innovative approach, laboratory and industrial scale TiO<sub>2</sub>, V-TiO<sub>2</sub>, Er-TiO<sub>2</sub>, and Ce-TiO<sub>2</sub> coatings with the anatase phase on glass substrates exhibit a multilayered mosaic architecture. The coatings’ refractive index, film thickness, and energy bandgap were observed to vary within the ranges of 1.6028–1.6075 nD, 2.408–2.750 μm, and 3.08–3.73 eV, respectively. Notably, a 95 % efficiency was achieved in cyanide degradation from wastewater using these modified TiO<sub>2</sub> films, indicating their significant potential for high-performance photocatalytic applications in environmental remediation. Photocatalytic samples demonstrated effective cyanide degradation over 10 industrial-scale cycles, with efficiency declining due to impurity buildup from real wastewater. Cleaning the surface restored activity, highlighting the material’s potential for recyclability. As a result, this innovation offers up to 95 % cyanide removal efficiency, reusability and sustainability through surface cleaning, and applicability at industrial scale.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101087"},"PeriodicalIF":0.0,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Z-scheme BiOCl/g-C3N4 nanocomposite for high performance photocatalytic degradation of organic pollutants and charge carrier dynamics 新型Z-scheme BiOCl/g-C3N4纳米复合材料的高效光催化降解有机污染物及载流子动力学研究
Q1 Environmental Science Pub Date : 2025-06-20 DOI: 10.1016/j.enmm.2025.101086
Orawan Rojviroon , Gomathi Abimannan , Priyadharsan Arumugam , Maadeswaran Palanisamy , Ranjith Rajendran , Govarthini Ramasamy , Sanya Sirivithayapakorn , Natacha Phetyim , Thammasak Rojviroon
In this research work, Z scheme BiOCl/g-C3N4 nanocomposite was synthesized through hydrothermal process and combined with thermal decomposition method. Numerous characterization techniques were utilized to examine the phase structure, functional groups, morphology, elemental composition, electronic structure and optical behaviour of as synthesized materials. The boosted light absorption capability of BiOCl/g-C3N4 nanocomposite which is accredited to the synergetic interaction between the BiOCl and g-C3N4 materials. The photocatalytic degradation efficacy of BiOCl/g-C3N4 nanocomposite over Rhodamine B (RhB) textile pollutant was exhibited 97 % within 100 min which is higher than the pristine BiOCl material. It’s caused by the active separation, allocation of electrons and holes and reduce the recombination. Five successive recycle process proved the stability and reusability of the material. Finally, This work demonstrates an enriched Z scheme BiOCl/g-C3N4 nanocomposite will deliver the impression of construct the Z scheme heterojunction photocatalyst to augment the photocatalytic activity in the occurrence of visible light.
本研究采用水热法结合热分解法合成了Z型BiOCl/g-C3N4纳米复合材料。许多表征技术被用于检测合成材料的相结构、官能团、形态、元素组成、电子结构和光学行为。BiOCl/g-C3N4纳米复合材料的光吸收能力增强是由于BiOCl和g-C3N4材料之间的协同作用。在100 min内,BiOCl/g-C3N4纳米复合材料对罗丹明B (Rhodamine B, RhB)纺织污染物的光催化降解效率达到97%,高于原始BiOCl材料。它是由电子和空穴的主动分离、分配和减少复合引起的。连续五次的回收过程证明了材料的稳定性和可重复使用性。最后,本研究证明了富含Z方案的BiOCl/g-C3N4纳米复合材料将提供构建Z方案异质结光催化剂的效果,以增强可见光发生时的光催化活性。
{"title":"Novel Z-scheme BiOCl/g-C3N4 nanocomposite for high performance photocatalytic degradation of organic pollutants and charge carrier dynamics","authors":"Orawan Rojviroon ,&nbsp;Gomathi Abimannan ,&nbsp;Priyadharsan Arumugam ,&nbsp;Maadeswaran Palanisamy ,&nbsp;Ranjith Rajendran ,&nbsp;Govarthini Ramasamy ,&nbsp;Sanya Sirivithayapakorn ,&nbsp;Natacha Phetyim ,&nbsp;Thammasak Rojviroon","doi":"10.1016/j.enmm.2025.101086","DOIUrl":"10.1016/j.enmm.2025.101086","url":null,"abstract":"<div><div>In this research work, Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite was synthesized through hydrothermal process and combined with thermal decomposition method. Numerous characterization techniques were utilized to examine the phase structure, functional groups, morphology, elemental composition, electronic structure and optical behaviour of as synthesized materials. The boosted light absorption capability of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite which is accredited to the synergetic interaction between the BiOCl and g-C<sub>3</sub>N<sub>4</sub> materials. The photocatalytic degradation efficacy of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite over Rhodamine B (RhB) textile pollutant was exhibited 97 % within 100 min which is higher than the pristine BiOCl material. It’s caused by the active separation, allocation of electrons and holes and reduce the recombination. Five successive recycle process proved the stability and reusability of the material. Finally, This work demonstrates an enriched Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite will deliver the impression of construct the Z scheme heterojunction photocatalyst to augment the photocatalytic activity in the occurrence of visible light.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101086"},"PeriodicalIF":0.0,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144366686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quantifying silver and gold nanoparticles in water via carbazole fluorescence quenching: A simple and economical approach 通过咔唑荧光猝灭定量水中的银和金纳米粒子:一种简单而经济的方法
Q1 Environmental Science Pub Date : 2025-06-14 DOI: 10.1016/j.enmm.2025.101084
Rodrigo Nicolás Núñez , Alicia Viviana Veglia , Natalia Lorena Pacioni
The fluorescence quenching of carbazole and carbazole@2-hydroxypropyl-β-cyclodextrin complex was evaluated in water as an analytical strategy for the quantification of six different silver and gold nanoparticles with either gallic acid, citrate, or p-(2-hydroxyethoxy) benzoic acid as ligands. The free carbazole is more sensitive to the analyzed metal nanoparticles with detection limits in the picomolar level (e.g., 0.106 pM for citrate-stabilized silver nanorods (AgNR) and 34.5 pM for citrate-stabilized silver nanospheres (AgNPc)) compared to the cyclodextrin-complexed carbazole (e.g., 0.200 pM for AgNR to insensitive for AgNPc). The recovery assays in spiked tap water and surface river water for all the analyzed nanoparticles were between 90 % and 112 % with 95 % confidence. The proposed method is an excellent alternative to more sophisticated methodologies for accurately quantifying silver and gold nanoparticles in aqueous systems.
以没食子酸、柠檬酸或对(2-羟基乙氧基)苯甲酸为配体,评价了咔唑和carbazole@2-hydroxypropyl-β-环糊精配合物在水中的荧光猝灭,作为对六种不同银和金纳米粒子的定量分析策略。游离卡唑对所分析的金属纳米颗粒更敏感,检测限在皮摩尔水平(例如,柠檬酸稳定的银纳米棒(AgNR)为0.106 pM,柠檬酸稳定的银纳米球(AgNPc)为34.5 pM),而环dextrin配合的卡唑(例如,AgNR为0.200 pM,对AgNPc不敏感)。在自来水和地表水中的回收率为90% ~ 112%,置信度为95%。所提出的方法是一个很好的替代更复杂的方法,准确定量在水系统中的银和金纳米颗粒。
{"title":"Quantifying silver and gold nanoparticles in water via carbazole fluorescence quenching: A simple and economical approach","authors":"Rodrigo Nicolás Núñez ,&nbsp;Alicia Viviana Veglia ,&nbsp;Natalia Lorena Pacioni","doi":"10.1016/j.enmm.2025.101084","DOIUrl":"10.1016/j.enmm.2025.101084","url":null,"abstract":"<div><div>The fluorescence quenching of carbazole and carbazole@2-hydroxypropyl-β-cyclodextrin complex was evaluated in water as an analytical strategy for the quantification of six different silver and gold nanoparticles with either gallic acid, citrate, or p-(2-hydroxyethoxy) benzoic acid as ligands. The free carbazole is more sensitive to the analyzed metal nanoparticles with detection limits in the picomolar level (e.g., 0.106 pM for citrate-stabilized silver nanorods (AgNR) and 34.5 pM for citrate-stabilized silver nanospheres (AgNP<sub>c</sub>)) compared to the cyclodextrin-complexed carbazole (e.g., 0.200 pM for AgNR to insensitive for AgNP<sub>c</sub>). The recovery assays in spiked tap water and surface river water for all the analyzed nanoparticles were between 90 % and 112 % with 95 % confidence. The proposed method is an excellent alternative to more sophisticated methodologies for accurately quantifying silver and gold nanoparticles in aqueous systems.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101084"},"PeriodicalIF":0.0,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis of Nigella sativa-mediated silver nanoparticles for enhanced antibacterial activity and wound healing: Mechanistic insights and biomedical applications 绿色合成黑草介导的银纳米颗粒增强抗菌活性和伤口愈合:机理见解和生物医学应用
Q1 Environmental Science Pub Date : 2025-06-12 DOI: 10.1016/j.enmm.2025.101085
Chella Perumal Palanisamy , Sirilux Poompradub , Kanokwan Sansanaphongpricha , Selvaraj Jayaraman , Karthik Subramani , Faridah Sonsudin
This study demonstrates an eco-friendly synthesis of silver nanoparticles (AgNPs) using chloroform extract of Nigella sativa seeds (CENSS) for combating bacterial infections and accelerating wound repair. The work highlights the dual therapeutic potential of CENSS-AgNPs through rigorous physicochemical, biological, and mechanistic analyses. The stable AgNPs was formed because of the transformation of silver ions by the CENSS. These NPs were thoroughly characterized using various physiochemical parameters. The biosynthesized CENSS-AgNPs demonstrated substantial antibacterial activity as indicated by the prominent inhibition areas observed on the agar plates. These are prominent bacteria which play significant roles in both human health and disease. Cytotoxicity assessment on human keratinocyte cells (HaCaT) revealed dose-dependent effects, with CENSS-AgNPs demonstrating feasible in wound healing by hastening scratch closure and enhancing cell migration. Furthermore, the protein expression analysis explored that CENSS-AgNPs stimulated the expression levels of platelet-derived growth factor (PDGF) and vascular endothelial growth factor (VEGF) which are crucial for wound repair. Over all, this study underscores the therapeutic promise of CENSS-mediated AgNPs in combating infections and promoting tissue regeneration, suggesting their prospective utility in advanced wound care and biomedical fields. Further exploration of their biological mechanisms and clinical applications is warranted to harness their full therapeutic potential.
这项研究展示了一种生态友好的合成银纳米粒子(AgNPs)的方法,该方法使用Nigella sativa种子(CENSS)的氯仿提取物来对抗细菌感染和加速伤口修复。通过严格的物理化学、生物学和机制分析,这项工作强调了CENSS-AgNPs的双重治疗潜力。稳定的AgNPs是由CENSS对银离子的转化而形成的。利用各种理化参数对这些NPs进行了全面表征。生物合成的CENSS-AgNPs显示出显著的抗菌活性,这表明在琼脂板上观察到明显的抑制区。这些都是在人类健康和疾病中发挥重要作用的重要细菌。对人角质形成细胞(HaCaT)的细胞毒性评估显示出剂量依赖效应,CENSS-AgNPs通过加速划痕闭合和增强细胞迁移,在伤口愈合中证明是可行的。此外,蛋白质表达分析发现,CENSS-AgNPs刺激了血小板衍生生长因子(PDGF)和血管内皮生长因子(VEGF)的表达水平,这对伤口修复至关重要。总之,这项研究强调了cnss介导的AgNPs在对抗感染和促进组织再生方面的治疗前景,表明它们在高级伤口护理和生物医学领域的潜在应用。进一步探索其生物学机制和临床应用是必要的,以充分利用其治疗潜力。
{"title":"Green synthesis of Nigella sativa-mediated silver nanoparticles for enhanced antibacterial activity and wound healing: Mechanistic insights and biomedical applications","authors":"Chella Perumal Palanisamy ,&nbsp;Sirilux Poompradub ,&nbsp;Kanokwan Sansanaphongpricha ,&nbsp;Selvaraj Jayaraman ,&nbsp;Karthik Subramani ,&nbsp;Faridah Sonsudin","doi":"10.1016/j.enmm.2025.101085","DOIUrl":"10.1016/j.enmm.2025.101085","url":null,"abstract":"<div><div>This study demonstrates an eco-friendly synthesis of silver nanoparticles (AgNPs) using chloroform extract of <em>Nigella sativa</em> seeds (CENSS) for combating bacterial infections and accelerating wound repair. The work highlights the dual therapeutic potential of CENSS-AgNPs through rigorous physicochemical, biological, and mechanistic analyses. The stable AgNPs was formed because of the transformation of silver ions by the CENSS. These NPs were thoroughly characterized using various physiochemical parameters. The biosynthesized CENSS-AgNPs demonstrated substantial antibacterial activity as indicated by the prominent inhibition areas observed on the agar plates. These are prominent bacteria which play significant roles in both human health and disease. Cytotoxicity assessment on human keratinocyte cells (HaCaT) revealed dose-dependent effects, with CENSS-AgNPs demonstrating feasible in wound healing by hastening scratch closure and enhancing cell migration. Furthermore, the protein expression analysis explored that CENSS-AgNPs stimulated the expression levels of platelet-derived growth factor (PDGF) and vascular endothelial growth factor (VEGF) which are crucial for wound repair. Over all, this study underscores the therapeutic promise of CENSS-mediated AgNPs in combating infections and promoting tissue regeneration, suggesting their prospective utility in advanced wound care and biomedical fields. Further exploration of their biological mechanisms and clinical applications is warranted to harness their full therapeutic potential.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101085"},"PeriodicalIF":0.0,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Environmental Nanotechnology, Monitoring and Management
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1