Pub Date : 2025-08-15DOI: 10.1016/j.enmm.2025.101094
Nurul Mutmainnah Ramlan , Isnaeni Isnaeni , Adnan Fatahillah Afiff , Maria M. Suliyanti , Dahlang Tahir
This study presents the development of a flexible Surface Enhanced Raman Spectroscopy (SERS) substrate by combining Silver Nanoparticles (Ag NPs) and Graphene Quantum Dots (GQD) on fiberglass (FG) substrates. GQD is synthesized using an electrolysis method, and Ag NPs are deposited onto the substrate via microwave-assisted hydrothermal synthesis. The resulting substrates, GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG, were used to detect Raman signals from three different dyes: Malachite Green (MG), Methylene Blue (MB), and Eriochrome Black T (EBT). The SERS results indicate that the GQD0.78 % + Ag NPs @FG substrate exhibits higher sensitivity than GQD25% + Ag NPs @FG. The SERS signal is enhanced by 1.98–2.26 times and 2.54–3.53 times on the GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG substrates, respectively, due to the presence of GQD, indicating the significant role of GQD concentration in enhancing the Raman signal. This research highlights the potential of flexible SERS substrates for cost-effective, high-sensitivity detection, particularly in environmental and industrial applications.
本研究提出了在玻璃纤维(FG)衬底上结合银纳米粒子(Ag NPs)和石墨烯量子点(GQD)的柔性表面增强拉曼光谱(SERS)衬底的开发。采用电解法合成了GQD,并通过微波辅助水热合成将银纳米粒子沉积在衬底上。所得底物GQD25% + Ag NPs @FG和gqd0.78% + Ag NPs @FG分别用于检测孔雀石绿(MG)、亚甲基蓝(MB)和Eriochrome Black T (EBT)三种不同染料的拉曼信号。SERS结果表明,gqd0.78% + Ag NPs @FG底物的灵敏度高于GQD25% + Ag NPs @FG底物。GQD的存在使GQD25% + Ag NPs @FG和gqd0.78% + Ag NPs @FG底物的SERS信号分别增强1.98 ~ 2.26倍和2.54 ~ 3.53倍,表明GQD浓度对拉曼信号的增强作用显著。这项研究强调了柔性SERS基板具有成本效益,高灵敏度检测的潜力,特别是在环境和工业应用中。
{"title":"Development of flexible SERS substrates based on silver nanoparticles and graphene quantum dots on fiberglass for enhanced dye detection","authors":"Nurul Mutmainnah Ramlan , Isnaeni Isnaeni , Adnan Fatahillah Afiff , Maria M. Suliyanti , Dahlang Tahir","doi":"10.1016/j.enmm.2025.101094","DOIUrl":"10.1016/j.enmm.2025.101094","url":null,"abstract":"<div><div>This study presents the development of a flexible Surface Enhanced Raman Spectroscopy (SERS) substrate by combining Silver Nanoparticles (Ag NPs) and Graphene Quantum Dots (GQD) on fiberglass (FG) substrates. GQD is synthesized using an electrolysis method, and Ag NPs are deposited onto the substrate via microwave-assisted hydrothermal synthesis. The resulting substrates, GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG, were used to detect Raman signals from three different dyes: Malachite Green (MG), Methylene Blue (MB), and Eriochrome Black T (EBT). The SERS results indicate that the GQD0.78 % + Ag NPs @FG substrate exhibits higher sensitivity than GQD25% + Ag NPs @FG. The SERS signal is enhanced by 1.98–2.26 times and 2.54–3.53 times on the GQD25% + Ag NPs @FG and GQD0.78 % + Ag NPs @FG substrates, respectively, due to the presence of GQD, indicating the significant role of GQD concentration in enhancing the Raman signal. This research highlights the potential of flexible SERS substrates for cost-effective, high-sensitivity detection, particularly in environmental and industrial applications.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101094"},"PeriodicalIF":0.0,"publicationDate":"2025-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144878922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-08-05DOI: 10.1016/j.enmm.2025.101092
Eman Ayman Nada , Mallak Eyad Abu Kaddorah , Mazen El Jamal , Amal Hamad , Fotouh R. Mansour
There has been substantial interest in using eggshell waste for the creation of environmentally-friendly products. This review discusses on the synthesis and examination of nanoparticles obtained from eggshells, with a particular focus on their suitability for usage in environmental and catalytic settings. Calcination and mechanical grinding are acknowledged as effective techniques for generating eggshell nanoparticles. Calcination is a high-temperature process that converts calcium carbonate (CaCO3) into calcium oxide (CaO). On the other hand, mechanical grinding is a method used to decrease the size of particles to the nanoscale. The text examines different methods employed for characterization, such as thermogravimetric analysis (TGA) for evaluating thermal stability, zeta potential for assessing surface charge and stability, X-ray diffraction (XRD) for identifying crystal structure, Fourier transform infrared (FTIR) spectroscopy for detecting functional groups, energy-dispersive X-ray (EDX) spectroscopy for determining elemental composition, dynamic light scattering (DLS) for analyzing particle size distribution, and atomic force microscopy (AFM) for visualizing surface morphology. The produced nano-hydroxyapatite shows promise as an adsorbent for effectively eliminating arsenic and heavy metals from water systems, hence contributing to sustainable waste management and advancements in materials. This work offers a thorough comprehension of the procedure involved in producing and examining eggshell nanoparticles. Acquiring this information is crucial for effectively utilizing them in environmental remediation and catalytic processes.
{"title":"Eggshell waste as a sustainable resource for nanoparticle preparation; synthesis, characterization and applications","authors":"Eman Ayman Nada , Mallak Eyad Abu Kaddorah , Mazen El Jamal , Amal Hamad , Fotouh R. Mansour","doi":"10.1016/j.enmm.2025.101092","DOIUrl":"10.1016/j.enmm.2025.101092","url":null,"abstract":"<div><div>There has been substantial interest in using eggshell waste for the creation of environmentally-friendly products. This review discusses on the synthesis and examination of nanoparticles obtained from eggshells, with a particular focus on their suitability for usage in environmental and catalytic settings. Calcination and mechanical grinding are acknowledged as effective techniques for generating eggshell nanoparticles. Calcination is a high-temperature process that converts calcium carbonate (CaCO<sub>3</sub>) into calcium oxide (CaO). On the other hand, mechanical grinding is a method used to decrease the size of particles to the nanoscale. The text examines different methods employed for characterization, such as thermogravimetric analysis (TGA) for evaluating thermal stability, zeta potential for assessing surface charge and stability, X-ray diffraction (XRD) for identifying crystal structure, Fourier transform infrared (FTIR) spectroscopy for detecting functional groups, energy-dispersive X-ray (EDX) spectroscopy for determining elemental composition, dynamic light scattering (DLS) for analyzing particle size distribution, and atomic force microscopy (AFM) for visualizing surface morphology. The produced nano-hydroxyapatite shows promise as an adsorbent for effectively eliminating arsenic and heavy metals from water systems, hence contributing to sustainable waste management and advancements in materials. This work offers a thorough comprehension of the procedure involved in producing and examining eggshell nanoparticles. Acquiring this information is crucial for effectively utilizing them in environmental remediation and catalytic processes.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101092"},"PeriodicalIF":0.0,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144771071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mercury (Hg) is a globally accepted highly toxic heavy metal pollutant and despite several important developments in the field, the determination of Hg2+ ions attrace levels in real-world samples is a challenge. Herein, the silver nanoparticles modified with three-dimensional graphene (AgNPs/3D-graphene) nanocomposite has been synthesised through a simple, cost-efficient, one-step freeze-casting routethat has been applied for highlysensitive determination of Hg2+. The 3D cellular network structure with continuous micrometersize open pores and uniformly decorated Ag nanoparticles with an average size of 30 nm has been suggested by the morphologies and structures of the as-prepared AgNPs/3D-Graphene nanocomposite. The AgNPs/3D-graphene nanocomposite-modifiedGCE (AgNPs/3D-graphene/GCE) exhibited a good linear relationship with Hg2+ concentrations ranging from 0.1 to 40 μg L−1. The results showed that the limit of detection (LOD) of 0.08 μg L−1 (S/N = 3), which is significantly less than the World Health Organization’s (WHO) recommended threshold. The method validation has been carried out using certified reference material (CRM). The sensitivity and stability from the composite has been achieved from the well scaffolded AgNPs all along the 3D-graphene network, which has made the method novel and stand out from othere reported. The suggested electrochemical sensor performed well in detecting Hg2+ in soil and borewell water samples as well as in clinical samples, which is crucial in safeguarding human health.
汞(Hg)是全球公认的高毒性重金属污染物,尽管在该领域取得了一些重要进展,但实际样品中Hg2+离子吸引水平的测定仍然是一个挑战。本文通过一种简单、经济、一步的冷冻铸造方法合成了三维石墨烯修饰的银纳米颗粒(AgNPs/ 3d -石墨烯),该方法已被用于高灵敏度的Hg2+测定。制备的AgNPs/3D-石墨烯纳米复合材料的形貌和结构表明其具有连续微米大小的开放孔和均匀装饰的平均尺寸为30 nm的银纳米颗粒的三维细胞网络结构。AgNPs/ 3d -石墨烯纳米复合材料修饰的GCE (AgNPs/ 3d -石墨烯/GCE)与Hg2+浓度在0.1 ~ 40 μg L−1范围内呈良好的线性关系。结果表明,该方法的检出限(LOD)为0.08 μ L−1 (S/N = 3),显著低于世界卫生组织(WHO)推荐阈值。采用标准物质(CRM)对方法进行了验证。这种复合材料的灵敏度和稳定性是通过3d -石墨烯网络上支架良好的AgNPs实现的,这使得该方法新颖,从其他报道中脱颖而出。该电化学传感器能很好地检测土壤和井水样品以及临床样品中的Hg2+,对保障人体健康具有重要意义。
{"title":"Rationale of AgNPsmodified 3-dimensional grapheneas electrochemical sensor for the ultra-tracedetermination of mercury ions","authors":"Prasanta Kumar Sahoo , Srikant Sahoo , Rajendra Prasad Pandey , Ashis Kumar Satpati","doi":"10.1016/j.enmm.2025.101089","DOIUrl":"10.1016/j.enmm.2025.101089","url":null,"abstract":"<div><div>Mercury (Hg) is a globally accepted highly toxic heavy metal pollutant and despite several important developments in the field, the determination of Hg<sup>2+</sup> ions attrace levels in real-world samples is a challenge. Herein, the silver nanoparticles modified with three-dimensional graphene (AgNPs/3D-graphene) nanocomposite has been synthesised through a simple, cost-efficient, one-step freeze-casting routethat has been applied for highlysensitive determination of Hg<sup>2+</sup>. The 3D cellular network structure with continuous micrometersize open pores and uniformly decorated Ag nanoparticles with an average size of 30 nm has been suggested by the morphologies and structures of the as-prepared AgNPs/3D-Graphene nanocomposite. The AgNPs/3D-graphene nanocomposite-modifiedGCE (AgNPs/3D-graphene/GCE) exhibited a good linear relationship with Hg<sup>2+</sup> concentrations ranging from 0.1 to 40 μg L<sup>−1</sup>. The results showed that the limit of detection (LOD) of 0.08 μg L<sup>−1</sup> (S/N = 3), which is significantly less than the World Health Organization’s (WHO) recommended threshold. The method validation has been carried out using certified reference material (CRM). The sensitivity and stability from the composite has been achieved from the well scaffolded AgNPs all along the 3D-graphene network, which has made the method novel and stand out from othere reported. The suggested electrochemical sensor performed well in detecting Hg<sup>2+</sup> in soil and borewell water samples as well as in clinical samples, which is crucial in safeguarding human health.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101089"},"PeriodicalIF":0.0,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144781269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-30DOI: 10.1016/j.enmm.2025.101091
Masih Darbandi, Hadis Asadi, At-har Najafi
The world’s waters threatened by the dual forces of demographic growth and industrial expansion. Advanced oxidation techniques, particularly photocatalytic processes, offer a practical and eco-friendly solution to this problem by decomposing organic contaminants, providing a cleaner and safer aquatic environment. Doping of iron(III) ions through the ball milling method was applied to study the activity of nanoparticles (NPs) in the visible spectrum. Advanced techniques were employed to characterize synthesized NPs, utilizing Transmission Electron Microscopy (TEM), X-ray Diffraction (XRD), and Brunauer-Emmett-Teller (BET). The synthesized NPs exhibit a consistent mesoporous structure, as demonstrated by the experimental findings. Research findings indicate that the application of sonocatalytic, photocatalytic, and sonophotocatalytic techniques significantly reduced amoxicillin (AMX), a pharmaceutical pollutant, levels by 46.26%, 60.34%, and 83.14%, respectively, within the one-hour timeframe when utilizing Co3O4/Fe3+ NPs. The 40.37% synergistic effect demonstrated the doped NPs’ efficiency. Additionally, the experimental data strongly aligns with the pseudo-second-order equation, confirming the reaction’s adherence to second-order kinetics. Scavengers like formic acid, disodium oxalate, and isopropanol demonstrated a reduction impact, slowing down the degradation rate by 29.44%, 36.62%, and 74%, respectively. Furthermore, across all four cycles, the negligible decline in the degradation rate confirmed the Co3O4/Fe3+ NPs’ reusability and performance.
{"title":"Evaluating the sonophotocatalytic activity of Fe(III) doped cobalt oxide nanoparticles prepared by planetary ball milling method in the degradation of amoxicillin as a pollutant","authors":"Masih Darbandi, Hadis Asadi, At-har Najafi","doi":"10.1016/j.enmm.2025.101091","DOIUrl":"10.1016/j.enmm.2025.101091","url":null,"abstract":"<div><div>The world’s waters threatened by the dual forces of demographic growth and industrial expansion. Advanced oxidation techniques, particularly photocatalytic processes, offer a practical and eco-friendly solution to this problem by decomposing organic contaminants, providing a cleaner and safer aquatic environment. Doping of iron(III) ions through the ball milling method was applied to study the activity of nanoparticles (NPs) in the visible spectrum. Advanced techniques were employed to characterize synthesized NPs, utilizing Transmission Electron Microscopy (TEM), X-ray Diffraction (XRD), and Brunauer-Emmett-Teller (BET). The synthesized NPs exhibit a consistent mesoporous structure, as demonstrated by the experimental findings. Research findings indicate that the application of sonocatalytic, photocatalytic, and sonophotocatalytic techniques significantly reduced amoxicillin (AMX), a pharmaceutical pollutant, levels by 46.26%, 60.34%, and 83.14%, respectively, within the one-hour timeframe when utilizing Co<sub>3</sub>O<sub>4</sub>/Fe<sup>3+</sup> NPs. The 40.37% synergistic effect demonstrated the doped NPs’ efficiency. Additionally, the experimental data strongly aligns with the pseudo-second-order equation, confirming the reaction’s adherence to second-order kinetics. Scavengers like formic acid, disodium oxalate, and isopropanol demonstrated a reduction impact, slowing down the degradation rate by 29.44%, 36.62%, and 74%, respectively. Furthermore, across all four cycles, the negligible decline in the degradation rate confirmed the Co<sub>3</sub>O<sub>4</sub>/Fe<sup>3+</sup> NPs’ reusability and performance.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101091"},"PeriodicalIF":0.0,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144771072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-25DOI: 10.1016/j.enmm.2025.101090
Alimin Alimin , Sri Juari Santosa , Akrajas Ali Umar , Rahmayanti Rahmayanti , Alham Alham
A green conductive magnetic nanocomposite paper that has been synthesized by decorating carbon nanofibers (CNFs) with Fe3O4 nanoparticles (Fe3O4/CNFs) and mixed with sago pulp as phenol adsorbents has been investigated. The paper was synthesized using sago pulp waste from the sago farmer’s community. To produce cellulose paper, Sago pulp was treated mechanically and chemically through dehemicellulose and delignification techniques. Fe3O4 was synthesized by ultrasonication of iron sand in NaOH solution (8 M) for 120 min at 70 °C. The nanocomposite of Fe3O4/CNFs was prepared by ultrasonication Fe3O4 and CNFs in water. The nanocomposite paper was finally prepared by mixing sago’s cellulose and polyvinyl alcohol (PVA) with ultrasonication, followed by solvent casting drying. The phase crystallinity of the paper was evaluated via X-ray Diffraction (XRD) and Fourier Transform infrared (FTIR) spectroscopy. The phenol’s sensing and adsorption kinetic properties over the magnetic paper were examined using a UV–Vis spectrophotometer at a maximum wavelength of 269 nm. The result showed that the phenol was efficiently adsorbed on magnetic paper under an optimum pH of 7 at a contact time of 90 min. The adsorption followed Ho-McKay pseudo-second-order kinetics with adsorption capacity at an equilibrium of 3.15 mg/g. The magnetic and conductive paper of Fe3O4/CNFs should be extensively used in the adsorption of phenolic compounds in the environment.
研究了用Fe3O4纳米粒子(Fe3O4/CNFs)修饰碳纳米纤维(CNFs),以西米浆为吸附剂制备绿色导电磁性纳米复合纸。该纸是利用西米农民社区的西米纸浆废料合成的。为了生产纤维素纸,对西米纸浆进行了机械和化学处理,采用脱半纤维素和脱木质素技术。采用超声法将铁砂在8 M NaOH溶液中,在70℃条件下反应120 min合成Fe3O4。采用超声法在水中制备了Fe3O4/CNFs纳米复合材料。以西米纤维素和聚乙烯醇(PVA)为原料,经超声混合,再经溶剂铸造干燥制备纳米复合纸。通过x射线衍射(XRD)和傅里叶变换红外光谱(FTIR)对纸的相结晶度进行了评价。用紫外可见分光光度计在最大波长269 nm处考察了苯酚在磁性纸上的传感和吸附动力学性质。结果表明,在最佳pH = 7、接触时间为90 min的条件下,苯酚在磁性纸上的吸附符合Ho-McKay准二级吸附动力学,吸附量为3.15 mg/g。Fe3O4/CNFs磁性导电纸在吸附环境中酚类化合物方面具有广泛的应用前景。
{"title":"Green conductive paper derived from sago pulp of Southeast Sulawesi based on magnetic nanocomposite of Fe3O4/carbon nanofibers for phenol adsorption","authors":"Alimin Alimin , Sri Juari Santosa , Akrajas Ali Umar , Rahmayanti Rahmayanti , Alham Alham","doi":"10.1016/j.enmm.2025.101090","DOIUrl":"10.1016/j.enmm.2025.101090","url":null,"abstract":"<div><div>A green conductive magnetic nanocomposite paper that has been synthesized by decorating carbon nanofibers (CNFs) with Fe<sub>3</sub>O<sub>4</sub> nanoparticles (Fe<sub>3</sub>O<sub>4</sub>/CNFs) and mixed with sago pulp as phenol adsorbents has been investigated. The paper was synthesized using sago pulp waste from the sago farmer’s community. To produce cellulose paper, Sago pulp was treated mechanically and chemically through dehemicellulose and delignification techniques. Fe<sub>3</sub>O<sub>4</sub> was synthesized by ultrasonication of iron sand in NaOH solution (8 M) for 120 min at 70 °C. The nanocomposite of Fe<sub>3</sub>O<sub>4</sub>/CNFs was prepared by ultrasonication Fe<sub>3</sub>O<sub>4</sub> and CNFs in water. The nanocomposite paper was finally prepared by mixing sago’s cellulose and polyvinyl alcohol (PVA) with ultrasonication, followed by solvent casting drying. The phase crystallinity of the paper was evaluated via X-ray Diffraction (XRD) and Fourier Transform infrared (FTIR) spectroscopy. The phenol’s sensing and adsorption kinetic properties over the magnetic paper were examined using a UV–Vis spectrophotometer at a maximum wavelength of 269 nm. The result showed that the phenol was efficiently adsorbed on magnetic paper under an optimum pH of 7 at a contact time of 90 min. The adsorption followed Ho-McKay pseudo-second-order kinetics with adsorption capacity at an equilibrium of 3.15 mg/g. The magnetic and conductive paper of Fe<sub>3</sub>O<sub>4</sub>/CNFs should be extensively used in the adsorption of phenolic compounds in the environment.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101090"},"PeriodicalIF":0.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144723920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-16DOI: 10.1016/j.enmm.2025.101088
Ederaldo Luiz Beline , Alexandre Amado de Moura , Alexandre Diório , Anna Carla Ribeiro , Benício Alves de Abreu Filho , Daniel Tait Vareschini , Débora Federici dos Santos , Leidiane Silva Vasconcelos , Rosângela Bergamasco , Maria Angélica Simões Dornellas de Barros
The rise of antibiotic-resistant bacteria has driven research into natural antimicrobial alternatives. Allicin, a compound formed in freshly crushed garlic cloves, exhibits antibacterial properties but suffers from poor stability in aqueous environments. That is why this study aimed to explore the synthesis and characterization of allicin-modified activated carbon (AMAC) and evaluate its potential application removing Escherichia coli from synthetic hospital wastewater (HWW). Sugarcane bagasse (SB) provided by a local Brazilian alcohol mill was transformed into activated carbon (SBAC) through a hydrothermal process (heating at 200 °C for 24 h followed by activation at 450 °C for 10 min). Allicin extract was obtained from fresh garlic and impregnated onto the SBAC surface, resulting in AMAC with 105 µm mean diameter. The materials were characterized (FT-IR, Raman and N2-physisorption), revealing significant structural and surface modifications. The antibacterial activity of allicin against E. coli was assessed through minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC) trials and disk diffusion, demonstrating effective bacterial growth inhibition, as expected. Adsorption assays showed that AMAC enhanced E. coli removal efficiency in synthetic HWW by 3 %, compared to the AMAC in deionized and sterile water. This improvement was attributed to the positive interactions and synergistic effects between AMAC and the wastewater constituents. In other words, it means that AMAC can be used in the E. coli removal even in presence of organic and inorganic molecules without any loss of efficiency. The study also highlights the environmentally friendly synthesis process of AMAC and its potential as a sustainable solution for treating HWWs without the use of antibiotics, thus avoiding the potential release of pharmaceutical compounds into the environment. The results suggest that AMAC could be a viable alternative for enhancing the removal of antibiotic-resistant bacteria from contaminated water sources, contributing to public health and environmental protection.
{"title":"Environmentally-friendly activated carbon for the removal of antibiotic-resistant bacteria removal from hospital wastewater","authors":"Ederaldo Luiz Beline , Alexandre Amado de Moura , Alexandre Diório , Anna Carla Ribeiro , Benício Alves de Abreu Filho , Daniel Tait Vareschini , Débora Federici dos Santos , Leidiane Silva Vasconcelos , Rosângela Bergamasco , Maria Angélica Simões Dornellas de Barros","doi":"10.1016/j.enmm.2025.101088","DOIUrl":"10.1016/j.enmm.2025.101088","url":null,"abstract":"<div><div>The rise of antibiotic-resistant bacteria has driven research into natural antimicrobial alternatives. Allicin, a compound formed in freshly crushed garlic cloves, exhibits antibacterial properties but suffers from poor stability in aqueous environments. That is why this study aimed to explore the synthesis and characterization of allicin-modified activated carbon (AMAC) and evaluate its potential application removing <em>Escherichia coli</em> from synthetic hospital wastewater (HWW). Sugarcane bagasse (SB) provided by a local Brazilian alcohol mill was transformed into activated carbon (SBAC) through a hydrothermal process (heating at 200 °C for 24 h followed by activation at 450 °C for 10 min). Allicin extract was obtained from fresh garlic and impregnated onto the SBAC surface, resulting in AMAC with 105 µm mean diameter. The materials were characterized (FT-IR, Raman and N<sub>2</sub>-physisorption), revealing significant structural and surface modifications. The antibacterial activity of allicin against <em>E. coli</em> was assessed through minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC) trials and disk diffusion, demonstrating effective bacterial growth inhibition, as expected. Adsorption assays showed that AMAC enhanced <em>E. coli</em> removal efficiency in synthetic HWW by 3 %, compared to the AMAC in deionized and sterile water. This improvement was attributed to the positive interactions and synergistic effects between AMAC and the wastewater constituents. In other words, it means that AMAC can be used in the <em>E. coli</em> removal even in presence of organic and inorganic molecules without any loss of efficiency. The study also highlights the environmentally friendly synthesis process of AMAC and its potential as a sustainable solution for treating HWWs without the use of antibiotics, thus avoiding the potential release of pharmaceutical compounds into the environment. The results suggest that AMAC could be a viable alternative for enhancing the removal of antibiotic-resistant bacteria from contaminated water sources, contributing to public health and environmental protection.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101088"},"PeriodicalIF":0.0,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144661988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-07-11DOI: 10.1016/j.enmm.2025.101087
Erkan Cakiroglu , Suleyman Demir , Erdal Celik
Industrial, agricultural, and domestic chemicals increasingly pollute the environment, affecting water, air, and soil even at low concentrations. This pollution, especially from waste, is a serious global problem. Using renewable energy like sunlight with photocatalysts offers an environmentally friendly way to remove pollutants. The focus of the innovation is the use of V, Er, and Ce-doped, multilayer mosaic-structured TiO2 thin films coated on glass substrates with their suitable band gap values to enhance the performance and sustainability of traditional TiO2 photocatalysts for the effective treatment of cyanide-containing wastewater under sunlight/UV light. In this study, it was aimed to produce V, Er, Ce pure/doped TiO2 thin coatings on glass substrates with sol–gel technique and photocatalytic degradation of cyanide in wastewater by using these substrates. The structural, microstructural and electrical properties of the produced films were investigated and thin films coated on glass substrates were used as photocatalysts in the photocatalytic degradation of cyanide in wastewater under UV/sun light source. As an innovative approach, laboratory and industrial scale TiO2, V-TiO2, Er-TiO2, and Ce-TiO2 coatings with the anatase phase on glass substrates exhibit a multilayered mosaic architecture. The coatings’ refractive index, film thickness, and energy bandgap were observed to vary within the ranges of 1.6028–1.6075 nD, 2.408–2.750 μm, and 3.08–3.73 eV, respectively. Notably, a 95 % efficiency was achieved in cyanide degradation from wastewater using these modified TiO2 films, indicating their significant potential for high-performance photocatalytic applications in environmental remediation. Photocatalytic samples demonstrated effective cyanide degradation over 10 industrial-scale cycles, with efficiency declining due to impurity buildup from real wastewater. Cleaning the surface restored activity, highlighting the material’s potential for recyclability. As a result, this innovation offers up to 95 % cyanide removal efficiency, reusability and sustainability through surface cleaning, and applicability at industrial scale.
{"title":"Detoxification of wastewater with toxic cyanide substance using TiO2-based photocatalysts","authors":"Erkan Cakiroglu , Suleyman Demir , Erdal Celik","doi":"10.1016/j.enmm.2025.101087","DOIUrl":"10.1016/j.enmm.2025.101087","url":null,"abstract":"<div><div>Industrial, agricultural, and domestic chemicals increasingly pollute the environment, affecting water, air, and soil even at low concentrations. This pollution, especially from waste, is a serious global problem. Using renewable energy like sunlight with photocatalysts offers an environmentally friendly way to remove pollutants. The focus of the innovation is the use of V, Er, and Ce-doped, multilayer mosaic-structured TiO<sub>2</sub> thin films coated on glass substrates with their suitable band gap values to enhance the performance and sustainability of traditional TiO<sub>2</sub> photocatalysts for the effective treatment of cyanide-containing wastewater under sunlight/UV light. In this study, it was aimed to produce V, Er, Ce pure/doped TiO<sub>2</sub> thin coatings on glass substrates with sol–gel technique and photocatalytic degradation of cyanide in wastewater by using these substrates. The structural, microstructural and electrical properties of the produced films were investigated and thin films coated on glass substrates were used as photocatalysts in the photocatalytic degradation of cyanide in wastewater under UV/sun light source. As an innovative approach, laboratory and industrial scale TiO<sub>2</sub>, V-TiO<sub>2</sub>, Er-TiO<sub>2</sub>, and Ce-TiO<sub>2</sub> coatings with the anatase phase on glass substrates exhibit a multilayered mosaic architecture. The coatings’ refractive index, film thickness, and energy bandgap were observed to vary within the ranges of 1.6028–1.6075 nD, 2.408–2.750 μm, and 3.08–3.73 eV, respectively. Notably, a 95 % efficiency was achieved in cyanide degradation from wastewater using these modified TiO<sub>2</sub> films, indicating their significant potential for high-performance photocatalytic applications in environmental remediation. Photocatalytic samples demonstrated effective cyanide degradation over 10 industrial-scale cycles, with efficiency declining due to impurity buildup from real wastewater. Cleaning the surface restored activity, highlighting the material’s potential for recyclability. As a result, this innovation offers up to 95 % cyanide removal efficiency, reusability and sustainability through surface cleaning, and applicability at industrial scale.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101087"},"PeriodicalIF":0.0,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this research work, Z scheme BiOCl/g-C3N4 nanocomposite was synthesized through hydrothermal process and combined with thermal decomposition method. Numerous characterization techniques were utilized to examine the phase structure, functional groups, morphology, elemental composition, electronic structure and optical behaviour of as synthesized materials. The boosted light absorption capability of BiOCl/g-C3N4 nanocomposite which is accredited to the synergetic interaction between the BiOCl and g-C3N4 materials. The photocatalytic degradation efficacy of BiOCl/g-C3N4 nanocomposite over Rhodamine B (RhB) textile pollutant was exhibited 97 % within 100 min which is higher than the pristine BiOCl material. It’s caused by the active separation, allocation of electrons and holes and reduce the recombination. Five successive recycle process proved the stability and reusability of the material. Finally, This work demonstrates an enriched Z scheme BiOCl/g-C3N4 nanocomposite will deliver the impression of construct the Z scheme heterojunction photocatalyst to augment the photocatalytic activity in the occurrence of visible light.
{"title":"Novel Z-scheme BiOCl/g-C3N4 nanocomposite for high performance photocatalytic degradation of organic pollutants and charge carrier dynamics","authors":"Orawan Rojviroon , Gomathi Abimannan , Priyadharsan Arumugam , Maadeswaran Palanisamy , Ranjith Rajendran , Govarthini Ramasamy , Sanya Sirivithayapakorn , Natacha Phetyim , Thammasak Rojviroon","doi":"10.1016/j.enmm.2025.101086","DOIUrl":"10.1016/j.enmm.2025.101086","url":null,"abstract":"<div><div>In this research work, Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite was synthesized through hydrothermal process and combined with thermal decomposition method. Numerous characterization techniques were utilized to examine the phase structure, functional groups, morphology, elemental composition, electronic structure and optical behaviour of as synthesized materials. The boosted light absorption capability of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite which is accredited to the synergetic interaction between the BiOCl and g-C<sub>3</sub>N<sub>4</sub> materials. The photocatalytic degradation efficacy of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite over Rhodamine B (RhB) textile pollutant was exhibited 97 % within 100 min which is higher than the pristine BiOCl material. It’s caused by the active separation, allocation of electrons and holes and reduce the recombination. Five successive recycle process proved the stability and reusability of the material. Finally, This work demonstrates an enriched Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite will deliver the impression of construct the Z scheme heterojunction photocatalyst to augment the photocatalytic activity in the occurrence of visible light.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101086"},"PeriodicalIF":0.0,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144366686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The fluorescence quenching of carbazole and carbazole@2-hydroxypropyl-β-cyclodextrin complex was evaluated in water as an analytical strategy for the quantification of six different silver and gold nanoparticles with either gallic acid, citrate, or p-(2-hydroxyethoxy) benzoic acid as ligands. The free carbazole is more sensitive to the analyzed metal nanoparticles with detection limits in the picomolar level (e.g., 0.106 pM for citrate-stabilized silver nanorods (AgNR) and 34.5 pM for citrate-stabilized silver nanospheres (AgNPc)) compared to the cyclodextrin-complexed carbazole (e.g., 0.200 pM for AgNR to insensitive for AgNPc). The recovery assays in spiked tap water and surface river water for all the analyzed nanoparticles were between 90 % and 112 % with 95 % confidence. The proposed method is an excellent alternative to more sophisticated methodologies for accurately quantifying silver and gold nanoparticles in aqueous systems.
{"title":"Quantifying silver and gold nanoparticles in water via carbazole fluorescence quenching: A simple and economical approach","authors":"Rodrigo Nicolás Núñez , Alicia Viviana Veglia , Natalia Lorena Pacioni","doi":"10.1016/j.enmm.2025.101084","DOIUrl":"10.1016/j.enmm.2025.101084","url":null,"abstract":"<div><div>The fluorescence quenching of carbazole and carbazole@2-hydroxypropyl-β-cyclodextrin complex was evaluated in water as an analytical strategy for the quantification of six different silver and gold nanoparticles with either gallic acid, citrate, or p-(2-hydroxyethoxy) benzoic acid as ligands. The free carbazole is more sensitive to the analyzed metal nanoparticles with detection limits in the picomolar level (e.g., 0.106 pM for citrate-stabilized silver nanorods (AgNR) and 34.5 pM for citrate-stabilized silver nanospheres (AgNP<sub>c</sub>)) compared to the cyclodextrin-complexed carbazole (e.g., 0.200 pM for AgNR to insensitive for AgNP<sub>c</sub>). The recovery assays in spiked tap water and surface river water for all the analyzed nanoparticles were between 90 % and 112 % with 95 % confidence. The proposed method is an excellent alternative to more sophisticated methodologies for accurately quantifying silver and gold nanoparticles in aqueous systems.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101084"},"PeriodicalIF":0.0,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study demonstrates an eco-friendly synthesis of silver nanoparticles (AgNPs) using chloroform extract of Nigella sativa seeds (CENSS) for combating bacterial infections and accelerating wound repair. The work highlights the dual therapeutic potential of CENSS-AgNPs through rigorous physicochemical, biological, and mechanistic analyses. The stable AgNPs was formed because of the transformation of silver ions by the CENSS. These NPs were thoroughly characterized using various physiochemical parameters. The biosynthesized CENSS-AgNPs demonstrated substantial antibacterial activity as indicated by the prominent inhibition areas observed on the agar plates. These are prominent bacteria which play significant roles in both human health and disease. Cytotoxicity assessment on human keratinocyte cells (HaCaT) revealed dose-dependent effects, with CENSS-AgNPs demonstrating feasible in wound healing by hastening scratch closure and enhancing cell migration. Furthermore, the protein expression analysis explored that CENSS-AgNPs stimulated the expression levels of platelet-derived growth factor (PDGF) and vascular endothelial growth factor (VEGF) which are crucial for wound repair. Over all, this study underscores the therapeutic promise of CENSS-mediated AgNPs in combating infections and promoting tissue regeneration, suggesting their prospective utility in advanced wound care and biomedical fields. Further exploration of their biological mechanisms and clinical applications is warranted to harness their full therapeutic potential.
{"title":"Green synthesis of Nigella sativa-mediated silver nanoparticles for enhanced antibacterial activity and wound healing: Mechanistic insights and biomedical applications","authors":"Chella Perumal Palanisamy , Sirilux Poompradub , Kanokwan Sansanaphongpricha , Selvaraj Jayaraman , Karthik Subramani , Faridah Sonsudin","doi":"10.1016/j.enmm.2025.101085","DOIUrl":"10.1016/j.enmm.2025.101085","url":null,"abstract":"<div><div>This study demonstrates an eco-friendly synthesis of silver nanoparticles (AgNPs) using chloroform extract of <em>Nigella sativa</em> seeds (CENSS) for combating bacterial infections and accelerating wound repair. The work highlights the dual therapeutic potential of CENSS-AgNPs through rigorous physicochemical, biological, and mechanistic analyses. The stable AgNPs was formed because of the transformation of silver ions by the CENSS. These NPs were thoroughly characterized using various physiochemical parameters. The biosynthesized CENSS-AgNPs demonstrated substantial antibacterial activity as indicated by the prominent inhibition areas observed on the agar plates. These are prominent bacteria which play significant roles in both human health and disease. Cytotoxicity assessment on human keratinocyte cells (HaCaT) revealed dose-dependent effects, with CENSS-AgNPs demonstrating feasible in wound healing by hastening scratch closure and enhancing cell migration. Furthermore, the protein expression analysis explored that CENSS-AgNPs stimulated the expression levels of platelet-derived growth factor (PDGF) and vascular endothelial growth factor (VEGF) which are crucial for wound repair. Over all, this study underscores the therapeutic promise of CENSS-mediated AgNPs in combating infections and promoting tissue regeneration, suggesting their prospective utility in advanced wound care and biomedical fields. Further exploration of their biological mechanisms and clinical applications is warranted to harness their full therapeutic potential.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101085"},"PeriodicalIF":0.0,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144321402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}