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Fully thermally evaporated perovskite solar cells based on reverse layer-by-layer deposition 基于反向逐层沉积的完全热蒸发钙钛矿太阳能电池
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-21 DOI: 10.1038/s41566-025-01768-0
Yutian Xu, Kui Xu, Tengfei Pan, Xinwu Ke, Yajing Li, Na Meng, Xiaorong Shi, Junhao Liu, Yuanhao Cui, Ziqiang Wang, Xue Min, Yifan Lv, Lingfeng Chao, Zhelu Hu, Qingxun Guo, Yingdong Xia, Yonghua Chen, Wei Huang
Thermal evaporation is a well-established technique in thin-film manufacturing and holds great promise for the scalable fabrication of perovskite solar cells. However, the performance of fully thermally evaporated perovskite solar cells lags behind that of solution-processed counterparts. Here we report a reverse layer-by-layer deposition strategy to control the diffusion of solid-phase precursor, whereby the organic formamidinium iodide is deposited before the inorganic precursors (CsI/PbCl2/PbI2). Subsequent annealing leads to enhanced interfacial contact, efficient charge extraction and top-down perovskite crystallization with enhanced vertical uniformity. We fabricate fully thermally evaporated inverted perovskite solar cells with power conversion efficiencies of 25.19% (for an active area of 0.066 cm2) and 23.38% (1 cm2 area). Unencapsulated devices retain 95.2% of their initial power conversion efficiency after 1,000 h of continuous operation at the maximum power point. A layer-by-layer thermal evaporation strategy enables thermally evaporated inverted perovskite solar cells with a power conversion efficiency of 25.19%, maintaining about 95% of their initial efficiency after 1,000 h of operation.
热蒸发是一种成熟的薄膜制造技术,对于钙钛矿太阳能电池的规模化制造具有很大的前景。然而,完全热蒸发钙钛矿太阳能电池的性能落后于溶液处理的同类产品。在这里,我们报道了一种反向逐层沉积策略来控制固相前驱体的扩散,即有机碘化甲脒在无机前驱体(CsI/PbCl2/PbI2)之前沉积。随后的退火导致界面接触增强,有效的电荷提取和自上而下的钙钛矿结晶,垂直均匀性增强。我们制造了完全热蒸发的倒置钙钛矿太阳能电池,其功率转换效率为25.19%(有效面积为0.066 cm2)和23.38% (1 cm2面积)。在最大功率点连续工作1000小时后,未封装的器件保留其初始功率转换效率的95.2%。采用逐层热蒸发策略,热蒸发倒钙钛矿太阳能电池的功率转换效率为25.19%,运行1000 h后仍能保持其初始效率的95%左右。
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引用次数: 0
Continuous terahertz band coverage through precise electron-beam tailoring in free-electron lasers 在自由电子激光器中通过精确的电子束裁剪实现连续的太赫兹波段覆盖
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-20 DOI: 10.1038/s41566-025-01775-1
Yin Kang, Tong Li, Zhen Wang, Yue Wang, Cheng Yu, Weiyi Yin, Zhangfeng Gao, Hanghua Xu, Hang Luo, Xiaofan Wang, Jian Chen, Taihe Lan, Xiaoqing Liu, Jinguo Wang, Huan Zhao, Fei Gao, Liping Sun, YanYan Zhu, Yongmei Wen, Qili Tian, Chenye Xu, Xingtao Wang, Jiaqiang Xu, Zheng Qi, Tao Liu, Bin Li, Lixin Yan, Kaiqing Zhang, Chao Feng, Bo Liu, Zhentang Zhao
High-power, continuously tunable narrowband terahertz (THz) sources are essential for advancing nonlinear optics, THz-driven material dynamics and ultrafast spectroscopy. Conventional techniques typically impose a trade-off between pulse energy and frequency tunability. Here we demonstrate a novel free-electron laser approach that overcomes these limitations by premodulating a relativistic electron beam with a frequency-beating laser pulse and leveraging bunch compression along with collective effects to enhance microbunching. Experimental results demonstrate that this technique generates narrowband THz emission with continuous frequency tunability from 7.8 to 30.8 THz, achieving pulse energies up to 385  $$upmu {rm{J}}$$ and maintaining spectral bandwidths between 7.7% and 14.7%. Moreover, the method exhibits exceptional robustness and scalability, highlighting its unique ability to bridge the long-standing THz gap and offering a promising solution for diverse cutting-edge scientific applications. High-power, tunable accelerator-based terahertz radiation is demonstrated. By electron-beam manipulation through laser heater beating, tunable capability from 7.8 to 30.8 THz, narrow spectral bandwidths (ranging from 7.7% to 14.7%) and pulse energies up to 385 μJ are obtained.
高功率、连续可调谐的窄带太赫兹(THz)源对于推进非线性光学、太赫兹驱动的材料动力学和超快光谱学至关重要。传统技术通常在脉冲能量和频率可调性之间进行权衡。在这里,我们展示了一种新的自由电子激光方法,通过用频率跳动的激光脉冲预调制相对论电子束,并利用束压缩和集体效应来增强微束,从而克服了这些限制。实验结果表明,该技术产生的窄带太赫兹发射具有7.8 ~ 30.8太赫兹的连续频率可调性,脉冲能量高达385 $$upmu {rm{J}}$$,频谱带宽保持在7.7之间% and 14.7%. Moreover, the method exhibits exceptional robustness and scalability, highlighting its unique ability to bridge the long-standing THz gap and offering a promising solution for diverse cutting-edge scientific applications. High-power, tunable accelerator-based terahertz radiation is demonstrated. By electron-beam manipulation through laser heater beating, tunable capability from 7.8 to 30.8 THz, narrow spectral bandwidths (ranging from 7.7% to 14.7%) and pulse energies up to 385 μJ are obtained.
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引用次数: 0
Perovskite crystallization control via an engineered self-assembled monolayer in perovskite–silicon tandem solar cells 钙钛矿结晶控制通过工程自组装单层钙钛矿硅串联太阳能电池
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-20 DOI: 10.1038/s41566-025-01778-y
Daoyong Zhang, Boning Yan, Rui Xia, Biao Li, Ruilin Li, Pengjie Hang, Haimeng Xin, Jiyao Wei, Ming Lei, Yifeng Chen, Jifan Gao, Hengyu Zhang, Zhenyi Ni, Deren Yang, Xuegong Yu
Buried defects at the interface between the wide-bandgap perovskite and the self-assembled monolayer (SAM) limit the performance of p–i–n solar cells, particularly in textured monolithic perovskite–silicon tandem solar cells. Here we reveal that uncontrolled perovskite crystallization dynamics on conventional SAMs drives the co-evolution of electronic defects and morphological degradation at the buried interface. This stems from structural and energetic incompatibility between the perovskite precursor solution and the SAM. To precisely control the perovskite crystallization, we develop a tailored SAM that mitigates defect formation and enhances interfacial electronic coupling. Integrated into a perovskite–silicon tandem solar cell, this approach enables a power conversion efficiency of 33.86% (certified as 33.59%) for a device with a 1-cm2 area and a power conversion efficiency of 29.25% (certified as 28.53%) for an area of 16 cm2. The tandem device demonstrates remarkable operational stability, retaining more than 90% of the initial power conversion efficiency after 2,000 h of operational under 1-sun illumination. An engineered self-assembled monolayer improves perovskite crystallization, enabling perovskite–silicon tandem solar cells with a certified power conversion efficiency of 33.59%, 90% of which is maintained after 2,000 h of operation at ambient temperature.
在宽带隙钙钛矿和自组装单层(SAM)之间的界面上的埋藏缺陷限制了p-i-n太阳能电池的性能,特别是在纹理单片钙钛矿-硅串联太阳能电池中。在这里,我们揭示了常规地对空材料上不受控制的钙钛矿结晶动力学驱动了埋藏界面上电子缺陷和形态退化的共同演化。这源于钙钛矿前驱体溶液与SAM之间的结构和能量不相容。为了精确控制钙钛矿的结晶,我们开发了一种定制的SAM,以减轻缺陷的形成并增强界面电子耦合。该方法集成到钙钛矿-硅串联太阳能电池中,对于面积为1 cm2的器件,功率转换效率为33.86%(认证为33.59%),对于面积为16 cm2的器件,功率转换效率为29.25%(认证为28.53%)。串联装置表现出显著的运行稳定性,在1个太阳光照下运行2000小时后,保持了90%以上的初始功率转换效率。设计的自组装单层改善了钙钛矿的结晶,使钙钛矿-硅串联太阳能电池的功率转换效率达到33.59%,在环境温度下工作2000小时后仍能保持90%的效率。
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引用次数: 0
Single-shot phase diversity wavefront sensing in deep turbulence via metasurface optics 基于超表面光学的深湍流单次相位分集波前传感
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-17 DOI: 10.1038/s41566-025-01772-4
Arturo Martin Jimenez, Marc Baltes, Jackson Cornelius, Neset Aközbek, Zachary J. Coppens
Free-space optical communication systems offer high-bandwidth, secure communication with minimal capital costs. Adaptive optics are typically added to these systems to decrease atmospheric channel losses; however, the performance of traditional adaptive optics wavefront sensors degrades in long-range, deep-turbulence conditions. Alternative wavefront sensors using phase diversity can successfully reconstruct wavefronts in deep turbulence, but current implementations require bulky setups with high latency. Here we use a nanostructured birefringent metasurface optic that enables low-latency phase diversity wavefront sensing in a compact form factor. We prove the effectiveness of this approach in mid-to-high turbulence (Rytov numbers from 0.2 to 0.6) through simulation and experimental demonstration. In both cases, an average 16-fold increase in signal from the corrected beam is obtained. We also demonstrate benefits such as noise tolerance and complex field reconstruction with high resolution. Our approach opens a pathway for compact, robust wavefront sensing that enhances range and accuracy of free-space optical communication systems. With free-space optical communications in mind, researchers used a nanostructured birefringent metasurface to achieve a 16-fold increase in the corrected beam signal in mid-to-high-turbulence conditions. Benefits of the noise-tolerant approach to wavefront reconstruction with high resolution are demonstrated.
自由空间光通信系统以最小的资本成本提供高带宽、安全的通信。自适应光学通常被添加到这些系统中,以减少大气信道损失;然而,传统的自适应光学波前传感器在长距离、深度湍流条件下性能下降。使用相位分集的波前传感器可以成功地重建深度湍流中的波前,但目前的实现需要庞大的设置和高延迟。在这里,我们使用纳米结构的双折射超表面光学器件,以紧凑的外形因素实现低延迟相位分集波前传感。通过仿真和实验验证了该方法在中高湍流(Rytov数为0.2 ~ 0.6)条件下的有效性。在这两种情况下,从修正光束中获得的信号平均增加16倍。我们还展示了诸如噪声容忍和高分辨率复杂场重建等优点。我们的方法为紧凑,稳健的波前传感开辟了一条途径,提高了自由空间光通信系统的范围和精度。考虑到自由空间光通信,研究人员使用纳米结构双折射超表面,在中高湍流条件下实现了16倍的校正光束信号。在高分辨率波前重建中,证明了容噪方法的优点。
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引用次数: 0
Author Correction: Broadband optical fibre with an attenuation lower than 0.1 decibel per kilometre 作者更正:衰减低于0.1分贝/公里的宽带光纤
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-17 DOI: 10.1038/s41566-025-01803-0
Marco Petrovich, Eric Numkam Fokoua, Yong Chen, Hesham Sakr, Abubakar Isa Adamu, Rosdi Hassan, Dong Wu, Ron Fatobene Ando, Athanasios Papadimopoulos, Seyed Reza Sandoghchi, Gregory Jasion, Francesco Poletti
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引用次数: 0
Frequency-modulated high-power photonic-crystal surface-emitting lasers for long-distance coherent free-space optical communications 用于远距离相干自由空间光通信的调频高功率光子晶体表面发射激光器
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-14 DOI: 10.1038/s41566-025-01782-2
Takuya Inoue, Ryohei Morita, Shota Ishimura, Shuei Nakano, Hidenori Takahashi, Takehiro Tsuritani, Menaka De Zoysa, Kenji Ishizaki, Masatoshi Suzuki, Susumu Noda
High-power coherent optical transmitters with high-speed controllability are in demand for a number of cutting-edge applications, including intersatellite communications and deep-space optical communications. The conventional transmitters used in these applications require many bulky optical components besides their semiconductor laser sources, such as fibre-optical amplifiers, external phase modulators, optical fibres and beam-collimation lenses, which are obstacles in achieving compact and efficient systems. Here we propose and experimentally demonstrate compact coherent optical transmitters based on frequency-modulated photonic-crystal surface-emitting lasers (PCSELs) towards achieving long-distance free-space optical (FSO) communications. We design two-section PCSELs that incorporate two photonic crystals with slightly different band-edge resonant frequencies, and we realize watt-class frequency modulation with suppressed amplitude modulation via anti-phase current injection into the two sections. Using the above two-section PCSELs as coherent optical transmitters, we demonstrate fibre-amplifier-free FSO communications with Gbps-class bandwidth, even when the laser power is attenuated by >80 dB. Our work opens avenues toward the realization of one-chip coherent optical transmitters whose volume and weight are several orders of magnitude smaller than conventional bulky systems for a wide variety of coherent free-space laser applications. Researchers realize watt-class frequency modulation using compact coherent optical transmitters based on frequency-modulated photonic-crystal surface-emitting lasers. The system has implications for long-distance free-space optical communications.
具有高速可控性的高功率相干光发射机在许多尖端应用中都有需求,包括卫星间通信和深空光通信。在这些应用中使用的传统发射机除了半导体激光源外,还需要许多笨重的光学元件,如光纤放大器、外部相位调制器、光纤和光束准直透镜,这些都是实现紧凑高效系统的障碍。在这里,我们提出并实验证明了基于调频光子晶体表面发射激光器(PCSELs)的紧凑型相干光发射机,以实现远距离自由空间光(FSO)通信。我们设计了包含两个带边谐振频率略有不同的光子晶体的两段PCSELs,并通过在两段注入反相电流来实现抑制调幅的瓦级调频。使用上述两段pcsel作为相干光发射机,我们演示了即使激光功率衰减了80 dB,也可以实现gbps级带宽的无光纤放大器FSO通信。我们的工作为实现单芯片相干光发射机开辟了道路,其体积和重量比传统的笨重系统小几个数量级,可用于各种相干自由空间激光应用。
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引用次数: 0
Temporal characterization of tunable few-cycle vacuum ultraviolet pulses 可调谐短周期真空紫外脉冲的时间特性
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-08 DOI: 10.1038/s41566-025-01770-6
José R. C. Andrade, Martin Kretschmar, Rostyslav Danylo, Stefanos Carlström, Tobias Witting, Alexandre Mermillod-Blondin, Serguei Patchkovskii, Misha Yu Ivanov, Marc J. J. Vrakking, Arnaud Rouzée, Tamas Nagy
In the past few decades, the development of ultrafast lasers has revolutionized our ability to gain insight into light–matter interactions. The emergence of few-cycle light sources operating from the visible to the mid-infrared spectral range—as well as attosecond extreme ultraviolet and X-ray technologies—provide the possibility to directly observe and control ultrafast electron dynamics in matter on their natural timescale; however, the temporal characterization of few-femtosecond sources in the deep ultraviolet (4–6 eV, 300–200 nm) and the vacuum ultraviolet (VUV; 6–12 eV, 200–100 nm) spectral regions is challenging. Here we fully characterize the temporal shape of microjoule-energy VUV pulses tuned between 160 and 190 nm generated via resonant dispersive wave emission during soliton self-compression in a capillary using frequency-resolved optical gating based on two-photon photoionization in noble gases. The in situ measurements reveal that in most of the cases the pulses are shorter than 3 fs. These findings pave the way toward investigating ultrafast electron dynamics and valence excitation of a large class of atoms and molecules with a time-resolution that has been hitherto inaccessible when using VUV pulses. The temporal characterization of few-femtosecond vacuum ultraviolet pulses bring new opportunities for investigating ultrafast light-matter interactions.
在过去的几十年里,超快激光器的发展彻底改变了我们洞察光与物质相互作用的能力。从可见到中红外光谱范围内工作的少周期光源的出现,以及阿秒极紫外和x射线技术,提供了在自然时间尺度上直接观察和控制物质超快电子动力学的可能性;然而,在深紫外(4-6 eV, 300-200 nm)和真空紫外(VUV; 6-12 eV, 200-100 nm)光谱区域的低飞秒源的时间表征是具有挑战性的。本文利用基于稀有气体中双光子光电离的频率分辨光门控技术,全面表征了在毛细管中孤子自压缩过程中共振色散波发射产生的微焦耳能量VUV脉冲的时间形状,该脉冲调谐在160 ~ 190 nm之间。现场测量表明,在大多数情况下,脉冲短于3秒。这些发现为研究一大类原子和分子的超快电子动力学和价态激发铺平了道路,这是迄今为止使用VUV脉冲无法实现的时间分辨率。几飞秒真空紫外脉冲的时间特性为研究超快光-物质相互作用带来了新的机会。
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引用次数: 0
High-power electrically pumped microcombs 大功率电泵微型梳子
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-07 DOI: 10.1038/s41566-025-01769-z
Andres Gil-Molina, Yair Antman, Ohad Westreich, Xingchen Ji, Min Chul Shin, Gaurang R. Bhatt, Ipshita Datta, Bok Young Kim, Yoshitomo Okawachi, Alexander L. Gaeta, Michal Lipson
Integrated microcombs are promising for numerous applications that require a small footprint, high output power and high efficiency, such as data communications, sensing and spectroscopy. Electrically pumped microcombs have been recently demonstrated via the integration of gain chips with high-quality-factor integrated resonators. However, the overall optical power remains well below what is necessary for practical solutions. Here we demonstrate high-power electrically pumped Kerr-frequency microcombs by integrating a low-coherence source with high output power and silicon nitride ring resonators. We design the resonators with normal group velocity dispersion and leverage self-injection locking in the nonlinear regime for generating high on-chip power combs whereas, simultaneously, purifying the coherence of the pump source. We show microcombs with total on-chip power levels up to 158 mW and comb lines with an intrinsic linewidth as narrow as 200 kHz. We demonstrate more than twice the number of comb lines exceeding 100 μW and an order-of-magnitude higher on-chip power levels compared with previously reported results. Our novel electrically pumped microcomb source has the size, power and linewidth required for data communications, and could strongly impact other areas such as high-performance computing and ubiquitous devices for spectral-sensing and time-keeping applications. Combining a low-coherence source with silicon nitride ring resonators featuring normal group velocity dispersion enables electrically pumped, high-power microcombs, providing on-chip power up to 158 mW and high-coherence comb lines with linewidths as narrow as 200 kHz.
集成微型梳对于许多需要占地面积小、输出功率高、效率高的应用很有希望,例如数据通信、传感和光谱学。电泵微梳最近通过集成增益芯片和高质量因数集成谐振器得到了证明。然而,整体光功率仍然远远低于实际解决方案所需的功率。在这里,我们展示了通过集成具有高输出功率的低相干源和氮化硅环谐振器的大功率电泵浦克尔频率微梳。我们设计了具有正常群速度色散的谐振器,并利用非线性状态下的自注入锁定来产生高片上功率梳,同时净化泵浦源的相干性。我们展示了芯片上总功率水平高达158 mW的微型梳,梳线的固有线宽窄至200 kHz。我们证明了超过100 μW的梳线数量增加了一倍以上,并且与先前报道的结果相比,片上功率水平提高了一个数量级。我们的新型电泵微梳源具有数据通信所需的尺寸,功率和线宽,并且可以强烈影响其他领域,例如高性能计算和无处不在的频谱传感和计时应用设备。将低相干源与具有正常群速度色散的氮化硅环形谐振器相结合,可以实现电泵浦的大功率微梳,提供高达158 mW的片上功率和线宽窄至200 kHz的高相干梳线。
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引用次数: 0
Mie resonances light up nanoplastics Mie共振点亮了纳米塑料
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-03 DOI: 10.1038/s41566-025-01766-2
Thomas F. Krauss
Photonic resonances provide an easy on-chip classification method for nanoplastic particles.
光子共振为纳米塑料粒子提供了一种简单的片上分类方法。
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引用次数: 0
A Compact Topological Microwave Isolator 紧凑型拓扑微波隔离器
IF 32.9 1区 物理与天体物理 Q1 OPTICS Pub Date : 2025-10-03 DOI: 10.1038/s41566-025-01761-7
Alexander Cerjan
A central goal of topological photonics has been to develop compact isolators using protected, non-reciprocal edge states. A recent demonstration of a ferrite-based microwave isolator leverages the magnon-induced topological photonic bandgap to achieve over 100 dB of isolation in a device smaller than a single free-space wavelength.
拓扑光子学的一个中心目标是利用受保护的非互易边缘状态来开发紧凑的隔离器。最近一项基于铁氧体的微波隔离器的演示利用了磁振子诱导的拓扑光子带隙,在小于单个自由空间波长的器件中实现了超过100 dB的隔离。
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引用次数: 0
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