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Vietnam Journal of Catalysis and Adsorption最新文献

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Synthesis and photocatalytic activity evaluation of Au/g-C3N4 material for hydrogen evolution reaction Au/g-C3N4析氢材料的合成及光催化活性评价
Pub Date : 2022-12-11 DOI: 10.51316/jca.2022.064
H. V. Giap, N. Steinfeldt, Mai Nguyen Thi Tuyet
In this research, we report on the synthesis of Au/g-C3N4 material and study the effect of Au deposition on g-C3N4to optimize its photocatalytic performance. The presence of Au significantly enhances the light absorption and reduces the recombination rate of electron-hole pairs leading to improve the H2 evolution efficiency. The highly improved efficiency is also due to the efficient transfer of photoelectrons between the g-C3N4and Au molecules. The report indicates that the chemical reduction method to deposit gold nanoparticles on g-C3N4is an appropriate method with significant photocatalytic efficiency. The results open up another path for the synthesis of Au/g-C3N4for hydrogen evolution applications.
在本研究中,我们报道了Au/g-C3N4材料的合成,并研究了Au沉积对g-C3N4光催化性能的影响。Au的存在显著增强了光吸收,降低了电子-空穴对的复合速率,从而提高了析氢效率。效率的提高也是由于g- c3n4和Au分子之间光电子的有效转移。研究结果表明,化学还原法制备金纳米颗粒在g- c3n4上是一种合适的方法,具有显著的光催化效率。研究结果为Au/g- c3n4的合成及析氢应用开辟了新的途径。
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引用次数: 0
Synthesis of bimetallic Ag-Au nanoparticles for surface-enhanced Raman scattering spectroscopy 用于表面增强拉曼散射光谱的双金属Ag-Au纳米颗粒的合成
Pub Date : 2022-12-11 DOI: 10.51316/jca.2022.063
Mai Nguyen Thi Tuyet, Hoai Hoang Thi Thu, Huy Nguyen Le, Hoai Tran Thanh, Hai Phan Van
In this report, bimetallic Au-Ag nanoparticles were successfully prepared by a chemical strategy using binary reduction agents. The metal ratio in bimetallic nanoparticles can be easily tuned by controlling the metal precursor ratio. Using Rhodamine as a probe molecule, we investigated the surface-enhanced Raman scattering (SERS) activity of synthesized bimetallic Au-Ag nanoparticles. The results demonstrate that our materials allow to enhance about 2×106 times the Raman signal of Rhodamine. Hence, the combination of unique features of two plasmonic metals opens up exciting prospects for the design of an ultra-sensitive sensor based on SERS.
本文利用二元还原剂,成功制备了双金属Au-Ag纳米颗粒。通过控制金属前驱体的比例,可以很容易地调节双金属纳米颗粒中的金属比例。以罗丹明为探针分子,研究了合成的双金属Au-Ag纳米粒子的表面增强拉曼散射(SERS)活性。结果表明,我们的材料允许提高约2×106倍罗丹明的拉曼信号。因此,结合两种等离子体金属的独特特性,为基于SERS的超灵敏传感器的设计开辟了令人兴奋的前景。
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引用次数: 0
Synthesis of inorganic polymer sodium aluminum silicate system based on sodium silicate and application as film forming agent for silicate paint 以硅酸钠为基料的无机聚合物硅酸钠铝体系的合成及其在硅酸盐涂料成膜剂中的应用
Pub Date : 2022-11-05 DOI: 10.51316/jca.2022.062
Cuong Le Manh, Nguyet Tran Thi Minh, Lan Anh Luu Thi, Khanh Bui Xuan, Than Nguyen Hoang
In this study, sodium aluminum silicate inorganic polymer was synthesized by sol-gel method. The parameters affecting the polymer formation were also investigated. Polymers with optimal parameters have been applied to make high temperature resistant inorganic paints. Modified infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD) methods were used to investigate the characteristics of the paint film. Furthermore, the mechanical and mechanical properties of heat-resistant inorganic paints and their heat resistance were also investigated.
本研究采用溶胶-凝胶法制备了硅酸铝钠无机聚合物。研究了影响聚合物形成的参数。采用最佳参数的聚合物制备了耐高温无机涂料。采用改进红外光谱(FTIR)、扫描电镜(SEM)和x射线衍射(XRD)等方法研究了漆膜的特性。此外,还研究了耐热无机涂料的力学性能和耐热性。
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引用次数: 0
Fabrication of the superhydrophobic and oleophilic graphene-based sponge for the treatment of oil- and organic solvent-contaminated wastewater 超疏水亲油石墨烯基海绵处理含油及有机溶剂污染废水的制备
Pub Date : 2022-11-05 DOI: 10.51316/jca.2022.061
Luong Tran Duc, Quyen Mai Le, Mui Pham Thi Thu
Graphene, a 2D nanomaterial, has been extensively studied and applied in many applications including, but not limited to, energy storage, environmental treatment, additives for paints, rubber, and composite, sensors, and electronic devices. In this work, graphene-based sponge was facilely fabricated by simply immersing melamine sponge into well-dispersed graphene nanoplaletes solution. The prepared graphene sponge revealed superhydrophobic and oleophillic properties in nature. The graphene-based sponge showed remarkable adsorption performance toward oils and organic solvents with the adsorption capacity ranging from 40 to 70 folds of sponge’s weight. The sponge also exhibited high recyclability, which is considered as a promising material for the practical application.
石墨烯是一种二维纳米材料,已被广泛研究并应用于许多应用领域,包括但不限于能源存储、环境处理、涂料添加剂、橡胶和复合材料、传感器和电子设备。在这项工作中,将三聚氰胺海绵简单地浸入分散良好的石墨烯纳米血小板溶液中,就可以很容易地制备出石墨烯基海绵。制备的石墨烯海绵在自然界中表现出超疏水性和亲油性。石墨烯基海绵对油脂和有机溶剂的吸附性能优异,吸附量为海绵重量的40 ~ 70倍。海绵具有较高的可回收性,是一种很有应用前景的材料。
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引用次数: 0
Rh-supported ionic-liquid catalysts on TiO2 for the conversion of Ethylene to propanol TiO2上铑负载离子液体催化剂催化乙烯制丙醇
Pub Date : 2022-10-16 DOI: 10.51316/jca.2022.058
Lam Vu Tung, Hung Trinh Ba, T. Le Minh
Rhodium catalyst systems for hydroformylation has been researched widely in the literature. Using ionic liquid for rhodium-supported catalyst facilitates this reaction. In this work, TiO2 support was first time used. From the FT-IR, EPR, and surface area analysis, the components of supported ionic liquid phase can be seen after the impregnation of ionic liquid into the support’s porous structure. The main product for the ethylene conversion is propan-2-ol, as a subsequent hydrogenation product after hydroformylation. Pressure and temperature difference are evaluated to understand the influence on selectivity and product formation.
铑催化体系的氢甲酰化已经在文献中得到了广泛的研究。使用离子液体作为负载铑的催化剂有利于该反应。在这项工作中,首次使用了TiO2载体。通过FT-IR、EPR和表面积分析,可以看出离子液体浸渍到载体的多孔结构中后,载体的离子液相组成。乙烯转化的主要产物是丙烯-2-醇,它是氢甲酰化后的后续加氢产物。通过评价压力和温差来了解对选择性和产物形成的影响。
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引用次数: 0
A comparative study on the catalytic activities of the SrTiO3 perovskite and oxide CuO-ZnO mixed oxides for the oxidative coupling of methane SrTiO3钙钛矿与氧化CuO-ZnO混合氧化物对甲烷氧化偶联催化活性的比较研究
Pub Date : 2022-10-16 DOI: 10.51316/jca.2022.060
Hung Nguyen Thanh, Phuong Pham Thi Mai, To Dang Thi, T. Le Minh
In this study, SrTiO3 catalyst was prepared by sol-gel method and CuO-ZnO by co-precipitation for oxidative coupling of methane (OCM). The results showed that the conversion rate in the SrTiO3 sample was high (about 35%) at 850 oC, and the product C2H4 with an yield of 0.12%. Several modern analytical methods such as XRD, BET, TPx, SEM have been characterized. The XRD results showed a stable phase structure and high crystallinity with both samples. NH3-TPD recorded weak acid centers on SrTiO3, leading to coke formation on the impact surface. H2-TPR and O2-TPD express the redox of CuO-ZnO, resulting in a deep oxidation product of CO2. Factors affecting the ratio of C2H6 and C2H4 were also considered.
本研究采用溶胶-凝胶法制备SrTiO3催化剂,采用共沉淀法制备CuO-ZnO催化剂用于甲烷(OCM)的氧化偶联。结果表明,在850℃时,SrTiO3样品的转化率较高(约35%),产物C2H4收率为0.12%。采用XRD、BET、TPx、SEM等现代分析方法对其进行了表征。XRD结果表明,两种样品的相结构稳定,结晶度高。NH3-TPD记录了SrTiO3上的弱酸中心,导致撞击表面形成焦炭。H2-TPR和O2-TPD表达CuO-ZnO的氧化还原,产生CO2的深度氧化产物。考虑了影响C2H6和C2H4配比的因素。
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引用次数: 0
Synthesis of some imidazolium based ionic liquids and influence of some factors on reaction yields 咪唑类离子液体的合成及其影响因素
Pub Date : 2022-10-16 DOI: 10.51316/jca.2022.059
Uong T.N. Ha, Ngoc C. Pham, Dung Hoang Thị Kim, Van Tang Ngoc Thanh, T. T. Bui
In this paper, three imidazolium ionic liquids 1-methyl -3-n-tetradecylimidazolium chloride ([C14MIM]Cl), 1-n-butyl -3-n-butylimidazolium chloride ([C4BIM]Cl), and 1-n-butyl-3-n-tetradecylimidazolium chloride ([C14BIM]Cl) with different alkyl chain lengths were synthesized and characterized by infrared, 1H-NMR and 13C-NMR NMR and nuclear magnetic resonance, and mass spectra. The effect of structure of alkyl chloride and imidazole compounds on the synthesis yield was evaluated. In addition, the effects of reaction conditions such as temperature, time, and molar ratio of reactants on the synthesis yield were also investigated to find out suitable conditions for the synthesis processes.
本文合成了3种不同烷基链长的咪唑类离子液体1-甲基-3-n-十四烷基咪唑氯([C14MIM]Cl)、1-正丁基-3-正丁基咪唑氯([C4BIM]Cl)和1-正丁基-3-n-十四烷基咪唑氯([C14BIM]Cl),并通过红外、1H-NMR和13C-NMR NMR、核磁共振和质谱对其进行了表征。考察了氯烷基化合物和咪唑化合物的结构对合成收率的影响。此外,还考察了反应温度、反应时间、反应物的摩尔比等条件对合成收率的影响,以寻找合适的合成工艺条件。
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引用次数: 2
Synthesis of WO3/AgI photocatalysts applying for degradation of antibiotics in water 水中抗生素降解用WO3/AgI光催化剂的合成
Pub Date : 2022-10-16 DOI: 10.51316/jca.2022.054
Tung Mai Hung Thanh, The Do Minh, Hien Tran Thị Thu, Chi Nguyen Thi Phuong Le, Quoc Nguyen Tri, Binh Nguyen Thi Thanh, Mai Nguyen Vu Ngoc, Hiep Phan Phuoc Minh, Cam Nguyen Thi Dieu
In this paper, AgI was successfully synthesized in the presence of WO3 to form AgI/WO3 Z scheme hetero-junction by solid-phase heating method and by varying the WO3 mole ratio (1:0.5, 1:1, 1:2 and 1:3) with respect to the AgI. The PL spectra indicate that the introduction of WO3 to AgI can efficiently suppress the recombination of photo-generated charge carrier. The photocatalytic activity of WO3/AgI was investigated under visible light by using the Amoxicillin (AMX) antibiotic as an organic target in aqueous solution. The WO3/AgI photoactivity for AXM was greatly enhanced when both materials were coupled to form a Z-scheme system. The highest degradation percentage was reached using the WO3/AgI material ratio mole of 1/1. As compared with to the pure WO3 and AgI, the WO3/AgI hybrid material show remarkably improved visible-induced photocatalytic activities in degrading AMX for the enhanced transport ability of electrons and holes.  
本文通过固相加热法和改变WO3相对于AgI的摩尔比(1:0.5,1:1,1:2和1:3),在WO3存在下成功合成了AgI,形成AgI/WO3 Z方案异质结。发光光谱表明,在AgI中引入WO3能有效抑制光生载流子的复合。以阿莫西林(AMX)抗生素为有机靶点,在可见光下研究了WO3/AgI在水溶液中的光催化活性。当两种材料耦合形成Z-scheme体系时,WO3/AgI对AXM的光活性大大增强。当WO3/AgI材料摩尔比为1/1时,降解率最高。与纯WO3和AgI相比,WO3/AgI杂化材料由于增强了电子和空穴的传输能力,在降解AMX方面表现出显著提高的可见光诱导光催化活性。
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引用次数: 0
Synthesis of WO3/Ag3VO4 photocatalyst with enhanced visible light efficiency photocatalysis 增强可见光效率的WO3/Ag3VO4光催化剂的合成
Pub Date : 2022-10-16 DOI: 10.51316/jca.2022.053
Chi Nguyen Thi Phuong Le, Phuong Tran Thi Thu, The Do Minh, Quoc Nguyen Tri, Binh Nguyen Thi Thanh, Hien Tran Thị Thu, Tung Mai Hung Thanh, Mai Nguyen Vu Ngoc, Dieu Phan Thi, Cam Nguyen Thi Dieu
WO3/Ag3VO4photocatalyst was synthesized for benefiting the visible region of solar spectrum for degradation of antibiotic pollutant. The prepared catalyst was characterized by using scanning electron microscope (SEM), X-ray diffraction (XRD), infrared spectroscopy (IR) and energy-dispersive X-ray spectroscopy (EDX). The photocatalytic performance of material was evaluated by the photoredution of degradation of Amoxicillin (AMX) antibiotic under visible light. Results show that the obtained WO3/Ag3VO4photocatalyst can significantly enhance photocatalytic activity in comparison with the pure WO3 and Ag3VO4. The enhanced photocatalytic activity of WO3/Ag3VO4 was predominantly attributed to the synergistic effect which increased visible-light absorption and facilitated the efficient separation of photoinduced electrons and holes.
合成了WO3/ ag3vo4光催化剂,利用太阳光谱可见区降解抗生素污染物。采用扫描电镜(SEM)、x射线衍射(XRD)、红外光谱(IR)和能量色散x射线光谱(EDX)对催化剂进行了表征。通过在可见光下光还原降解阿莫西林(AMX)抗生素来评价材料的光催化性能。结果表明,制备的WO3/Ag3VO4光催化剂与纯WO3和Ag3VO4光催化剂相比,能显著提高光催化活性。WO3/Ag3VO4光催化活性的增强主要是由于协同作用增加了可见光吸收,促进了光敏电子与空穴的有效分离。
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引用次数: 1
A Perspective on Metal Single Atom- Based Electrocatalytsts towards Hydrogen Peroxide Production 金属单原子电催化剂在过氧化氢生产中的应用前景
Pub Date : 2022-10-16 DOI: 10.51316/jca.2022.052
Thi Hong Chuong Nguyen, Hieu Le Trung, Son Le Lam, M. T. Nguyen Dinh, Chinh-Chien Nguyen, Q. Le Van
The green production of hydrogen peroxide has attracted considerable attention owing to the urge for an alternative production method to the current production. Electrocatalytic reduction via the 2e- pathway has emerged as the brightest approach. However, the finding of catalysts with high efficiency and selectivity to provide a proper interaction between active sites and *OOH is remaining as the primary obstacle. Employing metal single-atom catalysts (SACs) offers a potential manner to address those challenges. The presented review aims to provide cutting-edge development of a single metal catalyst for electrocatalytic H2O2 production. Also, perspective is laid out to propose novel approaches for material development in the future
双氧水的绿色生产已经引起了相当大的关注,因为迫切需要一种替代现有生产方法的生产方法。通过2e-途径的电催化还原已成为最有前途的方法。然而,寻找具有高效和选择性的催化剂来提供活性位点与*OOH之间的适当相互作用仍然是主要的障碍。使用金属单原子催化剂(SACs)为解决这些挑战提供了一种潜在的方法。本文综述了电催化生产H2O2的单金属催化剂的最新研究进展。此外,展望了未来材料发展的新途径
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引用次数: 0
期刊
Vietnam Journal of Catalysis and Adsorption
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