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Deposited oxides for high integrity applications 用于高完整性应用的沉积氧化物
D. Freeman, J. R. Monowski, G. Ruggles
Summary form only given. This study shows that the oxides deposited using tetraethylorthosilicate (TEOS) have electrical characteristics comparable to those of thermally grown oxides, and that TEOS-grown oxides have a lower defect density than thermal oxides grown under similar particle generating conditions. The breakdown data of TEOS films deposited at various temperatures are equivalent to those of thermal oxides of the same thickness provided that films undergo a densification step. The median breakdown field at 9 MV/cm is close to that of 9.5 MV/cm for the thermally grown control samples. Time-dependent breakdown data show TEOS deposited oxides have an order of magnitude longer lifetime than thermally grown oxides, indicating that improved reliability can be expected using a TEOS oxide.<>
只提供摘要形式。本研究表明,使用四乙基硅酸盐(TEOS)沉积的氧化物具有与热生长氧化物相当的电学特性,并且TEOS生长的氧化物具有比在类似颗粒生成条件下生长的热氧化物更低的缺陷密度。在不同温度下沉积的TEOS薄膜的击穿数据与相同厚度的热氧化物的击穿数据相当,只要薄膜经历致密化步骤。9 MV/cm的中位击穿场与热生长对照样品的9.5 MV/cm击穿场接近。时间相关击穿数据显示,TEOS沉积氧化物的寿命比热生长氧化物长一个数量级,这表明使用TEOS氧化物可以提高可靠性
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引用次数: 0
Advanced interconnection technologies and system-level communications functions 先进的互联技术和系统级通信功能
L. Hornak, S. Tewksbury, T. Weidman, E. W. Kwock
Drawing on advanced packaging and interconnection schemes along with advances in VLSI technologies, the authors consider some examples of novel interconnection technologies. Novel polymer waveguides requiring only exposure to deep UV to fabricate a waveguide are emphasized as a potentially important material compatible with overlaying complex VLSI circuitry. Superconducting microstrip interconnections are considered. These examples suggest that conventional VLSI silicon technologies will evolve to become the support for the selective introduction of advanced interconnection technologies, yielding within the smaller system volumes of wafer-level systems the heterogeneous mixture of technologies seen in, or being introduced into, conventional, complex systems. It is pointed out that the specific examples used are microfabricated structures on substrates appropriate for achieving narrow features.<>
利用先进的封装和互连方案以及VLSI技术的进步,作者考虑了一些新的互连技术的例子。新型聚合物波导只需要暴露在深紫外光下制造波导,强调作为一种潜在的重要材料兼容覆盖复杂的VLSI电路。考虑超导微带互连。这些例子表明,传统的VLSI硅技术将发展成为选择性引入先进互连技术的支持,在晶圆级系统的较小系统体积内产生在传统复杂系统中看到或正在引入的异质混合技术。指出所使用的具体实例是适合实现窄特征的基板上的微加工结构。
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引用次数: 4
Chip-level electromigration measurement technique for multi-segmented interconnect test structures 多分段互连测试结构的芯片级电迁移测量技术
N. Zamani, J. Dhiman, M. Buehler
Electromigration life testing of multisegment test structures involves the measurement and analysis of space- and time-variant stress temperature distributions. A technique using the concept of a thermal coupling matrix was developed which allows an accurate (>
多段试验结构的电迁移寿命测试涉及到对空间和时变应力温度分布的测量和分析。利用热耦合矩阵的概念开发了一种技术,可以实现精确的(>)
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引用次数: 4
Excimer laser processing of Al-1%Cu/TiW interconnect layers 准分子激光加工Al-1%Cu/TiW互连层
E. Broadbent, K. Ritz, P. Maillot, E. Ong
Planar thin-film stacks comprising 750-nm Al-1%Cu/100-nm TiW/100-nm SiO/sub 2/ were subjected to a 25-ns excimer laser pulse (XeCl, 308 nm) at an optical fluence of 3.5 to 5.0 J/cm/sup 2/ at a substrate temperature of 250 degrees to 400 degrees C, and a number of the important film properties were measured. Resultant grain sizes ranged from 2 mu m to in excess of 300 mu m, the largest grains corresponding to the highest fluence/temperature condition. The melting of the Al-Cu films was found to eliminate hillock growth completely during subsequent furnace annealing (450 degrees C). Laser processing at the higher fluence condition (5.0 J/cm/sup 2/) produced large (>30%) increases in layer resistivity. Ultramicrohardness was found to range from 39 to 52 kg/mm/sup 2/ for the treated films. Accelerated stress testing revealed no significant difference in open-circuit electromigration resistance between the as-deposited and the majority of the laser-processed Al-Cu films. However, one particular group of laser-melted samples (3.5 J/cm/sup 2/, 400 degrees C) demonstrated lifetimes at least 10 times greater than those of the other sample groups. Specular reflectivity, impurity distribution, and layer morphology were also examined.<>
在250°C至400°C的衬底温度下,采用25-ns准分子激光脉冲(XeCl, 308 nm)在3.5 ~ 5.0 J/cm/sup 2/的光通量下,对750-nm Al-1%Cu/100-nm TiW/100-nm SiO/sub 2/组成的平面薄膜层进行了测量,并测量了一些重要的薄膜性能。所得到的晶粒尺寸从2亩到300多亩不等,最大的晶粒对应于最高的通量/温度条件。在随后的炉退(450℃)过程中,发现Al-Cu薄膜的熔化完全消除了丘状生长。在较高通量条件下(5.0 J/cm/sup 2/)进行激光处理,层电阻率大幅提高(>30%)。处理后的薄膜的超微硬度在39 ~ 52 kg/mm/sup /之间。加速应力测试表明,沉积的Al-Cu薄膜和大多数激光加工的Al-Cu薄膜在开路电迁移电阻方面没有显著差异。然而,一组特定的激光熔化样品(3.5 J/cm/sup /, 400℃)的寿命至少是其他样品组的10倍。镜面反射率,杂质分布和层形态也进行了检查。
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引用次数: 2
Planarized aluminum deposition of TiW and TiN layers by high temperature evaporation 用高温蒸发法制备TiW和TiN平面化铝层
G. Georgiou, K. Cheung, R. Liu
The evaporation of Al onto a heated TiW- or TiN-coated substrate is used to planarize topography. The final temperature of 450 degrees C provides enough Al mobility to planarize 2- mu m-wide features. The deposition of 1.5-2.0 times the feature depth with a >250/450 degrees C two-temperature process and a deposition rate approximately=100 AA/s gives good planarization uniformity over >6-cm wafer radius. Submicron trenches are planarized without voids, whereas windows with h/w>1 have voids. Also, 1- mu m-deep trenches are filled, whereas 2- mu m-deep trenches are not filled with a similar process. Scanning electron microscopy correlates planarization and via filling with the evaporation process and substrate topography. The effect of high-temperature evaporation on materials integrity is studied with diode leakage measurements. At 450 degrees C for <2 min required for the second step, there is no Al/(TiW or TiN)/Si interaction. However, the process is close to the failure temperature of the 1000-AA-thick (less than or approximately equal to 500 AA thick in 1 mu m features) TiW barrier layer since Al spiking is seen when the final step is >or approximately=500 degrees C.<>
将Al蒸发到加热的TiW或tin涂层基板上用于使地形平坦化。450摄氏度的最终温度提供了足够的铝迁移率,以平面化2亩宽的特征。采用>250/450℃双温工艺,沉积1.5-2.0倍特征深度,沉积速率约=100 AA/s,在> 6cm晶圆半径范围内得到良好的平面化均匀性。亚微米沟槽平坦无空洞,而h/w >.1的窗口有空洞。同样,1 μ m深的沟槽被填充,而2 μ m深的沟槽不被填充类似的过程。扫描电子显微镜分析了蒸发过程和衬底地形对平面化和通孔填充的影响。通过二极管泄漏测量,研究了高温蒸发对材料完整性的影响。在450°C或大约=500°C时
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引用次数: 1
Multi-step aluminum planarization process 多步铝材平面化工艺
A. Aronson, J. Roberts, K. Armstrong, I. Wagner
Summary form only given. A major prerequisite for voidless planarization is the initial formation of a smooth continuous aluminum film on the walls of the vias. Thermal control diffusion length can then be used to transport metal from the top surface into the features. This has been achieved using a high throughput, multistep process on an ECLIPSE sputtering system. The initial substrate temperature determines the film thickness requirements for complete film coalescence. A smooth continuous film can be produced within the first step 250 AA if deposited below 200 degrees C. At higher temperatures a continuous film may not be formed until a much larger amount of aluminum is deposited, and shadowing of the opening may occur before via filling can be done. Once the continuous coating is formed, wafer temperature is elevated to a level where surface mobility is greatly enhanced: typically between 400 degrees C and 500 degrees C.<>
只提供摘要形式。无空平面化的一个主要先决条件是在过孔壁上初始形成光滑连续的铝膜。然后可以使用热控制扩散长度将金属从顶部表面输送到特征中。这是通过在ECLIPSE溅射系统上使用高通量、多步骤工艺实现的。基材的初始温度决定了薄膜完全聚结所需的薄膜厚度。如果沉积在200℃以下,则可以在第一步250aa内产生光滑的连续膜。在较高的温度下,直到沉积了大量的铝才可能形成连续膜,并且在通过填充可以完成之前可能会出现开口的阴影。一旦形成连续涂层,晶圆温度被提高到表面迁移率大大提高的水平:通常在400摄氏度到500摄氏度之间。
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引用次数: 1
Premetal planarization using spin-on-dielectric 使用介电自旋的金属前平面化
F. Whitwer, T. Davies, C. Lage
A silicate-type spin-on-glass (SOG) was used to planarize topography prior to metal deposition. SOG was chosen for this application because of the simplicity associated with processing. The topography smoothing capability was shown to be comparable to that of flowed CVD oxide. It was found that curing the SOG in a dry oxygen ambient caused the film to densify poorly and to result in inferior dielectric properties. Performing the cure in a steam ambient, however, resulted in films with dielectric properties similar to those of CVD oxide films. This dielectric was used successfully in a 1.0- mu m double-level metal process without degrading device performance. It was shown that the film does not need to be fully densified in order to be used in this application. Temperature/humidity testing showed no anomalous effects to devices due to moisture absorption or film delamination.<>
在金属沉积之前,使用硅酸盐型玻璃自旋(SOG)使地形平坦化。这个应用程序选择SOG是因为它的处理简单。表面平滑能力可与流动CVD氧化物相媲美。研究发现,在干燥的氧环境中固化SOG会导致薄膜致密性差,导致其介电性能差。然而,在蒸汽环境中进行固化,导致薄膜具有与CVD氧化膜相似的介电性能。该介电介质成功应用于1.0 μ m双能级金属工艺中,器件性能没有下降。结果表明,为了在这种应用中使用,薄膜不需要完全致密化。温度/湿度测试显示,由于吸湿或薄膜分层,对设备没有异常影响。
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引用次数: 2
SOG planarization for polysilicon and first metal interconnect in a one micron CMOS process 在一微米CMOS工艺中用于多晶硅和第一金属互连的SOG平面化
L. Forester, A. Butler, G. Schets
The application of spin-on-glass (SOG) planarization at both the polysilicon and first metal level in a 1- mu m CMOS process developed for the manufacture of ASIC devices is described. At the polysilicon level, SOG planarization is considered for future applications since the planarization can be optimized for performance and reliability almost independently of the salicide module which is an integral part of the process. This is possible because SOG planarization is essentially a low-temperature process which does not result in degradation of the salicide. Its performance is compared to that achieved with BPSG planarization under first metal. Above first metal, SOG is used in the process for reasons of manufacturability. The performance is compared to that achieved using a previously developed resist etchback process. For both applications, SOG shows excellent performance, as illustrated by electrical data. The SOG deposition process is discussed along with relevant materials data.<>
介绍了一种用于制造ASIC器件的1 μ m CMOS工艺在多晶硅和第一金属水平上的玻璃自旋(SOG)平面化应用。在多晶硅层面,SOG平面化被认为是未来的应用,因为平面化可以优化性能和可靠性,几乎独立于salicide模块,这是该工艺的一个组成部分。这是可能的,因为SOG平面化本质上是一个低温过程,不会导致水杨酸的降解。将其性能与第一金属下的BPSG平面化技术进行了比较。在第一种金属之上,由于可制造性的原因,在工艺中使用SOG。将其性能与先前开发的抗蚀剂蚀刻工艺进行了比较。对于这两种应用,SOG表现出优异的性能,如电气数据所示。讨论了SOG的沉积过程,并提供了相关的材料数据。
{"title":"SOG planarization for polysilicon and first metal interconnect in a one micron CMOS process","authors":"L. Forester, A. Butler, G. Schets","doi":"10.1109/VMIC.1989.78008","DOIUrl":"https://doi.org/10.1109/VMIC.1989.78008","url":null,"abstract":"The application of spin-on-glass (SOG) planarization at both the polysilicon and first metal level in a 1- mu m CMOS process developed for the manufacture of ASIC devices is described. At the polysilicon level, SOG planarization is considered for future applications since the planarization can be optimized for performance and reliability almost independently of the salicide module which is an integral part of the process. This is possible because SOG planarization is essentially a low-temperature process which does not result in degradation of the salicide. Its performance is compared to that achieved with BPSG planarization under first metal. Above first metal, SOG is used in the process for reasons of manufacturability. The performance is compared to that achieved using a previously developed resist etchback process. For both applications, SOG shows excellent performance, as illustrated by electrical data. The SOG deposition process is discussed along with relevant materials data.<<ETX>>","PeriodicalId":302853,"journal":{"name":"Proceedings., Sixth International IEEE VLSI Multilevel Interconnection Conference","volume":"40 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1989-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125653170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
An improved etchback planarization process using a super planarizing spin-on sacrificial layer 一种利用超平面化自旋牺牲层改进的蚀刻平面化工艺
C. Ting, P. Pai, Zbignew Sobczack
Summary form only given. An improved process that uses a novel thermal flow/thermal setting polymer that can planarize even the largest geometries after a reflow at 200 degrees C is described. The planarization properties of this novel polymer were determined by coating it over 1.0- mu m step heights of different widths. The step heights over the line structure before and after the polymer coating were measured using a profilometer. A 1.2- mu m thick coating was used in these studies. The planarization etch was carried out in a reactive-ion-etching system. The etch rates of SiON depended weakly on the oxygen content, while the etch rates of the new organic material are a strong function of the oxygen content. Due to local loading effects, the etch rate ratio of the polymer to the CVD dielectric film cannot be maintained at a 1:1 ratio as measured by test wafers. In fact, the ratio has to be considerably less than 1 to give a planarized surface.<>
只提供摘要形式。本文描述了一种改进的工艺,该工艺使用了一种新型的热流/热定型聚合物,在200摄氏度的回流后,即使是最大的几何形状也可以平坦化。通过在1.0 μ m台阶上涂覆不同宽度的台阶来测定这种新型聚合物的平面化性能。用轮廓仪测量了涂覆前后的台阶高度。在这些研究中使用了1.2 μ m厚的涂层。在反应-腐蚀系统中进行了平面化腐蚀。氧含量对腐蚀速率的影响较小,而氧含量对腐蚀速率的影响较大。由于局部加载效应,聚合物与CVD介电膜的蚀刻速率比不能保持在测试晶圆测量的1:1的比例。事实上,这个比例必须大大小于1才能得到一个平坦的表面。
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引用次数: 3
Area selective gold MOCVD for VLSI electronics 用于VLSI电子器件的面积选择性金MOCVD
S.D. Colgate, G.J. Palenik, V. E. House, D. Schoenfeld, C. Simon
Summary form only given. Area-selective metal-organic chemical vapor deposition (MOCVD) of gold thin films has been achieved on tungsten patterned on VLSI-type silicon wafers. Scanning Auger spectroscopy of the wafer deposition areas displays virtual exclusion of gold deposits on silicious regions with 4000-AA-thick gold films of high feature resolution covering the tungsten patterns. The films were deposited by exposing the heated wafer (T<500 degrees C) to an ambient of (C/sub 2/H/sub 5/)/sub 3/PAuCl vapor for 1 h.<>
只提供摘要形式。在大面积集成电路型硅片上实现了选择性金属有机化学气相沉积(MOCVD)金薄膜。晶圆沉积区域的扫描俄歇光谱显示,硅质区域几乎不存在金矿,4000- aa厚的高特征分辨率的金膜覆盖在钨图案上。通过加热晶圆片(T>)
{"title":"Area selective gold MOCVD for VLSI electronics","authors":"S.D. Colgate, G.J. Palenik, V. E. House, D. Schoenfeld, C. Simon","doi":"10.1109/VMIC.1989.78052","DOIUrl":"https://doi.org/10.1109/VMIC.1989.78052","url":null,"abstract":"Summary form only given. Area-selective metal-organic chemical vapor deposition (MOCVD) of gold thin films has been achieved on tungsten patterned on VLSI-type silicon wafers. Scanning Auger spectroscopy of the wafer deposition areas displays virtual exclusion of gold deposits on silicious regions with 4000-AA-thick gold films of high feature resolution covering the tungsten patterns. The films were deposited by exposing the heated wafer (T<500 degrees C) to an ambient of (C/sub 2/H/sub 5/)/sub 3/PAuCl vapor for 1 h.<<ETX>>","PeriodicalId":302853,"journal":{"name":"Proceedings., Sixth International IEEE VLSI Multilevel Interconnection Conference","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1989-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121390357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Proceedings., Sixth International IEEE VLSI Multilevel Interconnection Conference
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