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63rd Device Research Conference Digest, 2005. DRC '05.最新文献

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Phonon modification in SOI structures and its impact on electron transport SOI结构中的声子修饰及其对电子输运的影响
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553131
S. Unoa, N. Mori
Introduction Acoustic phonons in silicon-on-insulator (SOI) structures are different from those in bulk Si because of the large mechanical mismatch between Si and SiO2. Therefore, conventional modeling of electron transport in SOI, where bulk phonon wave function is assumed, must be re-examined. Equivalent investigations have been done for ILL-V semiconductors [1-3]. However, there are few investigations on Si/SiO2 systems such as SOI structures in spite of their technological significance. In this work, the impact of phonon wave modulation on electron transport in SOI is investigated theoretically. Phonon Normal Modes in SOI Structure Figure 1 shows an illustration of our SOI model used in the following analysis. The silicon plate is assumed to be embedded in bulk SiO with infinite extent. For mathematical convenience stress free boundaries are assumed at z + LJ2, and L is set much larger than the thickness of the Si plate, d. As the system is isotropic along the Si plate, the phonon normal modes in the x/l direction are simply plane waves. On the other hand, nonnal modes are more complicated in the z direction due to mechanical mismatch between Si and SiO2. Such phonon normal modes are often categorized using Fig. 2, where phonon frequency, a4 vs. wave vector along xll axis, qll, is plotted [4]. The two straight lines are defined by longitudinal sound velocities in Si (vsi,l = 9.0 x 10 m/s ) and SiO2 (v0,.l = 5.9 x 103 m/s). Type (I) w> viq,ll,: longitudinal phonon normal modes have sinusoidal wave forms as shown in Fig. 3 (I). Type (II) vsil qH > a)> vo,, qH,: normal modes are sinusoidal in SiO2, and decay exponentially in Si as in Fig. 3 (II). Type (III) vox,1q/l > w: normal modes decay exponentially both in Si and SiO2 as shown in Fig. 3 (III) (surface mode). It is important to note that no confined mode exists in the SOI structure, that is, there is no normal mode such that amplitude is limited in the Si region and energy is quantized. Reduction of Acoustic Phonon Scattering Potential The dominant electron-phonon interaction in Si is the acoustic deformation potential (ADP) scattering, and its scattering potential is written as HADP (z) = DADpV * u, where DADP is a coupling constant, and u is a phonon normal mode. Figure 4 shows the squared absolute value of V u as a function of z, which is equivalent to the strain caused by the phonon vibration u. Note that the strain in the Si region is less than that in bulk Si (dashed line), while the strain in the oxide region is increased. This has been observed in a similar SiISiO2 system, and referred to as 'strain absorption' [5]. Figure 5 shows an integral of HADP within Si region (-d/2 < z < d/2) plotted as a function of w. The value of qll was fixed, and the thickness of the Si region was set as (a) d = 50 nm (b) d = 10 nm. The spikes observed in solid curves are caused by interference between longitudinal and transverse phonon modes. The three types of phonon modes appear in different ranges of
绝缘体上硅(SOI)结构中的声子不同于体硅结构中的声子,这是因为硅与SiO2之间存在较大的力学失配。因此,传统的SOI中电子输运模型必须重新检查,其中假设了体声子波函数。对ILL-V半导体也进行了类似的研究[1-3]。然而,尽管SOI结构等Si/SiO2体系具有重要的技术意义,但对它们的研究却很少。本文从理论上研究了声子波调制对SOI中电子输运的影响。图1显示了我们在以下分析中使用的SOI模型的插图。假定硅板无限深度地嵌入到大块二氧化硅中。为了数学上的方便,假设应力自由边界在z + LJ2处,并且L的设置远大于Si板的厚度d。由于系统沿Si板是各向同性的,因此声子在x/ L方向上的法向模为简单的平面波。另一方面,由于Si和SiO2之间的力学失配,非标准模态在z方向上更加复杂。这种声子正常模式通常使用图2进行分类,图2绘制了声子频率a4与沿xll轴的波矢量qll的关系[4]。这两条直线由Si (vsi, 1 = 9.0 x 10m /s)和SiO2 (v0, 1)的纵向声速定义。L = 5.9 x 103 m/s)。(I)型w> viq,ll,:纵向声子正模具有正弦波形,如图3 (I)所示。(II)型vqh > a)> vo,, qH,:正模在SiO2中为正弦,在Si中呈指数衰减,如图3 (II)所示。(III)型vox,1q/l > w:正模在Si和SiO2中呈指数衰减,如图3 (III)(表面模)所示。值得注意的是,在SOI结构中不存在约束模态,即不存在使振幅在Si区域受到限制并使能量量子化的正模态。Si中占主导地位的电子-声子相互作用是声学变形势(ADP)散射,其散射势表示为HADP (z) = DADpV * u,其中DADP为耦合常数,u为声子正态模。图4显示了V u作为z的函数的平方绝对值,它相当于声子振动u引起的应变。注意,Si区应变小于体Si区应变(虚线),而氧化区应变增大。这已经在类似的SiISiO2体系中观察到,并被称为“应变吸收”[5]。图5显示了Si区域内HADP的积分(-d/2 < z < d/2)作为w的函数。qll的值固定,Si区域的厚度设为(a) d = 50 nm (b) d = 10 nm。在实体曲线中观察到的尖峰是由纵向和横向声子模式之间的干扰引起的。三种声子模式出现在w的不同范围内,如图所示。请注意,图4中应变的减小导致HADp的减小,与块体Si(虚线)相比,HADp的减小与c和d无关。我们发现,这种减小也发生在不同的qll值。因此,对于声子波调制,SOI结构中的ADP散射势小于体硅结构中的ADP散射势。然而,我们还不能决定性地得出结论,这导致电子-声子散射率的降低,因为在SOI中存在(H)型和(IIH)型声子模式,而在体硅中不存在。为了验证这一点,必须计算总散射率,这将在我们的报告中讨论。结论对SOI结构中声子修饰的严谨处理表明,声子散射势与体硅相比降低,而与声子能量、波数和硅层厚度无关。这些结果表明,由于声子波调制,SOI中电子-声子相互作用可能减少。感谢克莱蒙特研究生大学康伯巴奇教授对本文的支持。作者也要感谢Harvey Mudd学院的H. Williams教授和D. Yong教授所做的有益讨论。Uno博士获得了南加州大学i.s.i. MOSIS服务的奖学金。参考文献[1],王晓明等。Rev. B,第7459页(2000)。[2]张志强,张志强,张志强,等。启B 65。,第205315页(2002)。[3]李建平,李建平。期刊》95。,第5626页(2004)。[4]李晓明,李晓明,李晓明,等。水处理技术的研究进展[j]。[5]吴志强等,中国生物医学工程学报,2004,1-5,2004,东京;j:。理论物理。将于二零零五年五月出版。
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引用次数: 0
Underlap DGMOS for ultra-low power digital sub-threshold operation 超低功耗数字亚阈值操作的覆盖式DGMOS
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553132
B. Paul, A. Bansal, K. Roy
Inthis paperwe analyze theimpact ofgateunderlap on theeffective capacitance ofDoubleGateMOS (DGMOS) transistor fordigital sub-threshold operation. Results onaring oscillator showthat withoptimum underlap 40%improvement indelay canbeachieved with7.3Xreduction inpowerdelay product (PDP). I.Introduction Sub-threshold leakage current canbeusedinapplications requiring ultra-low powerconsumption withlowtomedium (tentohundreds ofmegahertz) frequency ofoperation [1], e.g.cellphones, PDA,pacemaker etc.DoublegateMOS (DGMOS)transistors aresuitable forsub-threshold operation (VDD < VTH(Fig. 1)) duetotheir nearideal sub-threshold slope andnegligible intrinsic capacitance [2]. Inthis paper we investigate theeffectiveness ofthegateunderlap inDGMOS device forfurther minimizing powerconsumption indigital sub-threshold operation. Unlike super-threshold operation, the intrinsic capacitance oftheDGMOS operated inthesubthreshold region isnegligible andisveryweakly dependent onthechannel length [2]. Hence, theeffective capacitance (CG) inthesub-threshold region isdominated bytheparasitic capacitance. We showthat withoptimum gateunderlap the parasitic capacitances ofDGMOScanbesignificantly reduced, whichinturn leads tolower circuit powerconsumption.
本文分析了栅极搭接对双栅极(DGMOS)晶体管数字亚阈值工作有效电容的影响。结果表明,在最优的欠接情况下,延时提高了40%,功率延迟积(PDP)降低了7.3倍。一、介绍亚阈值泄漏电流可用于低中频(10 -数百兆赫)工作频率要求超低功耗的应用[1],如手机、PDA、起搏器等。双栅极晶体管(DGMOS)适用于亚阈值工作(VDD < VTH)。1))由于其近似亚阈值斜率和可忽略的固有电容[2]。在本文中,我们研究了gateunderlap的inDGMOS器件在数字亚阈值操作中进一步降低功耗的有效性。与超阈值操作不同,在亚阈值区域操作的dgmos的固有电容可以忽略不计,并且对通道长度的依赖性非常弱[2]。因此,亚阈值区域的有效电容(CG)由寄生电容主导。我们的研究表明,通过优化门电路覆盖,dgmos的寄生电容显著降低,从而降低了电路功耗。
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引用次数: 10
Long term transients in MOSFEG 1/f noise under switched bias conditions 开关偏置条件下MOSFEG 1/f噪声的长期瞬态
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553064
M. Y. Louie, D. A. Miller, M. E. Jacob, L. Forbes
Klumperink et al.,[1] have recently had a number of publications on the low frequency noise of n-channel MOSFET's under switched gate bias conditions. We have also previously investigated the same type of devices, older 5 micron commercial devices, under the same type of switched bias conditions and have independently confirmed these prior results. There is an anomalous reduction in I/f noise at frequencies two orders of magnitude below the switching frequency.[2] The reduction occurs only when holes are accumulated at the surface under the gate when the transistor is off during the switched bias. We have also investigated the time dependence of switched bias 1/f noise and have discovered long term time dependent transients in the I/f noise.[3]
Klumperink等人[1]最近发表了许多关于n沟道MOSFET在开关栅极偏置条件下的低频噪声的文章。我们之前也研究过相同类型的器件,旧的5微米商用器件,在相同类型的开关偏置条件下,并独立证实了这些先前的结果。在低于开关频率两个数量级的频率处,I/f噪声异常降低。[2]只有当晶体管在开关偏置期间关断时,在栅极下的表面上积累了空穴时,才会发生减少。我们还研究了开关偏置1/f噪声的时间依赖性,并发现了I/f噪声中的长期时间依赖性瞬态。[3]
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引用次数: 0
Effect of surface treatment on the performances of vertical-structured GaN-based LEDs with electroplating metallic substrate 表面处理对电镀金属衬底垂直结构gan基led性能的影响
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553061
Shui-Jinn Wang, Shiue-lung Chen, K. Uang, Yu-Cheng Yang, Tron-min Chen, B. Liou
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引用次数: 0
Self-aligned enhancement-mode AlGaN/GaN HEMTs using fluoride-based plasma treatment 氟基等离子体处理自对准增强模式AlGaN/GaN hemt
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553110
Yong Cai, Yugang Zhou, K. J. Chen, K. Lau
Wide bandgap AlGaN/GaN high electron mobility transistors (HEMTs) are emerging as excellent candidates for high power, high frequency and also high temperature applications. Up to now, the focus has been to improve the performance of depletion-mode (D-mode) AlGaN/GaN HEMTs. From the application point of view, enhancement-mode (E-mode) HEMTs have many advantages. For applications such as high frequency PAs and LNAs, E-mode HEMTs allow elimination of negative-polarity voltage supply, thereby reducing the circuit complexity and cost. For digital applications, direct-coupled FET logic (DCFL) that features integration of D-mode and E-mode HEMTs offers the simplest circuit configuration. Several approaches, such as chloride-based ICP gate recess etching [1], [2] and gate metal (e.g. Pt) sunk into AlGaN cap layer by rapid thermal annealing [3], were used to achieve E-mode AlGaN/GaN HEMTs. However, the gate recess etching approach may encounter large gate leakage currents and the gate metal sinking process can only take effects on samples with near zero pinch off voltages. Here, we demonstrate a reliable technique to fabricate E-mode AlGaN/GaN HEMTs using a fluoride-based plasma treatment and post-gate rapid thermal annealing. The schematic cross section of E-mode AlGaN/GaN HEMT is shown in Fig. 1. Starting with a conventional D-mode AlGaN/GaN heterostructure sample, (electron sheet density 1.3x 1013 cm-2 and and mobility 1000 cm2/Vs), device mesa was etched using C12/He plasma dry etching followed by source/drain ohmic contact formation with Ti/Al/Ni/Au annealed at 850'C for 45 seconds. After gate windows with 1 gm length were opened by contact photolithography, the sample was treated by CF4 plasma in an RIE system at an RF plasma power of 150W for 150 sec. Ni/Au e-beam evaporation and lift-off were carried out subsequently to form the gate electrodes. The plasma treated gate region and the gate electrode were self-aligned. Post-gate rapid thermal annealing (RTA) was conducted at 400 °C for lOmins. The devices have a source-gate spacing of Lsg = I um and a gate-drain spacing of Lgd = 2 um. D-mode HEMTs were also fabricated on the same sample without plasma treatment to the gate region. Figure 2 shows the transfer characteristics of both D-mode and E-mode AlGaN/GaN HEMTs. Defining V,h as the gate bias intercept of the linear extrapolation of drain current at the point of peak transconductance (g) the V,h of E-mode device was determined to be 0.9 V, while the V1h of D-mode device is 4.0 V. At Vgs = OV, the transconductance reaches zero, indicating a true enhancement-mode operation. The drain current is well pinched off and shows a leakage of 28 gA/mm at Vd, = 6 V, the smallest value reported to date for E-mode AlGaN/GaN HEMTs. The peak gm, is 151 mS/mm for the D-mode HEMT and 148 mS/mm for the E-mode HEMT, respectively. The maximum drain current ('max) reaches 313mA/mm at a gate bias (Vgs) of 3V. Figure 3 shows the output curves of the E-mode device befor
宽带隙AlGaN/GaN高电子迁移率晶体管(hemt)正在成为高功率、高频和高温应用的优秀候选者。到目前为止,重点是提高耗尽模式(d模式)AlGaN/GaN hemt的性能。从应用的角度来看,增强模式hemt具有许多优点。对于高频PAs和lna等应用,E-mode hemt可以消除负极性电压供应,从而降低电路复杂性和成本。对于数字应用,集成了d模和e模hemt的直接耦合场效应管逻辑(DCFL)提供了最简单的电路配置。采用氯化物基ICP栅极凹槽刻蚀[1],[2]和栅极金属(如Pt)通过快速热退火埋入AlGaN帽层[3]等几种方法可实现e型AlGaN/GaN hemt。然而,栅极凹槽刻蚀方法可能会遇到较大的栅极漏电流,并且栅极金属下沉过程只能对接近零掐断电压的样品产生影响。在这里,我们展示了一种可靠的技术,利用氟基等离子体处理和栅极后快速热退火来制造e型AlGaN/GaN hemt。e模AlGaN/GaN HEMT的截面示意图如图1所示。从传统的d模AlGaN/GaN异质结构样品(电子片密度为1.3 × 1013 cm-2,迁移率为1000 cm2/Vs)开始,使用C12/He等离子体干蚀刻,然后在850℃退火45秒后形成源/漏欧姆接触Ti/Al/Ni/Au。通过接触光刻打开长度为1gm的栅极窗后,在RIE系统中以150W的射频等离子体功率对样品进行CF4等离子体处理150秒,随后进行Ni/Au电子束蒸发和升空形成栅极。等离子体处理的栅区和栅电极是自对准的。在400℃下对lOmins进行栅后快速热退火(RTA)。该器件的源极间距为Lsg = 1um,栅极漏极间距为Lgd = 2um。在同一样品上制备了d模hemt,但未对栅区进行等离子体处理。图2显示了d模式和e模式AlGaN/GaN hemt的转移特性。定义V,h为漏极电流在跨导峰值处线性外推的栅极偏置截距(g),确定e模器件的V,h为0.9 V, d模器件的V1h为4.0 V。在Vgs = OV时,跨导达到零,表明真正的增强模式工作。漏极电流被很好地掐断,并在Vd = 6 V时显示28 gA/mm的漏电流,这是迄今为止报道的e型AlGaN/GaN hemt的最小值。d模HEMT的峰值gm为151 mS/mm, e模HEMT的峰值gm为148 mS/mm。在栅极偏置(Vgs)为3V时,最大漏极电流('max)达到313mA/mm。图3为RTA处理前后e型设备的输出曲线。RTA后阈值电压无变化。对比RTA前后E-mode器件的电流-电压(I-V)特性表明,栅极后RTA在恢复等离子体处理引起的损伤中起着关键作用。制备的e模AlGaN/GaN HEMT的fT和fgax分别为10.1 GHz和34.3 GHz,略低于d模HEMT的fT和fgax分别为13.1 GHz和37.1 GHz。总之,我们展示了一种简单的自对准方法来制造具有低导通电阻和低膝电压的高性能e模hemt,这是单极性电源电压放大器和集成数字电路所必需的。
{"title":"Self-aligned enhancement-mode AlGaN/GaN HEMTs using fluoride-based plasma treatment","authors":"Yong Cai, Yugang Zhou, K. J. Chen, K. Lau","doi":"10.1109/DRC.2005.1553110","DOIUrl":"https://doi.org/10.1109/DRC.2005.1553110","url":null,"abstract":"Wide bandgap AlGaN/GaN high electron mobility transistors (HEMTs) are emerging as excellent candidates for high power, high frequency and also high temperature applications. Up to now, the focus has been to improve the performance of depletion-mode (D-mode) AlGaN/GaN HEMTs. From the application point of view, enhancement-mode (E-mode) HEMTs have many advantages. For applications such as high frequency PAs and LNAs, E-mode HEMTs allow elimination of negative-polarity voltage supply, thereby reducing the circuit complexity and cost. For digital applications, direct-coupled FET logic (DCFL) that features integration of D-mode and E-mode HEMTs offers the simplest circuit configuration. Several approaches, such as chloride-based ICP gate recess etching [1], [2] and gate metal (e.g. Pt) sunk into AlGaN cap layer by rapid thermal annealing [3], were used to achieve E-mode AlGaN/GaN HEMTs. However, the gate recess etching approach may encounter large gate leakage currents and the gate metal sinking process can only take effects on samples with near zero pinch off voltages. Here, we demonstrate a reliable technique to fabricate E-mode AlGaN/GaN HEMTs using a fluoride-based plasma treatment and post-gate rapid thermal annealing. The schematic cross section of E-mode AlGaN/GaN HEMT is shown in Fig. 1. Starting with a conventional D-mode AlGaN/GaN heterostructure sample, (electron sheet density 1.3x 1013 cm-2 and and mobility 1000 cm2/Vs), device mesa was etched using C12/He plasma dry etching followed by source/drain ohmic contact formation with Ti/Al/Ni/Au annealed at 850'C for 45 seconds. After gate windows with 1 gm length were opened by contact photolithography, the sample was treated by CF4 plasma in an RIE system at an RF plasma power of 150W for 150 sec. Ni/Au e-beam evaporation and lift-off were carried out subsequently to form the gate electrodes. The plasma treated gate region and the gate electrode were self-aligned. Post-gate rapid thermal annealing (RTA) was conducted at 400 °C for lOmins. The devices have a source-gate spacing of Lsg = I um and a gate-drain spacing of Lgd = 2 um. D-mode HEMTs were also fabricated on the same sample without plasma treatment to the gate region. Figure 2 shows the transfer characteristics of both D-mode and E-mode AlGaN/GaN HEMTs. Defining V,h as the gate bias intercept of the linear extrapolation of drain current at the point of peak transconductance (g) the V,h of E-mode device was determined to be 0.9 V, while the V1h of D-mode device is 4.0 V. At Vgs = OV, the transconductance reaches zero, indicating a true enhancement-mode operation. The drain current is well pinched off and shows a leakage of 28 gA/mm at Vd, = 6 V, the smallest value reported to date for E-mode AlGaN/GaN HEMTs. The peak gm, is 151 mS/mm for the D-mode HEMT and 148 mS/mm for the E-mode HEMT, respectively. The maximum drain current ('max) reaches 313mA/mm at a gate bias (Vgs) of 3V. Figure 3 shows the output curves of the E-mode device befor","PeriodicalId":306160,"journal":{"name":"63rd Device Research Conference Digest, 2005. DRC '05.","volume":"40 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2005-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127666051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 27
Large magnetic field induced by carbon nanotube current -proposal of carbon nanotube inductors 碳纳米管电流诱导的大磁场——碳纳米管电感器的设计
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553084
K. Tsubaki, H. Shioya, J. Ono, Y. Nakajima, T. Hanajiri, H. Yamaguchi
New concepts of electronic components are needed to fabricate further high-performance integrated circuit. One of the new concepts is the incorporation of inductors into integrated circuits. The incorporation into integrated circuits, however, has the difficulty in three dimensional nano-fabrication technique, and the small effect due to the small quantity of magnetic permeability of o = 4 it x10-7 H/m and the large diameter of the inductor's wires. We have proposed the inductors made of carbon nanotube [1, 2]. Ihough the fabrication of the proposed inductor is still challenging and has many problems, merits of the proposed inductor are following, 1. Since the radius (r) of carbon nanotube are several nm, the magnetic field (H) induced by the current (1) in carbon nanotube is about one thousand times larger than that induced by the current in normal copper wire whose radius is about several gm. (H = I/2;zr) 2. According to the relation between magnetic field (I) in the inductor and inductance (L) of the inductor, 1/2 JPOH2dV = 1/2LI2, the large magnetic field (A) results in the large inductance (L). 3. Since the carbon nanotube can be bent with small curvature, the inductor made of carbon nanotube is smaller than the inductor made of copper or gold. In this paper, we have observed the large magnetic field induced by the small current in carbon nanotube using magnetic force microscope [31. The used carbon nanotube was made by laser ablation method. After the dispersing the carbon nanotube on the SiO 2/Si substrate, gold/nickel metal interconnects to the carbon nanotube. By applying the alternating current in carbon nanotube, we have obtained the images of synchronized component in the force signal using lock' in measurement. Since the images were the convolution of Kelvin force microscopy and magnetic force microscopy images, we extracted the magnetic field distribution using the symmetry difference between the magnetic and electric field. Observed magnetic fields were proportional to the amplitude of the alternating current. The estimated magnetic field near the carbon nanotube of 8 mT at 250 pA roughly agrees with the theoretical one. This magnetic field is also very large compared with that produced by the copper wire in the normal inductor. Since the inductance of 1.0 ,um long carbon nanotube is estimated to be about 1 pH, normalized inductance is found to be larger than that of normal inductance [21. Therefore, carbon nanotube inductors are promising passive electric component for the integrated circuit Reference [1]Y. Sakurada, S. Irako, Y. Nakajima, T. Hanajiri, K. Tsubaki, Ext. Abstr. (51st Spring meet 2004); Japan Society of Applied Physics and Related Societies, 29p-F-16. 121S. Irako, Y. Sakurada, Y. Nakajima, T. Hanajiri, T. Toyabe, K. Tsubaki, Ext. Abstr. (51st Spring meet. 2004); Japan Society of Applied Physics and Related Societies, 29p-F-15. 13]D. Saida and T. Takahashi, Jpn. J. Appl. Phys. Vol. 42, pp.4874, 2003.
为了进一步制造高性能集成电路,需要新的电子元件概念。新概念之一是将电感器集成到集成电路中。然而,将其纳入集成电路存在三维纳米制造技术上的困难,并且由于电感器导线直径大,导磁率为0 = 4 × 10-7 H/m的量小,影响较小。我们提出了用碳纳米管制作的电感器[1,2]。虽然所提出的电感器的制作仍然具有挑战性和许多问题,但所提出的电感器的优点如下:1。由于碳纳米管的半径r为几nm,因此电流(1)在碳纳米管中产生的磁场(H)比半径约为几gm的普通铜线中产生的磁场(H = I/2;zr) 2大1000倍左右。根据电感的磁场(I)与电感的电感量(L)的关系,1/2 JPOH2dV = 1/2LI2,磁场(A)越大,电感量(L)越大。由于碳纳米管可以弯曲成较小的曲率,因此碳纳米管制成的电感比铜或金制成的电感要小。在本文中,我们利用磁力显微镜观察到了碳纳米管中小电流所产生的大磁场[31]。采用激光烧蚀法制备了碳纳米管。将碳纳米管分散在sio2 /Si衬底上后,金/镍金属与碳纳米管互连。通过在碳纳米管中施加交流电流,我们通过锁相测量获得了力信号中同步分量的图像。由于图像是开尔文力显微镜和磁力显微镜图像的卷积,我们利用磁场和电场的对称差提取磁场分布。观察到的磁场与交流电的振幅成正比。在250 pA条件下,碳纳米管附近的磁场估计值与理论值基本一致。与普通电感器中的铜线产生的磁场相比,这个磁场也非常大。由于估计1.0 μ m长碳纳米管的电感约为1 pH,因此发现归一化电感大于正常电感[21]。因此,碳纳米管电感器是集成电路中很有前途的无源电子元件。樱田,中岛,花尻,Tsubaki, Ext.摘要(2004年第51届春季运动会);日本应用物理学会及相关学会,29p-F-16。121年代。伊拉子,樱田,中岛,花尻,Toyabe, Tsubaki, Ext.摘要第51届春季会议。2004);日本应用物理学会及相关学会,29p-F-15。13] D。Saida和T. Takahashi,日本。j:。理论物理。第42卷,第4874页,2003。
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引用次数: 3
Spin mosfets using ferromagnetic schottky barrier contacts for the source and drain 自旋mosfet采用铁磁肖特基势垒触点作为源极和漏极
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553124
S. Sugahara, M. Tanaka
Spin transistors, which utilize two ferromagnetic layers as a spin injector and as a spin detector, are very attractive as a basis for spin-electronic integrated circuits, owing to their additional spin degree of freedom in controlling output currents. In particular, recently proposed spin MOSFETs that are spin transistors analogous to MOSFETs are promising, since its prospected large current-drive capability, large magnetocurrent ratio, and compatibility with present MOS technology can lead to novel nonvolatile memory and reconfigurable logic architectures [1-3]. The spin MOSFETs can be classified by the structure of the source/drain and the source/drain material [1]. The simplest and most feasible way to realize a spin MOSFET is to replace the source/drain material of an Schottky barrier (SB) MOSFET with a ferromagnetic metal that forms a ferromagnetic Schottky junction with the Si channel (Fig.l). In this paper, we present the theoretical analysis and experimental demonstration of spin MOSFETs using a ferromagnetic metal for the SB source/drain. Fig.1 shows the structure of our model device used in the calculations. Assuming the ballistic transport of spin-polarized carriers in the nanometer-scale channel, the device performance was theoretically analyzed. Solid and dashed curves in Fig. 2 show calculated drain currents IDP and IDAP as a function of drain bias VDs in the parallel and antiparallel magnetization configurations, respectively, where gate bias VGS varied from 0.0 to 1.0 V in steps of 0.2 V. When the relative magnetization configuration of the source/drain is parallel, the spin MOSFET shows a large output current comparable to that of high performance MOSFETs, indicating the high transcondactance of the spin MOSFET. The output current for small VDS conditions (less than the pinch-off voltage) can be reduced by changing the relative magnetization of the source/drain from the parallel to antiparallel configuration. Figs. 3 and 4 show magnetocurrent ratio Nc [=(IDP-IDAP)/IDAP] as a function of VDs and VGS, respectively. Nc falls with increasing VDs, but it is enhanced with increasing VGS. These phenomena can be rationalized by spin dependent transport similar to the tunneling magnetoresistance effect and the gate-induced enhancement of spin injection efficiency [1]. The SB height SB of the source/drain is important to obtain large output currents and also large Nc. IDP dramatically increases with decreasing S5B in comparison with IDAP, and thus Nc increases with decreasing B, as shown in Fig. 5. This means that IDP and Nc can simultaneously increase without any trade-off, which is important for spin-electronic integrated circuit applications. In order to demonstrate the transistor action of a spin MOSFET using a ferromagnetic metal for the SB source/drain, a prototypic spin MOSFET was fabricated by using ferromagnetic silicide Fe,-1Si,. A bottom-gate structure with a SOI substrate was employed for simplicity, where the buried oxide and
自旋晶体管利用两个铁磁层作为自旋注入器和自旋探测器,由于其在控制输出电流方面具有额外的自旋自由度,因此作为自旋电子集成电路的基础非常有吸引力。特别是,最近提出的自旋mosfet是一种类似于mosfet的自旋晶体管,由于其预期的大电流驱动能力,大磁流比,以及与现有MOS技术的兼容性,可以导致新的非易失性存储器和可重构逻辑架构[1-3]。自旋mosfet可根据源极/漏极结构和源极/漏极材料进行分类[1]。实现自旋MOSFET的最简单和最可行的方法是用铁磁性金属取代肖特基势垒(SB) MOSFET的源极/漏极材料,与Si沟道形成铁磁性肖特基结(图1)。本文对自旋mosfet进行了理论分析和实验证明,该器件采用铁磁金属作为SB源极/漏极。图1显示了我们在计算中使用的模型装置的结构。假设自旋极化载流子在纳米尺度通道内的弹道输运,对器件性能进行了理论分析。图2中的实线和虚线分别显示了平行和反平行磁化配置下计算漏极电流IDP和IDAP作为漏极偏置VDs的函数,其中栅极偏置VGS以0.2 V的阶跃从0.0到1.0 V变化。当源极/漏极的相对磁化配置为并联时,自旋MOSFET显示出与高性能MOSFET相当的大输出电流,这表明自旋MOSFET具有高跨电性。小VDS条件下的输出电流(小于引脚电压)可以通过将源极/漏极的相对磁化强度从并联改变为反并联来减小。图3和图4分别显示了磁流比Nc [=(IDP-IDAP)/IDAP]与VDs和VGS的关系。Nc随VDs的增加而下降,但随VGS的增加而增强。这些现象可以通过类似于隧道磁阻效应的自旋相关输运和栅极诱导的自旋注入效率增强来合理化[1]。源极/漏极的SB高度SB对于获得大输出电流和大Nc非常重要。与IDAP相比,IDP随着S5B的减小而急剧增大,因此Nc随着B的减小而增大,如图5所示。这意味着IDP和Nc可以同时增加而没有任何权衡,这对于自旋电子集成电路应用非常重要。为了证明使用铁磁性金属作为SB源极/漏极的自旋MOSFET的晶体管作用,用铁磁性硅化物Fe,-1Si,制作了一个自旋MOSFET的原型。为了简单起见,采用了带有SOI衬底的底栅结构,其中埋藏的氧化物和Si衬底分别用作栅极电介质和栅极电极(图6)。采用电阻率为10-20 Q-cm的p型(001)SOI晶圆作为衬底。SOI厚度为50nm。利用sio2硬掩膜确定通道区域,然后通过电子束蒸发在SOI表面沉积70 nm厚的Fe层。通过快速退火(RTA),在N2环境下,在700C下加热4min,形成Fe,-,Si。最后,对器件进行了台面隔离,确定了有源区域。制备的自旋MOSFET的物理栅长和宽度分别为1.6 gm和10 gm(图7)。制备的Fe1 xSi,/Si结具有明显的肖特基二极管特性,初步实验发现p型Si的肖特基势垒高度估计小于0.2 eV。图8显示了制作的自旋MOSFET的输出特性,其中栅极偏置VGS以5 V的阶跃从0到25 V变化。输出特性表现为p型场效应管的反沟道模式工作。应用负VGS和VDS也观察到积累通道模式的运作。这些结果表明所制备的自旋MOSFET可以作为SB型MOSFET工作。在本次会议上,我们将详细介绍所制备的自旋MOSET的磁性输运特性。[1]李志刚,《电路、器件与系统》。[2]杨志刚,《中国农业科学》。理论物理。[3]陈志强,陈志强。理论物理。Lett. 84(2004) 2307。
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引用次数: 4
Cobalt silicide nanocrystal memory 硅化钴纳米晶存储器
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553077
D. Zhao, Yan Zhu, Ruigang Li, Jianlin Liu
Nonvolatile Si nanocrystal memory is fast approaching commercialization. In order to extend the scaling limits, many kinds of nanocrystals or device architectures were used to replace Si nanocrystals. In this work, we report for the first time the experimental demonstration of a nonvolatile memory device using cobalt silicide nanocrystals as floating gates. The band diagram is shown in Fig. 1 (a). There are at least two advantage of using cobalt silicide nanocrystal over Si nanocrystal: first, cobalt silicide is a metallic material and its band edges for conduction and valence bands are all lower than those of the Si [1], which helps both electron and hole retentions. Second, cobalt silicide can be grown on Si nanocrystal plus a rapid thermal annealing (RTP) [2]. The self-aligned silicide remains while the unreacted metal cobalt is removed in selective etchant. The device fabrication begins with a thermal oxide growth at 1000 °C for 4.5 minutes on a 4-inch n-type Si substrate, which leads to a tunneling oxide thickness ofabout 3 nm. Si nanocrystals were formed in a LPCVD furnace followed by a deposition of ultra thin Co metal in an e-beam evaporator. RTP is then performed in nitrogen to form silicide. The unreacted cobalt metal was removed in a selective. The control oxide (40 nm) was grown in another LPCVD furnace. A MOS capacitor is finally obtained after depositing and patterning the aluminum electrodes on frond and back sides of the sample. An SEM image of the CoSi2 nanocrystals on SiO2 is shown in Fig.1 (b).
非易失性硅纳米晶存储器正迅速走向商业化。为了扩大尺度限制,人们采用了多种纳米晶体或器件结构来取代硅纳米晶体。在这项工作中,我们首次报道了使用硅化钴纳米晶体作为浮栅的非易失性存储器件的实验演示。其能带图如图1 (a)所示。与硅纳米晶体相比,使用硅化钴纳米晶体至少有两个优点:首先,硅化钴是一种金属材料,其导电带和价带的能带边缘都低于硅[1],这有助于电子和空穴的保留。其次,硅化钴可以在硅纳米晶上生长,并进行快速热退火(RTP)[2]。在选择性蚀刻剂中除去未反应的金属钴,保留自对准硅化物。该器件的制造始于在4英寸n型Si衬底上在1000°C下生长4.5分钟的热氧化物,这导致隧道氧化物厚度约为3nm。在LPCVD炉中形成硅纳米晶体,然后在电子束蒸发器中沉积超薄钴金属。然后在氮气中进行RTP以形成硅化物。未反应的钴金属被选择性地去除。对照氧化物(40 nm)在另一个LPCVD炉中生长。在样品的正面和背面沉积铝电极并进行图案化后,最终得到MOS电容器。CoSi2纳米晶体在SiO2上的SEM图像如图1 (b)所示。
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引用次数: 1
Analytic expression and approach for low subthreshold-swing tunnel transistors 低亚阈值摆动隧道晶体管的解析表达式与方法
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553102
Qin Zhang, Wei Zhao, A. Seabaugh
Recent experimental demonstrations of interband tunnel transistors by Appenzeller [1], in carbon nanotubes, and simulations by Bhuwalka [2], of vertical Si/SiGe p-i-n interband tunnel transistors show that subthreshold swings of 40 mV/decade or less can be achieved in tunneling transistors. We derive here, a simple analytic expression for the subthreshold swing in tunnel transistors which shows that there are two physical mechanisms in tunnel transistors which can be optimized to achieve low subthreshold swings. Extending from this analysis we propose a new silicon-on-insulator tunnel transistor to achieve low subthreshold swing toward significantly lowering power in digital logic devices.
最近Appenzeller[1]在碳纳米管中对带间隧道晶体管进行的实验演示,以及Bhuwalka[2]对垂直Si/SiGe p-i-n带间隧道晶体管的模拟表明,在隧道晶体管中可以实现40 mV/ 10年或更小的亚阈值振荡。本文推导了隧道晶体管亚阈值振荡的简单解析表达式,表明隧道晶体管中有两种物理机制可以优化以实现低亚阈值振荡。在此基础上,我们提出了一种新的绝缘体上硅隧道晶体管,以实现低亚阈值摆幅,从而显著降低数字逻辑器件的功耗。
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引用次数: 29
Optimization of a redox protein-carbon nanotube conjugate biosensor by siteselective binding 位点选择性结合优化氧化还原蛋白-碳纳米管共轭生物传感器
Pub Date : 2005-06-20 DOI: 10.1109/DRC.2005.1553087
G. Withey, A. Lazareck, M. Tzolov, A. Yin, P. Aich, Joanne I. Yeh, J.M. Xu
We report on a redox protein highly ordered carbon nanotube (CNT) array conjugate system that exhibits an exceptionally high level of bioelectrocatalytic activity. The performance of the conjugated system is dependent upon site-selective placement of the protein on the nanotube. Enzymes immobilized on the nanotube tip have generated electrical biosignals more than 60 times greater than enzymes bound to the nanotube side walls, and have shown electron transfer rates on the order of 1500 sQ1. The substrate concentration dependence of the bioelectrocatalytic signal was measured by CV, and a detection limit in the single micromolar range was achieved. We conclude that the covalent attachment of redox enzymes to CNT tips enhances electron transfer efficiency by orders of magnitude when compared to side-wall adsorption, and that the resulting system enables real-time monitoring ofbiomolecular activities. The nanoelectronic platform that has enabled this novel course of study is a hexagonally ordered array of aligned multi-walled carbon nanotubes (MWNTs). Unique features of this array critical to this study include identical exposed nanotube length across the entire array, highly regular center-to-center CNT spacing, and electrical insulation of individual nanotubes within an aluminum oxide nanopore array. This configuration of nanotubes allows us to differentiate between the two distinctly different regions of the CNTs: the side walls which are highly hydrophobic and amenable to protein adsorption, and the tips that are easily oxidized and can be covalently modified with enzymes by carboxyl-amine coupling. We have exploited these properties to independently study the bioelectrocatalytic activity of enzymes bound to the two regions. A CNT array electrode was first treated with the surfactant arabic gum (GA) to prevent protein adsorption to the side wall and then the enzyme glucose oxidase (GOx) was covalently bound to the nanotube tips. On another sample, the nanotube tips were capped with ethanolamine to remove any free carboxylic acid groups, and then GOx was adsorbed to the protein sidewall. Gold nanoparticle labeling experiments were used to visually confirm the successful selective immobilization of GOx at the CNT tips, and an ELISA was performed to quantify the extent of enzyme coverage on the tips and on the side walls. We determined there to be more than 60 times more protein adsorbed to the side walls than GOx covalently linked to the CNT tips. Cyclic voltammetry (CV) measurements revealed the current density of each sample to be nearly the same (-l20±A*cm-2). This means that each enzyme bound to the CNT tip is contributing, on average, more than 60 times the electrical signal as GOx adsorbed to the nanotube side wall. A saturation assay was then performed to determine the unimolecular electron transfer rate (kET) of the tip-bound GOx-CNT conjugate system. Based on the peak current density (330pA*cm2) and the surface enzyme coverage determined
我们报道了一种氧化还原蛋白高度有序碳纳米管(CNT)阵列偶联系统,该系统显示出异常高水平的生物电催化活性。共轭体系的性能取决于蛋白质在纳米管上的位置选择。固定在纳米管尖端的酶产生的电信号比固定在纳米管侧壁上的酶大60倍以上,并且显示出1500 sQ1的电子传递速率。利用CV法测定了生物电催化信号对底物浓度的依赖关系,并获得了单微摩尔范围内的检测限。我们得出结论,与侧壁吸附相比,氧化还原酶与碳纳米管尖端的共价附着提高了几个数量级的电子传递效率,并且由此产生的系统能够实时监测生物分子活动。纳米电子平台是一个六边形排列有序的多壁碳纳米管(MWNTs)阵列,它使这一新颖的研究过程成为可能。该阵列的独特特征对本研究至关重要,包括整个阵列中相同的暴露纳米管长度,高度规则的中心到中心碳纳米管间距,以及氧化铝纳米孔阵列中单个纳米管的电绝缘。纳米管的这种结构使我们能够区分碳纳米管的两个截然不同的区域:高度疏水且易于蛋白质吸附的侧壁,以及易于氧化且可通过羧基胺偶联与酶共价修饰的尖端。我们利用这些特性来独立研究结合这两个区域的酶的生物电催化活性。首先用表面活性剂阿拉伯胶(GA)处理碳纳米管阵列电极,以防止蛋白质吸附在侧壁上,然后将葡萄糖氧化酶(GOx)共价结合到纳米管尖端。在另一个样品上,用乙醇胺覆盖纳米管尖端以去除任何游离的羧基,然后将GOx吸附在蛋白质侧壁上。采用金纳米颗粒标记实验直观地证实了GOx在碳纳米管尖端的成功选择性固定,并采用ELISA法量化酶在尖端和侧壁上的覆盖程度。我们确定,与碳纳米管尖端共价连接的GOx相比,侧壁上吸附的蛋白质要多60倍以上。循环伏安法(CV)测量表明,两种样品的电流密度几乎相同(- 120±A*cm-2)。这意味着,与碳纳米管尖端结合的每一种酶,平均贡献的电信号是吸附在纳米管侧壁上的氧化石墨烯的60倍以上。然后进行饱和分析以确定尖端结合的GOx-CNT共轭体系的单分子电子转移速率(kET)。根据峰值电流密度(330pA*cm2)和使用ELISA测定的表面酶覆盖率(1 × 10-12 mol. cm2),我们使用先前建立的方法计算出了1500s-1的kET。这一比率高于体内GOx的既定比率2。有几个因素可能导致这一异常高的比率。首先,碳纳米管尖端共价键的性质使得蛋白质构象受到的压力最小,因此酶应保留其完整的生物电催化功能。此外,由于碳纳米管与相邻的碳纳米管是绝缘的,因此在CV测量过程中施加的任何电压都会在纳米管尖端产生最大的电场,并且碳纳米管将本质上作为有效电子传导的避雷针。如此高的电子转移率使这种酶-碳纳米管缀合物成为理想的生物传感系统。为了量化依赖于该共轭系统的生物传感器的潜在灵敏度和检测限,在低葡萄糖浓度的CNT阵列样品上进行了进一步的CV测量。检测到低至一微摩尔的能级,产生几十纳安培量级的信号。这已经优于其他基于酶的生物传感器系统,通常不会冒险低于毫摩尔范围。然而,通过使用能够测量皮安范围内电流的安培计,这个极限甚至可以进一步被推到更低的纳摩尔水平。这些GOx-CNT电极共轭生物传感器非常坚固,在50mM磷酸钠缓冲液(pH 7.0)中在4°C下储存两周后仅损失10%的活性,一个月后损失50%,每天测量一次。[1]肖宇,等。科学2003,299,1877 -1881。[2]张晓明,李晓明。J。化学。社会科学学报,1993,15,12264-12269。
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63rd Device Research Conference Digest, 2005. DRC '05.
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