Pub Date : 2025-01-08DOI: 10.1016/j.matt.2024.10.021
Shao-Fei Wu, Guo-Liang An, Wei-Guo Pan, Ting Yan, Li-Wei Wang
Heat transformation and storage based on the solid sorption principle, as a prospective sustainable and carbon-neutral technology, possesses significant potential for renewable energy utilization and carbon footprint reduction. However, the water and alcohols cannot adapt to critical conditions of low evaporation and high condensation temperatures, thus limiting the efficient utilization of thermal energy. This critical issue could be mitigated by engineering a transformative sorption working pair, known as a metal-organic framework (MOF)-ammonia working pair, which can reversibly convert solar-thermal energy to chemical energy and thermodynamic potential energy, enabled by the sorption and desorption processes. This perspective examines the feasibility and challenges of MOFs in saturated ammonia sorption for thermal energy utilization, such as refrigeration, ice making, heat pumps, and thermal energy storage. We discuss the evaluation and selection criteria for high-stability MOFs, the design of thermodynamic cycles, and performance assessments. Finally, this article also provides an ingenious insight into the potential applications of MOF-ammonia working pairs and proposes future research directions and solutions to advance the carbon neutrality vision.
{"title":"Emerging working pairs of MOF-ammonia for sustainable heat transformation and storage","authors":"Shao-Fei Wu, Guo-Liang An, Wei-Guo Pan, Ting Yan, Li-Wei Wang","doi":"10.1016/j.matt.2024.10.021","DOIUrl":"https://doi.org/10.1016/j.matt.2024.10.021","url":null,"abstract":"Heat transformation and storage based on the solid sorption principle, as a prospective sustainable and carbon-neutral technology, possesses significant potential for renewable energy utilization and carbon footprint reduction. However, the water and alcohols cannot adapt to critical conditions of low evaporation and high condensation temperatures, thus limiting the efficient utilization of thermal energy. This critical issue could be mitigated by engineering a transformative sorption working pair, known as a metal-organic framework (MOF)-ammonia working pair, which can reversibly convert solar-thermal energy to chemical energy and thermodynamic potential energy, enabled by the sorption and desorption processes. This perspective examines the feasibility and challenges of MOFs in saturated ammonia sorption for thermal energy utilization, such as refrigeration, ice making, heat pumps, and thermal energy storage. We discuss the evaluation and selection criteria for high-stability MOFs, the design of thermodynamic cycles, and performance assessments. Finally, this article also provides an ingenious insight into the potential applications of MOF-ammonia working pairs and proposes future research directions and solutions to advance the carbon neutrality vision.","PeriodicalId":388,"journal":{"name":"Matter","volume":"23 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-08DOI: 10.1016/j.matt.2024.11.010
Geoffrey Ozin
While the configurational entropy of a multi-element solid solution material contributes to its thermodynamic stability, by contrast, its performance as a heterogeneous catalyst depends on the kinetics of converting reactants to products. This calls into question whether a kinetic advantage originates in a high-entropy effect or a combinatorial means of optimizing surface chemistry and catalysis.
{"title":"High entropy or combinatorial heterogeneous catalysis?","authors":"Geoffrey Ozin","doi":"10.1016/j.matt.2024.11.010","DOIUrl":"https://doi.org/10.1016/j.matt.2024.11.010","url":null,"abstract":"While the configurational entropy of a multi-element solid solution material contributes to its thermodynamic stability, by contrast, its performance as a heterogeneous catalyst depends on the kinetics of converting reactants to products. This calls into question whether a kinetic advantage originates in a high-entropy effect or a combinatorial means of optimizing surface chemistry and catalysis.","PeriodicalId":388,"journal":{"name":"Matter","volume":"100 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-08DOI: 10.1016/j.matt.2024.11.017
Larrin Thomas
The development of steel traces its roots through knives and Damascus steel. Larrin Thomas became a metallurgist after meeting many knifemakers and the metallurgists who developed steel for the knife industry. Knives continue to inspire new materials scientists.
{"title":"I’m a metallurgist because of Damascus steel","authors":"Larrin Thomas","doi":"10.1016/j.matt.2024.11.017","DOIUrl":"https://doi.org/10.1016/j.matt.2024.11.017","url":null,"abstract":"The development of steel traces its roots through knives and Damascus steel. Larrin Thomas became a metallurgist after meeting many knifemakers and the metallurgists who developed steel for the knife industry. Knives continue to inspire new materials scientists.","PeriodicalId":388,"journal":{"name":"Matter","volume":"30 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-08DOI: 10.1016/j.matt.2024.11.015
Qian Wang, Changqing Qin, Chong Bai, Desheng Kong
Washability is essential for textile electronics to meet the demands of daily use. In this preview, we highlight textile-based electrochemical biosensors that incorporate moisture-resistant nanoflakes into ion-selective membranes, leading to substantially improved sensitivity and durability. These devices are integrated into a textile wristband designed for analyzing sweat biomarkers. Notably, they retain over 90% sensing capabilities for sodium, potassium, and protons even after 20 simulated washing cycles. This study marks a significant advancement toward washable and durable textile electronics for real-world applications.
{"title":"Development of washable biosensors for practical textile electronics","authors":"Qian Wang, Changqing Qin, Chong Bai, Desheng Kong","doi":"10.1016/j.matt.2024.11.015","DOIUrl":"https://doi.org/10.1016/j.matt.2024.11.015","url":null,"abstract":"Washability is essential for textile electronics to meet the demands of daily use. In this preview, we highlight textile-based electrochemical biosensors that incorporate moisture-resistant nanoflakes into ion-selective membranes, leading to substantially improved sensitivity and durability. These devices are integrated into a textile wristband designed for analyzing sweat biomarkers. Notably, they retain over 90% sensing capabilities for sodium, potassium, and protons even after 20 simulated washing cycles. This study marks a significant advancement toward washable and durable textile electronics for real-world applications.","PeriodicalId":388,"journal":{"name":"Matter","volume":"20 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The introduction of foreign ions, atoms, or molecules into emerging functional materials is crucial for manipulating the physical properties of materials and innovating device applications. The intercalation of emerging new materials can induce multiple intrinsic changes, such as charge doping, chemical bonding, and lattice expansion, which facilitate the exploration of structural phase transformations, the tuning of symmetry-breaking-related physics, and the creation of brain-inspired advanced devices. Moreover, incorporating various hosts and intercalants enables a series of crystal structures with a rich spectrum of characteristics, greatly expanding the scope and fundamental understanding of existing materials. Here, we summarize typically used methods for the intercalation of functional materials. We highlight recent progress in intercalation-based phase transitions and their emerging physics (i.e., ferroelectric, magnetic, insulator-metal, superconducting, and charge-density-wave phase transitions). We discuss prospective device applications for intercalation-based phase transitions (i.e., neuromorphic devices). Finally, we provide potential future research lines for promoting further development of intercalation-based phase transitions.
{"title":"Intercalation of functional materials with phase transitions for neuromorphic applications","authors":"Xin He, Hua Wang, Jian Sun, Xixiang Zhang, Kai Chang, Fei Xue","doi":"10.1016/j.matt.2024.10.011","DOIUrl":"https://doi.org/10.1016/j.matt.2024.10.011","url":null,"abstract":"The introduction of foreign ions, atoms, or molecules into emerging functional materials is crucial for manipulating the physical properties of materials and innovating device applications. The intercalation of emerging new materials can induce multiple intrinsic changes, such as charge doping, chemical bonding, and lattice expansion, which facilitate the exploration of structural phase transformations, the tuning of symmetry-breaking-related physics, and the creation of brain-inspired advanced devices. Moreover, incorporating various hosts and intercalants enables a series of crystal structures with a rich spectrum of characteristics, greatly expanding the scope and fundamental understanding of existing materials. Here, we summarize typically used methods for the intercalation of functional materials. We highlight recent progress in intercalation-based phase transitions and their emerging physics (i.e., ferroelectric, magnetic, insulator-metal, superconducting, and charge-density-wave phase transitions). We discuss prospective device applications for intercalation-based phase transitions (i.e., neuromorphic devices). Finally, we provide potential future research lines for promoting further development of intercalation-based phase transitions.","PeriodicalId":388,"journal":{"name":"Matter","volume":"79 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-08DOI: 10.1016/j.matt.2024.10.017
Zhaoyu Ma, Kai Zhang, Yanli Zhao
By fusing biomimetic strategies with functional materials, engineered biomimetic materials have become an emerging trend in cancer therapy. It is vital for therapeutic agents to reverse the "enemy state" to a "camouflaged state" to evade the host’s own immune system, which is one of the main challenges in clinical medicine. Engineered biomimetic materials are endowed with biological functions such as good biocompatibility, tumor specificity, long circulation, immune escape, tumor infiltration, and microenvironmental modulation, thus providing insights into precision oncology therapy. In this review, we highlight the recent research progress in the design and application of engineered biomimetic materials in cancer therapy. We summarize the advancements of biomimetic strategies from microscopic to macroscopic levels, including systems based on biomolecules, biomembranes, microorganisms, and individual organisms. Foreseeable challenges to and prospects for this direction in future research and clinical translation are also discussed, aiming to expand the applications of biomimetic materials in biomedicine.
{"title":"Strategies for engineering biomimetic materials for tumor therapy","authors":"Zhaoyu Ma, Kai Zhang, Yanli Zhao","doi":"10.1016/j.matt.2024.10.017","DOIUrl":"https://doi.org/10.1016/j.matt.2024.10.017","url":null,"abstract":"By fusing biomimetic strategies with functional materials, engineered biomimetic materials have become an emerging trend in cancer therapy. It is vital for therapeutic agents to reverse the \"enemy state\" to a \"camouflaged state\" to evade the host’s own immune system, which is one of the main challenges in clinical medicine. Engineered biomimetic materials are endowed with biological functions such as good biocompatibility, tumor specificity, long circulation, immune escape, tumor infiltration, and microenvironmental modulation, thus providing insights into precision oncology therapy. In this review, we highlight the recent research progress in the design and application of engineered biomimetic materials in cancer therapy. We summarize the advancements of biomimetic strategies from microscopic to macroscopic levels, including systems based on biomolecules, biomembranes, microorganisms, and individual organisms. Foreseeable challenges to and prospects for this direction in future research and clinical translation are also discussed, aiming to expand the applications of biomimetic materials in biomedicine.","PeriodicalId":388,"journal":{"name":"Matter","volume":"67 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-20DOI: 10.1016/j.matt.2024.11.031
Zhilin Ren, Juraj Ovčar, Tik Lun Leung, Yanling He, Yin Li, Dongyang Li, Xinshun Qin, Hongbo Mo, Zhengtian Yuan, Jueming Bing, Martin P. Bucknall, Luca Grisanti, Muhammad Umair Ali, Peng Bai, Tao Zhu, Ali Ashger Syed, Jingyang Lin, Jingbo Wang, Abdul Khaleed, Wenting Sun, Aleksandra B. Djurišić
2D metal halide perovskites have enabled significant stability improvements in perovskite devices, particularly in resistance to moisture. However, some 2D perovskites are even more susceptible to photooxidation compared to 3D perovskites. This is particularly true for more commonly investigated Ruddlesden-Popper (RP) perovskites, which exhibit increased susceptibility to photoinduced degradation compared to Dion-Jacobson (DJ) perovskites. Comparisons between different RP and DJ perovskites reveal that this phenomenon cannot be explained by commonly proposed differences in superoxide ion generation, interlayer distance, or lattice structural rigidity differences. Instead, the resistance to photooxidation of DJ perovskites can be attributed to a decreased likelihood of double deprotonation events (compared to single deprotonation events in RP perovskites) required for the loss of organic cations and perovskite decomposition. Consequently, DJ perovskites are less susceptible to oxidative degradation (induced both photo- and electrochemically), which leads to improved operational stability of solar cells based on these materials.
{"title":"Increased resistance to photooxidation in Dion-Jacobson lead halide perovskites: Implication for perovskite device stability","authors":"Zhilin Ren, Juraj Ovčar, Tik Lun Leung, Yanling He, Yin Li, Dongyang Li, Xinshun Qin, Hongbo Mo, Zhengtian Yuan, Jueming Bing, Martin P. Bucknall, Luca Grisanti, Muhammad Umair Ali, Peng Bai, Tao Zhu, Ali Ashger Syed, Jingyang Lin, Jingbo Wang, Abdul Khaleed, Wenting Sun, Aleksandra B. Djurišić","doi":"10.1016/j.matt.2024.11.031","DOIUrl":"https://doi.org/10.1016/j.matt.2024.11.031","url":null,"abstract":"2D metal halide perovskites have enabled significant stability improvements in perovskite devices, particularly in resistance to moisture. However, some 2D perovskites are even more susceptible to photooxidation compared to 3D perovskites. This is particularly true for more commonly investigated Ruddlesden-Popper (RP) perovskites, which exhibit increased susceptibility to photoinduced degradation compared to Dion-Jacobson (DJ) perovskites. Comparisons between different RP and DJ perovskites reveal that this phenomenon cannot be explained by commonly proposed differences in superoxide ion generation, interlayer distance, or lattice structural rigidity differences. Instead, the resistance to photooxidation of DJ perovskites can be attributed to a decreased likelihood of double deprotonation events (compared to single deprotonation events in RP perovskites) required for the loss of organic cations and perovskite decomposition. Consequently, DJ perovskites are less susceptible to oxidative degradation (induced both photo- and electrochemically), which leads to improved operational stability of solar cells based on these materials.","PeriodicalId":388,"journal":{"name":"Matter","volume":"41 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142858056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-20DOI: 10.1016/j.matt.2024.11.032
Liquan Pi, Erik Björklund, Gregory J. Rees, Weixin Song, Chen Gong, John-Joseph Marie, Xiangwen Gao, Shengda D. Pu, Mikkel Juelsholt, Philip A. Chater, Joohyuk Park, Min Gyu Kim, Jaewon Choi, Stefano Agrestini, Mirian Garcia-Fernandez, Ke-Jin Zhou, Alex W. Robertson, Robert S. Weatherup, Robert A. House, Peter G. Bruce
Disordered rocksalt cathodes deliver high energy densities, but they suffer from pronounced capacity and voltage fade on cycling. Here, we investigate fade using two disordered rocksalt lithium manganese oxyfluorides: Li3Mn2O3F2 (Li1.2Mn0.8O1.2F0.8), which stores charge by Mn2+/Mn4+ redox, and Li2MnO2F, where charge storage involves both Mn3+/Mn4+ and oxygen redox (O-redox). Li3Mn2O3F2 is reported for the first time. We identify the growth of an electronically resistive surface layer with cycling that is present in both Li2MnO2F and Li3Mn2O3F2 but more pronounced in the presence of O-redox. This resistive surface inhibits electronic contact between particles, leading to the observed voltage polarization and capacity loss. By increasing carbon loading in the composite cathode, it is possible to substantially improve the cycling performance. These results help to disentangle O-redox from other leading causes of capacity fading in Mn oxyfluorides and highlight the importance of maintaining electronic conductivity in improving capacity and voltage retention.
{"title":"Factors affecting capacity and voltage fading in disordered rocksalt cathodes for lithium-ion batteries","authors":"Liquan Pi, Erik Björklund, Gregory J. Rees, Weixin Song, Chen Gong, John-Joseph Marie, Xiangwen Gao, Shengda D. Pu, Mikkel Juelsholt, Philip A. Chater, Joohyuk Park, Min Gyu Kim, Jaewon Choi, Stefano Agrestini, Mirian Garcia-Fernandez, Ke-Jin Zhou, Alex W. Robertson, Robert S. Weatherup, Robert A. House, Peter G. Bruce","doi":"10.1016/j.matt.2024.11.032","DOIUrl":"https://doi.org/10.1016/j.matt.2024.11.032","url":null,"abstract":"Disordered rocksalt cathodes deliver high energy densities, but they suffer from pronounced capacity and voltage fade on cycling. Here, we investigate fade using two disordered rocksalt lithium manganese oxyfluorides: Li<sub>3</sub>Mn<sub>2</sub>O<sub>3</sub>F<sub>2</sub> (Li<sub>1.2</sub>Mn<sub>0.8</sub>O<sub>1.2</sub>F<sub>0.8</sub>), which stores charge by Mn<sup>2+</sup>/Mn<sup>4+</sup> redox, and Li<sub>2</sub>MnO<sub>2</sub>F, where charge storage involves both Mn<sup>3+</sup>/Mn<sup>4+</sup> and oxygen redox (O-redox). Li<sub>3</sub>Mn<sub>2</sub>O<sub>3</sub>F<sub>2</sub> is reported for the first time. We identify the growth of an electronically resistive surface layer with cycling that is present in both Li<sub>2</sub>MnO<sub>2</sub>F and Li<sub>3</sub>Mn<sub>2</sub>O<sub>3</sub>F<sub>2</sub> but more pronounced in the presence of O-redox. This resistive surface inhibits electronic contact between particles, leading to the observed voltage polarization and capacity loss. By increasing carbon loading in the composite cathode, it is possible to substantially improve the cycling performance. These results help to disentangle O-redox from other leading causes of capacity fading in Mn oxyfluorides and highlight the importance of maintaining electronic conductivity in improving capacity and voltage retention.","PeriodicalId":388,"journal":{"name":"Matter","volume":"35 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142858095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-20DOI: 10.1016/j.matt.2024.11.030
Jian-Xin Wang, Tengjiao He, Osama Shekhah, Luis Gutiérrez-Arzaluz, Esma Ugur, Simil Thomas, Youdong Cheng, Xin Zhu, Hao Jiang, Tengyue He, Lijie Wang, Jiangtao Jia, Stefaan De Wolf, Husam N. Alshareef, Osman M. Bakr, Mohamed Eddaoudi, Omar F. Mohammed
In the field of X-ray imaging, innovative techniques using continuous screens composed of pure scintillation materials provide promising avenues to achieve high spatial resolution and cost effectiveness while reshaping future X-ray imaging technologies. Here, we present a versatile approach based on in situ electrochemical-directed synthesis for the growth of uniform polycrystalline metal-organic framework (MOF) thin films that are tailored for X-ray imaging. Through this electrochemical process, a series of continuous MOF thin films were successfully synthesized and deposited using interconnected lanthanides as the metal centers and terephthalic acid as the organic linkers. Notably, Tb-terephthalate MOF thin films were revealed as excellent materials that enable ultrahigh-resolution X-ray imaging. This achievement is attributed to improved material density and a significant reduction in light scattering. Remarkably, this MOF thin film surpassed most reported organic and inorganic scintillators, achieving an X-ray imaging resolution of 32 line pairs per millimeter.
{"title":"In situ electrochemical deposition of compact metal-organic framework thin films for high-resolution X-ray imaging","authors":"Jian-Xin Wang, Tengjiao He, Osama Shekhah, Luis Gutiérrez-Arzaluz, Esma Ugur, Simil Thomas, Youdong Cheng, Xin Zhu, Hao Jiang, Tengyue He, Lijie Wang, Jiangtao Jia, Stefaan De Wolf, Husam N. Alshareef, Osman M. Bakr, Mohamed Eddaoudi, Omar F. Mohammed","doi":"10.1016/j.matt.2024.11.030","DOIUrl":"https://doi.org/10.1016/j.matt.2024.11.030","url":null,"abstract":"In the field of X-ray imaging, innovative techniques using continuous screens composed of pure scintillation materials provide promising avenues to achieve high spatial resolution and cost effectiveness while reshaping future X-ray imaging technologies. Here, we present a versatile approach based on <em>in situ</em> electrochemical-directed synthesis for the growth of uniform polycrystalline metal-organic framework (MOF) thin films that are tailored for X-ray imaging. Through this electrochemical process, a series of continuous MOF thin films were successfully synthesized and deposited using interconnected lanthanides as the metal centers and terephthalic acid as the organic linkers. Notably, Tb-terephthalate MOF thin films were revealed as excellent materials that enable ultrahigh-resolution X-ray imaging. This achievement is attributed to improved material density and a significant reduction in light scattering. Remarkably, this MOF thin film surpassed most reported organic and inorganic scintillators, achieving an X-ray imaging resolution of 32 line pairs per millimeter.","PeriodicalId":388,"journal":{"name":"Matter","volume":"50 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142858096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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