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Unlocking hidden battery mechanistic insights: A novel mechano-electrochemical impedance spectroscopy approach 解锁隐藏的电池机理:一种新的机械电化学阻抗谱方法
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102603
Hang Hu , Shengyu Tao
Mechano-electrochemical signals are vital for battery diagnostics but have lacked direct interpretability for chemical experts. Fang et al. introduce mechano-electrochemical impedance spectroscopy (MEIS), a frequency-domain framework that decodes mechanical responses. This technique links mechanical response to electrochemical level ion dynamics, unlocking a powerful, interpretable new dimension for assessing broader energy storage systems.
机械电化学信号对电池诊断至关重要,但化学专家缺乏直接的可解释性。Fang等人介绍了机械电化学阻抗谱(MEIS),这是一种解码机械响应的频域框架。这项技术将机械反应与电化学水平的离子动力学联系起来,为评估更广泛的储能系统解锁了一个强大的、可解释的新维度。
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引用次数: 0
Lightweight and robust cellulosic triboelectric aerogels: Design, properties, and applications 轻质、坚固的纤维素摩擦电气凝胶:设计、性能和应用
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102415
Lixin Zhang , Bin Luo , Jinlong Wang , Tao Liu , Mingchao Chi , Chenchen Cai , Shuangxi Nie
With technological advancements, the demand for self-powered wearable electronics continues to grow. However, conventional triboelectric materials face a trade-off between lightweight properties and robustness, limiting their application in wearable electronics. The flexible and efficient cellulosic triboelectric aerogel, demonstrating remarkable advantages in unifying lightweight and robust properties, has emerged as an ideal candidate. This review summarizes recent advances in lightweight and robust cellulosic triboelectric aerogels. The unique advantages of cellulosic triboelectric aerogels are discussed. The design strategies for cellulosic triboelectric aerogels are systematically summarized, including structural design and triboelectric performance enhancement. The applications of cellulosic triboelectric aerogels in self-powered portable electronics are outlined, including energy harvesting and self-powered sensing. Finally, future research directions for cellulosic triboelectric aerogels are discussed, including the study and modification of novel cellulose aerogels, device structural design and optimization, multifunctional integration, the development of implantable systems, and scalable manufacturing processes combined with advanced equipment.
随着技术的进步,对自供电可穿戴电子产品的需求持续增长。然而,传统的摩擦电材料面临着轻质性能和坚固性之间的权衡,限制了它们在可穿戴电子产品中的应用。柔性和高效的纤维素摩擦电气凝胶,在统一轻量化和坚固性方面表现出显着的优势,已成为理想的候选者。本文综述了近年来轻质、坚固的纤维素摩擦电气凝胶的研究进展。讨论了纤维素摩擦电气凝胶的独特优点。系统地总结了纤维素摩擦电气凝胶的设计策略,包括结构设计和摩擦电性能增强。概述了纤维素摩擦电气凝胶在自供电便携式电子设备中的应用,包括能量收集和自供电传感。最后,展望了纤维素摩擦电气凝胶的未来研究方向,包括新型纤维素气凝胶的研究与改性、器件结构设计与优化、多功能集成、可植入系统的开发以及与先进设备相结合的可扩展制造工艺。
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引用次数: 0
Rotational-bouncing nanomotors with atomic edges for lysosomal mechanoporation 用于溶酶体机械加工的具有原子边缘的旋转弹跳纳米马达
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102491
Feng Tao , Chenkai Sun , Yingze Li , Yingying Wang , Peng Ning , Xiaolei Chen , Donglei Yang , Rui Gao , Yuan Li , Chang Xu , Zihan Guo , Haotian Chen , Xing Fan , Li Peng , Cheng Lv , Xinjian Fan , Chang Chen , Yu Cheng
Nanomotors offer a promising strategy for cancer mechanotherapy by harnessing programmable motion to induce lysosomal mechanoporation. Although generating localized pressure in lysosomes is achievable via adjusting the size or assembly of nanomotors, applying high pressure at the sub-nanometer scale remains challenging. Herein, we present an atom-edged magnetic nanomotor (MagGO) coupled with a three-dimensional rotating fluctuating magnetic field (3D MF) for lysosomal mechanoporation. The MagGO integrates the 0.83 ± 0.06-nm monolayer graphene oxide and assembled cubic magnetic nanomotors, leveraging a sub-nanometer-scale rigid edge with high saturation magnetization. Compared with the rotation or oscillation motion of 19.3 ± 2.3-nm cubic nanomotors, the field programmed rotational-bouncing motion of MagGO increases the localized pressure by 8.1- to 37.5-fold. MagGO can be internalized in lysosomes and achieve mechanoporation via rotational-bouncing motion for cancer destruction. It overcomes the pressure generation limitation of conventional nanomotors, pioneering the design of sub-nanometer-scale nanomotors for precise mechanotherapy.
纳米马达利用可编程运动诱导溶酶体机械加工,为癌症机械治疗提供了一种很有前途的策略。虽然通过调整纳米马达的大小或组装可以在溶酶体中产生局部压力,但在亚纳米尺度上施加高压仍然具有挑战性。在此,我们提出了一种原子边缘磁性纳米马达(MagGO)与三维旋转波动磁场(3D MF)相结合,用于溶酶体机械加工。MagGO集成了0.83±0.06 nm单层氧化石墨烯和组装的立方磁性纳米电机,具有亚纳米级的刚性边缘和高饱和磁化强度。与19.3±2.3 nm立方纳米电机的旋转或振荡运动相比,MagGO的场编程旋转-弹跳运动使局部压力增加8.1- 37.5倍。MagGO可以内化在溶酶体中,并通过旋转弹跳运动实现对癌症破坏的机械作用。它克服了传统纳米马达产生压力的限制,开创了亚纳米级纳米马达用于精确机械治疗的设计。
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引用次数: 0
Matter 2025 editorial picks and 2026 anticipation 2025年的编辑选择和2026年的展望
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102611
Connor Wells , Yuqing Lin , Yan Li , Dominque Lungwitz , Steve Cranford
In this Matter of Opinion, the members of the editorial team at Matter each highlight two of their favorite articles from the prior year while looking ahead at planned events for 2026.
在这篇文章中,《Matter》的编辑团队成员在展望2026年的计划活动时,每人重点介绍了他们最喜欢的两篇前一年的文章。
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引用次数: 0
The art of the appeal 呼吁的艺术
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102521
Steve Cranford
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引用次数: 0
Evolution from topological Dirac metal to flat-band-induced antiferromagnet in layered KxNi4S2 (0 ≤ x ≤ 1) 层状KxNi4S2从拓扑Dirac金属到平带诱导反铁磁体的演化(0≤x≤1)
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102418
Hengdi Zhao , Xiuquan Zhou , Hyowon Park , Tianqi Deng , Brandon Wilfong , Alann P. Au II , Samuel E. Pate , Craig M. Brown , Hui Wu , Tushar Bhowmick , Tessa McNamee , Ravhi Kumar , Yu-Sheng Chen , Zhi-Li Xiao , Russell Hemley , Weizhao Cai , Shanti Deemyad , Duck-Young Chung , Stephan Rosenkranz , Mercouri G. Kanatzidis
Condensed matter systems with coexisting Dirac cones and flat bands and a switchable control between them within a single system are desirable but remarkably uncommon. Here, we report a layered quantum material system, KxNi4S2 (0 ≤ x ≤ 1), that simultaneously hosts both characteristics without involving typical Kagome/honeycomb lattices. Enabled by a topochemical K-deintercalation process, the Fermi surface can be fine-tuned continuously over a wide range of energies. Consequently, a non-magnetic Dirac-metal state with a topological nontrivial Z2 index of 1;(000), supported by first-principles calculations and high mobility up to 1,471 cm2V−1s−1, is observed on the K-rich x = 1 side, whereas a flat-band-induced antiferromagnetic state with TN up to 10.1 K emerges as the K-content approaches 0. The KxNi4S2 system offers a versatile platform for exploring emerging phenomena and underscores a viable pathway for in situ control of quantum materials dominated by Dirac cones, flat bands, and their interplay.
具有狄拉克锥和平带共存以及在单一系统中两者之间可切换控制的凝聚态系统是理想的,但非常罕见。在这里,我们报道了一种层状量子材料系统KxNi4S2(0≤x≤1),它同时具有这两种特性,而不涉及典型的Kagome/蜂窝晶格。通过拓扑化学k脱嵌过程,费米表面可以在很宽的能量范围内连续微调。因此,具有拓扑非平凡Z2指数为1的非磁性狄拉克-金属态;(000)得到第一性原理计算的支持,在富K的x = 1侧观察到高达1,471 cm2V−1s−1的高迁移率,而当K含量接近0时,出现了TN高达10.1 K的平带诱导反铁磁态。KxNi4S2系统为探索新兴现象提供了一个通用的平台,并强调了由狄拉克锥、平带及其相互作用主导的量子材料的原位控制的可行途径。
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引用次数: 0
Perturbing dynamics of active emulsions and their collectives 活性乳剂及其集体的扰动动力学
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102419
Muhammad Turab Ali Khan , Gaurav Gardi , Ren Hao Soon , Mingchao Zhang , Metin Sitti
Controlling fluidic flows in active droplets is crucial in developing intelligent models to understand and mimic single-celled microorganisms. Typically, these fluidic flows are affected by the interfacial dynamics of chemical agents. We found that these flows can be reconfigured by the mere presence of an anisotropic solid boundary embedded within active droplets. Spontaneous fluidic flows dynamically orient an embedded magnetic cluster, and the magnetic cluster, when realigned, causes these flows to reorient, thus providing control over the propulsion dynamics of chemotactic emulsions. When continuously perturbed, achiral emulsions exhibit emergent chiral motion with rotating fluidic flows. Such solid-fluid interactions occur in a number of self-propelling oil droplet systems, thereby enabling control over the emergent collective behaviors of chemically distinct active droplets.
控制活性液滴中的流体流动对于开发智能模型以理解和模拟单细胞微生物至关重要。通常,这些流体流动受到化学试剂界面动力学的影响。我们发现这些流动可以通过嵌入在活动液滴内的各向异性固体边界的存在而重新配置。自发的流体流动动态地定向嵌入的磁团,当磁团重新排列时,导致这些流动重新定向,从而提供对趋化乳剂推进动力学的控制。当连续扰动时,非手性乳剂表现出随流体旋转而涌现的手性运动。这种固流相互作用发生在许多自推进油滴系统中,从而能够控制化学上不同的活性油滴的紧急集体行为。
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引用次数: 0
From understanding to control: Unifying mechanistic insights and interface engineering in energy storage through advanced characterization 从理解到控制:通过高级表征统一能量存储的机制见解和界面工程
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102523
Jiao Wu , Naisheng Jiang , Ming Xu
Electrolyte-electrode interfaces (EEIs) critically shape the performance, stability, and lifetime of energy storage systems, yet their buried complexity in structure, chemistry, and kinetics remains challenging to decode. This review synthesizes recent advances enabled by cryogenic electron microscopy, operando spectroscopy, and 3D tomography, which have uncovered interfacial heterogeneity, chemical evolution, and non-classical charge-transfer pathways. These findings revise static interphase models and explain discrepancies across systems once thought to be mechanistically similar. We highlight how integrated, multiscale diagnostics can resolve these differences and inform design. Building on this foundation, we examine emerging engineering strategies, including electrolyte reformulation, surface reconstruction, and artificial interphase design, that target specific interfacial failure modes. By bridging mechanism, measurement, and materials design, this review offers a road map for decoding and directing EEI behavior across diverse chemistries, from lithium-ion and solid-state batteries to supercapacitors, guiding next-generation energy devices toward greater reliability, efficiency, and control.
电解质-电极界面(eei)对储能系统的性能、稳定性和寿命有着至关重要的影响,但其在结构、化学和动力学方面的复杂性仍然具有挑战性。本文综述了低温电子显微镜、operando光谱和3D断层扫描技术的最新进展,这些进展揭示了界面非均质性、化学演化和非经典电荷转移途径。这些发现修正了静态间期模型,并解释了曾经被认为在机制上相似的系统之间的差异。我们强调了集成的多尺度诊断如何解决这些差异并为设计提供信息。在此基础上,我们研究了针对特定界面失效模式的新兴工程策略,包括电解质重组、表面重建和人工界面设计。通过桥接机制、测量和材料设计,本综述为解读和指导从锂离子电池和固态电池到超级电容器等不同化学物质的EEI行为提供了路线图,指导下一代能源设备实现更高的可靠性、效率和控制。
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引用次数: 0
An unconventional path to convergence 一条非常规的趋同之路
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102574
Xiangkun Elvis Cao
In this Matter of Opinion, Xiangkun (Elvis) Cao reflects on how his humble background from rural China sparked his scientific curiosity. Cao also shares how his unconventional journey spanning academia, policy, entrepreneurship, and industry consulting has shaped his vision as he starts his independent scientific career at Imperial College London, aiming to impact climate and sustainability at the convergence of technology, business, and policy.
在本书中,曹翔坤回顾了他来自中国农村的卑微背景如何激发了他对科学的好奇心。曹还分享了他在伦敦帝国理工学院(Imperial College London)开始独立科学生涯时,跨越学术界、政策、创业和行业咨询的非常规旅程如何塑造了他的愿景,他的目标是通过技术、商业和政策的融合来影响气候和可持续发展。
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引用次数: 0
Graph theory-based bio-derived solid lubricant 基于图论的生物衍生固体润滑剂
IF 17.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-07 DOI: 10.1016/j.matt.2025.102474
Dhanush U. Jamadgni , Paul Gregory , Xiong Ye Xiao , Andrew Martin , Daisy Kiptoo , Alana M. Jones , Kien Trung Nguyen , Souvik Banerjee , Anastasia Visheratina , Nancy Muyanja , Boyce Chang , Paul Bogdan , Nicholas A. Kotov , Martin Thuo
Granular matter processing necessitates fluidization for predictable and coherent flow. In agriculture, for example, toxic solid lubricants (talc or microplastics) are often deployed as fluency agents, contaminating fragile (e.g., waterways) or precious (e.g., farmlands or pollinators) ecosystems. We applied graph theory to design bio-derived fluency agents with seeds as a model system of complex granular matter. Adopting graph theory, we evaluated multibody effects and transient clustering in 2D and 3D motion of seeds. Time-dependent graph characteristics (e.g., Ollivier-Ricci curvature, fractality, and multifractal spectrum) reveal that modified cellulose-derived lubricants effectively disrupt clustering and enhance seed flow. Flow energy trends support graph-based inferences and confirm improved coherent flow. Lubricity was confirmed with a stationary seed metering system and field trials. The developed materials are biodegradable, sustainable, and field-deployable replacements of current toxic products.
粒状物质处理需要流化,以实现可预测和连贯的流动。例如,在农业中,有毒固体润滑剂(滑石粉或微塑料)经常被用作流畅剂,污染脆弱(如水道)或珍贵(如农田或传粉媒介)的生态系统。我们应用图论来设计具有种子的生物衍生流畅性代理作为复杂颗粒物质的模型系统。采用图论方法,对种子在二维和三维运动中的多体效应和瞬态聚类进行了评价。时间相关的图特征(如奥利维-里奇曲率、分形和多重分形谱)表明,改性纤维素衍生的润滑剂有效地破坏了聚类,增强了种子流动。流动能量趋势支持基于图形的推断,并确认改进的连贯流动。润滑性通过固定种子计量系统和现场试验得到了证实。开发的材料是可生物降解的,可持续的,可现场部署的现有有毒产品的替代品。
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引用次数: 0
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Matter
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