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Femtosecond Laser-induced Nanoparticle Implantation into Flexible Substrate for Sensitive and Reusable Microfluidics SERS Detection 将飞秒激光诱导的纳米粒子植入柔性基底,实现灵敏、可重复使用的微流体 SERS 检测
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-05-08 DOI: 10.1088/2631-7990/ad48e9
Yongxiang Hu, Yu Zhou, Guohu Luo, Dege Li, Minni Qu
Surface-enhanced Raman spectroscopy (SERS) microfluidic system, which enables rapid detection of chemical and biological analytes, offers an effective platform to monitor various food contaminants and disease diagnoses. The efficacy of SERS microfluidic systems is greatly dependent on the sensitivity and reusability of SERS detection substrates to ensure repeated use for prolonged periods. This study proposed a novel process of femtosecond laser nanoparticle array (NPA) implantation to achieve homogeneous forward transfer of gold NPA on a flexible polymer film and accurately integrated it within microfluidic chips for SERS detection. The implanted Au-NPA strips show a remarkable electromagnetic field enhancement with the factor of 9×108 during SERS detection of malachite green (MG) solution, achieving a detection limit lower than 10 ppt, far better than most laser-prepared SERS substrates. Furthermore, Au-NPA strips show excellent reusability after several physical and chemical cleaning, because of the robust embedment of laser-implanted NPA in flexible substrates. To demonstrate the performance of Au-NPA, a SERS microfluidic system is built to monitor the online oxidation reaction between MG/NaClO reactants, which helps infer the reaction path. The proposed method of nanoparticle implantation is more effective than the direct laser structuring technique. It provides better performance for SERS detection, robustness of detection, and substrate flexibility and has a wider range of applications for microfluidic systems without any negative impact.
表面增强拉曼光谱(SERS)微流控系统能够快速检测化学和生物分析物,为监测各种食品污染物和疾病诊断提供了一个有效的平台。SERS 微流控系统的功效在很大程度上取决于 SERS 检测基底的灵敏度和可重复使用性,以确保长期重复使用。本研究提出了一种飞秒激光纳米粒子阵列(NPA)植入的新工艺,在柔性聚合物薄膜上实现金 NPA 的均匀正向转移,并将其精确集成到微流控芯片中用于 SERS 检测。在孔雀石绿(MG)溶液的 SERS 检测过程中,植入的 Au-NPA 带显示出显著的电磁场增强效果,系数达到 9×108,检测限低于 10 ppt,远远优于大多数激光制备的 SERS 基底。此外,由于激光植入的 NPA 能够牢固地嵌入柔性基底中,因此 Au-NPA 带在经过多次物理和化学清洗后仍可重复使用。为了证明 Au-NPA 的性能,建立了一个 SERS 微流控系统来监测 MG/NaClO 反应物之间的在线氧化反应,这有助于推断反应路径。所提出的纳米粒子植入方法比直接激光结构化技术更有效。它具有更好的 SERS 检测性能、检测稳健性和基底灵活性,在微流体系统中的应用范围更广,且不会产生任何负面影响。
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引用次数: 0
Customized heat treatment process enabled excellent mechanical properties in wire arc additively manufactured Mg-RE-Zn-Zr alloys 定制热处理工艺使线弧添加法制造的 Mg-RE-Zn-Zr 合金具有优异的机械性能
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-05-08 DOI: 10.1088/2631-7990/ad48ea
Dong Ma, Chunjie Xu, Shang Sui, Yuanshen Qi, Can Guo, Zhong-ming Zhang, Jun Tian, Fanhong Zeng, S. Remennik, Dan Shechtman
Customized heat treatment is essential for enhancing the mechanical properties of additively manufactured metallic materials, especially for the alloys with complex phase constituents and heterogenous microstructure. However, the interrelated evolutions of different microstructure features make it difficult to establish optimal heat treatment process. Herein, we proposed a method for customized heat treatment process exploration and establishment to overcome this challenge for such kind of alloys, and a wire arc additively manufactured (WAAM) Mg-Gd-Y-Zn-Zr alloy with layered heterostructure was used for feasibility verification. Through this method, an optimal microstructure (fine grain, controllable amount of LPSO structure and nano-scale β' precipitates) and the corresponding customized heat treatment process (520 °C/30 min + 200 °C/48 h) were obtained to achieve a combination of a high strength of 364 MPa and a considerable elongation of 6.2 %, which surpassed those of other state-of-the-art WAAM-processed Mg alloys. Furthermore, we evidenced for the first time that the favorable effect of the undeformed LPSO structure on the mechanical properties was emphasized only when the nano-scale β’ precipitates were present. It is believed that the findings promote the development of advanced Mg alloys and help to establish customized heat treatment process for additively manufactured materials.
定制热处理对于提高添加制造金属材料的机械性能至关重要,尤其是对于具有复杂相成分和异质微观结构的合金。然而,由于不同微观结构特征的演变相互关联,因此难以确定最佳热处理工艺。在此,我们提出了一种探索和建立定制热处理工艺的方法,以克服此类合金所面临的这一挑战,并使用具有层状异质结构的线弧快速成型(WAAM)Mg-Gd-Y-Zn-Zr 合金进行可行性验证。通过这种方法,我们获得了最佳的微观结构(细晶粒、可控数量的 LPSO 结构和纳米级 β' 沉淀)以及相应的定制热处理工艺(520 °C/30 min + 200 °C/48 h),实现了 364 MPa 的高强度和 6.2 % 的可观伸长率,超过了其他最先进的 WAAM 加工镁合金。此外,我们还首次证明,只有当存在纳米级 β' 沉淀物时,未变形 LPSO 结构对力学性能的有利影响才会得到强调。相信这些发现将促进先进镁合金的发展,并有助于为添加制造材料建立定制的热处理工艺。
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引用次数: 0
Additive Manufacturing of Micropatterned Functional Surfaces: A Review 微图案功能表面的快速成型制造:综述
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-04-23 DOI: 10.1088/2631-7990/ad4240
Aditya Chivate, Chi Zhou
Over the course of millions of years, nature has evolved to ensure survival and presents us with a myriad of functional surfaces and structures that can boast high efficiency, multifunctionality, and sustainability. What makes these surfaces particularly practical and effective is the intricate micropatterning that enables selective interactions with microstructures. Most of these structures have been realized in the laboratory environment using numerous fabrication techniques by tailoring specific surface properties. Of the available manufacturing methods, additive manufacturing (AM) has created opportunities for fabricating these structures as the complex architectures of the naturally occurring microstructures that far exceed the traditional ways. This paper presents a concise overview of the fundamentals of such patterned microstructured surfaces, their fabrication techniques, and diverse applications. A comprehensive evaluation of micro fabrication methods is conducted, delving into their respective strengths and limitations. Greater emphasis is placed on AM processes like inkjet printing and micro digital light projection printing due to the innate advantages of these processes to additively fabricate high resolution structures with high fidelity and precision. The paper explores the various advancements in these processes in relation to their use in microfabrication and also presents the recent trends in applications like the fabrication of microlens arrays, microneedles, and tissue scaffolds.
经过数百万年的进化,大自然向我们展示了无数高效、多功能和可持续的功能性表面和结构,以确保人类的生存。使这些表面特别实用和有效的是错综复杂的微图案,它能与微结构进行选择性互动。这些结构大多是在实验室环境中通过定制特定的表面特性,利用多种制造技术实现的。在现有的制造方法中,增材制造(AM)为制造这些结构创造了机会,因为天然微结构的复杂架构远远超过了传统方法。本文简要概述了此类图案化微结构表面的基本原理、制造技术和各种应用。本文对微制造方法进行了全面评估,深入探讨了它们各自的优势和局限性。重点介绍了喷墨打印和微型数字光投影打印等自动机械加工工艺,因为这些工艺具有先天优势,能以加成法制造出高保真、高精度的高分辨率结构。本文探讨了这些工艺在微加工方面的各种进展,还介绍了微透镜阵列、微针和组织支架制造等应用的最新趋势。
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引用次数: 0
Bioinspired directional structures for inhibiting wetting on super-melt-philic surfaces above 1200 °C 用于抑制 1200 °C 以上超熔体亲水性表面润湿的生物启发定向结构
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-04-18 DOI: 10.1088/2631-7990/ad4074
Hujun Wang, Xiuyuan Zhao, Zhengcan Xie, Biao Yang, Jing Zheng, Kai Yin, Zhongrong Zhou
Over the past two decades, superhydrophobic surfaces that are easily created have aroused considerable attention for their superior performances in various applications at room temperature. Nowadays, there is a growing demand in special fields for the development of surfaces that can resist wetting by high-temperature molten droplets (>1200 °C) using facile design and fabrication strategies. Herein, bioinspired directional structures (BDSs) were prepared on Y2O3-stabilized ZrO2 (YSZ) surfaces using femtosecond laser ablation. Benefiting from the anisotropic energy barriers, the BDSs featured with no additional modifiers showed a remarkable 552.2% increase in the contact angle of CaO-MgO-Al2O3-SiO2 (CMAS) melt and a 70.1% reduction in the spreading area of CMAS at 1250 oC, compared with polished super-CMAS-melt-philic YSZ surfaces. Moreover, the BDSs demonstrated exceptional wetting inhibition even at 1400 °C, with an 848.5% increase in contact angle and a 67.9% decrease in spreading area. This work provides valuable insight and a facile preparation strategy for effectively inhibiting the wetting of molten droplets on super-melt-philic surfaces at extremely high temperatures.
在过去的二十年里,易于制造的超疏水表面因其在室温下各种应用中的卓越性能而引起了广泛关注。如今,特殊领域对利用简便的设计和制造策略开发可抵抗高温熔滴(>1200 °C)润湿的表面的需求日益增长。本文利用飞秒激光烧蚀技术在 Y2O3 稳定 ZrO2(YSZ)表面制备了生物启发定向结构(BDS)。与抛光的超CMAS熔体亲水性YSZ表面相比,受益于各向异性的能量势垒,没有额外改性剂的BDSs在1250 oC时与CaO-MgO-Al2O3-SiO2(CMAS)熔体的接触角显著增加了552.2%,CMAS的扩散面积减少了70.1%。此外,即使在 1400 摄氏度时,BDSs 也表现出优异的润湿抑制能力,接触角增加了 848.5%,铺展面积减少了 67.9%。这项研究为在超高温条件下有效抑制熔滴在超亲水表面上的润湿提供了宝贵的见解和简便的制备策略。
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引用次数: 0
Pulsed current-assisted twelve-roll precision rolling deformation of SUS304 ultra-thin strips with exceptional mechanical properties 脉冲电流辅助十二辊精密轧制变形 SUS304 超薄带材,使其具有优异的机械性能
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-04-18 DOI: 10.1088/2631-7990/ad4073
W. Fan, Tao Wang, Ginxiong Hou, Zhong-kai Ren, Qingxue Huang, Guanghui Wu
Innovative pulsed current-assisted multi-pass rolling tests were conducted on a twelve-roll mill during the rolling deformation processing of SUS304 ultra-thin strips. The results show that in the first rolling pass, the rolling reduction rate of a conventionally rolled sample (at room temperature) is 33.8%, which can be increased to 41.5% by pulsed current-assisted rolling, enabling the formation of an ultra-thin strip with a size of 67.3 μm in only one rolling pass. After three passes of pulsed current-assisted rolling, the thickness of the ultra-thin strip can be further reduced to 51.7 μm. To clearly compare the effects of a pulsed current on the microstructure and mechanical response of the ultra-thin strip, ultra-thin strips with nearly the same thickness reduction were analyzed. It was found that pulsed current can reduce the degree of work-hardening of the rolled samples by promoting dislocation detachment, reducing the density of stacking faults, inhibiting martensitic phase transformation, and shortening the total length of grain boundaries. As a result, the ductility of ultra-thin strips can be effectively restored to approximately 16.3% while maintaining a high tensile strength of 1118 MPa. Therefore, pulsed current-assisted rolling deformation shows great potential for the formation of ultra-thin strips with a combination of high strength and ductility.
在 SUS304 超薄带材的轧制变形加工过程中,在十二辊轧机上进行了创新的脉冲电流辅助多道轧制试验。结果表明,在第一道轧制中,传统轧制试样(室温下)的轧制减薄率为 33.8%,而脉冲电流辅助轧制可将其提高到 41.5%,仅需一道轧制即可形成尺寸为 67.3 μm 的超薄带材。经过三次脉冲电流辅助轧制后,超薄带材的厚度可进一步降至 51.7 μm。为了清楚地比较脉冲电流对超薄带材微观结构和机械响应的影响,我们分析了厚度几乎相同的超薄带材。结果发现,脉冲电流可通过促进位错脱落、降低堆积断层密度、抑制马氏体相变和缩短晶界总长度来降低轧制样品的加工硬化程度。因此,超薄带材的延展性可有效恢复到约 16.3%,同时保持 1118 兆帕的高抗拉强度。因此,脉冲电流辅助轧制变形在形成兼具高强度和延展性的超薄带材方面显示出巨大潜力。
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引用次数: 0
Laser-based bionic manufacturing 激光仿生制造
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-04-16 DOI: 10.1088/2631-7990/ad3f59
Xingran Li, Baoyu Zhang, Timothy Jakobi, Zhenglei Yu, Luquan Ren, Zhihui Zhang
Over millions of years of natural evolution, organisms have developed nearly perfect structures and functions. The self-fabrication of organisms serves as a valuable source of inspiration for designing the next-generation of structural materials, and is driving the future paradigm shift of modern materials science and engineering. However, the complex structures and multifunctional integrated optimization of organisms far exceed the capability of artificial design and fabrication technology, and new manufacturing methods are urgently needed to achieve efficient reproduction of biological functions. As one of the most valuable advanced manufacturing technologies of the 21st century, laser processing technology provides an efficient solution to the critical challenges of bionic manufacturing. This review outlines the processing principles, manufacturing strategies, potential applications, challenges, and future development outlook of laser processing in bionic manufacturing domains. Three primary manufacturing strategies for laser-based bionic manufacturing are proposed: subtractive manufacturing, equivalent manufacturing, and additive manufacturing. The progress and trends in bionic subtractive manufacturing applied to micro/nano structural surfaces, bionic equivalent manufacturing for surface strengthening, and bionic additive manufacturing aiming to achieve bionic spatial structures, are reported. Finally, the key problems faced by laser-based bionic manufacturing, its limitations, and the development trends of its existing technologies are discussed.
经过数百万年的自然进化,生物已经发展出近乎完美的结构和功能。生物体的自制造能力为设计下一代结构材料提供了宝贵的灵感来源,并推动着现代材料科学与工程的未来范式转变。然而,生物的复杂结构和多功能集成优化远远超出了人工设计和制造技术的能力,迫切需要新的制造方法来实现生物功能的高效再现。作为 21 世纪最有价值的先进制造技术之一,激光加工技术为仿生制造的关键挑战提供了高效的解决方案。本综述概述了激光加工在仿生制造领域的加工原理、制造策略、潜在应用、挑战和未来发展前景。提出了基于激光的仿生制造的三种主要制造策略:减法制造、等效制造和加法制造。报告了应用于微/纳米结构表面的仿生减法制造、用于表面强化的仿生等效制造以及旨在实现仿生空间结构的仿生增材制造的进展和趋势。最后,讨论了基于激光的仿生制造所面临的关键问题、局限性及其现有技术的发展趋势。
{"title":"Laser-based bionic manufacturing","authors":"Xingran Li, Baoyu Zhang, Timothy Jakobi, Zhenglei Yu, Luquan Ren, Zhihui Zhang","doi":"10.1088/2631-7990/ad3f59","DOIUrl":"https://doi.org/10.1088/2631-7990/ad3f59","url":null,"abstract":"\u0000 Over millions of years of natural evolution, organisms have developed nearly perfect structures and functions. The self-fabrication of organisms serves as a valuable source of inspiration for designing the next-generation of structural materials, and is driving the future paradigm shift of modern materials science and engineering. However, the complex structures and multifunctional integrated optimization of organisms far exceed the capability of artificial design and fabrication technology, and new manufacturing methods are urgently needed to achieve efficient reproduction of biological functions. As one of the most valuable advanced manufacturing technologies of the 21st century, laser processing technology provides an efficient solution to the critical challenges of bionic manufacturing. This review outlines the processing principles, manufacturing strategies, potential applications, challenges, and future development outlook of laser processing in bionic manufacturing domains. Three primary manufacturing strategies for laser-based bionic manufacturing are proposed: subtractive manufacturing, equivalent manufacturing, and additive manufacturing. The progress and trends in bionic subtractive manufacturing applied to micro/nano structural surfaces, bionic equivalent manufacturing for surface strengthening, and bionic additive manufacturing aiming to achieve bionic spatial structures, are reported. Finally, the key problems faced by laser-based bionic manufacturing, its limitations, and the development trends of its existing technologies are discussed.","PeriodicalId":52353,"journal":{"name":"International Journal of Extreme Manufacturing","volume":null,"pages":null},"PeriodicalIF":14.7,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140696696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polar-coordinate line-projection light-curing continuous 3D printing for tubular structures 用于管状结构的极坐标线投影光固化连续 3D 打印技术
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-04-09 DOI: 10.1088/2631-7990/ad3c7f
Huiyuan Wang, Siqin Liu, Xincheng Yin, Mingming Huang, Yanzhe Fu, Xun Chen, Chao Wang, Jingyong Sun, Xin Yan, Jianmin Han, Jiping Yang, Zhijian Wang, Lizhen Wang, Yubo Fan, Jiebo Li
3D printing techniques offer an effective method in fabricating complex radially multi-material structures. However, it is challenging for complex and delicate radially multi-material model geometries without supporting structures, such as tissue vessels and tubular graft, among others. In this work, we tackle these challenges by developing a polar digital light processing technique which use a rod as the printing platform. The 3D model fabrication is accomplished through line projection. The rotation and translation of the rod are synchronized to project and illuminate the photosensitive material volume. By controlling the distance between the rod and the printing window, we achieved the printing of tubular structures with a minimum wall thickness as thin as 50 micrometers. By controlling the width of fine slits at the printing window, we achieved the printing of structures with a minimum feature size of 10 micrometers. Our process accomplished the fabrication of thin-walled tubular graft structure with a thickness of only 100 micrometers and lengths of several centimeters within a timeframe of just 100 seconds. Additionally, it enables the printing of axial multi-material structures, thereby achieving adjustable mechanical strength. This method is conducive to rapid customization of tubular grafts and the manufacturing of tubular components in fields such as dentistry, aerospace, and more.
三维打印技术为制造复杂的径向多材料结构提供了一种有效方法。然而,对于没有支撑结构的复杂而精细的径向多材料模型几何形状,如组织血管和管状移植物等,则具有挑战性。在这项工作中,我们通过开发一种极地数字光处理技术来应对这些挑战,该技术使用杆作为打印平台。三维模型的制作是通过线投影完成的。杆的旋转和平移同步进行,以投射和照亮光敏材料体积。通过控制杆和打印窗口之间的距离,我们打印出了最小壁厚为 50 微米的管状结构。通过控制打印窗口细缝的宽度,我们实现了最小特征尺寸为 10 微米的结构打印。我们的工艺能在短短 100 秒内制造出厚度仅为 100 微米、长度达数厘米的薄壁管状移植结构。此外,它还能打印轴向多材料结构,从而实现可调节的机械强度。这种方法有利于快速定制管状移植物,以及在牙科、航空航天等领域制造管状部件。
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引用次数: 0
Bidirectional Rotating Direct-Current Triboelectric Nanogenerator with Self-adaptive Mechanical Switching for Harvesting Reciprocating Motion 具有自适应机械开关的双向旋转直流三电纳米发电机,用于采集往复运动
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-04-02 DOI: 10.1088/2631-7990/ad3998
Donghan Lee, Joonmin Chae, Sumin Cho, Jong Woo Kim, Awais Ahmad, Mohammad Rezaul Karim, Moonwoo La, Sung Jea Park, D. Choi
Amid the growing interest in triboelectric nanogenerators (TENGs) as novel energy-harvesting devices, several studies have focused on direct current (DC) TENGs to generate a stable DC output for operating electronic devices. However, owing to the working mechanisms of conventional DC TENGs, generating a stable DC output from reciprocating motion remains a challenge. Accordingly, we propose a bidirectional rotating DC TENG (BiR-TENG), which can generate DC outputs, regardless of the direction of rotation, from reciprocating motions. The distinct design of the BiR-TENG enables the mechanical rectification of the alternating current output into a rotational-direction-dependent DC output. Furthermore, it allows the conversion of the rotational-direction-dependent DC output into a unidirectional DC output by adapting the configurations depending on the rotational direction. Owing to these tailored design strategies and subsequent optimizations, the BiR-TENG could generate an effective unidirectional DC output. Applications of the BiR-TENG for the reciprocating motions of swinging doors and waves were demonstrated by harnessing this output. This study demonstrates the potential of the BiR-TENG design strategy as an effective and versatile solution for energy harvesting from reciprocating motions, highlighting the suitability of DC outputs as an energy source for electronic devices.
随着人们对三电纳米发电机(TENGs)作为新型能量收集设备的兴趣与日俱增,一些研究重点关注直流(DC)TENGs,以产生稳定的直流输出,用于操作电子设备。然而,由于传统直流纳米发电机的工作机制,从往复运动中产生稳定的直流输出仍然是一个挑战。因此,我们提出了一种双向旋转直流 TENG(BiR-TENG),它可以从往复运动中产生直流输出,而不受旋转方向的影响。BiR-TENG 的独特设计可将交流电输出机械整流为与旋转方向有关的直流电输出。此外,它还可以根据旋转方向调整配置,将旋转方向相关的直流输出转换为单向直流输出。通过这些量身定制的设计策略和后续优化,BiR-TENG 可以产生有效的单向直流输出。通过利用这种输出,BiR-TENG 在摆动门和波浪的往复运动中的应用得到了验证。这项研究证明了 BiR-TENG 设计策略作为从往复运动中收集能量的有效和多功能解决方案的潜力,突出了直流输出作为电子设备能源的适用性。
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引用次数: 0
Recent advances in high charge density triboelectric nanogenerators 高电荷密度三电纳米发电机的最新进展
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-04-02 DOI: 10.1088/2631-7990/ad39ba
Xin Cui, Jiaheng Nie, Yan Zhang
Triboelectric materials with high charge density are the building-block for the commercial application of triboelectric nanogenerators (TENGs). Unstable dynamic processes influence the change of the charge density on the surface and inside of triboelectric materials. The charge density of triboelectric materials depends on the surface and the internal charge transfer processes. The focus of this review is on recent advances in high charge density triboelectric materials and advances in the fabrication of TENGs. We summarize the existing strategies for achieving high charge density in triboelectric materials as well as their fundamental properties. We then review current optimization methods for regulating dynamic charge transfer processes to increase the output charge density: first, increasing charge injection and limiting charge dissipation to achieve a high average surface charge density, and second, regulating the internal charge transfer process and storing charge in triboelectric materials to increase the output charge density. Finally, we present the challenges and prospects in developing high-performance triboelectric materials.
具有高电荷密度的三电材料是三电纳米发电机(TENGs)商业应用的基础。不稳定的动态过程会影响三电材料表面和内部电荷密度的变化。三电材料的电荷密度取决于表面和内部的电荷转移过程。本综述的重点是高电荷密度三电材料的最新进展以及三电材料制造的进展。我们总结了在三电材料中实现高电荷密度的现有策略及其基本特性。然后,我们回顾了目前调节动态电荷转移过程以提高输出电荷密度的优化方法:首先,增加电荷注入并限制电荷耗散,以实现较高的平均表面电荷密度;其次,调节内部电荷转移过程并在三电材料中存储电荷,以提高输出电荷密度。最后,我们介绍了开发高性能三电材料所面临的挑战和前景。
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引用次数: 0
Role of heterogenous microstructure and deformation behavior in achieving superior strength-ductility synergy in zinc fabricated via laser powder bed fusion 异质微观结构和变形行为在通过激光粉末床熔融技术制造的锌中实现优异强度-电导率协同效应中的作用
IF 14.7 1区 工程技术 Q1 Engineering Pub Date : 2024-03-29 DOI: 10.1088/2631-7990/ad3929
Zhi Dong, Changjun Han, Yanzhe Zhao, Jinmiao Huang, Chenrong Ling, Gaoling Hu, Yunhui Wang, Di Wang, Changhui Song, Yongqiang Yang
Zinc (Zn) is considered a promising biodegradable metal for implant applications due to its appropriate degradability and favorable osteogenesis properties. In this work, laser powder bed fusion (LPBF) additive manufacturing was employed to fabricate pure Zn with a heterogenous microstructure and exceptional strength-ductility synergy. An optimized processing window of LPBF was established for printing Zn samples with relative densities greater than 99% using a laser power range of 80–90 W and a scanning speed of 900 mm/s. The Zn sample printed with a power of 80 W at a speed of 900 mm/s exhibited a hierarchical heterogenous microstructure consisting of millimeter-scale molten pool boundaries, micrometer-scale bimodal grains, and nanometer-scale pre-existing dislocations, due to rapid cooling rates and significant thermal gradients formed in the molten pools. The printed sample exhibited the highest ductility of ~12.1% among all reported LPBF-printed pure Zn to date with appreciable ultimate tensile strength (~128.7 MPa). Such superior strength-ductility synergy can be attributed to the presence of multiple deformation mechanisms that are primarily governed by heterogeneous deformation-induced hardening resulting from the alternatively arrangement of bimodal Zn grains with pre-existing dislocations. Additionally, continuous strain hardening was facilitated through the interactions between deformation twins, grains and dislocations as strain accumulated, further contributing to the superior strength-ductility synergy. These findings provide valuable insights into the deformation behavior and mechanisms underlying exceptional mechanical properties of LPBF-printed Zn and its alloys for implant applications.
锌(Zn)具有适当的可降解性和良好的成骨特性,因此被认为是一种很有前景的生物可降解植入金属。本研究采用激光粉末床熔融(LPBF)快速成型技术制造具有异质微观结构和优异强度-电导率协同作用的纯锌。在激光功率为 80-90 W、扫描速度为 900 mm/s 的条件下,建立了 LPBF 的优化加工窗口,可打印出相对密度大于 99% 的 Zn 样品。功率为 80 W、扫描速度为 900 mm/s 的 Zn 样品呈现出分层异质微观结构,包括毫米级熔池边界、微米级双峰晶粒和纳米级预存在位错,这是由于熔池中形成了快速冷却速率和显著的热梯度。在迄今报道的所有 LPBF 印刷纯 Zn 样品中,该印刷样品的延展性最高(约为 12.1%),并具有可观的极限拉伸强度(约为 128.7 兆帕)。这种卓越的强度-延展性协同作用可归因于多种变形机制的存在,而这些机制主要是由具有预存在位错的双峰锌晶粒的交替排列所产生的异质变形诱导硬化所支配的。此外,随着应变的累积,变形孪晶、晶粒和位错之间的相互作用促进了持续的应变硬化,从而进一步促成了卓越的强度-电导率协同作用。这些发现为我们深入了解用于植入应用的 LPBF 印刷锌及其合金的变形行为和特殊机械性能的内在机制提供了宝贵的见解。
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引用次数: 0
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