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3D Printing of Periodic Porous Metamaterials for Tunable Electromagnetic Shielding Across Broad Frequencies 三维打印周期性多孔超材料,实现宽频可调电磁屏蔽。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-09-03 DOI: 10.1007/s40820-024-01502-5
Qinniu Lv, Zilin Peng, Haoran Pei, Xinxing Zhang, Yinghong Chen, Huarong Zhang, Xu Zhu, Shulong Wu

Highlights

  • The stable periodic porous shielding materials were prepared by combining the strategies of 3D printing and metamaterial design.

  • The relationship between porous material structure and electromagnetic interference shielding efficiency (EMI SE) effectiveness was deeply explored, revealing the important structural parameters for realizing tunable EMI SE property.

  • The optimized design of the periodic porous shielding box achieves effective EMI shielding in a wide wavelength range (over 2.4 GHz).

新一代电子元件需要在电磁干扰屏蔽效率和开放式结构因素(如通风和散热)之间取得平衡。此外,实现多孔屏蔽罩在宽波长范围内的可调屏蔽更是一项挑战。在本研究中,利用精心制备的热塑性聚氨酯/碳纳米管复合材料,采用熔融沉积建模三维打印技术制造了新型周期性多孔柔性超材料。研究重点尤其放在孔隙几何形状、大小、位错配置和材料厚度的优化上,从而在结构参数和屏蔽性能之间建立了明确的相关性。实验和模拟结果都验证了六边形衍生蜂窝结构的屏蔽性能优于其他设计,并提出了失效屏蔽尺寸(Df ≈λ/8 - λ/5)和临界倾斜角(θf ≈43°-48°),可作为可调电磁屏蔽的新基准。此外,适当调节材料厚度可显著提高最大屏蔽能力(85 - 95 dB)和吸收系数 A(超过 0.83)。多孔屏蔽盒的最终创新设计还在较宽的频率范围(超过 2.4 GHz)内表现出良好的屏蔽效果,为个性化和多样化的屏蔽解决方案开辟了新的途径。
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引用次数: 0
Correction: Impact of Transition Metal Layer Vacancy on the Structure and Performance of P2 Type Layered Sodium Cathode Material 更正:过渡金属层空位对 P2 型层状钠阴极材料结构和性能的影响。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-30 DOI: 10.1007/s40820-024-01492-4
Orynbay Zhanadilov, Sourav Baiju, Natalia Voronina, Jun Ho Yu, A-Yeon Kim, Hun-Gi Jung, Kyuwook Ihm, Olivier Guillon, Payam Kaghazchi, Seung-Taek Myung
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引用次数: 0
Highly Sensitive Ammonia Gas Sensors at Room Temperature Based on the Catalytic Mechanism of N, C Coordinated Ni Single-Atom Active Center 基于 N、C 配位镍单原子活性中心催化机理的室温高灵敏度氨气传感器。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-27 DOI: 10.1007/s40820-024-01484-4
Wenjing Quan, Jia Shi, Min Zeng, Wen Lv, Xiyu Chen, Chao Fan, Yongwei Zhang, Zhou Liu, Xiaolu Huang, Jianhua Yang, Nantao Hu, Tao Wang, Zhi Yang

Highlights

  • Exploiting single-atom catalytic activation and targeted adsorption properties, Ni single-atom active sites based on N, C coordination are constructed on the surface of two-dimensional MXene nanosheets (Ni–N–C/Ti3C2Tx), enabling highly sensitive and selective NH3 gas detection.

  • The catalytic activation effect of Ni–N–C/Ti3C2Tx effectively reduces the Gibbs free energy of the sensing elemental reaction, while its electronic structure promotes the spill-over effect of reactive oxygen species at the gas–solid interface.

  • An end-sealing passivation strategy utilizing a conjugated hydrogen bond network of the conductive polymer was employed on MXene-based flexible electrodes, effectively mitigating the oxidative degradation of MXene-based gas sensors.

由于气体传感机制的局限性,氨(NH3)的痕量检测面临巨大挑战。在本研究中,我们提出利用单原子催化活化和定向吸附特性来实现高灵敏度和高选择性的 NH3 气体检测。具体来说,我们在二维(2D)MXene 纳米片(Ni-N-C/Ti3C2Tx)表面界面限制了基于 N、C 配位(Ni-N-C)的镍单原子活性位点,并集成了一种全柔性气体传感器(MNPE-Ni-N-C/Ti3C2Tx)。该传感器对 5 ppm 的 NH3 具有显著的响应值(27.3%),对 NH3 具有出色的选择性,理论检测限低至 12.1 ppb。密度泛函计算的模拟分析表明,具有 N、C 配位的镍单原子中心对 NH3 具有特定的定向吸附特性。此外,其催化活化效应有效降低了传感元素反应的吉布斯自由能,而其电子结构则促进了气固界面上活性氧物种的溢出效应。该传感器具有化学敏化和电子敏化的双通道传感机制,有利于电子高效地转移到二维 MXene 导电网络,从而形成 NH3 气体分子传感信号。此外,共轭氢键网络对 MXene 边缘缺陷的钝化增强了基于 MXene 的电极在高湿度条件下的长期稳定性。该研究基于 N、C 配位的 Ni 单原子活性中心的催化机理,实现了高灵敏度的室温 NH3 气体检测,为室温痕量气体检测研究提供了一种新的气体传感机制。
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引用次数: 0
Light–Material Interactions Using Laser and Flash Sources for Energy Conversion and Storage Applications 利用激光和闪光灯光源进行光-材料相互作用,实现能量转换和存储应用。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-26 DOI: 10.1007/s40820-024-01483-5
Jung Hwan Park, Srinivas Pattipaka, Geon-Tae Hwang, Minok Park, Yu Mi Woo, Young Bin Kim, Han Eol Lee, Chang Kyu Jeong, Tiandong Zhang, Yuho Min, Kwi-Il Park, Keon Jae Lee, Jungho Ryu

Highlights

  • This review paper provides a comprehensive analysis of light–material interaction (LMI) parameters, offering insights into their significance in material processing.

  • It examines a wide array of photothermal and photochemical processes, showcasing their versatility in creating advanced materials for energy conversion and storage applications.

  • The review presents a multidisciplinary approach to advancing LMI technologies and highlights their potential contribution to the commercialization of future energy conversion and storage systems.

这篇综述全面概述了光-材料相互作用(LMI)的进展,重点是用于能量转换和存储应用的激光和闪光灯。我们讨论了复杂的光-材料相互作用参数,如光源、相互作用时间和通量,以阐明它们在材料加工中的重要性。此外,本研究还涉及各种光诱导的光热和光化学过程,从熔化、结晶、烧蚀到掺杂和合成,这些过程对于开发能源材料和设备至关重要。最后,我们介绍了 LMI 技术所展示的广泛的能量转换和存储应用,包括能量收集器、传感器、电容器和电池。尽管 LMIs 面临着一些挑战,如复杂的机理和高自由度,但我们相信,通过全面的学术研究和多学科合作来推动光学技术的发展,可以为未来能源系统的商业化做出重大贡献并带来巨大潜力。
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引用次数: 0
Enhancing the Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Through Cascade Structure Tuning for Highly Stable Biomass Upgrading 通过级联结构调整增强 5-羟甲基糠醛的电催化氧化作用,实现高稳定性生物质升级。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-22 DOI: 10.1007/s40820-024-01493-3
Xiaoli Jiang, Xianhui Ma, Yuanteng Yang, Yang Liu, Yanxia Liu, Lin Zhao, Penglei Wang, Yagang Zhang, Yue Lin, Yen Wei

Highlights

  • A novel cascade strategy is proposed to construct Pd-NiCo2O4 electrocatalyst.

  • First time discovery that Ni incorporation together with Pd loading is able to balance the competitive adsorption of OH and 5-hydroxymethylfurfural.

  • Pd–NiCo2Opromotes both the indirect and direct synergistic oxidation process.

  • Pd–NiCo2O4 catalyst exhibits extraordinary current density and excellent Faradaic Efficiency at a low potential.

电催化 5-羟甲基糠醛氧化反应(HMFOR)为将生物质衍生物转化为高附加值化学品提供了一种前景广阔的策略。本文提出了一种级联策略,通过在掺镍 Co3O4 上负载钯来构建 Pd-NiCo2O4 电催化剂,从而实现高活性和稳定的 HMF 氧化协同反应。在 1.5 V 的电压下,电流密度可达 800 mA cm-2,连续 10 次电解的法拉第效率和 2,5-呋喃二甲酸的产率均接近 100%。实验和理论结果表明,钯原子的引入可以调节 Ni/Co 的局部电子结构,不仅平衡了 HMF 和 OH- 物种的竞争吸附,还促进了活性 Ni3+ 物种的形成,诱导了高间接氧化活性。我们还发现,Ni 的加入促进了 Co2+ 的预氧化和亲电 OH* 的生成,有助于直接氧化过程。这项工作为设计先进的生物质升级电催化剂提供了一种新方法。
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引用次数: 0
Light-Activated Virtual Sensor Array with Machine Learning for Non-Invasive Diagnosis of Coronary Heart Disease 利用机器学习的光激活虚拟传感器阵列用于冠心病的非侵入性诊断。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-16 DOI: 10.1007/s40820-024-01481-7
Jiawang Hu, Hao Qian, Sanyang Han, Ping Zhang, Yuan Lu

Highlights

  • Photoresponsive black phosphorus (BP)/Ti3C2Tx composites were synthesized by a self-assembly strategy.

  • Enhanced gas sensitive property was achieved by visible light modulation.

  • Light activated virtual sensor array was fabricated based on BP/Ti3C2Tx composite.

  • Diagnosis of coronary heart disease was achieved with the help of machine learning.

早期无创诊断冠心病(CHD)至关重要。然而,通过检测呼气来实现冠心病的准确诊断具有挑战性。在这项工作中,利用自组装策略配制了具有高气体灵敏度和光响应性的黑磷(BP)与二维碳化物和氮化物(MXene)的异质结构复合物。在光调节下制备了基于 BP/Ti3C2Tx 的光激活虚拟传感器阵列(LAVSA),并将其进一步组装成即时气体传感平台(IGSP)。此外,还引入了机器学习(ML)算法,帮助 IGSP 检测和识别呼气样本信号,以诊断心脏病。由于 BP 和 Ti3C2Tx 以及光激发的协同作用,合成的异质结构复合物比原始 Ti3C2Tx 表现出更高的性能,响应值比原始 Ti3C2Tx 高 26%。此外,在模式识别算法的帮助下,LAVSA 成功地检测和识别了 15 种气味分子,分别与醇、酮、醛、酯和酸有关。同时,在 ML 的帮助下,IGSP 对 45 名健康人和心脏病患者志愿者呼气气味的检测准确率达到了 69.2%。总之,我们设计并制造出了一种即时、低成本、准确的原型,用于无创诊断心脏病,为诊断其他疾病和其他更复杂的应用场景提供了通用解决方案。
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引用次数: 0
Enhancing Defect-Induced Dipole Polarization Strategy of SiC@MoO3 Nanocomposite Towards Electromagnetic Wave Absorption 增强 SiC@MoO3 纳米复合材料对电磁波吸收的缺陷诱导偶极极化策略
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-16 DOI: 10.1007/s40820-024-01478-2
Ting Wang, Wenxin Zhao, Yukun Miao, Anguo Cui, Chuanhui Gao, Chang Wang, Liying Yuan, Zhongning Tian, Alan Meng, Zhenjiang Li, Meng Zhang

Highlights

  • Oxygen-vacancy-rich SiC@MoO3 nanocomposite with strong reflection loss (− 50.49 dB at 1.27 mm thickness) and broadband absorption band (8.72 GHz at 2.68 mm thickness) were constructed via in situ etching strategy.

  • The presence of oxygen vacancy leads to an increased conductive loss and defect-induced dipole polarization, which plays significant role in attenuating the incident electromagnetic wave.

过渡金属氧化物半导体(TMOs)中的缺陷工程正引起人们的极大兴趣,因为它可以通过有意引入缺陷来调节材料的电子结构,从而增强导电性。然而,要全面了解微结构与电磁波吸收能力之间的关系仍然遥不可及,这对过渡金属氧化物吸波材料的发展构成了巨大挑战。目前的研究描述了在碳化硅纳米线上沉积氧化钼层的过程,该过程是通过电沉积后高温煅烧实现的。随后,研究人员有意识地在 MoO3 层中制造氧空位,从而精确调整电磁特性,提高材料的微波吸收性能。值得注意的是,在匹配厚度为 1.27 mm 时,SiC@MO-t4 样品的最小反射损耗为 - 50.49 dB。此外,厚度为 2.81 毫米的 SiC@MO-t6 样品显示出 8.72 千兆赫的有效吸收带宽,全面覆盖了整个 Ku 波段。这些结果不仅凸显了缺陷工程在细微调整电磁特性方面的关键作用,也为应用缺陷工程方法拓宽电磁波吸收频谱提供了宝贵的启示。通过原位刻蚀 SiC@MoO3 纳米复合材料,制备了具有不同氧空位浓度的 SiC@MO-t 样品。氧空位的存在在调整带隙和局部电子分布方面起着至关重要的作用,这反过来又增强了导电性损耗和诱导极化损耗能力。这一发现揭示了一种通过缺陷工程改善电磁波吸收特性的新策略。
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引用次数: 0
3D-Printed MOF Monoliths: Fabrication Strategies and Environmental Applications 三维打印 MOF 单片:制造策略和环境应用。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-15 DOI: 10.1007/s40820-024-01487-1
Hossein Molavi, Kamyar Mirzaei, Mahdi Barjasteh, Seyed Yahya Rahnamaee, Somayeh Saeedi, Aliakbar Hassanpouryouzband, Mashallah Rezakazemi

Highlights

  • Challenges and future directions for 3D-printed metal-organic frameworks (MOFs) monoliths in environmental applications are discussed.

  • Various strategies for fabrication of 3D-printed MOF monoliths are summarized.

  • Advancements in 3D printing enable customizable and high-performance MOF monoliths.

  • 3D orienting of MOFs opens avenues for applications in water treatment and gas adsorption.

金属有机框架(MOFs)具有比表面积大、孔隙率高、结构和组成可定制、功能多样、孔隙/尺寸分布控制良好等特点,被广泛认为是最有前途的多孔和结晶有机无机材料之一。然而,大多数已开发的 MOFs 都是粉末状的,仍然存在一些技术难题,包括磨损、粉尘、堆积密度低、堵塞、传质/传热限制、环境污染以及堆积过程中的机械不稳定性等,限制了它们在工业应用中的适用性。因此,近年来,人们将注意力集中在将 MOF 粉末转化为珠子、膜、单片、凝胶/海绵和纳米纤维等宏观材料的技术上,以克服这些挑战。三维(3D)打印技术可以根据数字模型生产出许多具有复杂形状和几何结构的高分辨率宏观框架,因此备受关注。因此,本综述总结了不同三维打印策略与 MOFs 和 MOF 基材料的结合,用于制造三维打印 MOF 单体及其环境应用,重点是水处理和气体吸附/分离应用。本文结合相关实例,介绍了制造三维打印MOF单体的各种策略,如直接墨水写入、种子辅助原位生长、固体前驱体配位复制、基质掺入、选择性激光烧结和数字光处理等。最后,还介绍了三维打印 MOF 单体的未来发展方向和挑战,以便更好地规划未来 MOF 材料的成型轨迹,改进对三维打印 MOF 单体的结构、组成和纹理特性的控制。
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引用次数: 0
Selection of Negative Charged Acidic Polar Additives to Regulate Electric Double Layer for Stable Zinc Ion Battery 选择带负电荷的酸性极性添加剂来调节稳定锌离子电池的双电层。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-14 DOI: 10.1007/s40820-024-01475-5
Xing Fan, Lina Chen, Yongjing Wang, Xieyu Xu, Xingxing Jiao, Peng Zhou, Yangyang Liu, Zhongxiao Song, Jiang Zhou

Highlights

  • Negative charged acidic polarity (NCAP) has been unveiled as the guideline for selecting additives to regulate electric double layer (EDL) for Zn-ion batteries.

  • NCAP glutamate has been verified to regulate EDL structure with synergetic effects, including preferential adsorption on Zn anode and reconstruction of hydrated Zn-ion clusters.

  • Adding NCAP additives, Zn|Cu half-cell achieves a high Coulombic efficiency of 99.83% for 2000 cycles, and NH4V4O10|Zn full cell realizes a high-capacity retention of 82.1% for 3000 cycles.

锌离子电池在大规模电化学储能系统中大有可为,但仍存在界面问题,例如氢演化副反应(HER)、自腐蚀和不可控制的树枝状锌电沉积。虽然电双电层(EDL)的调节作用已在界面问题上得到验证,但选择添加剂作为调节剂的原理仍是迷雾重重。在此,我们研究了几种具有不同特性的典型氨基酸,以揭示在锌阳极上调节双电层的界面行为。带负电荷的酸性极性(NCAP)已被揭示为选择添加剂的准则,以重建具有内部亲锌 H2O 贫层的 EDL,并用 NCAP 谷氨酸取代水合 Zn2+ 的 H2O 分子。利用 EDL 调节的协同效应,通过抑制 HER 和抗自腐蚀的均匀电沉积,可显著稳定不可控界面。因此,通过添加 NCAP 谷氨酸钠,Zn|Cu 不对称电池在超过 2000 次循环后,Zn 金属的平均库仑效率高达 99.83%,而 NH4V4O10|Zn 全电池在 2 A g-1 条件下循环 3000 次后,显示出 82.1% 的高容量保持率。综上所述,这里公布的 NCAP 原理可加快设计用于锌基水性电化学储能系统的开拓性电解质添加剂。
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引用次数: 0
Overcoming the Limits of Cross-Sensitivity: Pattern Recognition Methods for Chemiresistive Gas Sensor Array 克服交叉灵敏度的限制:化学电阻式气体传感器阵列的模式识别方法。
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2024-08-14 DOI: 10.1007/s40820-024-01489-z
Haixia Mei, Jingyi Peng, Tao Wang, Tingting Zhou, Hongran Zhao, Tong Zhang, Zhi Yang

Highlights

  • The types, working principles, advantages and limitations of pattern recognition methods based on chemiresistive gas sensor array are reviewed and discussed comprehensively.

  • Outstanding and novel advancements in the application of machine learning methods for gas recognition in different important areas are compared, summarized and evaluated.

  • The current challenges and future prospects of machine learning methods in artificial olfactory systems are discussed and justified.

作为人工嗅觉的信息采集终端,化学电阻式气体传感器常常受到交叉敏感性的困扰,降低其对环境气体的交叉反应一直是气体传感领域的难点和重点。基于传感器阵列的模式识别是克服气体传感器交叉敏感性的最显著方法。选择合适的模式识别方法对于加强数据分析、减少误差、提高系统可靠性、获得更好的分类或气体浓度预测结果至关重要。在本综述中,我们分析了化学电阻式气体传感器交叉灵敏度的感应机制。我们进一步研究了气体传感阵列中使用的模式识别算法的类型、工作原理、特点和适用的气体检测范围。此外,我们还报告、总结和评估了用于气体识别的模式识别方法的突出和新进展。同时,本研究还展示了利用这些方法进行气体识别的最新进展,特别是在确保食品安全、监测环境和辅助医疗诊断这三个关键领域。总之,本研究通过考虑现有的情况和挑战,预测了未来的研究前景。希望这项工作能为减轻气敏设备的交叉敏感性做出积极贡献,并为气体识别应用中的算法选择提供有价值的见解。
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引用次数: 0
期刊
Nano-Micro Letters
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