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Hydrogen production from wastewater using interdigitated printed electrode-based Single-Chamber microbial electrolysis cells 利用基于互嵌印刷电极的单室微生物电解槽从废水中制氢
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-14 DOI: 10.1016/j.matdes.2024.113237

In the ever-increasing quest for alternative energy sources, hydrogen emerged as a promising green option, but efficient and economical production and management have been the primary constraints. Converting wastewater into H2 and other forms of energy attracted significant attention in terms of simultaneously and sustainably managing both the wastewater and the energy generation problems. Microbial Electrolysis Cells (MEC) evolved recently as promising options for converting wastewater into H2 and electricity but with serious constraints on scalability. The current research aims to explore design and manufacturing solutions to build structurally strong and electrochemically effective electrodes that can also lead to scalable MEC. Two designs based on the interdigitated and spiral electrode architectures are proposed and evaluated. The added design freedom with additive manufacturing by selective laser melting of specific alloys of choice is effectively utilised in physically prototyping the interdigitated and spiral electrode forms designed with controlled porosity constraints. Microstructural, electrochemical, and cell performance characterisations led to the understanding that the spiral electrode configuration with polypyrrole-coated stainless steel 316L anode is a promising design option for both longitudinal and lateral scale-up of the MEC.

在不断寻求替代能源的过程中,氢气成为一种前景广阔的绿色选择,但高效、经济的生产和管理一直是主要制约因素。将废水转化为氢气和其他形式的能源,在同时可持续地解决废水和能源生产问题方面引起了广泛关注。微生物电解池(MEC)是最近发展起来的将废水转化为 H2 和电力的有前途的选择,但在可扩展性方面存在严重制约。目前的研究旨在探索设计和制造解决方案,以建造结构坚固、电化学效果显著的电极,从而实现可扩展的微生物电解池。研究人员提出并评估了基于交错式和螺旋式电极结构的两种设计。通过选择性激光熔化特定合金的增材制造技术增加了设计自由度,这一点在设计具有受控孔隙率限制的交错式和螺旋式电极物理原型时得到了有效利用。通过对微结构、电化学和电池性能的分析,我们认识到,带有聚吡咯涂层的 316L 不锈钢阳极的螺旋电极配置是 MEC 纵向和横向扩展的理想设计方案。
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引用次数: 0
A critical review on machine learning applications in fiber composites and nanocomposites: Towards a control loop in the chain of processes in industries 机器学习在纤维复合材料和纳米复合材料中的应用评述:实现工业流程链中的控制环
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-13 DOI: 10.1016/j.matdes.2024.113247

Fiber composites must be evaluated to achieve correct use in various fields. Their properties, performance, condition, and integrity can be quickly predicted and optimized by machine learning (ML), after extensive training, compared with experiments and conventional computational simulations. In this document, papers on ML applications in fiber composites were collected and critically reviewed. It was revealed that kind learning environments have been primarily used. Supervised ML has been more frequently used than unsupervised ML, whereas some specific semi–supervised ML (e.g., reinforcement learning) or deep predictive control have been overlooked. Most ML applications have been successful on the laboratory scale and in the short term. Furthermore, the deployment of ML applications has been overlooked. In addition, retroactive feedback from the manufacturing of fiber and polymers to the manufacturing of composite laminates and structures was neglected. Accordingly, a control loop in the chain of manufacturing processes was discussed. Additionally, language processing tools and statistics were used to summarize and analyze the papers. Finally, it was proposed that multiscale modeling using ML and physics is a potential approach to advance predictions for future applications. Therefore, physicochemical interactions (van der Waals or electrostatic) from nanoscale can be included.

纤维复合材料必须经过评估才能在各个领域正确使用。与实验和传统计算模拟相比,通过机器学习(ML),经过大量训练,可以快速预测和优化纤维复合材料的特性、性能、状态和完整性。本文收集了有关 ML 在纤维复合材料中应用的论文,并对其进行了严格审查。结果显示,主要使用的是同类学习环境。有监督的 ML 比无监督的 ML 更常用,而一些特定的半监督 ML(如强化学习)或深度预测控制则被忽视。大多数 ML 应用在实验室规模和短期内都取得了成功。此外,人们还忽视了 ML 应用的部署。此外,从纤维和聚合物制造到复合材料层压板和结构制造的追溯反馈也被忽视。因此,讨论了制造过程链中的控制环。此外,还使用了语言处理工具和统计方法对论文进行总结和分析。最后,论文提出,使用 ML 和物理学进行多尺度建模是推进未来应用预测的一种潜在方法。因此,可以将纳米尺度的物理化学相互作用(范德华或静电)纳入其中。
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引用次数: 0
The nonlinear analysis of Portevin-Le Chatelier (PLC) effect: An application to medium Mn steel 波特文-勒夏特列(PLC)效应的非线性分析:中锰钢的应用
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-13 DOI: 10.1016/j.matdes.2024.113250

The instability of plastic flow in medium manganese steel was investigated through uniaxial tensile tests conducted at room temperature across various strain rates. The Portvin-Le Chatelier (PLC) effect was analyzed using statistical methods and a multifractal approach. The findings indicate that the zigzag stress–strain curves associated with instability plastic flow exhibit typical multifractal characteristics. Furthermore, the multifractal analysis quantifies the influence of strain rate and initial phase composition on the instability characteristics of the stress–strain curves. Specifically, it was observed that lower strain rates and austenite content correspond to a chaotic state, whereas higher strain rates and austenite content result in self-organizing critical dynamics. Finally, the underlying physical mechanisms driving these differing modes of behavior are discussed, with a focus on their relationship to strain rate and the initial austenitic phase fraction.

通过在室温下进行各种应变率的单轴拉伸试验,研究了中锰钢塑性流动的不稳定性。采用统计方法和多分形方法分析了波特文-勒夏特列(PLC)效应。研究结果表明,与不稳定塑性流动相关的之字形应力-应变曲线表现出典型的多分形特征。此外,多分形分析还量化了应变速率和初始相组成对应力-应变曲线不稳定性特征的影响。具体而言,观察到较低的应变率和奥氏体含量对应于混乱状态,而较高的应变率和奥氏体含量则导致自组织临界动力学。最后,讨论了驱动这些不同行为模式的基本物理机制,重点是它们与应变速率和初始奥氏体相分数的关系。
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引用次数: 0
Modeling of bonding pressure based on the plastic deformation mechanism of interfacial voids closure in solid-state diffusion bonding 基于固态扩散键合中界面空隙闭合的塑性变形机制的键合压力建模
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-11 DOI: 10.1016/j.matdes.2024.113239

The model of the diffusion bonding pressure was established using the analysis calculation method and further verified by the finite element analysis (FEA) and the experiments. The normalized temperature was defined as the ratio of temperature and the melting point of the base materials. And the normalized bonding pressure was defined as the ratio of the applied bonding pressure and the yield strength at the bonding temperature. The contribution of the plastic deformation to the void closure expressed a linear relationship with the normalized bonding pressure, of which the slope was 3. The relationship was appropriate in TiAl6V4, pure copper C11000, aluminium alloy AA6061, stainless steel SUS 304, and Ni-based alloy Inconel 617 using analysis calculation. The diffusion bonding pressure design range can be summarized as σn = 0.05–0.577. Subsequently, the analytic computational model was verified by FEA. The results showed that the maximum stress was concentrated in the position of the void neck. And the linear relationship between the normalized bonding pressure and the bonded ratio was also tenable. There was a stable static error existed between FEA and the analytic computational analysis. Furthermore, the experimental verification showed the verification and accuracy of the analytic computational analysis results.

利用分析计算方法建立了扩散结合压力模型,并通过有限元分析(FEA)和实验进行了进一步验证。归一化温度定义为基体材料的温度与熔点之比。归一化粘合压力定义为施加的粘合压力与粘合温度下的屈服强度之比。通过分析计算,TiAl6V4、纯铜 C11000、铝合金 AA6061、不锈钢 SUS 304 和镍基合金 Inconel 617 的塑性变形对空隙闭合的贡献与归一化结合压力呈线性关系,斜率为 3。扩散结合压力设计范围可概括为 σn = 0.05-0.577。随后,分析计算模型通过有限元分析进行了验证。结果表明,最大应力集中在空隙颈部位置。归一化结合压力与结合率之间的线性关系也是成立的。有限元分析与解析计算分析之间存在稳定的静态误差。此外,实验验证也证明了分析计算分析结果的正确性和准确性。
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引用次数: 0
Effects of adding zeolite particles on the hierarchical microstructure of zeolite-geopolymer composites and their Sr2+ adsorption properties 添加沸石颗粒对沸石-土工聚合物复合材料分层微结构及其 Sr2+ 吸附性能的影响
IF 8.4 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-10 DOI: 10.1016/j.matdes.2024.113233
Samuel Vannier, Alban Gossard, Lucile Magnier, Vanessa Proust, Thomas David, Agnès Grandjean
Strontium ions can be removed from wastewater in fixed-bed reactors by adsorption on hierarchical materials (different pore sizes and phases). A detailed understanding of the materials multiscale structure is therefore crucial to optimize their sorption properties. This article presents a multi-technique approach developed to characterize the relationship between microstructure and adsorption in a range of Linde-type A (LTA) zeolite-geopolymer composites,. Two-dimensional scanning electron microscopy and 3D X-ray tomography were used to image the porous and solid phases at different length scales. Advanced numerical methods involving machine learning were applied to segment the images and provide quantitative morphological values describing the porous network geometry and the location and accessibility of the zeolite particles in the geopolymer. These results were then correlated with the materials sorption properties, measured in batch and column processes. Increasing the materials zeolite content (from 0 to 27 wt%) slowed down their adsorption kinetics but increased their maximal adsorption capacities from 20 to 49 mg.g and Sr-selectivity at equilibrium. In breakthrough experiments, the material with highest zeolite content had a much higher breakthrough volume passing from 169 to 478 ml in the presented experimental conditions (much higher wastewater decontamination capacity), but a shallower breakthrough curve (lower column efficiency).
在固定床反应器中,锶离子可以通过吸附在分层材料(不同的孔径和相位)上而从废水中去除。因此,详细了解材料的多尺度结构对于优化其吸附特性至关重要。本文介绍了一种多技术方法,用于表征一系列林德A型(LTA)沸石-土工聚合物复合材料的微观结构与吸附之间的关系。利用二维扫描电子显微镜和三维 X 射线断层扫描技术对不同长度尺度的多孔相和固相进行成像。应用机器学习的先进数值方法对图像进行分割,并提供描述多孔网络几何形状以及沸石颗粒在土工聚合物中的位置和可及性的定量形态值。然后,将这些结果与在间歇式和柱式工艺中测量的材料吸附特性相关联。增加材料的沸石含量(从 0 到 27 wt%)会减缓其吸附动力学,但会提高其最大吸附容量(从 20 mg.g 到 49 mg.g)和平衡时的硒选择性。在突破实验中,沸石含量最高的材料在实验条件下的突破体积从 169 毫升增加到 478 毫升(废水净化能力大大提高),但突破曲线较浅(色谱柱效率较低)。
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引用次数: 0
A detailed investigation of acetylated cellulose nanofiber films as a substrate for printed electronics 将乙酰化纤维素纳米纤维薄膜作为印刷电子产品基底的详细研究
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-10 DOI: 10.1016/j.matdes.2024.113230

The increased interest in printed electronics necessitates the development of suitable sustainable substrates for them. In this study, the suitability of acetylated cellulose nanofiber (ACNF) films as substrates for printed electronics were examined through (I) the ink-substrates interaction, (II) print quality, and (III) electrical and (IV) mechanical properties of the printed pattern on the ACNF substrates. The results have been compared with cellulose nanofiber (CNF) and commercial reference material (CRM) substrates. The wetting of the silver nanoparticle (AgNP) ink on the ACNF substrate was found out to be excellent. The thickness of the printed pattern increased and the hole area fraction decreased with each consecutive layer of ink. The comparative investigations demonstrated that the electrical properties of the printed patterns were almost as good for 4 layers of ink on the ACNF substrate (1.6 Ω resistance) as the ones on the CRM substrate (1.2 Ω resistance). Additionally, the printed pattern on the ACNF substrate endured the adhesion and bending tests significantly better compared to the CRM substrate. Therefore, this study demonstrates that ACNF substrates could be a suitable candidate for printed electronics, which are more sustainable yet with similar functionalities in comparison with the conventional fossil based substrates.

随着人们对印刷电子产品的兴趣与日俱增,有必要为其开发合适的可持续基材。在本研究中,通过(I)油墨与基材的相互作用、(II)印刷质量、(III)ACNF 基材上印刷图案的电气和(IV)机械性能,考察了乙酰化纤维素纳米纤维(ACNF)薄膜作为印刷电子基材的适用性。研究结果与纤维素纳米纤维(CNF)和商业参考材料(CRM)基底进行了比较。结果发现,银纳米粒子 (AgNP) 油墨在 ACNF 基底上的润湿性非常好。随着油墨层数的增加,印刷图案的厚度也随之增加,孔面积分数则随之减少。对比研究表明,在 ACNF 基底上印刷 4 层油墨的图案的电气性能(1.6 Ω 电阻)与在 CRM 基底上印刷的图案的电气性能(1.2 Ω 电阻)几乎一样好。此外,与 CRM 基底相比,ACNF 基底上的印刷图案能更好地经受粘附和弯曲测试。因此,这项研究表明,ACNF 基底面是印刷电子产品的合适候选材料,与传统的化石基底面相比,ACNF 基底面具有更强的可持续发展性和相似的功能。
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引用次数: 0
A novel method to establish friction coefficient model for numerical simulation of inertia friction welding 为惯性摩擦焊接数值模拟建立摩擦系数模型的新方法
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-10 DOI: 10.1016/j.matdes.2024.113234

The precise friction coefficient at interface determines the friction behavior in inertia friction welding (IFW), its model is the basis to precisely describe the friction behavior in the numerical simulation of IFW. To measure the friction coefficient related to the temperature, pressure, and sliding velocity, the IFW trials between 2219-O Al alloy and 304 stainless steel were conducted with the simultaneous measurement of temperature and angular velocity evolutions. Two types of friction coefficient models were established by considering whether the effects of temperature and friction pressure were independent. The S-(T&P) L model, which considered the couple effect of temperature and friction pressure, was recommended as the best suitable model with its very high accuracy and best simplicity. The proposed model was successfully used in simulating the temperature evolution of IFW between Al alloy and steel tubes. The effect of the influencing variables on the friction coefficient was also discussed.

精确的界面摩擦系数决定了惯性摩擦焊接(IFW)中的摩擦行为,其模型是在 IFW 数值模拟中精确描述摩擦行为的基础。为了测量与温度、压力和滑动速度相关的摩擦系数,对 2219-O Al 合金和 304 不锈钢进行了惯性摩擦焊接试验,同时测量了温度和角速度的变化。通过考虑温度和摩擦压力的影响是否独立,建立了两种摩擦系数模型。考虑了温度和摩擦压力耦合效应的 S-(T&P) L 模型以其极高的精度和最佳的简易性被推荐为最合适的模型。所提出的模型被成功地用于模拟铝合金和钢管之间 IFW 的温度演变。此外,还讨论了影响变量对摩擦系数的影响。
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引用次数: 0
Impact of design strategy favoring powder removal on mechanical performance of bio-inspired porous architectures for laser-based powder-bed fusion additive manufacturing 有利于去除粉末的设计策略对激光粉末床熔融快速成型制造中生物启发多孔结构机械性能的影响
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-10 DOI: 10.1016/j.matdes.2024.113240

Mass reduction is a concern both in mechanical engineering and living organisms to reduce energy and materials consumption. Lately, transfer of knowledge from biology to engineering has become easier thanks to additive manufacturing. Trabecular bone for example optimally adapts to the mechanical stress it undergoes. Mass reduction methods bio-inspired from trabecular architecture, proposed in the literature, are not always applicable for laser-based powder-bed fusion. In particular, bio-inspired mass reduction methods based on a material removal principle generate porosities throughout a solid initial part which can result in enclosed porosities that trap un-melted powders. Here, we propose a 3D depowderable bio-inspired mass reduction method. Powder removal was controlled in different samples through weighing and X-ray computed microtomography and the impact of the design strategy that ensures correct powder removal on mechanical performance (stiffness) was quantified. Mean performance difference is 10.35 % (between 1.82 % and 26.47 %). For stiff and light parts loaded in bending, the proposed method outperforms parts made of bulk steel alloy by leveraging an architecture bio-inspired from trabecular bone.

减少质量是机械工程和生物工程都关注的问题,目的是减少能源和材料消耗。最近,由于增材制造技术的出现,从生物学到工程学的知识转移变得更加容易。例如,骨小梁可最佳地适应其所承受的机械压力。文献中根据骨小梁结构提出的生物启发减小质量的方法并不总是适用于基于激光的粉末床融合。特别是,基于材料去除原理的生物启发质量还原方法会在整个固体初始部分产生孔隙,从而导致封闭的孔隙捕获未熔化的粉末。在这里,我们提出了一种三维可脱粉生物启发质量还原法。我们通过称重和 X 射线计算机显微层析技术控制了不同样品的粉末去除情况,并量化了确保正确去除粉末的设计策略对机械性能(刚度)的影响。平均性能差异为 10.35 %(介于 1.82 % 和 26.47 % 之间)。对于在弯曲状态下加载的刚度和重量较轻的部件,所提出的方法通过利用从骨小梁中获得的生物启发结构,在性能上优于由散钢合金制成的部件。
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引用次数: 0
Formation mechanism of blade surface integrity based on hybrid process of cryogenic minimum quantity lubrication and ultrasonic rolling strengthening process 基于低温最小量润滑和超声波滚动强化混合工艺的叶片表面完整性形成机制
IF 7.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-09 DOI: 10.1016/j.matdes.2024.113235

This study proposes a hybrid process method based on Cryogenic Minimum Quantity Lubrication and Ultrasonic Rolling Strengthening Process (CMQL-URSP) to improve the surface integrity and enhance the mechanical properties of blade surface. First, the principle of the CMQL-URSP hybrid process was described. Second, the TEM experiments were conducted to clarify the influence of the CMQL-URSP hybrid process on aircraft engine blades. Finally, the blade processing experiments were performed to demonstrate the effectiveness of the CMQL-URSP hybrid process on the blade surface micro-morphology, micro-hardness and residual stress. The results indicate that the CMQL-URSP hybrid process effectively overcomes the limitations inherent to the solitary application of URSP. The CMQL process inhibits work hardening, thereby allowing the URSP to achieve better low-plastic surface improvement. Grain refinement governed by the continuous dynamic recrystallization mechanism leads to the formation of nanocrystals, which significantly improves mechanical properties of blade surface. The CMQL-URSP hybrid process results in a reduction in surface roughness from Ra 2.644 μm to Ra 0.055 μm, an increase in surface residual compressive stress from 321 MPa to 657 MPa, and the formation of a reinforced layer with a depth of 3.7 mm on the blade, thereby enhancing the surface integrity of the blade.

本研究提出了一种基于低温最小量润滑和超声波滚动强化工艺(CMQL-URSP)的混合工艺方法,以改善叶片表面完整性并提高其机械性能。首先,介绍了 CMQL-URSP 混合工艺的原理。其次,通过 TEM 实验阐明了 CMQL-URSP 混合工艺对航空发动机叶片的影响。最后,进行了叶片加工实验,以证明 CMQL-URSP 混合工艺对叶片表面微形态、微硬度和残余应力的影响。结果表明,CMQL-URSP 混合工艺有效克服了单独应用 URSP 所固有的局限性。CMQL 工艺抑制了加工硬化,从而使 URSP 能够更好地改善低塑性表面。由连续动态再结晶机制控制的晶粒细化导致纳米晶体的形成,从而显著改善了叶片表面的机械性能。CMQL-URSP 混合工艺使表面粗糙度从 Ra 2.644 μm 降至 Ra 0.055 μm,表面残余压应力从 321 MPa 增至 657 MPa,并在叶片上形成了深度为 3.7 mm 的强化层,从而提高了叶片的表面完整性。
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引用次数: 0
Revealing the mechanism of abruptly dropping of the wetting angle for the cast iron and zirconia ceramic system 揭示铸铁和氧化锆陶瓷体系润湿角骤降的机理
IF 8.4 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-08 DOI: 10.1016/j.matdes.2024.113232
Zilong Zhao, Yefei Li, Qiaoling Zheng, Dawei Yi, Hao Cheng, Su Zhang
The wettability behavior and characteristics of the high chromium cast iron (HCCI)/zirconium dioxide system were studied using the sessile drop method. A complete and uniform layer of titanium was prepared on the surface of ZrO ceramics using the salt bath coating method. The introduction of titanium reduced the contact angle of the HCCI/ZrO system abruptly from 110° to approximately 13°, at the solid/liquid interface, no complete layer of reaction products was detected, XRD results indicated that TiO, ZrO, and non-stoichiometric ZrO were primarily formed at the interface; thereby the spreading of HCCI on the Ti-coated ZrO ceramic plate was primarily dominated by the adsorption of titanium elements at the interface with generation of non-stoichiometric ZrO, and the diffusion of Fe and Cr elements into the interior of the ceramics. Meanwhile, the introduction of titanium elements at the interface between HCCI and ZrO benefits the preparation of metallurgical well-bonded composite interfaces.
采用无梗滴法研究了高铬铸铁(HCCI)/二氧化锆体系的润湿行为和特性。采用盐浴涂覆法在氧化锆陶瓷表面制备了一层完整均匀的钛层。钛的引入使 HCCI/ZrO 体系的接触角从 110°骤降至约 13°,在固/液界面上,没有检测到完整的反应产物层,XRD 结果表明,在界面上主要形成了 TiO、ZrO 和非均相 ZrO;因此,HCCI 在钛涂层 ZrO 陶瓷板上的扩散主要由钛元素在界面上的吸附和非均相 ZrO 的生成以及铁和铬元素向陶瓷内部的扩散所主导。同时,在 HCCI 和 ZrO 之间的界面引入钛元素有利于制备冶金结合良好的复合界面。
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引用次数: 0
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