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Magnetic field regulation of mouse bone marrow mesenchymal stem cell behaviours on TiO2 nanotubes via surface potential mediated by Terfenol-D/P(VDF-TrFE) film Terfenol‐D/P(VDF‐TrFE)膜介导的表面电位对小鼠骨髓间充质干细胞在TiO2纳米管上行为的磁场调节
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-08-08 DOI: 10.1049/bsb2.12042
Haisheng Qi, Qi Ke, Qiwen Tang, Lei Yin, Lixin Yang, Chengyun Ning, Jianyu Su, Liming Fang

It is challenging to match the mutual interactions between implant and host because the biomaterials usually cannot actively adjust their performance to the changing microenvironment. Surface potential is one of the critical factors affecting the bioactivity of biomaterials, but it is difficult to be directly controlled in vivo. Magnetic stimulation has attracted much attention due to its deep penetrability, good reliability, and convenient operability. Here, titanium dioxide (TiO2) nanotubes and Terfenol-D/P(VDF-TrFE) composite film are prepared by anodic oxidation and solution casting methods on opposite sides of a titanium sheet, respectively. Terfenol-D magnetostrictive microparticles deform under a magnetic field, generating surface potential on the P(VDF-TrFE) piezoelectric matrix through magneto-electric coupling. Correspondingly, equal opposite charges are induced on the surface of TiO2 nanotubes. Stem cells cultured on TiO2 nanotubes show that cell adhesion, proliferation, and differentiation abilities can be regulated by magnetic strength, which correlates with the absorption of charged proteins. Therefore, a cascade coupling of magnetic, mechanical, electric, biochemical, and cellular effects is established. This work demonstrates the feasibility of regulating the bioactivity of biomaterials in vivo through a magnetic field.

由于生物材料通常不能主动调整其性能以适应不断变化的微环境,因此很难匹配种植体与宿主之间的相互作用。表面电位是影响生物材料生物活性的关键因素之一,但在体内很难直接控制。磁刺激因其渗透性深、可靠性好、操作方便等优点而备受关注。本文采用阳极氧化法和溶液铸造法分别在钛片的两侧制备了二氧化钛(TiO2)纳米管和Terfenol-D/P(VDF-TrFE)复合膜。Terfenol-D磁致伸缩微粒在磁场作用下变形,通过磁电耦合在P(VDF-TrFE)压电基体上产生表面电位。相应的,TiO2纳米管表面会产生相等的相反电荷。在TiO2纳米管上培养的干细胞表明,细胞的粘附、增殖和分化能力可以受到磁场强度的调节,而磁场强度与带电蛋白的吸收有关。因此,建立了磁、机械、电、生化和细胞效应的级联耦合。这项工作证明了通过磁场调节生物材料体内生物活性的可行性。
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引用次数: 3
Metal surface wettability modification by nanosecond laser surface texturing: A review 纳秒激光表面织构修饰金属表面润湿性的研究进展
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-06-07 DOI: 10.1049/bsb2.12039
Zhifang Liu, Tong Niu, Yaxi Lei, Yuanxin Luo

Laser surface texturing (LST) is a non-contact manufacturing process for fabricating functional surfaces in a manner that improves the corresponding wettability, and is widely used in biomedicine and industry. Laser surface texturing is a facile approach that is compatible with various materials, can result in a hierarchical texture, and enables a high degree of surface wetting (i.e., extreme wetting). In addition to surface structures, surface chemical modification is a primary factor in producing extreme wetting surfaces. This review discusses the effects of various surface textures and surface chemistries on wettability. Optimal laser parameters for the desired surface texture are based on the fundamental wettability and laser mechanism. In particular, bumps in the morphology are conducive to obtaining extreme wetting. Diverse surface chemical strategies result in extreme wetting by different mechanisms. This paper makes a rigorous evaluation of the laser parameters and optimal surface chemical modifications by elucidating the relationships between the surface structure, surface chemical modification, and wettability, and in so doing, determines the final wettability. The unresolved problems of LST are presented in the conclusion. This review provides guidance, development directions, and an integrated framework for LST, which will be useful for fabricating extreme wetting surfaces on various metals.

激光表面织构(LST)是一种非接触制造工艺,以提高相应的润湿性来制造功能表面,在生物医学和工业中得到广泛应用。激光表面纹理是一种简单的方法,与各种材料兼容,可以产生分层纹理,并实现高度的表面润湿(即极端润湿)。除了表面结构外,表面化学修饰是产生极端润湿表面的主要因素。本文讨论了各种表面结构和表面化学对润湿性的影响。获得所需表面纹理的最佳激光参数是基于基本的润湿性和激光机理。特别是,形态上的凹凸有利于获得极端润湿。不同的表面化学策略通过不同的机制导致极端润湿。本文通过阐明表面结构、表面化学修饰和润湿性之间的关系,对激光参数和最佳表面化学修饰进行了严格的评估,从而确定了最终的润湿性。结论部分提出了LST尚未解决的问题。本文综述为LST的研究提供了指导、发展方向和一个完整的框架,将有助于在各种金属表面上制造极端润湿表面。
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引用次数: 12
Natural polymer-based adhesive hydrogel for biomedical applications 用于生物医学应用的天然聚合物基粘合剂水凝胶
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-06-07 DOI: 10.1049/bsb2.12036
Siyu Long, Chaoming Xie, Xiong Lu

Hydrogel is a polymer network system that can form a hydrophilic three-dimensional network structure through different cross-linking methods. In recent years, hydrogels have received considerable attention due to their good biocompatibility and biodegradability by introducing different cross-linking mechanisms and functional components. Compared with synthetic hydrogels, natural polymer-based hydrogels have low biotoxicity, high cell affinity, and great potential for biomedical fields; however, their mechanical properties and tissue adhesion capabilities have been unable to meet clinical requirements. In recent years, many efforts have been made to solve these issues. In this review, the recent progress in the field of natural polymer-based adhesive hydrogels is highlighted. The authors first introduce the general design principles for the natural polymer-based adhesive hydrogels being used as excellent tissue adhesives and the challenges associated with their design. Next, their usages in biomedical applications are summarised, such as wound healing, haemostasis, nerve repair, bone tissue repair, cartilage tissue repair, electronic devices, and other tissue repairs. Finally, the potential challenges of natural polymer-based adhesive hydrogels are presented.

水凝胶是一种聚合物网络体系,可以通过不同的交联方式形成亲水性的三维网络结构。近年来,通过引入不同的交联机制和功能组分,水凝胶因其良好的生物相容性和生物降解性而备受关注。与人工合成的水凝胶相比,天然聚合物基水凝胶具有生物毒性低、细胞亲和力高的特点,在生物医学领域具有很大的应用潜力;然而,它们的力学性能和组织粘附能力还不能满足临床要求。近年来,人们为解决这些问题做出了许多努力。本文综述了近年来天然聚合物基胶粘剂水凝胶领域的研究进展。作者首先介绍了天然聚合物基胶粘剂水凝胶作为优良组织胶粘剂的一般设计原则及其设计中面临的挑战。其次,总结了它们在生物医学中的应用,如伤口愈合、止血、神经修复、骨组织修复、软骨组织修复、电子设备和其他组织修复。最后,提出了天然聚合物基胶粘剂水凝胶的潜在挑战。
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引用次数: 3
Preparation of a biomimetic superomniphobic hierarchical structure and analysis of droplet wettability 仿生超全憎层次化结构的制备及液滴润湿性分析
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-05-18 DOI: 10.1049/bsb2.12037
Jing Li, Qunxiang Feng, Nan Guo, Fei Wang, Xin Du, Feng Du

In this study, a bioinspired hierarchical structure was formed with superomniphobicity on a 7075 aluminium alloy using laser ablation. The morphology and wetting characteristics of the biomimetic sample surface were characterised using scanning electron microscopy, laser confocal microscopy, and contact angle measurements. The effect of the liquid properties and surface structures on the rolling behaviour was investigated. The results suggest that the fabricated biomimetic sample surface was a hierarchical structure. The prepared sample had superomniphobicity and low adhesion properties, and the contact angles of six different liquid droplets on the sample surface reached or approached 150°. Specifically, the largest contact angle was 152°, and the average rolling angle was 7.7°. This multi-hydrophobic surface provides a valuable reference for the research study and use of a variety of solid–liquid contacts.

在本研究中,利用激光烧蚀在7075铝合金上形成了具有超疏水性的仿生分层结构。利用扫描电子显微镜、激光共聚焦显微镜和接触角测量对仿生样品表面的形貌和润湿特性进行了表征。研究了液体性质和表面结构对轧制性能的影响。结果表明,制备的仿生样品表面呈层次结构。制备的样品具有超疏水性和低粘附性能,6种不同液滴在样品表面的接触角达到或接近150°。其中,最大接触角为152°,平均滚动角为7.7°。这种多疏水表面为各种固液接触的研究和使用提供了有价值的参考。
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引用次数: 1
Bio-tribological characterisation of ultra-high molecular weight polyethylene against different metal counterparts 超高分子量聚乙烯对不同金属对应物的生物摩擦学特性
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-05-11 DOI: 10.1049/bsb2.12038
Hua Xin, Haitao Liang, Lei Zhang, JunHong Jia, Xiashuang Li, Zhongmin Jin

Excessive wear is a key issue affecting the performance of ultra-high molecular weight polyethylene (UHMWPE)-based artificial prosthesis. This work is focussed on the bio-tribology behaviours of UHMWPE when mating with different metal counterparts (iron-based 316L, Co-based Stellite-S21 and Stellite-S22). According to the ASTM F732 standard, two million cycles comparative wear tests were carried out under bovine serum lubrication. When coupled with S21, S22, and 316L metal counterparts, the obtained average wear factors of UHMWPE were 1.333 ± 0.192, 1.360 ± 0.160, and 1.190 ± 0.177 × 10−6 mm3/N · m, respectively. Initial surface roughness of the metal counterpart has shown an important role in controlling the volume of UHMWPE wear, especially the first one million cycles. Compared with 316L, CoCrMo-based counterparts possessed relative higher hardness and exhibited less rise in surface roughness caused by wear. For UHMWPE-on-metal bearings, random scratch, surface pit, and wear debris attachment were commonly seen, which suggested the coexistence of abrasion, third-body abrasion, and adhesion-based wear. In contrast, the metal counterpart was slightly scratched with no polymer transfer film formation. The work conducted in the present study gives useful knowledge regarding the UHMWPE-on-metal bearing design. With an intention to minimise wear, surface roughness of metal counterpart should be carefully controlled.

过度磨损是影响超高分子量聚乙烯(UHMWPE)人工假体性能的关键问题。这项工作的重点是UHMWPE与不同金属材料(铁基316L、钴基Stellite-S21和Stellite-S22)配合时的生物摩擦学行为。根据ASTM F732标准,在牛血清润滑下进行了200万次循环比较磨损试验。当UHMWPE与S21、S22和316L金属材料耦合时,其平均磨损系数分别为1.333±0.192、1.360±0.160和1.190±0.177 × 10−6 mm3/N·m。金属材料的初始表面粗糙度对UHMWPE磨损量的控制具有重要作用,特别是在前一百万次循环中。与316L合金相比,cocrmo基合金的硬度相对较高,磨损引起的表面粗糙度上升较小。对于uhmwpe -金属轴承,常见的是随机划痕、表面凹坑和磨损碎屑附着,这表明磨损、第三体磨损和粘附磨损并存。相比之下,金属对应物被轻微划伤,没有聚合物转移膜形成。本研究为超高分子量聚乙烯-金属轴承设计提供了有用的知识。为了尽量减少磨损,应仔细控制金属对应物的表面粗糙度。
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引用次数: 1
Finite element analysis of tibio-femoral contact mechanics of a customised knee spacer 定制膝关节垫片胫股接触力学的有限元分析
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-04-27 DOI: 10.1049/bsb2.12035
Alex C. T. Choh, Andy Yew, Seng Jin Yeo, Desmond Y. R. Chong, Shi-Lu Chia

With one-third of patients having osteoarthritis predominantly in one compartment of the knee, unicompartmental knee spacers have been introduced as a less invasive alternative to total knee replacement. However, patients with the knee spacer implanted were seen to have persistent pain, resulting in high revision rates. A static finite element model of the knee and its interaction with a knee spacer implant at full extension and 90° flexion was used to investigate the tibio-femoral contact mechanics of the knee joint after a knee spacer surgery. Three different knee spacer designs (contoured, flat and C-shaped) were modelled and prescribed with cobalt-chrome, ultra-high molecular polyethylene and polyurethane material properties. The results suggested that a softer spacer is generally preferred as this helps in the conformity of knee spacer to the condyle, effectively distributing the load subjected to the implant. Flat spacers that result in high stresses resulting from lower contact areas should be avoided.

由于三分之一的患者骨关节炎主要发生在膝关节的一个腔室,单腔室膝关节间隔器作为一种侵入性较小的替代全膝关节置换术被引入。然而,植入膝关节垫片的患者出现持续疼痛,导致翻修率高。采用膝关节静态有限元模型及其与膝关节间隔植入物在完全伸展和90°屈曲时的相互作用来研究膝关节间隔手术后膝关节的胫股接触力学。三种不同的膝关节间隔设计(轮廓,平面和c形)建模并规定了钴铬,超高分子聚乙烯和聚氨酯材料的性能。结果表明,较软的垫片通常是首选,因为这有助于膝关节垫片与髁状突的一致性,有效地分配受植入物的负荷。应避免使用因接触面积较低而产生高应力的扁平垫片。
{"title":"Finite element analysis of tibio-femoral contact mechanics of a customised knee spacer","authors":"Alex C. T. Choh,&nbsp;Andy Yew,&nbsp;Seng Jin Yeo,&nbsp;Desmond Y. R. Chong,&nbsp;Shi-Lu Chia","doi":"10.1049/bsb2.12035","DOIUrl":"10.1049/bsb2.12035","url":null,"abstract":"<p>With one-third of patients having osteoarthritis predominantly in one compartment of the knee, unicompartmental knee spacers have been introduced as a less invasive alternative to total knee replacement. However, patients with the knee spacer implanted were seen to have persistent pain, resulting in high revision rates. A static finite element model of the knee and its interaction with a knee spacer implant at full extension and 90° flexion was used to investigate the tibio-femoral contact mechanics of the knee joint after a knee spacer surgery. Three different knee spacer designs (contoured, flat and C-shaped) were modelled and prescribed with cobalt-chrome, ultra-high molecular polyethylene and polyurethane material properties. The results suggested that a softer spacer is generally preferred as this helps in the conformity of knee spacer to the condyle, effectively distributing the load subjected to the implant. Flat spacers that result in high stresses resulting from lower contact areas should be avoided.</p>","PeriodicalId":52235,"journal":{"name":"Biosurface and Biotribology","volume":"8 2","pages":"121-128"},"PeriodicalIF":0.0,"publicationDate":"2022-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ietresearch.onlinelibrary.wiley.com/doi/epdf/10.1049/bsb2.12035","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47425686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional fluorine-free superhydrophobic coating with flame-retardant, anti-icing, anti-corrosion, and oil–water separation properties 具有阻燃、防冰、防腐和油水分离性能的多功能无氟超疏水涂层
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-02-17 DOI: 10.1049/bsb2.12034
Shuyi Li, Chuankun Xie, Wenliang Zhang, Dongsong Wei, Zaihang Zheng, Yan Liu

A fluorine-free and multifunctional superhydrophobic coating (r-MSC) was prepared by the one-step spraying method. The coating had superhydrophobic and low-adhesion properties with the water contact angle of 161.5° ± 1° and the sliding angle of 3.2° ± 0.5°. It could be prepared by spraying while maintaining superhydrophobic surface characteristics on any substrates. The coating owed outstanding mechanical durability and chemical stability. Moreover, the coating also possessed the ability of self-cleaning, anti-fouling, anti-icing, and flame retardant ability. Importantly, the presence of multifunctional coating endowed the substrate with both water-resistant and fireproof properties. Besides, it also showed excellent oil-water separation ability, which presented the oil-water separation efficiency of over 90% for different types of oils after 10 separation cycles. Furthermore, the coating could improve corrosion inhibition performance and the corrosion current density was reduced by two orders of magnitude from the polarization curve. The r-MSC had the advantages of simple preparation, fluorine-free, environmentally friendly and appropriate for large-area fabrication, which could be applied to various fields.

采用一步喷涂法制备了一种无氟多功能超疏水涂层。涂层的水接触角为161.5°±1°,滑动角为3.2°±0.5°,具有超疏水性和低粘附性能。它可以通过喷涂制备,同时在任何基材上保持超疏水表面特性。该涂层具有优异的机械耐久性和化学稳定性。此外,该涂层还具有自洁、防污、防结冰和阻燃能力。重要的是,多功能涂层的存在赋予了基材防水和防火性能。此外,它还表现出优异的油水分离能力,经过10次分离循环,对不同类型的油水分离效率均在90%以上。镀层的缓蚀性能明显提高,腐蚀电流密度从极化曲线上看降低了2个数量级。该材料具有制备简单、无氟、环境友好、适合大面积制备等优点,可应用于各个领域。
{"title":"Multifunctional fluorine-free superhydrophobic coating with flame-retardant, anti-icing, anti-corrosion, and oil–water separation properties","authors":"Shuyi Li,&nbsp;Chuankun Xie,&nbsp;Wenliang Zhang,&nbsp;Dongsong Wei,&nbsp;Zaihang Zheng,&nbsp;Yan Liu","doi":"10.1049/bsb2.12034","DOIUrl":"10.1049/bsb2.12034","url":null,"abstract":"<p>A fluorine-free and multifunctional superhydrophobic coating (r-MSC) was prepared by the one-step spraying method. The coating had superhydrophobic and low-adhesion properties with the water contact angle of 161.5° ± 1° and the sliding angle of 3.2° ± 0.5°. It could be prepared by spraying while maintaining superhydrophobic surface characteristics on any substrates. The coating owed outstanding mechanical durability and chemical stability. Moreover, the coating also possessed the ability of self-cleaning, anti-fouling, anti-icing, and flame retardant ability. Importantly, the presence of multifunctional coating endowed the substrate with both water-resistant and fireproof properties. Besides, it also showed excellent oil-water separation ability, which presented the oil-water separation efficiency of over 90% for different types of oils after 10 separation cycles. Furthermore, the coating could improve corrosion inhibition performance and the corrosion current density was reduced by two orders of magnitude from the polarization curve. The r-MSC had the advantages of simple preparation, fluorine-free, environmentally friendly and appropriate for large-area fabrication, which could be applied to various fields.</p>","PeriodicalId":52235,"journal":{"name":"Biosurface and Biotribology","volume":"8 1","pages":"23-33"},"PeriodicalIF":0.0,"publicationDate":"2022-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ietresearch.onlinelibrary.wiley.com/doi/epdf/10.1049/bsb2.12034","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48165749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effect of plantar pressure on stepping friction under cross-slope condition 横坡条件下足底压力对踩踏摩擦力的影响
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-02-12 DOI: 10.1049/bsb2.12032
Yanzhao Wang, Deqiang Chen, Yongzhen Zhang, Yongping Niu, Xiaohui Yang

There are various walking pavements in daily life. Slip accidents will happen if required friction for safe walking is greater than available friction between the foot and ground surface. Existing researches mostly focus on horizontal or slope pavements, whereas the cross-slope walkways are less. A self-developed gait friction test platform was used to test friction, distribution of plantar pressure and spatiotemporal parameters of human walking under cross-slope condition. With the increase of cross-slope angles, the mediolateral friction increases (R 2 = 0.972, P < 0.001), the anterior-posterior friction shows no significant change (R 2 = 0.758, P = 0.017), the normal pressure decreases (R 2 = 0.915, P = 0.007), and the high foot is more prone to slip and fall than low foot. Therefore, plantar pressure distribution of both feet was shifted to left. The gait cycle was prolonged (P < 0.001), swing period of both feet decreased (P = 0.029) and support period increased (P = 0.015) with the increase of cross-slope angle.

日常生活中有各种各样的人行道。如果安全行走所需的摩擦力大于足部与地面之间的可用摩擦力,就会发生滑倒事故。现有的研究多集中在水平或斜坡人行道上,而跨坡人行道的研究较少。采用自行研制的步态摩擦试验平台,对人体在横坡条件下行走时的摩擦力、足底压力分布及时空参数进行了测试。随着横坡角的增大,中外侧摩擦力增大(r2 = 0.972, P <0.001),前后摩擦力无显著变化(r2 = 0.758, P = 0.017),正常压力降低(r2 = 0.915, P = 0.007),高足比低足更容易滑倒。因此,双脚的足底压力分布向左偏移。步态周期延长(P <0.001),随着横坡角的增大,双脚摆动周期减小(P = 0.029),支撑周期增大(P = 0.015)。
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引用次数: 0
Hydrophilic polymer-coated PVC surface for reduced cell and bacterial adhesions 亲水聚合物涂层PVC表面,减少细胞和细菌粘附
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-02-06 DOI: 10.1049/bsb2.12033
Rashed Almousa, Xin Wen, Sungsoo Na, Gregory Anderson, Dong Xie

Hydrophilic polymers are very useful in biomedical applications. In this study, biocompatible polyethylene glycol (PEG) and polyvinylpyrrolidone (PVP) polymers end-capped with succinimidyl groups were either modified or synthesised and attached to polyvinylchloride surfaces. The modified surfaces were evaluated with cell adhesion and bacterial adhesion. 3T3 mouse fibroblast cells and three bacteria species were used to evaluate surface adhesion activity. Results showed that the modified surface exhibited significantly reduced 3T3 cell adhesion with a 50%–69% decrease for PEG and a 64%–81% for PVP, as compared to unmodified polyvinylchloride. The modified surface also showed significantly reduced bacterial attachment with 22%–78%, 18%–76% and 20%–75% decrease for PEG and 22%–76%, 18%–76% and 20%–73% for PVP to Staphylococcus aureus, Escherichia coli and Pseudomonas aeruginosa, respectively, as compared to unmodified polyvinylchloride. It seems that an appropriate chain length or molecular weight (neither the longest nor the shortest chain length) determines the lowest cell and bacterial adhesion in terms of PEG. On the other hand, a mixture of polymers with different chain lengths exhibited the lowest cell and bacterial adhesion in terms of PVP.

亲水聚合物在生物医学应用中非常有用。在本研究中,生物相容性聚乙二醇(PEG)和聚乙烯吡咯烷酮(PVP)聚合物被修饰或合成,末端以琥珀酰亚胺基为上限,并附着在聚氯乙烯表面。用细胞黏附和细菌黏附来评价修饰后的表面。用3T3小鼠成纤维细胞和3种细菌评价表面粘附活性。结果表明,与未改性的聚氯乙烯相比,改性后的表面明显降低了3T3细胞的粘附,PEG降低了50%-69%,PVP降低了64%-81%。与未改性的聚氯乙烯相比,改性后的聚氯乙烯表面对金黄色葡萄球菌、大肠杆菌和铜绿假单胞菌的附着率分别降低22% ~ 78%、18% ~ 76%和20% ~ 75%,PVP的附着率分别降低22% ~ 76%、18% ~ 76%和20% ~ 73%。似乎合适的链长或分子量(既不是最长的链长也不是最短的链长)决定了PEG对细胞和细菌的最低粘附。另一方面,不同链长聚合物的混合物在PVP方面表现出最低的细胞和细菌粘附。
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引用次数: 3
Tribo-corrosion mechanisms and electromechanical behaviours for metal implants materials of CoCrMo, Ti6Al4V and Ti15Mo alloys CoCrMo、Ti6Al4V和Ti15Mo合金金属植入材料的摩擦学机制和机电性能
Q4 ENGINEERING, BIOMEDICAL Pub Date : 2022-01-26 DOI: 10.1049/bsb2.12031
Hongxiang Wang, Jingjing Zheng, Xiaolei Sun, Yong Luo

Corrosion and wear play significant roles in the aseptic loosening of artificial hip joints for the long-term service. In this present study, tribo-corrosion tests were carried out through a reciprocating ball-on-plate system to evaluate the corrosion and wear properties of CoCrMo, Ti6Al4V and Ti15Mo alloys in a simulated body fluid (SBF) solution. It was found that the tribo-corrosion behaviours of CoCrMo/Al2O3 and Ti15Mo/Al2O3 systems had significant wear-corrosion synergistic interaction, and wear-induced corrosion was dominant. For Ti6Al4V/Al2O3 systems, their wear mechanism under SBF lubrication was a combination of abrasive, adhesive and fatigue wear. While the wear mechanism of the Ti15Mo/Al2O3 system under synergistic interaction was a combination of abrasive and adhesive wear. Finally, it was suggested that the Ti15Mo alloy would be the better alternative for metal implant applications compared with the CoCrMo alloy for the consideration of both wear and potential poisonous ions such as Co(III) and Cr(VI).

腐蚀和磨损在人工髋关节无菌松动中起着重要的作用。在本研究中,通过往复球-板系统进行了摩擦腐蚀试验,以评估CoCrMo, Ti6Al4V和Ti15Mo合金在模拟体液(SBF)溶液中的腐蚀和磨损性能。结果表明:CoCrMo/Al2O3体系和Ti15Mo/Al2O3体系的摩擦腐蚀行为具有显著的磨损-腐蚀协同作用,以磨损腐蚀为主;对于Ti6Al4V/Al2O3体系,SBF润滑下的磨损机制为磨粒磨损、黏着磨损和疲劳磨损的结合。而Ti15Mo/Al2O3体系在协同作用下的磨损机制为磨粒磨损和粘着磨损的结合。最后,考虑到磨损和潜在的有毒离子如Co(III)和Cr(VI),建议与CoCrMo合金相比,Ti15Mo合金将是金属种植体应用的更好选择。
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引用次数: 3
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