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2015 IEEE International Interconnect Technology Conference and 2015 IEEE Materials for Advanced Metallization Conference (IITC/MAM)最新文献

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Thin amorphous silicon oxide ICPECVD layer on gold surface for surface plasmon resonance measurements 薄非晶氧化硅ICPECVD层在金表面表面等离子体共振测量
E. Herth, R. Zeggari, J. Rauch, F. Remy-Martin, W. Boireau
The present study demonstrates that thin layers of amorphous silicon oxide (SiOx) grown by inductively-coupled plasma enhanced chemical vapor deposition (ICPECVD) technology at lower temperatures can be successfully combined with biosensors. In particular, gold-amorphous silica (Au/SiOx) interfaces were investigated for their potential applications as a low-cost Surface Plasmon Resonance (SPR) sensor chip. We report here on the fabrication and characterization of stable and good reliabilities of SiOx deposited at 80°C at different pressures. The refractive index (n) of SiOx varied from 1.456 to 1.462. The results show that the sensitivity and minimum light reflectivity at the resonance angle is extremely sensitive to any changes in the index of refraction and any changes in optical thickness.
本研究表明,通过电感耦合等离子体增强化学气相沉积(ICPECVD)技术在较低温度下生长的非晶氧化硅(SiOx)薄层可以成功地与生物传感器结合。研究了金-非晶二氧化硅(Au/SiOx)界面作为低成本表面等离子体共振(SPR)传感器芯片的潜在应用。我们在这里报告了在80°C下不同压力下沉积的稳定和良好可靠性的SiOx的制备和表征。SiOx的折射率n在1.456 ~ 1.462之间变化。结果表明,谐振角处的灵敏度和最小光反射率对折射率和光学厚度的变化极为敏感。
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引用次数: 0
Influence of the substrate on the solid-state reaction of ultra-thin Ni film with a In0.53Ga0.47As under-layer by means of full 3D reciprocal space mapping 利用全三维倒易空间映射技术研究了衬底对含In0.53Ga0.47As的超薄Ni薄膜固相反应的影响
S. Zhiou, P. Rodriguez, P. Gergaud, F. Nemouchi, T. Thanh
We studied the solid-state reaction of Ni thin films with InGaAs layers grown on InP or Si substrates. The inter-metallics obtained carried an hexagonal structure, but yielded a difference in orientation regarding either the substrates or the annealing temperature.
我们研究了Ni薄膜与生长在InP或Si衬底上的InGaAs层的固相反应。所获得的金属间化合物具有六边形结构,但在衬底或退火温度方面产生了取向差异。
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引用次数: 5
Direct copper electrodeposition on novel CoMo diffusion barrier 新型CoMo扩散屏障上直接电沉积铜
Xu Wang, L. Cao, X. Qu
In this work, an alkaline electrolyte containing copper sulfate and ethanediamine (En) as ligand was used for direct Cu electrodeposition on novel alloy barrier CoxMoy films and comparison was made between alkaline bath and H2SO4-CuSO4 acidic bath. In alkaline bath, the nucleation density of Cu on Co1Mo3 is much higher than that in acidic bath. It is found that the Cu island density increases and the surface roughness decreases with the higher content of Co in CoxMoy films. Results show that adhesion between Cu and Co is better than that between Cu and Mo, which affects initial nucleation behavior and surface roughness of the deposited Cu films. Uniform and conformal copper was successfully electroplated on 5 nm Co1Mo3 layers covered patterned wafers in alkaline bath without additives.
本文采用以硫酸铜和乙二胺为配体的碱性电解液在新型合金屏障CoxMoy薄膜上直接电沉积Cu,并比较了碱性电解液和H2SO4-CuSO4酸性电解液的电沉积效果。在碱性浴中,Cu在Co1Mo3上的成核密度远高于酸性浴。结果表明,随着Co含量的增加,CoxMoy薄膜中的Cu岛密度增大,表面粗糙度降低。结果表明,Cu与Co之间的结合力优于Cu与Mo之间的结合力,这影响了Cu薄膜的初始成核行为和表面粗糙度。在无添加剂的碱性镀液中,成功地在覆盖图案晶圆的5 nm Co1Mo3层上电镀出均匀的共形铜。
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引用次数: 1
Post-etch template removal strategy for reduction of plasma induced damage in spin-on OSG low-k dielectrics 降低自旋OSG低k介电体等离子体损伤的刻蚀后模板去除策略
M. Krishtab, K. Vanstreels, S. De Gendt, M. Baklanov
In this study we demonstrate an approach for reduction of plasma induced damage in spin-on organosilica low-k dielectric films. These films are deposited from sols containing amphiphilic surfactant molecules as sacrificial phase. Both bulk material hydrophilization and surface roughening caused by etching plasma were significantly lowered. This is related to controlled partial removal of templating organic molecules at the material preparation stage. Short UV-assisted curing with broadband UV-light source (λ > 200 nm) was found to be an efficient strategy for the template residue removal applied after completing the etching process. Three steps of the proposed approach, including initial material pre-formation, etching and cleaning of pore walls from template residue, are investigated on blanket films.
在这项研究中,我们展示了一种减少等离子体诱导的自旋有机硅低k介电膜损伤的方法。这些薄膜是由含有两亲性表面活性剂分子作为牺牲相的溶胶沉积而成的。等离子体刻蚀引起的块状材料亲水性和表面粗化均显著降低。这与在材料制备阶段控制部分去除模板有机分子有关。利用宽带紫外光源(λ > 200 nm)进行短时间的紫外辅助固化是一种有效的去除模板残留的方法。研究了该方法的三个步骤,包括初始材料预成型、蚀刻和模板渣孔壁的清洗。
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引用次数: 1
Resistive switching in oxides for nonvolatile memories and neuromorphic computing 用于非易失性存储器和神经形态计算的氧化物的电阻开关
S. Spiga
Summary form only given. Resistive switching (RS) phenomena in oxides have received a large interest for ultra-scaled and high-density non-volatile memories, and many prototypes have been proposed at industrial level. Recently, RS have been also exploited for new type of applications, such as reconfigurable logic and synaptic electronics. In the latter field, the interest is towards RS devices which can be used to fabricate artificial synapses, able to emulate the synaptic functions of biological synapses, and to be integrated with standard CMOS circuits to build neuromorphic systems. These RS devices, also named memristive systems, are of particular interest due to their simple two terminal structure, low power operation, high-scalability, low thermal budget fabrication and, depending on material system, easy integration into CMOS based platform. This talk will first introduce the current state of the art and materials systems investigated for non-volatile memories as well as synaptic devices for neuromorphic circuits, highlighting the materials/device differences versus target application. Then, the talk will present our recent advancements on HfO2 and Al-doped-HfO2 based RS devices. The oxide layers (binary and doped oxides) are deposited by atomic layer deposition and the resistive switching properties are analysed from micro- to nanoscale. The fabrication of high-density and nanoscale HfOx-based memristive devices is achieved by block-copolymer lithography. Furthermore, in view of application of these devices as synaptic elements, the long term plasticity, as potentiation and depression typical of biological synapses, are characterized by various pulsed operation schemes. Special emphasis is given to programming algorithms based on a train of identical pulses. It will be shown that a careful choice of the pulse amplitude/pulse width combination is fundamental to achieve an analogue modulation of the device.
只提供摘要形式。氧化物中的电阻开关(RS)现象在超尺度和高密度非易失性存储器中引起了很大的兴趣,并且在工业水平上提出了许多原型。近年来,RS也被用于新型应用,如可重构逻辑学和突触电子学。在后一个领域,兴趣是RS设备,可用于制造人工突触,能够模拟生物突触的突触功能,并与标准CMOS电路集成以构建神经形态系统。这些RS器件也被称为忆阻系统,由于其简单的双端结构,低功耗运行,高可扩展性,低热预算制造以及根据材料系统易于集成到基于CMOS的平台而受到特别关注。本讲座将首先介绍非易失性记忆的最新技术和材料系统,以及神经形态电路的突触装置,重点介绍材料/装置与目标应用的差异。然后,演讲将介绍我们在HfO2和al -掺杂HfO2的RS器件方面的最新进展。采用原子层沉积法制备了氧化层(二元氧化物和掺杂氧化物),并从微观到纳米尺度分析了其电阻开关性能。利用嵌段共聚物光刻技术,实现了高密度纳米级hfox基忆阻器件的制备。此外,鉴于这些装置作为突触元件的应用,不同的脉冲操作方案具有不同的长期可塑性,如生物突触的增强和抑制。特别强调了基于同一脉冲序列的编程算法。将表明,仔细选择脉冲幅度/脉冲宽度组合是实现器件模拟调制的基础。
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引用次数: 0
Demonstration of new planar capacitor (PCAP) vehicles to evaluate dielectrics and metal barrier thin films 新型平面电容(PCAP)车辆的演示,以评估电介质和金属阻隔薄膜
Kevin L. Lin, J. Bielefeld, J. Chawla, C. Carver, R. Chebiam, J. Clarke, Jacob Faber, M. Harmes, T. Indukuri, C. Jezewski, R. Kasim, M. Kobrinsky, N. Kabir, B. Krist, Narendra V. Lakamraju, H. Lang, E. Mays, A. Myers, J. Plombon, K. Singh, J. Torres, H. Yoo
Planar capacitors can quickly test material properties of metals and dielectrics for interconnects. A sidewall capacitor device is used to evaluate metal thin-film barriers. Etch stop planar capacitors in turn can test multi-layer etch stops, exposing differences between leaky and good etch stop films. Fillable planar capacitors are also fabricated and results presented for that class of fill materials.
平面电容器可以快速测试金属和电介质的材料性能。一种侧壁电容器装置用于评价金属薄膜屏障。蚀刻停止平面电容器反过来可以测试多层蚀刻停止,暴露泄漏和良好的蚀刻停止膜之间的差异。还制备了可填充的平面电容器,并给出了该类填充材料的结果。
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引用次数: 1
Reliability mechanisms and lifetime extrapolation methods for scaled interconnect technologies 规模化互连技术的可靠性机制和寿命外推方法
K. Croes, C. Wu, D. Kocaay, J. Bommels, Z. Tokei
We review our current understanding of the degradation mechanisms in scaled interconnects. Concerns on the applicability of today's reliability evaluation methods are expressed. Regarding electromigration (EM), both scaling line dimensions and using mechanically weaker intermetal dielectrics (IMDs) have a negative impact on its performance, where remedial measures to overcome this downward trend are discussed. With aggressively scaled barriers, we also show that EM test methodology adaptation towards constant voltage testing might be needed. Regarding dielectric reliability, we quantify the reliability degradation induced by both k-value and spacing reduction. Also, we review the current understanding on lifetime models used for predicting high field data to lower fields. Both for copper and dielectric reliability, we highlight that the development of ways to account for process variability during lifetime prediction will become key in the future.
我们回顾了目前对尺度互连中退化机制的理解。对现有可靠性评估方法的适用性表示了关注。对于电迁移(EM),垢线尺寸和使用机械较弱的金属间介电体(imd)都会对其性能产生负面影响,本文讨论了克服这种下降趋势的补救措施。对于大规模的障碍,我们还表明可能需要适应恒电压测试的电磁测试方法。对于介质可靠性,我们量化了k值和间距减小引起的可靠性退化。此外,我们回顾了目前对用于预测高场数据到低场数据的寿命模型的理解。对于铜和介质可靠性,我们强调,在寿命预测中考虑工艺变异性的方法的发展将成为未来的关键。
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引用次数: 2
In situ cleaning/passivation of surfaces for contact technology on III-V materials III-V材料接触技术表面的原位清洗/钝化
P. Rodriguez, L. Toselli, E. Ghegin, F. Nemouchi, N. Rochat, E. Martinez
In this work we introduce the use of physical plasmas (e.g. Ar- and He-based plasmas) in order to study the in situ cleaning (prior to metal deposition) of InGaAs layers dedicated to the realisation of self-aligned contacts. For the characterisation of cleaning efficiency, we performed surface analyses like X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy in attenuated total reflection mode. The first results described in this work are encouraging. We have found efficient processes for removing totally or partially III-V native oxides.
在这项工作中,我们介绍了物理等离子体(例如Ar基和he基等离子体)的使用,以研究用于实现自对准接触的InGaAs层的原位清洗(金属沉积之前)。为了表征清洁效率,我们在衰减全反射模式下进行了x射线光电子能谱和傅里叶变换红外能谱等表面分析。在这项工作中描述的第一个结果是令人鼓舞的。我们已经找到了完全或部分去除III-V原生氧化物的有效方法。
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引用次数: 0
Resistivity of sub-30 nm copper lines 30nm以下铜线的电阻率
J. Roberts, A. Kaushik, J. Clarke
Resistivity data are presented for lines from 22 nm to 108 nm wide measured at room temperature and at 4.6 K. We also present numerical simulation data for 2-10 nm features. The experimental data are fit with standard Mayadas-Shatzkes and Fuchs-Sondheimer models which indicate that electron scattering from surfaces and from grains are the main contributors to resistivity for small features. The simulation data show that surface scattering dominates resistivity at smaller dimensions. This suggests that improvements in resistivity should focus on minimizing the impact of surfaces and grains, which has implications for interconnect material selection.
电阻率数据为22 nm至108 nm宽的线,在室温和4.6 K下测量。我们还提供了2-10 nm特征的数值模拟数据。实验数据符合标准的Mayadas-Shatzkes和Fuchs-Sondheimer模型,表明来自表面和颗粒的电子散射是小特征电阻率的主要贡献因素。模拟数据表明,在较小的尺度上,表面散射优于电阻率。这表明电阻率的改进应该集中在最小化表面和晶粒的影响上,这对互连材料的选择有影响。
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引用次数: 18
Investigation of barrier formation and stability of self-forming barriers with CuMn, CuTi and CuZr alloys CuMn、CuTi和CuZr合金的势垒形成及自形成势垒的稳定性研究
M. Franz, R. Ecke, C. Kaufmann, J. Kriz, S. Schulz
In this work, we present the recent work on self-forming barriers. Focus on investigation laid on the barrier formation and its stability against copper diffusion. The investigated alloys were Cu(Mn), Cu(Ti) and Cu(Zr) respectively. It can be shown that these alloys are capable to form an enrichment layer on the SiO2 interface. Here the substrate influences mainly the thickness of the generated barrier. Electrical measurements show the barrier stability against copper diffusion. Mn and Ti are promising elements as barrier materials.
在这项工作中,我们介绍了自形成屏障的最新工作。重点研究了屏障的形成及其对铜扩散的稳定性。所研究的合金分别是Cu(Mn)、Cu(Ti)和Cu(Zr)。结果表明,这些合金能够在SiO2界面上形成富集层。在这里,衬底主要影响所生成势垒的厚度。电测量显示阻挡铜扩散的稳定性。锰和钛是很有前途的势垒材料。
{"title":"Investigation of barrier formation and stability of self-forming barriers with CuMn, CuTi and CuZr alloys","authors":"M. Franz, R. Ecke, C. Kaufmann, J. Kriz, S. Schulz","doi":"10.1109/IITC-MAM.2015.7325640","DOIUrl":"https://doi.org/10.1109/IITC-MAM.2015.7325640","url":null,"abstract":"In this work, we present the recent work on self-forming barriers. Focus on investigation laid on the barrier formation and its stability against copper diffusion. The investigated alloys were Cu(Mn), Cu(Ti) and Cu(Zr) respectively. It can be shown that these alloys are capable to form an enrichment layer on the SiO2 interface. Here the substrate influences mainly the thickness of the generated barrier. Electrical measurements show the barrier stability against copper diffusion. Mn and Ti are promising elements as barrier materials.","PeriodicalId":6514,"journal":{"name":"2015 IEEE International Interconnect Technology Conference and 2015 IEEE Materials for Advanced Metallization Conference (IITC/MAM)","volume":"64 1","pages":"95-98"},"PeriodicalIF":0.0,"publicationDate":"2015-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91266585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
2015 IEEE International Interconnect Technology Conference and 2015 IEEE Materials for Advanced Metallization Conference (IITC/MAM)
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