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2015 IEEE International Interconnect Technology Conference and 2015 IEEE Materials for Advanced Metallization Conference (IITC/MAM)最新文献

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Reliability study of liner/barrier/seed options for via-middle TSV's with 3 micron diameter and below 直径3微米及以下的中通径TSV衬垫/屏障/种子选择的可靠性研究
Yunlong Li, S. Van Huylenbroeck, P. Roussel, M. Brouri, S. Gopinath, D. M. Anjos, Matthew Thorum, Jengyi Yu, G. Beyer, E. Beyne, K. Croes
In high aspect ratio TSV's, the step coverage (conformality) of liner, barrier and seed is critical for both the integration and reliability. If the conformality of a deposition technique is improved, the required thickness to be deposited on the field of the wafer can be reduced. Consequently, less material needs to be removed by CMP on the field, which reduces the manufacturing cost. In this paper, the reliability of two liner/barrier/seed options, which were successfully integrated into via-middle TSV's with a diameter of 3 micron and an aspect ratio (AR) of 17 is investigated. Both controlled ramp rates (IVctri) as well as standard Time Dependent Dielectric Breakdown (TDDB) at 100°C were employed as electrical testing methods to investigate the dielectric and barrier reliability properties of the studied systems. The first studied system consists of a non-conformal CVD O3 TEOS liner, an ALD TiN barrier and a PVD Cu seed. The second studied system employs a conformal ALD liner, a thermal ALD WN barrier and an ELD NiB seed. Both studied systems show excellent reliability properties. Scalable highly conformal liners are more sensitive to local field enhancement at the high fields applied during highly accelerated tests which are far above normal operation conditions. Their performance at lower fields, however, still meets standard reliability specifications.
在高纵横比TSV系统中,衬垫、屏障和种子的阶跃覆盖(一致性)对系统的集成和可靠性至关重要。如果沉积技术的一致性得到改善,则可以减少在晶圆片上沉积所需的厚度。因此,CMP在现场需要去除的材料更少,从而降低了制造成本。本文对成功集成到直径为3微米、宽高比(AR)为17的中通径TSV中的两种衬垫/屏障/种子方案的可靠性进行了研究。采用100°C下的受控斜坡速率(IVctri)和标准时间相关介电击穿(TDDB)作为电气测试方法来研究所研究系统的介电和阻挡可靠性。第一个研究的系统由一个非共形CVD O3 TEOS衬垫、一个ALD TiN势垒和一个PVD Cu种子组成。第二个研究系统采用保形ALD衬垫,热ALD WN屏障和ELD NiB种子。两种系统均具有良好的可靠性。在远高于正常工作条件的高加速试验中,可伸缩的高保形衬管对高场的局部增强更加敏感。然而,在较低的油田,它们的性能仍然符合标准的可靠性规范。
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引用次数: 3
Robust TiN HM process to overcome under etch issue for SAV scheme on 14nm node 稳健的TiN HM工艺克服了14nm节点SAV方案的腐蚀问题
Tzu-Hao Fu, Y. Ke, Shi-Chun Tsai, Chun-Ling Lin, Kuo-Wei Chen, M. Huang, Gary Cho, San-Fu Lin, Ting-Jun Wang, A. Cheng
For advance node such as 14nm technology and beyond, back end of line interconnect has implemented self-aligned via (SAV) schemes for better via-metal short process window [1]. A TiN metal hard mask (MHM) is used for the trench pattern definition, after which via lithography and partial via (PV) etch is performed where the TiN was opened. The via etch condition has very good selectivity so that via is formed in a self-aligned fashion by TiN HM [2]. It is indeed to have significant benefit of via to metal short [3]. However, one of the trade off in SAV scheme is the via under etch that whether or not via can well land on an opened oxide area during PV etch. To define the contact area between via resist hole and opened HM oxide as an effective area for via to open successfully. “Fig. 1” shows the effective area change during process variation due to Via alignment, Via photo resist CD variation (Via ADICD) and post hard mask etch CD variation (AMICD). “Fig. 2” shows the mechanism of this under etch failure mode and typical TEM image from 64nm metal pitch test vehicle. In this work, we try to enlarge the process window by an aggressive AMICD targeting in combining with a higher density TiN material to maintain profile.
对于先进的节点,如14nm及以上的技术,后端线互连已经实现了自对准通孔(SAV)方案,以获得更好的通孔金属短工艺窗口[1]。TiN金属硬掩膜(MHM)用于沟槽图案定义,然后通过光刻和部分通孔(PV)蚀刻在TiN打开的地方进行。通过蚀刻条件具有很好的选择性,使得通过形成自对准方式的TiN HM[2]。确实是通过对金属短[3]有显著的好处。然而,SAV方案中的一个权衡是蚀刻下的通孔,在PV蚀刻期间,通孔是否能很好地落在开放的氧化区。确定通孔电阻孔与打开的HM氧化物之间的接触面积,作为通孔成功打开的有效面积。“图1”显示了在工艺变化过程中由于Via对准、Via光抗蚀CD变化(Via ADICD)和后硬掩模蚀刻CD变化(AMICD)而导致的有效面积变化。如图2所示为腐蚀失效模式下的机理,以及64nm金属间距测试车的典型TEM图像。在这项工作中,我们试图通过积极的AMICD瞄准结合更高密度的TiN材料来扩大工艺窗口,以保持轮廓。
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引用次数: 2
TC degradation and root-cause analysis of SACVD BPSG film for robust IC fabrication 稳健集成电路制造用SACVD BPSG薄膜的TC退化及根本原因分析
Jongwoo Park, Miji Lee, Hanbyul Kang, Donghwan Lee, Jungin Kim, S. Pae
Enhanced etch rate in the phosphorus enriched area in PTEOS/BPSG stacked interlayer dielectric (ILD) during contact open process were shown to have tungsten notch and micro-crack nucleation at the interface. Subsequent CVD TiN and W deposition can lead to penetration into this micro-crack that can lead to delamination after temperature cycling (TC) stress test. The notch defect was a result of higher etch rate at the PTEOS/BPSG interface due to high phosphorous concentration and profile associated with intrinsic process parameters and SACVD equipment. With further process optimization and tight process control, such defect free and robust production has been archived. Detailed failure mechanism using TEM and TOF-SIMS analyses and critical process parameters will be discussed and then intrinsic attributes of the SACVD equipment will be presented.
接触打开过程中PTEOS/BPSG层间介质(ILD)富磷区蚀刻速率增强,界面处出现钨缺口和微裂纹形核。随后的CVD TiN和W沉积会导致渗透到该微裂纹中,从而在温度循环(TC)应力测试后导致分层。缺口缺陷是由于PTEOS/BPSG界面的高磷浓度和与内在工艺参数和SACVD设备相关的轮廓导致较高的蚀刻速率造成的。通过进一步的工艺优化和严格的工艺控制,这种无缺陷和健壮的生产已经存档。利用TEM和TOF-SIMS分析和关键工艺参数讨论了详细的失效机制,然后介绍了SACVD设备的内在属性。
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引用次数: 0
Cobalt compatible cleaning solutions for 14nm and beyond 钴兼容的清洁解决方案,14纳米及以上
K. Courouble, L. Broussous, S. Zoll, K. Haxaire, M. Mellier, G. Druais
In this paper, wet cleaning solution compatible with cobalt are investigated to achieve low Co etching rate on blankets film and no film attack on patterned 14nm wafer after line and via etching. Proposed solutions are compared to conventional wet cleaning solutions.
本文研究了一种与钴相容的湿清洗溶液,以实现低Co在毯膜上的蚀刻率,并且在蚀刻后和蚀刻过程中对14nm图案化晶圆无膜侵蚀。提出的解决方案与传统的湿式清洗方案进行了比较。
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引用次数: 0
Morphic atomic switch networks for beyond-Moore computing architectures 超摩尔计算体系结构的形态原子交换网络
Renato Aguilera, Eleanor Demis, Kelsey S. Scharnhorst, A. Stieg, M. Aono, J. Gimzewski
We discuss the utility of ASNs as a uniquely scalable physical platform capable of hybrid-CMOS architectures and novel computation. Through a combination of controlled design with spontaneous self-organization, an atomic switch network (ASN) has been produce as a purpose-built complex system. A highly interconnected system of Ag2S resistive switches, the ASN has been shown to produce fault-tolerant switching and a set of complex dynamics similar to biological neural networks.
我们讨论了自动神经网络作为一个独特的可扩展的物理平台的效用,能够混合cmos架构和新颖的计算。通过控制设计与自发自组织的结合,原子交换网络(ASN)作为一种专门构建的复杂系统得以产生。ASN是一个高度互连的Ag2S电阻开关系统,已被证明可以产生容错开关和一组类似于生物神经网络的复杂动态。
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引用次数: 1
Modeling and analysis of vertical noise coupling between clock tree and channel routing wire in 3D mixed signal integration 三维混合信号集成中时钟树与信道路由线垂直噪声耦合建模与分析
Shiwei Wang, Yingtao Ding, Huanyu He, Jian-Qiang Lu
This paper reports on the vertical noise coupling between a clock wire in digital IC and channel routing wires in analog IC in 3D mixed signal integration. Full wave electromagnetic simulations are employed to evaluate the vertical noise coupling. The coupling mechanism is discussed with transfer impedance. Insights to vertical noise coupling between interconnects in 3D integration are offered and possible solutions are provided to reduce the noise.
本文研究了三维混合信号集成中数字集成电路中的时钟线与模拟集成电路中的通道布线线之间的垂直噪声耦合问题。采用全波电磁仿真对垂直噪声耦合进行了评价。从传递阻抗的角度讨论了耦合机理。对三维集成中互连之间的垂直噪声耦合提供了见解,并提供了可能的解决方案来降低噪声。
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引用次数: 1
Atomic oxygen treatment of carbon containing low-k dielectric materials to facilitate manganese silicate barrier formation 原子氧处理含碳低k介电材料,有利于锰硅酸盐阻挡层的形成
J. Bogan, A. McCoy, C. Byrne, R. O'Connor, G. Hughes
The surface treatment of low-k dielectric layers by exposure to atomic oxygen is presented as an alternative to plasma based treatments prior to barrier layer formation. High carbon content porous low-k dielectric films were subjected to increasing exposures of atomic oxygen and X-ray photoelectron spectroscopy (XPS) studies reveal both the depletion of carbon and the addition of oxygen at the surface. This treatment is shown to be thermally stable up to 400 °C. High resolution electron energy loss spectroscopy (EELS) elemental profiles show the removal of carbon from the surface of the treated films to a depth of ~ 20 nm. In a separate experiment manganese (~1-2 nm) was deposited on an oxygen treated substrate and thermally annealed to form MnSiO3. It is shown that the modification of the low-k surface made the chemical identification of MnSiO3 formation possible by XPS analysis.
通过暴露于原子氧的低k介电层的表面处理被提出作为在阻挡层形成之前基于等离子体的处理的替代方法。高碳含量的多孔低k介电膜受到原子氧的不断增加的暴露,x射线光电子能谱(XPS)研究揭示了表面碳的消耗和氧的增加。这种处理在高达400°C时表现出热稳定性。高分辨率电子能量损失谱(EELS)元素谱显示,碳从处理过的薄膜表面去除至~ 20nm深度。在另一项实验中,将锰(~1-2 nm)沉积在氧处理的衬底上并进行热退火以形成MnSiO3。结果表明,低k表面的修饰使得XPS分析可以对MnSiO3的形成进行化学鉴定。
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引用次数: 0
Nanocarbon interconnects: Demonstration of properties better than Cu and remaining issues 纳米碳互连:性能优于铜的演示和遗留问题
Shintaro Sato
Nanocarbon materials including graphene and carbon nanotubes (CNTs) are promising candidates for future LSI interconnects. We recently demonstrated sub-10-nm-wide graphene interconnects whose resistivity is lower than that of Cu with similar dimensions. In this paper, we first describe the fabrication and evaluation of such graphene interconnects. We then explain a newly-developed fabrication process for carbon nanotube (CNT) vias and plugs, which relies on implantation of CNTs into sub-micrometer-sized holes. We then point out further issues to be addressed for realizing nanocarbon interconnects.
包括石墨烯和碳纳米管(CNTs)在内的纳米碳材料是未来大规模集成电路互连的有前途的候选材料。我们最近展示了低于10纳米宽的石墨烯互连,其电阻率低于相似尺寸的铜。在本文中,我们首先描述了这种石墨烯互连的制造和评估。然后,我们解释了一种新开发的碳纳米管(CNT)过孔和塞的制造工艺,该工艺依赖于将碳纳米管植入亚微米大小的孔中。然后我们指出了实现纳米碳互连需要解决的进一步问题。
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引用次数: 2
Cobalt UBM for fine pitch microbump applications in 3DIC 钴UBM用于3DIC中的细间距微凸点应用
J. Derakhshandeh, I. de Preter, K. Vandersmissen, D. Dictus, L. di Piazza, L. Hou, S. Guerrieri, G. Vakanas, S. Armini, R. Daily, A. Lesniewska, Yannick Vandelaer, M. Van De Peer, J. Slabbekoorn, K. Rebibis, Andy Miller, G. Beyer, E. Beyne
In this paper we report results and challenges of replacing Cu with Co as UBM (under bump metallization) in microbumps for 3D technology applications. Cobalt has softer and single IMC (intermetallic compounds) and according to calculations using Cobalt as UBM can reduce consumption of UBM material by solder which is attractive for sub 10um pitches of microbumps. However, cobalt oxidizes very fast which results in poor wetting by solder as shown in Figure 1. This Figure shows two SEM images of cross section of 20um (left) and 50um (right) pitches microbumps from IMEC test vehicles where poor solder wetting is observed. It can be seen than in both cases Sn is deformed during TCB (thermo-compression bonding) bonding but due to oxide formation on cobalt bumps there is no reaction between Sn and Co. Such a joints may have weak electrical connection however, it is not suitable for a reliable device. Therefore surface treatment/passivation is required for cobalt bumps.
在本文中,我们报告了用Co代替Cu作为微凸点金属化(在凸点金属化下)用于3D技术应用的结果和挑战。钴具有较软的单一IMC(金属间化合物),根据计算,使用钴作为UBM可以通过焊料减少UBM材料的消耗,这对于小于10um间距的微凸起是有吸引力的。然而,钴氧化非常快,导致焊料润湿不良,如图1所示。该图显示了IMEC测试车辆上20um(左)和50um(右)间距微凸起的横截面的两张SEM图像,观察到焊料润湿不良。可以看出,在这两种情况下,Sn在TCB(热压键合)键合过程中都发生了变形,但由于钴凸起处形成了氧化物,因此Sn和Co之间没有发生反应。这种接头可能具有弱的电气连接,但不适合用于可靠的器件。因此,需要对钴凸起进行表面处理/钝化。
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引用次数: 9
Low-cost, single-step hybrid bond/barrier films for Cu bondlines in advanced packaging 用于先进封装中铜键线的低成本、单步混合键/障膜
Qiran Xiao, Brian L. Watson, R. Dauskardt
The presence of weak Cu-oxides has detrimental implications for the adhesion, moisture sensitivity, stress-and electro-migration of Cu bondlines in advanced packaging, often leading to premature device failure. We report on a novel, low-cost, single-step sol-gel synthetic route capable of reducing the weak Cu-oxide while simultaneously depositing a high-performance hybrid film, which acts both as an adhesion layer at the Cu/epoxy interface, as well as potentially a barrier film that prevents moisture degradation and Cu stress- and electro-migration.
弱氧化铜的存在对先进封装中铜键线的附着力、湿气敏感性、应力和电迁移具有不利影响,经常导致器件过早失效。我们报告了一种新颖的、低成本的、单步溶胶-凝胶合成路线,能够在沉积高性能杂化膜的同时减少弱Cu氧化物,该杂化膜既可以作为Cu/环氧界面的粘附层,也可以作为防止水分降解和Cu应力和电迁移的屏障膜。
{"title":"Low-cost, single-step hybrid bond/barrier films for Cu bondlines in advanced packaging","authors":"Qiran Xiao, Brian L. Watson, R. Dauskardt","doi":"10.1109/IITC-MAM.2015.7325656","DOIUrl":"https://doi.org/10.1109/IITC-MAM.2015.7325656","url":null,"abstract":"The presence of weak Cu-oxides has detrimental implications for the adhesion, moisture sensitivity, stress-and electro-migration of Cu bondlines in advanced packaging, often leading to premature device failure. We report on a novel, low-cost, single-step sol-gel synthetic route capable of reducing the weak Cu-oxide while simultaneously depositing a high-performance hybrid film, which acts both as an adhesion layer at the Cu/epoxy interface, as well as potentially a barrier film that prevents moisture degradation and Cu stress- and electro-migration.","PeriodicalId":6514,"journal":{"name":"2015 IEEE International Interconnect Technology Conference and 2015 IEEE Materials for Advanced Metallization Conference (IITC/MAM)","volume":"94 1","pages":"225-228"},"PeriodicalIF":0.0,"publicationDate":"2015-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83557145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
2015 IEEE International Interconnect Technology Conference and 2015 IEEE Materials for Advanced Metallization Conference (IITC/MAM)
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