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Influence of parameters of high-boiling organic compounds on the efficiency of gas-phase chromatography system 高沸点有机化合物参数对气相色谱系统效率的影响
Pub Date : 2022-11-15 DOI: 10.37474/0365-8554/2022-11-38-42
V. Farzaliyev, M. Aliyeva
In this work, the dependences of the retention time of organic substances (aromatic hydrocarbons, C10-C14 alkanes and n-aliphatic alcohols) at 150 oC temperature on the concentration of Apiezon L brand lubricant, and of the polar liquid phase of poly-ethylene glycol adipianate are specified. It is shown that the dependence of the corrected retention time of organic compounds (n-xylene, mesitylene, durol) for various mobile phases (nitrogen, hexane, ethyl alcohol) is almost linear. The dependence of the retention time on the boiling point of aromatic hydrocarbons at 150 oC temperature on the nature of the mobile phase (nitrogen, hexane, ethyl alcohol) and on the percentage of the polar liquid phase of polyethylene glycol adipianate (2–15 %) is linear.
在这项工作中,规定了有机物质(芳香烃,C10-C14烷烃和正脂肪醇)在150℃温度下的保留时间对Apiezon L牌润滑剂浓度的依赖性,以及极性液相聚乙二醇己二酸酯的依赖性。结果表明,不同流动相(氮、己烷、乙醇)对有机物(n-二甲苯、间三甲苯、杜鲁)的校正保留时间的依赖关系几乎是线性的。保留时间与150℃时芳烃沸点、流动相(氮气、己烷、乙醇)性质以及极性液相聚乙二醇己二酸酯(2 - 15%)的百分比呈线性关系。
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引用次数: 0
On formation of structural regimes in vertical multiphase flows 垂直多相流中构造型的形成
Pub Date : 2022-11-15 DOI: 10.37474/0365-8554/2022-11-28-33
G. Ismayilov, F. Ismayilova, G.A. Zeynalova
Since the effect of phase interrelation was not considered in hydrodynamic calculations of multiphase flows, such phenomena as mass transfer and migration of the particles of dispersed phases along the cross-section of the flow are related to the hydrodynamic paradox and the calculations did not meet the requirements of engineering practice. The paper reviews the issues of the formation of structural regimes in the vertical upward multiphase flow considering the effect of phase interaction (Bernoulli principle). The speed of transfer of the particles of dispersed phase into the flow core and the factors affecting them were estimated as well.
由于在多相流的水动力计算中没有考虑相间关系的影响,分散相颗粒沿流截面的传质和迁移等现象与水动力悖论有关,计算结果不符合工程实际的要求。本文综述了考虑相作用(伯努利原理)影响的垂直向上多相流结构区形成问题。分析了分散相颗粒向流芯内转移的速度及其影响因素。
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引用次数: 0
Estimation of theoretical production capacity of long-term operated well stock 长期作业井存量理论产能估算
Pub Date : 2022-11-15 DOI: 10.37474/0365-8554/2022-11-20-23
I. Ahmadov, S. Taghiyeva, H. Huseynov
The paper deals with the issue of the rational use of well stock via the specification of the capacity increase of production in the long-term developed fields. The distribution graph of oil by all wells has been developed based on the statistical processing using a system approach of obtained field data. The hyperbolic nature of obtained distributions indicates the irregularity of the development and operation processes of the fields. The distributions of the total oil and water production by selected output intervals have been developed and analyzed as well. Mathematic models of obtained distribution functions have been specified. The results of studies carried out enable us to estimate the theoretic production capacity of reviewed well stock.
本文通过对长期开发油田增产能力的说明,论述了井存量的合理利用问题。采用系统的方法对获得的现场数据进行统计处理,绘制了各井产油量分布图。所得分布的双曲性质表明了油田开发和操作过程的不规律性。并对不同产层的总油水产量分布进行了研究和分析。给出了所得分布函数的数学模型。研究结果使我们能够估计评审井库存的理论产能。
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引用次数: 0
Oxidation of chlorotoluene, toluene and chlorobenzene in the presence of Ag/MnO2 catalyst Ag/MnO2催化剂存在下氯甲苯、甲苯和氯苯的氧化
Pub Date : 2022-10-15 DOI: 10.37474/0365-8554/2022-10-47-52
I. H. Melikova
The process of oxidation of toluene, chlorotoluene and chlorobenzene is studied and the optimum parameters for successful implementation of the synthesis modeling industrial processes selected as well. The results obtained in catalytic oxidation of toluene, chlorotoluene and chlorobenzene justify that Ag/MnO2 based catalytic systems have high activeness. Mentioned hydrothermal synthesized catalyst keeps its activeness and properties during the reaction of transition of compounds of toluene, chlorotoluene and chlorobenzene. In the presence of catalysts with Ag/MnO2 nanoparticles, the reaction runs with high percent (90 %) of conversion. The activeness of the catalyst in conversion process of these compounds is optimal with 8000 s-1 volume rate. The optimum temperature for high activeness of toluene, chlorotoluene and chlorobenzene is equal to 543, 490 and 658 К correspondingly. According to the results of analysis on the effect of the components and particles size of catalysts on its activeness, the systems are active in high conversion of the components of Ag/MnO2 + Mn, R-Ag/MnO2 + Ag, R-Ag/MnO2 + Al. These systems containing nanoparticles have high catalytic activeness as well.
对甲苯、氯甲苯和氯苯的氧化工艺进行了研究,并选择了成功实现合成的最佳工艺参数。对甲苯、氯甲苯和氯苯的催化氧化结果表明,Ag/MnO2基催化体系具有较高的活性。所述水热合成催化剂在甲苯、氯甲苯和氯苯化合物的过渡反应中保持了活性和性能。在银/二氧化锰纳米颗粒催化剂的存在下,反应的转化率高达90%。当体积速率为8000s -1时,催化剂在这些化合物转化过程中的活性最佳。甲苯、氯甲苯和氯苯活性较高的最佳温度分别为543,490和658 К。分析了催化剂组分和粒径对其活性的影响,结果表明,该体系在Ag/MnO2 + Mn、R-Ag/MnO2 + Ag、R-Ag/MnO2 + Al组分的高转化率下具有活性,且含有纳米颗粒的体系具有较高的催化活性。
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引用次数: 0
Method of immediate control on technical state of offshore facilities 海上设施技术状态的即时控制方法
Pub Date : 2022-10-15 DOI: 10.37474/0365-8554/2022-10-29-35
Y. Ahmadov, I.G. Huseynov, Sh.I. Mustafayev, A.T. Ismailova
A method of immediate estimation of technical state and possibilities of further operation of offshore oil-gas hydrotechnical facilities is suggested. Predictive capability of suggested technique is described through the implementation on the structure of a specific deep-water jacket in “Guneshli” field.
提出了一种对海上油气水利设施的技术状态和进一步运行可能性进行即时评估的方法。通过在“古内什里”油田某深水套管结构上的实施,描述了所建议技术的预测能力。
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引用次数: 0
The difficulties in achievement of observance of environmental standards: legal enforcement and stability 实现遵守环境标准的困难:执法和稳定
Pub Date : 2022-10-15 DOI: 10.37474/0365-8554/2022-10-53-59
E. Aliyev
The speed of development of human society for the last fifty years threatens to lead the Earth and environment to a catastrophe. The development we observe today did not always exist. About four thousand years ago a human lived in a comparative harmony with the environment and did not harm it. However, as the human being developed and the tools he used advanced, the negative impact of human activity on the environment significantly increased. The mankind replied to this challenge – it developed and implemented environmental laws, norms and standards. Nevertheless, a great deal of rules could not prevent the damage on the environment due to the reasons reviewed in the paper. Thus, the author says, there is a significant mission before the humanity, which should be implemented by 2030. The mission consists of the decrease of harmful impact of human activity and environmental protection as well. Moreover, the author supposes that the laws of environment can play a significant role in support of this mission. He divides the theme into key aspects and reviews them. As a result, the paper studies the legal fundamentals of environmental laws and the ways of their introduction. The proportional spaces and global issues of environmental laws; their fragmental structure, poor attention to the environmental problems, the absence of efficient legal enforcement are just few of them. The paper generalizes the body of knowledge associated with the models of observance of environmental standards. Besides, the issues of legal enforcement, which various countries experience are discussed from a global point of view. In conclusion, the author suggests the views of how to support the observance of environmental norm.
过去五十年来人类社会的发展速度有可能导致地球和环境陷入灾难。我们今天看到的发展并不总是存在的。大约四千年前,人类与环境相对和谐地生活在一起,没有破坏环境。然而,随着人类的发展和人类使用的工具的进步,人类活动对环境的负面影响显著增加。人类回应了这一挑战,制定并实施了环境法律、规范和标准。然而,由于本文所述的原因,大量的规则无法阻止对环境的破坏。因此,作者说,人类面临着一个重大的使命,应该在2030年之前实现。该任务包括减少人类活动的有害影响和保护环境。此外,作者认为环境规律可以在支持这一使命方面发挥重要作用。他将主题划分为几个关键方面并进行了回顾。因此,本文对环境法的法律基础及其引入途径进行了研究。环境法律的比例空间与全球性问题;它们的结构支离破碎,对环境问题的关注不足,缺乏有效的执法只是其中的几个问题。本文概括了与遵守环境标准的模式有关的知识体系。此外,还从全球的角度讨论了各国经验丰富的执法问题。最后,对如何支持环境规范的遵守提出了自己的看法。
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引用次数: 0
The study of hydrodynamic forces effecting submarine riser in 300 m depth in the Caspian Sea 里海300 m海底立管的水动力研究
Pub Date : 2022-10-15 DOI: 10.37474/0365-8554/2022-10-60-64
M.E. Shahlarly
The subsea pipelines play a significant role in secure transportation of oil, gas and other energetic resources from the seabed to the shore and bases. The research of the hydrodynamic forces in the subsea pipelines and risers is a key factor from the point of view of regularity and efficiency of technological processes. The paper studies the impact of hydrodynamic forces affecting the subsea pipelines in the Caspian Sea. For diameter and thickness of pipe wall selected according to the ASME B36.10 standard, the forces of wind, wave and current, as well as the combination of forces affecting it were studied. The research was carried out in SACS computer software for three cases; as a result, the simulation and a table of force combinations for the optimum and unwanted occurrences appearing due to the impact of hydrodynamic forces and load combination were developed.
海底管道在将石油、天然气和其他能源从海底安全输送到岸上和基地方面发挥着重要作用。从工艺过程的规律性和效率的角度来看,海底管道和隔水管的水动力研究是一个关键因素。本文研究了水动力对里海海底管道的影响。根据ASME B36.10标准选择管壁直径和管壁厚度,研究了影响管壁直径和管壁厚度的风、浪、流作用力及其组合。在SACS计算机软件中对三个案例进行了研究;因此,建立了流体动力和载荷组合影响下的最佳和不希望出现的情况的模拟和力组合表。
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引用次数: 0
The study of reservoir parameters of subsurface rocks based on the core data of anticline belt of Sangachal-deniz–Bulla-deniz 基于Sangachal-deniz-Bulla-deniz背斜带岩心资料的地下储层参数研究
Pub Date : 2022-10-15 DOI: 10.37474/0365-8554/2022-10-4-9
H.I. Shekerov, J. Abbasov
Alongside the geological-geophysical characteristics of the fields being developed and explored, the calculation of hydrocarbon reserves, the modeling of the fields, as well as the specification and direction of a new exploration are of great importance with regard to the study of their reservoir parameters. With this purpose, the geological-geophysical studies carried out in the anticline belt of Sangachal-deniz–Bulla-deniz, and the data of samples of subsurface rocks from well intervals have been analyzed as well. The changes in reservoir parameters of the rocks of various granulometric content in the anticline zone have been investigated and the graphs of parameters depending on the depth have been developed. The studies justify that the sand and sand deposits keep their reservoir parameters even in comparatively large depths. These characteristics indicate the presence of favorable litofacies and structural-petrographic conditions for the accumulation of oil and gas reserves in deep sections.
除了开发勘探油田的地质地球物理特征外,油气储量的计算、油田的建模以及新勘探的规范和方向对储层参数的研究具有重要意义。为此,对Sangachal-deniz-Bulla-deniz背斜带进行了地质地球物理研究,并对井段地下岩石样品资料进行了分析。研究了背斜带不同粒度含量岩石储层参数的变化规律,并绘制了参数随深度的变化曲线。研究证明,即使在较深的地层中,砂体和砂体也能保持其储层参数。这些特征表明该区存在深部油气聚集的有利岩相和构造岩相条件。
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引用次数: 0
The study of the effect of flooding process in Neft Dashlary field on parameters of aggressive medium Neft - Dashlary油田驱油过程对侵蚀介质参数影响的研究
Pub Date : 2022-10-15 DOI: 10.37474/0365-8554/2022-10-23-28
N.A. Veliyev, K. K. Mehdiyev, N.B. Khaligov, N.Ya. Ismailzade, Sh.Sh. Kazimova, A.H. Gayibova
The paper reviews the damage effect of aggressive medium occurring as a result of sea water injection for the maintenance of reservoir pressure and production in Neft Dashlary field, which is in a long-term development, as well as the treatment of bottomhole zone with various agents, biological contamination and hydrogen sulphide (H2S) arising due to the bacterial activity on the works towards the consolidation of well bottomhole zone. Depending on the contact degree of cement stone with aggressive medium its corrosion probability is defined. Corrosion activity increases fast when well product contains small amount of H2S gas. According to the gas law, the gas solubility in fluids including in water is in direct proportion to the pressure. Small amount of H2S gas in produced water has a great effect on corrosion activity. On the basis of the studies of rock-operation data, it was specified that the degree of the consolidation of well bottomhole zone carried out in the well of IX horizons and Low Kirmaki suite is inversely proportional to the amount of H2S. Thus, in the zones with great amount of H2S, the efficiency degree is low, and in the zones with small amount – high. These zones and the efficiency degree are reflected in the current maps of development of IX horizon and Low Kirmaki suite of the field.
本文综述了Neft Dashlary油田长期开发过程中为维持储层压力和产量而注入海水所产生的侵蚀介质的破坏效果,以及井底层固结工程中由于细菌活动而产生的各种药剂、生物污染和硫化氢(H2S)的处理方法。根据水泥石与腐蚀性介质的接触程度确定其腐蚀概率。当井产品中含有少量H2S气体时,腐蚀活性迅速增加。根据气体定律,气体在流体(包括在水中)中的溶解度与压力成正比。采出水中少量的H2S气体对腐蚀活性影响很大。在岩石作业资料研究的基础上,明确了IX层和Low Kirmaki套井的井底层固结程度与H2S的用量成反比。因此,在H2S含量高的区域,效率程度低,而在H2S含量低的区域,效率程度高。这些区域和效率程度反映在该油田目前的IX层和Low Kirmaki套开发图中。
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引用次数: 0
The study of nanosilica in cement base materials 纳米二氧化硅在水泥基材料中的应用研究
Pub Date : 2022-10-15 DOI: 10.37474/0365-8554/2022-10-36-40
E. Shahbazov, A. Guvalov
The effect of nanoparticles of nanosilica on the characteristics of the systems of cement-sand-water is studied. In the studies, 50–110 nm nanoparticles obtained through the separation of nanosilica from the soluble glass using the method of sol-gel were applied. The characteristics of solid samples were measured after their hardening during 3-28 days. The effect of nanoadditive on the density, speed of accumulation of final durability of cement samples in squeezing was defined. Obtained results on the increase of durability in squeezing of solid cement samples should be explained with the effect of nanostructuring achieved with adding nanoparticles of silica. These particles are characterized with high specific surface and its high physical-chemical activity. It is shown that due to the effect of surface of silica nanoparticles, hydration speed of cement rises and direct formation of ordered permolecular structures of hydrates of calcium silicate structuring the cement matrix and improving its hardness occurs. The results may be applied in construction technologies for the structuring of cement materials and improving their characteristics as well: durability, density, water permeability, cold resistance.
研究了纳米二氧化硅纳米颗粒对水泥-砂-水体系性能的影响。在本研究中,采用溶胶-凝胶法将纳米二氧化硅从可溶性玻璃中分离得到50-110 nm的纳米颗粒。固体试样在3 ~ 28天硬化后测定其特性。定义了纳米添加剂对水泥试样在挤压过程中密度、累积速度和最终耐久性的影响。所获得的关于固体水泥试样在挤压过程中耐久性提高的结果,应该用添加二氧化硅纳米颗粒所实现的纳米结构效应来解释。这些颗粒具有高比表面和高物理化学活性的特点。结果表明,受纳米二氧化硅表面的影响,水泥的水化速度加快,水化硅酸钙直接形成有序的过分子结构,使水泥基体结构有序,硬度提高。研究结果可应用于水泥材料结构的施工技术,改善其耐久性、密度、透水性、耐寒性等性能。
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引用次数: 0
期刊
Azerbaijan Oil Industry
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