The insufficient soluble silicon and heavy metal contamination in soil severely threaten the yield and quality of crops, which urgently requires dual-functional materials to address the above issues. Herein, a high-performance hierarchical magnesium silicate/diatomite (Si/Mg/xK) composite is synthesized via a one-step hydrothermal method. Natural diatomite serves as both a porous support and silicon source, while cost-effective magnesium sulfate concentrate derived from flue gas desulfurization (FGD) waste provides the magnesium source and weak alkalinity condition. Potassium hydroxide is introduced as an alkaline activator to accelerate the in-situ formation of magnesium silicate nanostructure on diatomite, creating hierarchical porosity that significantly enhances the specific surface area and increases the interaction interface with target solutions. The resulting composite achieves a remarkable citrate-soluble silicon content of 391.89 mg/L, representing a 39-fold improvement over raw diatomite, while concurrently releasing beneficial soluble magnesium (253.33 mg/L). Furthermore, the composite demonstrates exceptional heavy metal ion adsorption performance with a maximum cadmium ion (Cd2+) adsorption capacity of 184.5 mg/L, indicating dual-functional potential for soil remediation. This work establishes a sustainable pathway to valorize natural diatomite and FGD waste into dual-functional materials capable of efficient silicon/magnesium release and Cd2+ adsorption.
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