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Modelling the hydration of bentonites under isothermal and non-isothermal conditions using a double-porosity approach 用双孔隙法模拟等温和非等温条件下膨润土的水化作用
IF 5.8 2区 地球科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-05 DOI: 10.1016/j.clay.2026.108148
Ramon Vasconcelos , Antonio Gens , Carlos E. Rodríguez , Jean Vaunat
The constitutive model for expansive materials described here follows the usual double-porosity approach that represents the clay soil as two overlapping pore media (microstructure and macrostructure) coupled through a micro-macro strain mechanism. However, the current formulation also includes a local water mass transfer controlling the saturation of the microstructure, the definition of water retention curves for each structural level, and the occurrence of thermal strains in both pore domains. These additional features enhance the model's ability to simulate the response of bentonites under varying moisture conditions. This double-porosity model satisfactorily simulated some infiltration tests taken from the literature, reproducing the main test observations and validating its use for predicting the behaviour of bentonites in various geotechnical engineering scenarios. The infiltration tests selected were carried out in columns made of FEBEX and MX-80 bentonites under isothermal and non-isothermal conditions to characterize the main hydro-mechanical and thermo-hydro-mechanical processes that occur within a bentonite barrier hydrated under confined conditions. The numerical simulations showed that structural changes in bentonite materials during the transient hydration phase are due to the irreversible response of the macrostructure (changes in macroporosity) but also depend on the mechanisms controlling the saturation of the microstructure.
本文描述的膨胀材料的本构模型遵循通常的双孔隙率方法,将粘土视为通过微观-宏观应变机制耦合的两种重叠的孔隙介质(微观结构和宏观结构)。然而,目前的公式还包括控制微观结构饱和度的局部水传质,每个结构水平的保水曲线的定义,以及两个孔隙域中热应变的发生。这些附加功能增强了模型在不同湿度条件下模拟膨润土响应的能力。该双重孔隙率模型令人满意地模拟了一些来自文献的渗透试验,再现了主要的试验观察结果,并验证了其在各种岩土工程场景下预测膨润土行为的用途。所选择的渗透试验在等温和非等温条件下在FEBEX和MX-80膨润土制成的柱中进行,以表征在受限条件下水化的膨润土屏障内发生的主要水-力学和热-水-力学过程。数值模拟结果表明,膨润土材料在瞬态水化阶段的结构变化是由宏观结构的不可逆反应(宏观孔隙度的变化)引起的,但也取决于微观结构饱和的控制机制。
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引用次数: 0
Morphology and C-isotopic composition affirm biogenicity of Mesoarchean sphaeromorph organic-walled microfossils from the ∼3.0 Ga Farrel Quartzite, Western Australia 澳大利亚西部~ 3.0 Ga Farrel石英岩中太古代球型有机壁微化石的形态和碳同位素组成证实了其生物源性
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-03-03 DOI: 10.1016/j.precamres.2026.108062
Kenichiro Sugitani , Kohei Sasaki , Akizumi Ishida , Motoko Igisu , Kaho Ishibashi , Mariko Yamamoto , Minako Hashiguchi , Heda Agić , Stanley M. Awramik
Carbonaceous cherts of the ca. 3.0 Ga Farrel Quartzite in the Pilbara Craton, Western Australia host abundant morphologically diverse microfossils including filaments, spheroids, and lenses of unknown biological affinities, as well as films. The Farrel Quartzite microfossils are organically walled, include forms similar to younger (Proterozoic) leiosphaerids, and some can be extracted by palynological acid maceration. Thus, they represent the oldest records of organic-walled microfossils (OWMs) and non-pollen palynomorphs. The Farrel Quartzite OWMs are composed largely of lenses, with subordinate of flexible-walled large spheroids (FWLSs) and films, among which the FWLSs and films have been poorly described and examined. In this study, we report morphology, texture, and chemical features including Raman spectra, Fourier transform infrared spectra, and carbon isotopic composition of the FWLSs, all of which point to their biogenicity. Their dispersed occurrence in petrographic thin sections and the lack of morphologies corresponding to reproduction stages such as budding and division imply that they represent resting stage, which remains to be explored further. The major axis of the extracted FWLSs (n = 185) ranges from 67 µm to 247 µm with the mean value of 180 µm, which are correlative to the Proterozoic and the 3.2 Ga South African OWMs that can be extractable by acid maceration. This study provides additional evidence of early evolution of microorganisms that could have produced flexible and acid-resistant sac-like large vesicles.
西澳皮尔巴拉克拉通约3.0 Ga Farrel石英岩的碳质燧石中含有大量形态多样的微化石,包括生物亲缘未知的细丝、球状体和透镜体,以及薄膜。法雷尔石英岩微化石为有机壁状,包括与较年轻的(元古代)球状生物相似的形态,部分可通过孢粉酸浸提取。因此,它们代表了最古老的有机壁微化石(OWMs)和非花粉微态化石的记录。Farrel石英岩owm主要由透镜组成,其次是柔性壁大球体(FWLSs)和薄膜,其中FWLSs和薄膜的描述和研究较少。在这项研究中,我们报告了fwls的形态,质地和化学特征,包括拉曼光谱,傅里叶变换红外光谱和碳同位素组成,所有这些都指向它们的生物原性。它们在岩石薄片中分布较分散,且缺乏与萌芽和分裂等繁殖阶段相对应的形态,这意味着它们代表着静止阶段,这有待进一步探讨。提取的fwlms (n = 185)长轴在67 ~ 247µm之间,平均值为180µm,与酸浸法可提取的元古代和3.2 Ga南非owm相关。这项研究为微生物的早期进化提供了额外的证据,这些微生物可以产生柔性和耐酸的囊状大囊泡。
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引用次数: 0
In situ Rb–Sr geochronology records multiple fluid pulses in Neoproterozoic sequences from the Lubambe-Mingomba Cu deposits in the Zambian Copperbelt 原位Rb-Sr年代学记录了赞比亚铜带Lubambe-Mingomba铜矿床新元古代序列中的多个流体脉冲
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-20 DOI: 10.1016/j.precamres.2026.108059
Victor Ikechukwu Vincent , Koen Torremans , Darwinaji Subarkah , Sarah E. Gilbert , Juraj Farkaš , Alan S. Collins , Jon Stacey , Aileen L. Doran , Simon Jones , Murray W. Hitzman
Beta-decay chronometers such as Rb–Sr are useful in constraining geological histories in Proterozoic basins. However, solution-based beta-decay Rb–Sr dating has limited applicability to resolve complex alteration history in Proterozoic basins affected by multiple thermal and fluid-flow events. This study applies tandem laser ablation ICP-MS/MS Rb–Sr dating to K-rich minerals to constrain depositional and alteration history of Neoproterozoic metasedimentary rocks in the Central African Copperbelt. Multiple generations of K-feldspar, muscovite, biotite-phlogopite and illite from the Lubambe-Mingomba Cu deposit yield both detrital (∼1700–920 Ma) and post-depositional ages (767–466 Ma) tied to successive alteration episodes. Altered K-feldspars show trace element redistribution and Rb–Sr resetting relative to detrital grains with broad depletion in Ba, Pb and Na and enrichment in Fe, Ti, Co and REEs. Cathodoluminescence emission broadly correlates with alteration intensity and style, suggesting its potential use as a proxy for feldspar alteration. The oldest alteration age (767 ± 95 Ma) records early diagenetic processes involving seawater-derived fluids, indicated by initial 87Sr/86Sr ratios similar to values for Tonian seawater and overlaps published Re–Os ages (820–770 Ma) for early Cu mineralization. Late Tonian ages (∼713 Ma) from altered detrital K-feldspars likely mark rift-driven thermal and fluid flow processes coeval with the break-up of Rodinia supercontinent. Ediacaran ages (636–600 Ma) likely record Congo–Kalahari convergence and brine migration associated with halokinesis. Early Cambrian (∼530 Ma) ages and late Cambrian-Ordovician ages (480–459 Ma) record peak Lufilian to post-Lufilian fluid flow. Phlogopite and fine-grained illite yield comparable Cambro-Ordovician ages (528–466 Ma), indicating widespread resetting during the Pan-African event in the Central African Copperbelt. These results show that in situ analysis coupled with detailed petrography can reveal progressive Rb–Sr re-equilibration in K-bearing minerals tied to tectono-hydrothermal episodes. This approach is useful for refining the chronostratigraphic framework for fluid flow in altered Proterozoic basins worldwide.
像Rb-Sr这样的β衰变计时器在限制元古代盆地的地质历史方面是有用的。然而,基于溶液的β衰变Rb-Sr测年在解决受多种热流体事件影响的元古代盆地复杂蚀变史方面适用性有限。利用串联激光烧蚀ICP-MS/MS Rb-Sr测年技术对中非铜带新元古代变质沉积岩的沉积蚀变历史进行了研究。来自Lubambe-Mingomba铜矿床的多代钾长石、白云母、黑云母-绿云母和伊利石产生了碎屑(~ 1700-920 Ma)和沉积后时代(767-466 Ma),与连续的蚀变事件有关。蚀变钾长石相对于碎屑颗粒表现出微量元素重分布和Rb-Sr重置,Ba、Pb和Na普遍亏缺,Fe、Ti、Co和ree富集。阴极发光发射与蚀变强度和样式广泛相关,表明其可能用作长石蚀变的代理。最古老的蚀变年龄(767±95 Ma)记录了早期成岩作用,包括海水衍生流体,其初始87Sr/86Sr比值与东尼亚海水相似,与早期铜成矿的Re-Os年龄(820 ~ 770 Ma)重叠。蚀变钾长石碎屑的晚托尼世年龄(~ 713 Ma)可能标志着与Rodinia超大陆分裂同时发生的裂谷驱动的热流体流动过程。埃迪卡拉纪(636-600 Ma)可能记录了刚果-喀拉哈里的辐合和与卤化作用相关的盐水迁移。早寒武世(~ 530 Ma)和晚寒武世—奥陶世(480 ~ 459 Ma)为陆菲连—后陆菲连流体流动高峰。辉云母和细粒伊利石的年龄可与寒武纪-奥陶纪相比较(528-466 Ma),表明中非铜带泛非事件期间广泛重置。这些结果表明,原位分析结合详细的岩石学可以揭示与构造-热液期有关的含钾矿物中Rb-Sr的渐进式再平衡。这种方法有助于完善世界范围内蚀变元古代盆地流体流动的年代地层格架。
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引用次数: 0
Comparative analysis in sensitivity of PM2.5 mass to ammonia and nitrate availability between Hong Kong and Shanghai reveals comparative importance of chemistry and meteorology 香港和上海的PM2.5质量对氨和硝酸盐有效性的敏感性比较分析显示化学和气象的相对重要性
IF 4.4 2区 地球科学 Q1 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2026-06-01 Epub Date: 2026-02-09 DOI: 10.1016/j.atmosres.2026.108846
Zijing Zhang , Min Zhou , Shuhui Zhu , Hongli Wang , Liping Qiao , Dandan Huang , Jian Zhen Yu
Reductions in sulfate over recent years have increased the relative contributions of nitrate and ammonium to PM2.5 in Chinese megacities, shifting the focus of further PM abatement toward these semi-volatile species. This shift in focus makes understanding gas-particle partitioning, which is governed by aerosol pH and temperature, central to predicting their particle-phase contributions. Using hourly measurements of water-soluble inorganic ions (WSIIs) and related gases in Hong Kong and Shanghai, we constrained aerosol pH and aerosol water content (AWC) with ISORROPIA-II and evaluated PM2.5 mass sensitivity to total nitrate (TNO3 = HNO3 + NO3) and total ammonia (TNH3 = NH3 + NH4+). In Hong Kong, sulfate dominated the WSIIs, whereas nitrate was dominant in Shanghai. The seasonally lower temperature (≈ 6–9 °C) in Shanghai, combined with a lower sulfate fraction, contributed to an aerosol pH approximately one unit higher than that in Hong Kong. The combination of higher pH and lower temperature in Shanghai favored particulate nitrate formation (high ε(NO3)), increasing PM sensitivity to TNO3. Our quantitative sensitivity analysis showed that cutting TNO3 in Shanghai was as effective as cutting sulfate for PM2.5 reduction, while TNH3 controls required reductions of >40% to become effective. Consistent with its distinct chemical and meteorological regime, PM2.5 in Hong Kong was co-sensitive to both TNH3 and TNO3, indicating that a synergistic control strategy is optimal. Meteorology modulated these sensitivities primarily by altering aerosol pH and partitioning. Temperature exerted the strongest influence by directly controlling the thermodynamic equilibrium. High relative humidity favored greater aerosol water content, elevating aerosol pH and further promoting nitrate partitioning. Chemical composition, notably the sulfate and nitrate levels, also played a decisive role by setting the initial chemical regime. This contrast demonstrates that the lower temperatures and higher aerosol pH in Shanghai amplifies PM2.5 sensitivity to TNO3, warranting prioritized NOx control. In warmer Hong Kong, the lower aerosol pH and dominant role of sulfate result in co-sensitivity to both precursors, necessitating coordinated abatement. Thus, effective PM2.5 mitigation requires strategies tailored to local chemical-meteorological regimes.
近年来硫酸盐的减少增加了中国大城市中硝酸盐和铵对PM2.5的相对贡献,将进一步减少PM的重点转移到这些半挥发性物种上。这种焦点的转变使得理解由气溶胶pH值和温度控制的气-颗粒分配成为预测其颗粒相贡献的核心。利用香港和上海的水溶性无机离子(WSIIs)和相关气体的每小时测量数据,利用ISORROPIA-II限制气溶胶pH和气溶胶含水量(AWC),并评估PM2.5对总硝酸盐(TNO3 = HNO3 + NO3−)和总氨(TNH3 = NH3 + NH4+)的质量敏感性。在香港,硫酸盐在wsii中占主导地位,而在上海,硝酸盐占主导地位。上海季节性较低的气温(≈6-9°C),加上硫酸盐含量较低,导致气溶胶pH值比香港高约一个单位。上海较高的pH和较低的温度有利于颗粒硝酸盐的形成(高ε(NO3−)),增加PM对TNO3的敏感性。我们的定量敏感性分析表明,在上海减少TNO3与减少硫酸盐一样有效,而TNH3控制需要减少40%才能生效。香港的PM2.5对TNH3和TNO3都是共同敏感的,这与它独特的化学和气象机制相一致,表明协同控制策略是最佳的。气象学主要通过改变气溶胶的pH值和分配来调节这些敏感性。温度的影响最大,直接控制热力学平衡。较高的相对湿度有利于增加气溶胶含水量,提高气溶胶pH值,进一步促进硝酸盐的分配。化学成分,特别是硫酸盐和硝酸盐的水平,也起了决定性的作用,通过设置初始化学制度。这一对比表明,上海较低的温度和较高的气溶胶pH值放大了PM2.5对TNO3的敏感性,需要优先控制NOx。在较暖的香港,较低的气溶胶pH值和硫酸盐的主导作用导致对这两种前体共同敏感,需要协调减排。因此,有效减缓PM2.5需要针对当地化学气象制度量身定制战略。
{"title":"Comparative analysis in sensitivity of PM2.5 mass to ammonia and nitrate availability between Hong Kong and Shanghai reveals comparative importance of chemistry and meteorology","authors":"Zijing Zhang ,&nbsp;Min Zhou ,&nbsp;Shuhui Zhu ,&nbsp;Hongli Wang ,&nbsp;Liping Qiao ,&nbsp;Dandan Huang ,&nbsp;Jian Zhen Yu","doi":"10.1016/j.atmosres.2026.108846","DOIUrl":"10.1016/j.atmosres.2026.108846","url":null,"abstract":"<div><div>Reductions in sulfate over recent years have increased the relative contributions of nitrate and ammonium to PM<sub>2.5</sub> in Chinese megacities, shifting the focus of further PM abatement toward these semi-volatile species. This shift in focus makes understanding gas-particle partitioning, which is governed by aerosol pH and temperature, central to predicting their particle-phase contributions. Using hourly measurements of water-soluble inorganic ions (WSIIs) and related gases in Hong Kong and Shanghai, we constrained aerosol pH and aerosol water content (AWC) with ISORROPIA-II and evaluated PM<sub>2.5</sub> mass sensitivity to total nitrate (TNO<sub>3</sub> = HNO<sub>3</sub> + NO<sub>3</sub><sup>−</sup>) and total ammonia (TNH<sub>3</sub> = NH<sub>3</sub> + NH<sub>4</sub><sup>+</sup>). In Hong Kong, sulfate dominated the WSIIs, whereas nitrate was dominant in Shanghai. The seasonally lower temperature (≈ 6–9 °C) in Shanghai, combined with a lower sulfate fraction, contributed to an aerosol pH approximately one unit higher than that in Hong Kong. The combination of higher pH and lower temperature in Shanghai favored particulate nitrate formation (high ε(NO<sub>3</sub><sup>−</sup>)), increasing PM sensitivity to TNO<sub>3</sub>. Our quantitative sensitivity analysis showed that cutting TNO<sub>3</sub> in Shanghai was as effective as cutting sulfate for PM<sub>2.5</sub> reduction, while TNH<sub>3</sub> controls required reductions of &gt;40% to become effective. Consistent with its distinct chemical and meteorological regime, PM<sub>2.5</sub> in Hong Kong was co-sensitive to both TNH<sub>3</sub> and TNO<sub>3</sub>, indicating that a synergistic control strategy is optimal. Meteorology modulated these sensitivities primarily by altering aerosol pH and partitioning. Temperature exerted the strongest influence by directly controlling the thermodynamic equilibrium. High relative humidity favored greater aerosol water content, elevating aerosol pH and further promoting nitrate partitioning. Chemical composition, notably the sulfate and nitrate levels, also played a decisive role by setting the initial chemical regime. This contrast demonstrates that the lower temperatures and higher aerosol pH in Shanghai amplifies PM<sub>2.5</sub> sensitivity to TNO<sub>3</sub>, warranting prioritized NO<sub>x</sub> control. In warmer Hong Kong, the lower aerosol pH and dominant role of sulfate result in co-sensitivity to both precursors, necessitating coordinated abatement. Thus, effective PM<sub>2.5</sub> mitigation requires strategies tailored to local chemical-meteorological regimes.</div></div>","PeriodicalId":8600,"journal":{"name":"Atmospheric Research","volume":"336 ","pages":"Article 108846"},"PeriodicalIF":4.4,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Revision of the specimen MMCh-PV 47 (Rebbachisauridae, Sauropoda) from the Candeleros Formation (lower Cenomanian) with comments about the musculature of the caudal region 来自下Cenomanian Candeleros组的标本MMCh-PV 47 (Rebbachisauridae, Sauropoda)的修正及对尾端肌肉组织的评论
IF 1.7 3区 地球科学 Q1 GEOLOGY Pub Date : 2026-06-01 Epub Date: 2026-01-12 DOI: 10.1016/j.cretres.2025.106307
Lucas N. Lerzo
The sauropod fauna of the Upper Cretaceous of Patagonia is dominated by large titanosaurs and medium to large-sized rebbachisaurids. Particularly, rebbachisaurid sauropods dominated the Cenomanian-Turonian of Patagonia. Specimen MMCh-PV 47, which includes 10 middle to posterior caudal vertebrae and haemal arches, was recovered from the Candeleros Formation of Villa El Chocón, Neuquén, Argentina, and was formerly described as a titanosaur sauropod. On the base of the amphicoelous centra with the posterior articular surface more concave than the anterior one, the placement of the neural arch close to the anterior margin of the centrum, the ventral longitudinal hollow, and middle haemal arches with a stellated morphology, the specimen MMCh-PV 47 is instead considered within Rebbachisauridae. A phylogenetic analysis recovered it in a basal clade with Sidersaura, Campananeyen, Zapalasaurus, Astigmasaura and specimen MACN-Pv-N-35. This basal clade is characterized by the presence of middle haemal arches exhibiting two set of anterior and posterior projections, one on the proximal rami and another on the distal blade. In lateral view, the first six caudal vertebrae of the specimen MMCh-PV 47 exhibit rugose surfaces on the dorsal end of the centrum, indicating that the M. caudofemoralis longus extends much further posterior than in other sauropods. Laterodorsally projected ventral bar of the transverse processes, and the development of the haemal arches would increase the surface of attachment for the M. caudofemoralis longus, being a muscle of greater functional significance compared to other sauropod clades.
巴塔哥尼亚上白垩纪蜥脚类动物群以大型泰坦龙和中、大型雷巴奇龙为主。尤其是巴塔哥尼亚的塞诺曼尼亚-土尔onian, rebbachisaurid蜥脚类占优势。标本MMCh-PV 47,包括10个中后侧尾椎骨和血液弓,从阿根廷neuqu的Villa El Chocón的Candeleros地层中发现,以前被描述为泰坦龙蜥脚类动物。以后关节面较前关节面凹的双掌中央为基础,神经弓靠近椎体前缘,腹侧纵向凹陷,中间血弓呈星形形态,MMCh-PV 47标本被认为属于Rebbachisauridae科。系统发育分析发现其与Sidersaura、Campananeyen、Zapalasaurus、Astigmasaura和标本MACN-Pv-N-35属于一个基支。这个基部分支的特征是存在中间的血弓,表现出两组前后突出,一组在近支,另一组在远端。从侧面看,标本MMCh-PV 47的前六块尾椎骨在椎体的背端呈现出皱纹表面,表明尾状长尾椎骨比其他蜥脚类动物向后延伸得更远。尾部长肌横向突起的腹侧横突和血液弓的发育会增加附着面,与其他蜥脚类动物相比,尾部长肌具有更大的功能意义。
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引用次数: 0
Chemical equilibrium of solid phases governing phosphorus solubility in intensively cultivated soils of the Indo-Gangetic Plains 印度-恒河平原密集耕作土壤中控制磷溶解度的固相化学平衡
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-03 DOI: 10.1016/j.pce.2026.104313
K.K. Rao , Mandira Barman , S.P. Datta , Debarup Das , V.K. Sharma , Debrup Ghosh , T.K. Das
The problem of phosphorus (P) fixation into insoluble mineral forms is particularly acute in the intensively cultivated Indo-Gangetic Plains (IGP), where decades of fertilizer application have created complex P dynamics. Although earlier studies have examined P availability in different soils, the mechanistic understanding of equilibrium relationships between soil-solution phosphate species and solid P phases under varying pH across the IGP remains limited.
To address this gap, the present study quantitatively assessed the chemical equilibria between soil-solution phosphate (H2PO4) and dominant solid P phases by modelling soil solution and solid-phase interactions using geochemical equilibrium approaches across a representative pH gradient. This methodological framework enabled identification of the controlling mineral-phases and their saturation states under different soil reactions.
Results revealed that H2PO4 concentrations varied markedly with pH, ranging from 3901 × 10−6 to 397 × 10−6 M. Oversaturation of mineral phases such as variscite and K-taranakite was observed, particularly in soils receiving long-term applications of potassium- and ammonium-based phosphatic fertilizers. In acidic soils, P solubility was governed by iron- and aluminium-phosphate equilibria, whereas in neutral to alkaline soils, calcium phosphate phases predominated.
These findings demonstrate that soil pH and fertilizer legacy effects jointly regulate P solubility equilibria and phase transitions across the IGP. The study underscores the necessity of developing management strategies to mobilize the accumulated, less-available P pools through pH-specific interventions. Such approaches can enhance sustainable P use efficiency, reduce fertilizer dependency, and improve long-term crop productivity, contributing valuable insights to regional nutrient management and global P sustainability frameworks.
在集约耕种的印度河-恒河平原(IGP),磷(P)以不溶性矿物形式固定的问题尤其严重,在那里,几十年的施肥造成了复杂的磷动态。虽然早期的研究已经检测了不同土壤的磷有效性,但在不同pH值下,对土壤溶液磷酸盐和固体磷相之间平衡关系的机制理解仍然有限。为了解决这一差距,本研究通过使用地球化学平衡方法模拟土壤溶液和固相之间的相互作用,定量评估了土壤溶液磷酸盐(H2PO4−)和主要固体P相之间的化学平衡。该方法框架能够识别控制矿物相及其在不同土壤反应下的饱和状态。结果表明,H2PO4−浓度随pH值变化显著,范围为3901 × 10−6 ~ 397 × 10−6 m。在长期施用钾基和铵基磷肥的土壤中,观察到variscite和K-taranakite等矿物相的过饱和。在酸性土壤中,磷的溶解度受铁和磷酸铝平衡控制,而在中性至碱性土壤中,磷酸钙相占主导地位。这些发现表明,土壤pH和肥料遗留效应共同调节了磷在IGP中的溶解度平衡和相变。该研究强调了制定管理战略的必要性,通过针对ph值的干预措施来调动积累的、较少可用的P池。这些方法可以提高可持续磷肥利用效率,减少对肥料的依赖,提高作物的长期生产力,为区域养分管理和全球磷肥可持续性框架提供有价值的见解。
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引用次数: 0
Harnessing vegetation indices and remote sensing to assess the impact of Cyclone Kenneth on banana plantations: Insights from Ngazidja Island (Comoros) 利用植被指数和遥感评估“肯尼斯”气旋对香蕉种植园的影响:来自恩加济加岛(科摩罗)的见解
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-03 DOI: 10.1016/j.pce.2026.104332
Andlia Abdoussalami , Dinesh Madhushanka , Xuesong Zhang , Qi Li , Zhenghua Hu , Abu Reza Md Towfiqul Islam
Tropical cyclones pose major risks to Small Island Developing States (SIDS) and their agriculture. Banana is one of the island's key subsistence and market crops, supporting household food security and local economies. As a vital crop, it holds significant importance both for daily consumption and economic exchange. This study provides the first island-level, crop-specific assessment of Cyclone Kenneth's impact on banana plantations across Ngazidja (Grande Comore). The Normalized Difference Vegetation Index (NDVI) is a spectral index derived from satellite imagery, which quantifies vegetation health. NDVI is calculated as the difference between near-infrared and red reflectance, providing a measure of canopy greenness. In this study, we used seasonally paired NDVI composites to reduce cloud contamination and account for short-term phenological variations between the pre- and post-cyclone imagery. Island-scale land-use analysis revealed a cropland decrease of −18.7% and a bare-land increase of +24.3%, while representative northern banana parcels (contiguous field of banana crops, delineated from high-resolution satellite imagery that is large enough to be represented accurately at a 10-m resolution) experienced severe canopy loss (ΔNDVI ≈ −0.32). Spatial regression identified proximity to the cyclone track, wind speed, and rainfall as the most significant predictors of vegetation loss, amplified in low-elevation and gentle-slope areas. The findings demonstrate the effectiveness of integrating multi-sensor remote sensing with exposure modeling for rapid post-cyclone agricultural damage assessment in data-limited island environments, supporting evidence-based recovery and resilience planning.
热带气旋对小岛屿发展中国家及其农业构成重大威胁。香蕉是岛上主要的生计和市场作物之一,支持家庭粮食安全和当地经济。作为一种重要的农作物,它在日常消费和经济交流中都具有重要意义。这项研究首次在岛屿层面对肯尼斯气旋对Ngazidja(大科摩罗)各地香蕉种植园的影响进行了具体的作物评估。归一化植被指数(NDVI)是一种基于卫星影像的光谱指数,用于量化植被健康状况。NDVI是用近红外反射率和红光反射率之间的差来计算的,提供了冠层绿度的度量。在这项研究中,我们使用季节配对的NDVI复合材料来减少云污染,并解释气旋前和气旋后图像之间的短期物候变化。海岛尺度的土地利用分析显示,耕地减少了−18.7%,裸地增加了+24.3%,而具有代表性的北部香蕉地块(香蕉作物的连片田,由高分辨率卫星图像描绘,大到足以以10 m分辨率精确表示)经历了严重的冠层损失(ΔNDVI≈−0.32)。空间回归发现,接近气旋路径、风速和降雨量是植被损失的最重要预测因子,在低海拔和缓坡地区被放大。研究结果表明,在数据有限的岛屿环境中,将多传感器遥感与暴露建模相结合,可用于气旋后农业灾害快速评估,支持基于证据的恢复和复原力规划。
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引用次数: 0
Uncertainty quantification in the estimation of Probable Maximum Precipitation (PMP) in Iran: A comprehensive analysis 伊朗可能最大降水(PMP)估算中的不确定性量化:综合分析
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-05 DOI: 10.1016/j.pce.2026.104331
Mahdi Delghandi, Behnam Abdollah-Abadi
Probable Maximum Precipitation (PMP) is a fundamental input for estimating the Probable Maximum Flood (PMF), and therefore plays a key role in the safe and cost-effective design of hydraulic structures. However, the estimation of PMP is inherently associated with various sources of uncertainty. This study investigates uncertainties in PMP estimation in Iran, focusing on calculation methods (Hershfield method (H), the Site-Specific (SS) method, and a newly proposed Developed Site-Specific (DSS) approach), rain-gauge station density, and climatic conditions. Monte Carlo simulation and Sobol’ global sensitivity analysis were employed to quantify contribution of frequency factor curve parameters (α, c and LR) to the uncertainty in PMP estimates. Results revealed that H approach produced the highest PMP values (135-1175 mm), while DSS, most compatible with Iran's climate, yielded lower values (110-632 mm). Application of DSS reduced the weighted mean PMP from 309 mm to 230 mm, which can significantly reduce design costs of high-hazard hydraulic structures. Uncertainty analysis demonstrated that climatic conditions accounted for the largest share of total uncertainty (41.2%), followed by the number of stations (36.2%) and the PMP estimation method (22.6%), respectively. Regardless of the specific contribution of each source of uncertainty, it is evident that all three factors have a significant impact on PMP estimation. Sobol’ analysis demonstrated that parameter c is the dominant contributor to PMP uncertainty. These findings highlight the need for an uncertainty-aware framework to support cost-efficient and safe hydraulic infrastructure planning.
最大可能降水量(PMP)是估计最大可能洪水(PMF)的基本输入,因此在水工建筑物的安全和经济设计中起着关键作用。然而,PMP的估计本质上与各种不确定性来源有关。本研究调查了伊朗PMP估算中的不确定性,重点研究了计算方法(赫什菲尔德方法(H)、特定站点方法(SS)和新提出的特定站点方法(DSS))、雨量站密度和气候条件。采用蒙特卡罗模拟和Sobol全局敏感性分析来量化频率因子曲线参数(α, c和LR)对PMP估计不确定性的贡献。结果表明,H方法的PMP值最高(135 ~ 1175 mm),而与伊朗气候最相容的DSS方法的PMP值较低(110 ~ 632 mm)。DSS的应用将加权平均PMP从309 mm降低到230 mm,可以显著降低高危水工结构的设计成本。不确定性分析表明,气候条件在总不确定性中所占比例最大(41.2%),其次是台站数(36.2%)和PMP估算方法(22.6%)。不考虑每个不确定性来源的具体贡献,很明显,所有三个因素对PMP估计都有重大影响。Sobol的分析表明,参数c是PMP不确定性的主要贡献者。这些发现强调了需要一个具有不确定性意识的框架来支持经济高效和安全的水利基础设施规划。
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引用次数: 0
A novel hydrogeophysical framework for developing conceptual site models and simulating groundwater flow conditions in heterogeneous aquifer systems 一个新的水文地球物理框架,用于开发概念场地模型和模拟非均质含水层系统中的地下水流动条件
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-27 DOI: 10.1016/j.pce.2026.104326
Musaab A.A. Mohammed , Norbert P. Szabó , Péter Szűcs
Numerical simulation of groundwater flow is crucial for understanding and managing aquifer systems, especially in heterogeneous environments. One of the key challenges in groundwater flow simulation is the limited availability of detailed geological and hydrogeological data, which is essential for accurately characterizing aquifer properties and flow dynamics. This study presents a novel approach to simulate the flow conditions in data-scare regions in which the primary inputs are obtained from the interpretation of the geophysical well-logging data. The conceptual model is established through the novel application of the Most Frequent Value-assisted Cluster Analysis (MFV-CA) and Csókás method, complemented by available water level data. MFV-CA is a robust clustering technique that uses Stiener Distance (Weighted Euclidean Distance) for rock differentiation mitigating the drawbacks of the standard k-means cluster analysis (CA) being sensitive to outliers in the dataset. On the other hand, the Csókás method is introduced as a modified version of the Kozeny-Carman equation to provide a continuous estimation of hydraulic conductivity. Accordingly, a 3D geological model is constructed, discretized, and characterized. The conceptual model is translated into a numerical model using the MODFLOW-USG framework employing a control volume finite difference unstructured grid that allows the representation of the system heterogeneity. The results showed an acceptable agreement between the observed and the calibrated hydraulic head. The study demonstrated the effectiveness of using geophysical data as an input for groundwater flow models that enhance data coverage and resolution. The proposed approach provides a practical decision-support tool for improving groundwater management and planning in data-scarce and geologically complex settings.
地下水流动的数值模拟对于理解和管理含水层系统至关重要,特别是在非均质环境中。地下水流动模拟的关键挑战之一是详细的地质和水文地质数据的可用性有限,而这些数据对于准确表征含水层性质和流动动力学至关重要。该研究提出了一种新的方法来模拟数据稀缺地区的流动条件,其中主要输入来自地球物理测井数据的解释。概念模型是通过最频繁值辅助聚类分析(MFV-CA)和Csókás方法的新应用建立的,并辅以可用的水位数据。MFV-CA是一种鲁棒的聚类技术,它使用斯蒂纳距离(加权欧氏距离)来区分岩石,减轻了标准k-均值聚类分析(CA)对数据集中的异常值敏感的缺点。另一方面,Csókás方法作为Kozeny-Carman方程的修改版本被引入,以提供水力导电性的连续估计。据此,构建三维地质模型,对其进行离散化和表征。使用MODFLOW-USG框架将概念模型转换为数值模型,该框架采用控制体积有限差分非结构化网格,允许表示系统异质性。结果表明,在观测和校准水头之间的一致性是可以接受的。该研究表明,将地球物理数据作为地下水流动模型的输入是有效的,可以提高数据的覆盖范围和分辨率。提出的方法为改善数据稀缺和地质复杂环境下的地下水管理和规划提供了一种实用的决策支持工具。
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引用次数: 0
Multi-sensor deep learning approach for landslide susceptibility mapping under climate and anthropogenic pressures 气候和人为压力下滑坡易感性制图的多传感器深度学习方法
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-21 DOI: 10.1016/j.pce.2026.104305
Xiuping Zhang , Xulong Duan , Umer Khalil , Muhammad Ali Muhammadi , Hela Elmannai , Abeer D. Algarni , Dmitry E. Kucher
The Karakoram Highway (KKH) is a critical high-altitude transportation corridor connecting and is frequently affected by landslides due to steep terrain, complex geology, intense rainfall, and increasing anthropogenic activities. Reliable landslide susceptibility mapping is therefore essential for hazard mitigation and infrastructure resilience along this corridor. In this study, landslide susceptibility was assessed along a section of the KKH using two ensemble Machine Learning (ML) models: Random Forest (RF) and Extreme Gradient Boosting (XGB). A landslide inventory comprising 447 events was classified into fall, flow, and slide types and combined with non-landslide samples for supervised modeling. Fourteen conditioning factors derived from remote sensing, hydrological indices, and geological data were used. Multicollinearity was addressed using Variance Inflation Factor analysis. Models were trained and validated using a 70/30 train–test split, and performance was evaluated using accuracy, precision, recall, F1-score, and AUC–ROC. The models showed excellent predictive performance for slide-type landslides (AUC = 0.99 for both RF and XGB) and strong performance for fall-type landslides (AUC = 0.92 for RF and 0.89 for XGB). Flow-type landslides exhibited moderate predictability (AUC = 0.68 for RF and 0.65 for XGB). The combined (total) models achieved very high accuracy (0.95) and AUC values of 0.99 (RF) and 0.98 (XGB). XGB classified a larger proportion of the study area into very high susceptibility (281.99 km2) compared to RF (71.23 km2), while RF distributed more area into low-to-moderate susceptibility classes. Both models produced geomorphologically consistent susceptibility patterns aligned with known landslide-prone zones along the KKH. XGB emphasized localized high-risk hotspots, whereas RF provided a more conservative spatial distribution. The results highlight the strong influence of anthropogenic activities and terrain controls on landslide occurrence and demonstrate the suitability of ensemble ML methods for robust landslide susceptibility assessment in complex mountainous environments.
喀喇昆仑公路(KKH)是连接喀喇昆仑地区的重要的高海拔交通走廊,由于地形陡峭、地质复杂、强降雨和人为活动增加,经常受到山体滑坡的影响。因此,可靠的滑坡易感性测绘对于减轻灾害和增强走廊沿线基础设施的复原力至关重要。在这项研究中,使用两种集成机器学习(ML)模型:随机森林(RF)和极端梯度增强(XGB),沿着KKH的一段评估了滑坡的易感性。由447个事件组成的滑坡清单被分为坠落、流动和滑动类型,并与非滑坡样本相结合,进行监督建模。利用遥感、水文指数和地质资料得出的14个条件因子。利用方差膨胀因子分析解决多重共线性问题。采用70/30训练-检验分割法对模型进行训练和验证,并使用准确性、精密度、召回率、f1评分和AUC-ROC来评估模型的性能。该模型对滑坡型滑坡(RF和XGB的AUC均为0.99)和滑坡型滑坡(RF和XGB的AUC分别为0.92和0.89)具有良好的预测性能。流型滑坡具有中等的可预测性(RF的AUC = 0.68, XGB的AUC = 0.65)。组合(总)模型获得了非常高的精度(0.95),AUC值为0.99 (RF)和0.98 (XGB)。XGB将研究区划分为非常高易感区(281.99 km2)的比例大于RF (71.23 km2),而RF则将更多的区域划分为中低易感区。这两个模型都得出了地貌上一致的易感性模式,与KKH沿线已知的滑坡易发带一致。XGB强调局部高风险热点,而RF提供更保守的空间分布。研究结果强调了人为活动和地形控制对滑坡发生的强烈影响,并证明了集成ML方法在复杂山区环境中滑坡易感性评估的适用性。
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引用次数: 0
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