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Superior compressive energy absorption and ultra-high damping via synergistic effects in an inoculated Zn–22Al alloy foam-filled CFRP tube composite 接种Zn-22Al合金泡沫填充CFRP管复合材料具有优异的压缩能吸收和超高阻尼效应
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-05 DOI: 10.1016/j.compositesb.2026.113493
Jianjun Zhang , Zhengqi Lu , Guangli Bi , Weirong Li , Zhixian Jiao , Yuandong Li , Tijun Chen , Qingzhou Wang , Le Gao , Chunhua Li
Modern aerospace design demands lightweight materials capable of simultaneous energy absorption and vibration suppression. To address this demand, a grain-refined Zn–22Al (ZA22) alloy foam-filled carbon fiber-reinforced polymer (CFRP) tube composite (ZA22-CFRP FFTC) was developed, featuring a robust interface between the CFRP tube and ZA22 foam core. The foam pore walls consist of fine equiaxed α-phase and reticular η-phase, achieved via grain refinement with an (Al3Ni + Al3Ti)/Al inoculant. Quasi-static and dynamic compression tests indicate the FFTC exhibits superior and more stable load-bearing capacity and energy absorption compared to the theoretical superposition of its individual constituents, confirming a significant synergistic effect. Under quasi-static loading, the 1.0 mm wall-thickness FFTC achieves optimal performance, with a specific energy absorption (SEA) 50.25% higher than that of pure ZA22 foam. Under dynamic loading, the 0.5 mm wall-thickness FFTC shows an extended, stable compression plateau, leading to a 114.4% increase in SEA. The composites also display distinct strain-rate sensitivity, with mechanical properties following a non-monotonic“increase-then-decrease”trend. Furthermore, the FFTC demonstrates ultra-high damping capacity over wide ranges of strain amplitudes (10−5–10−3) and temperatures (30–100 °C), with room-temperature damping enhanced by up to 401.9% relative to the theoretical superposition with increasing CFRP volume fraction. These enhancements in compressive energy absorption and damping, exceeding the sum of individual components, are attributed to the coupling effect induced by synergistic component interactions. The underlying mechanisms are thoroughly elucidated through in-depth microstructural analysis and finite element analysis (FEA).
现代航空航天设计需要能够同时吸收能量和抑制振动的轻质材料。为了满足这一需求,研究人员开发了一种晶粒细化Zn-22Al (ZA22)合金泡沫填充碳纤维增强聚合物(CFRP)管复合材料(ZA22-CFRP FFTC),该材料在CFRP管和ZA22泡沫芯之间具有坚固的界面。泡沫孔壁由细小的等轴α相和网状的η相组成,由(Al3Ni + Al3Ti)/Al孕育剂细化而成。准静态和动态压缩试验表明,与单个成分的理论叠加相比,FFTC表现出更优越、更稳定的承载能力和能量吸收,证实了显著的协同效应。准静态载荷下,1.0 mm壁厚的FFTC性能最佳,比能吸收(SEA)比纯ZA22泡沫提高50.25%。在动载荷作用下,0.5 mm壁厚的FFTC表现出延长的、稳定的压缩平台,导致SEA增加114.4%。复合材料表现出明显的应变速率敏感性,力学性能呈现非单调的“先增加后减少”趋势。此外,FFTC在应变幅值(10−5 ~ 10−3)和温度(30 ~ 100℃)范围内均表现出超高的阻尼能力,随着CFRP体积分数的增加,相对于理论叠加,室温阻尼增强高达401.9%。这些压缩能量吸收和阻尼的增强,超过单个成分的总和,归因于协同成分相互作用引起的耦合效应。通过深入的微观结构分析和有限元分析(FEA),彻底阐明了其潜在机制。
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引用次数: 0
A carbon fiber elastomer film for mechanically anisotropic enhancement of stretchable electronics 一种用于可拉伸电子器件机械各向异性增强的碳纤维弹性体薄膜
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-05 DOI: 10.1016/j.compositesb.2026.113417
Junhao Ni , Carola Böhmer , Markus Koenigsdorff , Andreas Richter , Gerald Gerlach , E.-F. Markus Vorrath
Stretchable electronic devices with micro-to sub-millimeter thickness are increasingly used in soft robotics, wearable healthcare, and human-machine interfaces. However, the mechanical isotropy of commonly used elastomers leads to undesirable deformation in transverse directions, reducing actuation efficiency, sensing precision, and geometric stability. Here, we present a low-cost, easy-to-produce and readily applicable carbon fiber elastomer film (CFEF) that imparts pronounced mechanical anisotropy when laminated onto isotropic elastomers. The CFEF is fabricated by embedding unidirectionally aligned carbon fiber monofilaments within a polydimethylsiloxane (PDMS) matrix. The composite exhibits high stiffness along the carbon fiber axis, while remaining highly compliant in the direction perpendicular to the fibers. Fabrication requires only commercially available materials and standard processes, ensuring compatibility with existing devices. For a 200 μm thick PDMS film, it suppresses transverse strain by 95%. Applied to strip-type multilayer dielectric elastomer actuators, the CFEF increases actuation strain by 22%. In dielectric elastomer sensors, an anisotropy ratio of 80.6:1 is achieved. This approach offers an effective and manufacturing-friendly solution for tailoring directional mechanical properties in thin, soft electronic systems without compromising flexibility.
微至亚毫米厚度的可拉伸电子设备越来越多地用于软机器人、可穿戴医疗保健和人机界面。然而,常用弹性体的力学各向同性导致了在横向上的不良变形,降低了驱动效率、传感精度和几何稳定性。在这里,我们提出了一种低成本、易于生产和易于应用的碳纤维弹性体薄膜(CFEF),当层压在各向同性弹性体上时,它具有明显的机械各向异性。CFEF是通过在聚二甲基硅氧烷(PDMS)基体中嵌入单向排列的碳纤维单丝而制成的。该复合材料沿碳纤维轴具有高刚度,同时在垂直于纤维的方向上保持高度柔顺。制造只需要市售材料和标准工艺,确保与现有设备的兼容性。对于200 μm厚的PDMS薄膜,它可以抑制95%的横向应变。应用于带状多层介电弹性体致动器,CFEF使致动应变提高22%。在介电弹性体传感器中,各向异性比达到80.6:1。这种方法提供了一种有效且易于制造的解决方案,可以在不影响灵活性的情况下定制薄软电子系统的定向机械性能。
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引用次数: 0
Robust doping strategy for carbon nanotube sheets via covalent functionalization 共价功能化碳纳米管片的鲁棒掺杂策略
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-05 DOI: 10.1016/j.compositesb.2026.113482
Minseouk Choi , Kyung Tae Park , Dong Uk Woo , Jinho Jang , Kyunbae Lee , Yeonsu Jung , Hyejin Jang , Taehoon Kim
Doped carbon nanotube sheets (CNTSs) are promising conductive materials for copper alternatives, but their practical use is limited by poor doping stability from weak van der Waals interactions, causing desorption in solvents. Here, we introduce a novel method for stable n-type and p-type doping by covalently functionalizing CNTSs with amine and sulfonic groups, respectively. Our amine- and sulfonic-functionalized CNTSs show significantly improved specific electrical conductivities of 20,490 and 17,593 S cm2 g−1, compared to 11,475 S cm2 g−1 for pristine CNTS. For practical applications, they were applied as electromagnetic interference (EMI) shielding films and current collectors for supercapacitors. They exhibit enhanced EMI shielding effectiveness (SE) of 44.6 and 40.9 dB at 8.2 GHz (5.2 μm), respectively, compared to 34.5 dB of pristine CNTSs. Also, amine-functionalized CNTSs show outstanding absolute SE of 431,250 dB cm2 g−1 owing to improved conductivity while maintaining lightweight nature of CNTSs. Critically, they maintained their conductivity and EMI SE after washing with diluted sulfuric acid, potassium hydroxide solution, DI water, as well as after annealing, bending, and air exposure, unlike conventionally doped CNTSs suffering from dopant leaching. Furthermore, when applied as supercapacitor current collectors and electrode, functionalized CNTSs exhibit enhanced rate capabilities due to their robust conductivity. Unlike physisorbed dopants, which leach into electrolytes and degrade performance, covalent functionalization ensures stable doping and consistent performance within the electrolyte. This new strategy offers a significant breakthrough in both the electrical conductivity and long-term stability of CNTSs, opening doors for diverse and demanding applications.
掺杂碳纳米管片(CNTSs)是一种很有前途的铜替代品导电材料,但由于弱范德华相互作用导致掺杂稳定性差,导致溶剂解吸,限制了其实际应用。在这里,我们介绍了一种新的方法,通过胺基和磺酸基的共价官能化cnts来稳定n型和p型掺杂。与原始碳纳米管的11,475 S cm2 g - 1相比,我们的胺和磺酸功能化碳纳米管的比电导率显著提高,分别为20,490和17,593 S cm2 g - 1。在实际应用中,它们被应用于超级电容器的电磁干扰(EMI)屏蔽膜和集流器。与原始cnts的34.5 dB相比,它们在8.2 GHz (5.2 μm)下的EMI屏蔽效率(SE)分别为44.6和40.9 dB。此外,胺功能化碳纳米管的绝对SE值为431,250 dB cm2 g−1,这是由于碳纳米管的导电性得到了改善,同时又保持了碳纳米管的轻量化。关键的是,它们在用稀释的硫酸、氢氧化钾溶液、去离子水洗涤以及退火、弯曲和空气暴露后保持了导电性和EMI SE,而不像传统掺杂的cnts受到掺杂剂浸出的影响。此外,当用作超级电容器集流器和电极时,功能化碳纳米管由于其强大的导电性而表现出增强的速率能力。不像物理吸附的掺杂剂会渗入电解质并降低性能,共价官能化确保了稳定的掺杂和电解质内一致的性能。这种新策略在cnts的导电性和长期稳定性方面都取得了重大突破,为各种苛刻的应用打开了大门。
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引用次数: 0
Interpretable and physics-informed graph neural modeling for intelligent damage localization in CFRP composites CFRP复合材料智能损伤定位的可解释和物理信息图神经模型
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-04 DOI: 10.1016/j.compositesb.2026.113469
Xinming Li , Jinrui Zhang , Kehui Zhu , Qingrui Hu , Lingyu Sun , Jiawei Gu , Wenhan Lyu , Yanxue Wang
Reliable and interpretable detection of structural damage in carbon fiber–reinforced polymer (CFRP) composites remains a fundamental challenge in structural health monitoring, as wave propagation is strongly influenced by anisotropy, multimodal interference, and complex boundary conditions. Traditional model driven and deep learning approaches often fail to maintain both accuracy and physical consistency in such heterogeneous propagation environments, thereby limiting their scalability to real world engineering applications. To address these limitations, this study introduces a Physics-Informed Graph Modeling framework with Individualized Dynamics (PIGMind), which integrates physical priors with graph based representation learning to achieve intelligent damage localization. The framework embeds physics derived energy indicators into graph construction, allowing the adjacency topology to explicitly represent the directional dependence of ultrasonic guided wave propagation. Furthermore, a node personalized embedding mechanism and a regularization enhanced decoding module are incorporated to capture path level heterogeneity and preserve geometric consistency within the latent space. Extensive experiments on a CFRP plate instrumented with an eight-sensor array demonstrate that PIGMind achieves a mean localization error of 10.18 mm, representing a 7.8% improvement over the graph based methods, while maintaining stable performance under anisotropic and noisy conditions. Beyond quantitative performance, the framework reconstructs physically interpretable latent manifolds that capture intrinsic patterns of energy diffusion and coupling, thereby bridging data driven inference with wave propagation physics. This work establishes a generalizable paradigm for physics-informed spatiotemporal graph learning, paving the way for scalable, interpretable, and physically consistent intelligent damage diagnosis in complex composite structures.
由于波的传播受到各向异性、多模态干涉和复杂的边界条件的强烈影响,对碳纤维增强聚合物(CFRP)复合材料的结构损伤进行可靠和可解释的检测仍然是结构健康监测的一个基本挑战。传统的模型驱动和深度学习方法往往无法在这种异构传播环境中保持准确性和物理一致性,从而限制了它们在现实世界工程应用中的可扩展性。为了解决这些限制,本研究引入了具有个性化动力学的物理知情图建模框架(PIGMind),该框架将物理先验与基于图的表示学习相结合,以实现智能损伤定位。该框架将物理导出的能量指示器嵌入到图构造中,允许邻接拓扑明确地表示超声导波传播的方向依赖性。此外,采用节点个性化嵌入机制和正则化增强解码模块来捕获路径级异构性并保持潜在空间内的几何一致性。在装有8个传感器阵列的CFRP板上进行的大量实验表明,PIGMind的平均定位误差为10.18 mm,比基于图的方法提高了7.8%,同时在各向异性和噪声条件下保持稳定的性能。除了定量性能之外,该框架还重建了物理上可解释的潜在流形,这些流形捕获了能量扩散和耦合的内在模式,从而将数据驱动的推断与波传播物理联系起来。这项工作为基于物理的时空图学习建立了一个可推广的范式,为复杂复合结构中可扩展、可解释和物理一致的智能损伤诊断铺平了道路。
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引用次数: 0
Constructing a cross-dimensional interfacial transition layer with MXene and aramid nanofiber for carbon fiber/ poly (ether ether ketone) composites interfacial enhancement 用MXene和芳纶纳米纤维构建跨维界面过渡层增强碳纤维/聚醚醚酮复合材料界面
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-03 DOI: 10.1016/j.compositesb.2026.113491
Yingze Li , Xingyue Tang , Jiqiang Hu , Lianchao Wang , Dongxing Zhang , Xinghong Zhang , Bing Wang
The intrinsic inert surface structure of carbon fiber (CF) results in a weak interfacial adhesion with poly (ether ether ketone) (PEEK), deteriorating the mechanical performance of CF/PEEK composites. In order to solve this longstanding obstacle, a cross-dimensional interfacial transition layer strategy is proposed, containing of aramid nanofiber (ANF), Ti3C2Tx MXene, and a matrix-compatibilizer of polyetherimide (PEI) to coat on CF surface. The interactions between each component contributes to constructing a uniform sizing layer on CF surface, significantly increasing the CF surface roughness and improving the wettability between CF and PEEK. Furthermore, the crystallinity of PEEK displays a slight increment and the interphase region has been expanded, forming a gradient modulus-plateau as the introduction of MXene-ANF/PEI sizing agent. These synergistically reinforcement mechanism results in the elevated mechanical performance of CF/PEEK composites. In brief, this cross-dimensional transition layer approach provides an effective route for fabricating the high-performance CF/PEEK composites.
碳纤维(CF)固有的表面惰性结构导致其与聚醚醚酮(PEEK)的界面附着力较弱,使其复合材料的力学性能恶化。为了解决这一长期存在的障碍,提出了一种包含芳纶纳米纤维(ANF)、Ti3C2Tx MXene和聚醚酰亚胺(PEI)基质相容剂的跨维界面过渡层策略。各组分之间的相互作用有助于在CF表面形成均匀的施胶层,显著提高CF表面粗糙度,改善CF与PEEK之间的润湿性。此外,随着MXene-ANF/PEI施胶剂的引入,PEEK的结晶度略有增加,相间区扩大,形成梯度模量平台。这些协同增强机制提高了CF/PEEK复合材料的力学性能。总之,这种跨维过渡层方法为制备高性能CF/PEEK复合材料提供了一条有效途径。
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引用次数: 0
Multifunctional graphene thermal switch material with adaptive heat control, flame retardant and machine learning-assisted monitor for high-efficiency battery management 多功能石墨烯热开关材料,具有自适应热控制,阻燃和机器学习辅助监视器,用于高效电池管理
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-03 DOI: 10.1016/j.compositesb.2026.113480
Haiqin Zhang , Yihao Li , Peng Wang , Song Shi , Lili Zheng , Tianle Zhang , Hongyao Xue , Zhiming Liu , Mingjia Li , Yan He
Safe and efficient operation of high-energy-density battery systems relies on thermal management. But current methods of thermal management are not always up to snuff when it comes to thermal response and flame resistance. By manipulating the microstructure of low-grade graphene through gas evaporation and directional freeze-drying, we were able to create a thermally switchable flame-retardant material that can undergo fast transitions. In 20 s at around 140 °C, the material goes from being conductive (1.23 W m−1 K−1) to being insulating (0.11 W m−1 K−1), thus combining the roles of efficient heat transfer and thermal insulation. By acting as a separator in nickel-manganese lithium-ion batteries, this material improves the stability of the modules and decreases the dangers of explosions caused by thermal runaway by drastically reducing heat diffusion. Additionally, a thermosensitive flame-retardant composite with many functions based on graphene was created to assist with responsive heat management. In order to facilitate proactive risk assessment, infrared imaging and real-time temperature data were used to detect early-stage thermal abnormalities using the machine learning system. A new, economical, and scalable method for controlling electric vehicle and energy storage battery safety has been developed through the combination of intelligent detection and thermal switching. This method promotes improvements in performance and inherent safety.
高能量密度电池系统的安全高效运行依赖于热管理。但是,当涉及到热响应和阻燃性时,目前的热管理方法并不总是令人满意。通过气体蒸发和定向冷冻干燥来控制低品位石墨烯的微观结构,我们能够创造出一种可以快速转变的热切换阻燃材料。在140°C左右的20秒内,材料从导电(1.23 W m−1 K−1)变为绝缘(0.11 W m−1 K−1),从而结合了高效传热和隔热的作用。作为镍锰锂离子电池的分离器,这种材料提高了组件的稳定性,并通过大幅减少热扩散来降低由热失控引起的爆炸危险。此外,基于石墨烯的热敏阻燃复合材料具有多种功能,有助于响应性热管理。为了便于进行前瞻性风险评估,利用机器学习系统,利用红外成像和实时温度数据来检测早期热异常。将智能检测与热开关相结合,开发了一种经济、可扩展的新型电动汽车和储能电池安全控制方法。这种方法提高了性能和固有安全性。
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引用次数: 0
Aligned cellulose nanofibril ionogels with continuous micro-nanochannels for ionic thermoelectrics and self-powered sensors 具有连续微纳米通道的定向纤维素纳米纤维离子凝胶,用于离子热电和自供电传感器
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-03 DOI: 10.1016/j.compositesb.2026.113490
Nan Liu , Xinpeng Che , Wenjing Cao , He Zhang , Xinming Wei , Mingjie Li , Anshan Xiao
The growing demand for sustainable and distributed power sources, driven by advances in the Internet of Things and flexible wearable electronics, has intensified the focus on thermoelectric energy harvesting. Although inorganic thermoelectric materials (e.g., Bi2Te3) exhibit high conversion efficiency, their rigidity, high cost, and dependence on scarce or toxic elements hinder their use in flexible applications. In contrast, ionic thermoelectric materials (i-TEs) show advantages, including high Seebeck coefficients, flexibility, and biocompatibility. However, conventional ionogels typically possess disordered polymer networks, which lead to low ionic conductivity and limited Seebeck coefficient enhancement. To address this challenge, we use cellulose nanofibrils (CNFs) to construct a well-aligned micro-nanochannel via directional freezing. This design offers continuous and low-resistance pathways, markedly facilitating ion transport. Meanwhile, nano-confinement effects enhance ion selectivity at low concentrations and promote asymmetric ion distribution, leading to a synergistic improvement of thermoelectric performance. The resulting ionic thermoelectric material achieves a Seebeck coefficient of 3.47 mV K−1 and an outstanding power output of 223.51 mW m−2 at ΔT∼20 °C, comparable or superior to many reported conventional i-TE systems. This work proposes a novel strategy for regulating ion migration pathways and provides a fundamental basis for developing high-performance flexible ion-thermoelectric devices and self-powered sensors.
在物联网和柔性可穿戴电子产品进步的推动下,对可持续和分布式电源的需求不断增长,加剧了对热电能量收集的关注。尽管无机热电材料(如Bi2Te3)具有很高的转换效率,但它们的刚性、高成本以及对稀缺或有毒元素的依赖阻碍了它们在灵活应用中的使用。相比之下,离子热电材料(i-TEs)表现出优势,包括高塞贝克系数、柔韧性和生物相容性。然而,传统的离子凝胶通常具有无序的聚合物网络,这导致离子电导率低,塞贝克系数增强有限。为了解决这一挑战,我们使用纤维素纳米原纤维(CNFs)通过定向冷冻构建了一个排列良好的微纳米通道。这种设计提供了连续和低电阻的通道,显著促进离子传输。同时,纳米约束效应增强了离子在低浓度下的选择性,促进了离子的不对称分布,从而协同提高了热电性能。所得的离子热电材料在ΔT ~ 20°C下实现了3.47 mV K−1的塞贝克系数和223.51 mW m−2的出色功率输出,与许多报道的传统i-TE系统相当或优于。这项工作提出了一种调节离子迁移途径的新策略,为开发高性能柔性离子热电器件和自供电传感器提供了基础。
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引用次数: 0
Microwave-assisted activation of high-modulus carbon fibres for interface engineering: Elucidating the distinct roles of electrostatic wetting and van der Waals locking 微波辅助激活界面工程高模量碳纤维:阐明静电润湿和范德华锁的独特作用
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-03 DOI: 10.1016/j.compositesb.2026.113479
Jiabao Zhu , Yuhong Dong , Zheng Chen , Jianjun Yi , Cong Liu , Xiaopeng Chen , Hongbo Geng , Tianming Li , Xianhua Huan , Hefeng Li , Xiaolong Jia , Xiaoping Yang
Interface is pivotal for optimizing the performance of carbon fibre reinforced polymer composites. However, high-modulus carbon fibres (HMCFs) featured with a high degree of graphitization and a scarcity of microcrystalline active sites exhibit intrinsic surface inertness that hinders effective interfacial stress transfer. Here, an innovative microwave-assisted activation strategy was developed to employ the intrinsic electromagnetic duality of HMCFs, converting structural adversity (surface inertness) into functional advantage (surface responsiveness). In contrast to previous phenomenological microwave treatments, the graphitization degree of HMCFs is explicitly treated as a process-design parameter to regulate microwave response and activation outcome. The maximum interfacial enhancement was achieved by the mM55J/epoxy (EP) due to its higher microwave responsiveness induced by the higher graphitization degree. Specifically, cross-scale DFT-MD simulations with separate mechanism analysis and a quantitatively parameterized roughness model were constructed to elucidate the molecular interaction mechanisms, revealing that electrostatic interactions from oxygen-containing groups predominantly govern resin wetting, whereas roughness-induced van der Waals confinement stabilizes interfacial adhesion. Furthermore, an enhancement of 49.1% in the thickness of the interphase modulus transition layer was evaluated by AFM, and the thickening mechanism was attributed to the coupling of molecular confinement and vdW interaction energy. This work quantitatively elucidates the microscopic mechanism by which changes in the physicochemical state of fibre surfaces enhance interfacial reinforcement, and establishes a transferable methodology for the rational design of roughness-sensitive carbon-polymer interfaces. Finally, the efficient and environmentally-friendly strategy used in this work provides a promising pathway for the rapid interface construction of next-generation inert carbon materials.
界面是优化碳纤维增强聚合物复合材料性能的关键。然而,高模量碳纤维(HMCFs)具有高度石墨化和缺乏微晶活性位点的特点,表现出固有的表面惰性,阻碍了有效的界面应力传递。本研究开发了一种创新的微波辅助激活策略,利用hmcf固有的电磁对偶性,将结构劣势(表面惰性)转化为功能优势(表面响应性)。与以往的现象学微波处理不同,hmcf的石墨化程度被明确地作为一个工艺设计参数来调节微波响应和激活结果。由于石墨化程度高,mM55J/环氧树脂(EP)具有较高的微波响应性,因此界面增强效果最大。具体来说,通过跨尺度DFT-MD模拟和单独的机理分析和定量参数化的粗糙度模型来阐明分子相互作用机制,揭示了含氧基团的静电相互作用主要控制树脂润湿,而粗糙度诱导的范德华约束稳定了界面粘附。原子力显微镜(AFM)分析结果表明,相间模量过渡层厚度增加了49.1%,增厚机制归因于分子约束和vdW相互作用能的耦合作用。这项工作定量地阐明了纤维表面物理化学状态变化增强界面增强的微观机制,并为合理设计粗糙度敏感的碳-聚合物界面建立了一种可转移的方法。最后,本研究中采用的高效环保策略为下一代惰性碳材料的快速界面构建提供了一条有希望的途径。
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引用次数: 0
Investigation on synergistic effects of acoustic and mechanical properties of 3D-Printed continuous flax fiber reinforced PLA composites through controlling impregnation speed and printing parameters 控制浸渍速度和打印参数对3d打印连续亚麻纤维增强PLA复合材料声学和力学性能协同效应的研究
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-03 DOI: 10.1016/j.compositesb.2026.113487
Zhixiong Bi , Qian Li , Zhen Zhang , Zhongsen Zhang , Yu Long , Weidong Yang , Yan Li
Plant fibers have attracted growing interest as sustainable acoustic materials owing to their remarkable sound absorption properties and biodegradability. In this study, a systematic control strategy involving impregnation speed and fused filament fabrication (FFF) printing parameters was implemented to optimize the acoustic and mechanical performance of continuous flax fiber-reinforced polylactic acid (PLA) composites (CFFRCs). Firstly, a physics-based infiltration numerical model was developed to characterize the relationship between impregnation speed and resin penetration depth by solving the Brinkman-Forchheimer equations. The resin flow process was illustrated through incorporating the inherent non-uniform fiber distributions arising from natural discontinuities and the hierarchical structure of flax yarns to guide the preparation of pre-impregnated flax yarns with different impregnation speeds. The continuous nature of the flax fibers was maintained throughout the printing and impregnating process, forming the structural backbone of the final CFFRCs. Subsequently, the influence of impregnation speed on void formation was investigated by evaluating the tensile and sound absorption properties of CFFRCs fabricated using pre-impregnated flax yarns at various impregnation speeds. Finally, the relationships between the critical printing parameters (i.e., printing orientations, line width, and infill layers), voids formation, and acoustic and mechanical performances of CFFRCs were established. The experimental and numerical results demonstrated a fundamental trade-off where increased porosity significantly improved sound absorption coefficients through enhanced viscous friction and resonance effects within the void networks, while concurrently reducing tensile strength due to disrupted load transfer pathways. The non-uniform fiber distributions in the flax yarns exhibited significant sensitivity to impregnation speed during the impregnation process. Through precise control of impregnation parameters, substantial improvements in fiber-matrix interfacial bonding were achieved in 3D-printed CFFRCs, accompanied by a remarkable reduction in porosity. Both the enhanced mechanical properties and maintained sound absorption capabilities were achieved by designing the printing parameters. Printing orientations was critical for mechanical optimization, while acoustic performance depended on line width. The findings provided a clear pathway for designing the 3D-printed CFFRCs integrated with load-bearing and functionality in future.
植物纤维由于其显著的吸声性能和生物可降解性,作为可持续声学材料引起了越来越多的关注。本研究采用浸渍速度和熔丝制造(FFF)打印参数作为系统控制策略,优化连续亚麻纤维增强聚乳酸(cffrc)复合材料(cffrc)的声力学性能。首先,通过求解Brinkman-Forchheimer方程,建立了基于物理的浸渍数值模型,表征浸渍速度与树脂渗透深度之间的关系。结合天然不连续引起的纤维固有的不均匀分布和亚麻纱线的层次结构,说明了树脂的流动过程,指导了不同浸渍速度的预浸渍亚麻纱线的制备。亚麻纤维的连续特性在整个印刷和浸渍过程中保持不变,形成了最终cffrc的结构骨架。随后,通过评价不同浸渍速度下预浸渍亚麻纱制备的cffrc的拉伸性能和吸声性能,研究了浸渍速度对孔隙形成的影响。最后,建立了关键打印参数(打印方向、线宽、填充层数)、孔洞形成与cffrc声学和力学性能之间的关系。实验和数值结果表明,孔隙率的增加通过增强空隙网络内的粘性摩擦和共振效应显著提高了吸声系数,同时由于载荷传递路径的中断而降低了抗拉强度。在浸渍过程中,亚麻纱线中的纤维分布不均匀,对浸渍速度非常敏感。通过对浸渍参数的精确控制,3d打印cffrc的纤维-基质界面结合得到了显著改善,同时孔隙率显著降低。通过对打印参数的设计,既提高了机械性能,又保持了吸声能力。印刷方向是机械优化的关键,而声学性能取决于线宽。该研究结果为未来设计具有承重和功能的3d打印cffrc提供了明确的途径。
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引用次数: 0
A novel architecture of soft magnetoelectric composites for human-machine interaction 一种新型人机交互软磁电复合材料结构
IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2026-02-02 DOI: 10.1016/j.compositesb.2026.113484
Zhangbo Wang , Wei Xiao , Yihua Xiao , Hanlin Zhu
Soft magnetoelectric composites have great potential in energy harvesting, flexible sensing, and human-machine interaction (HMI). However, their electrical output capacity is limited, as mechanical deformation typically induces only minimal changes in magnetic flux. Herein, a new soft magnetoelectric composite (SMEC) is proposed to enhance voltage output. The SMEC integrates a coil, a soft scaffold, and a soft magnetoelastic block. Under axial load, the soft magnetoelastic block rotates while approaching the coil. The rotation of the magnetic field and the changed distance between the magnetoelastic block and the coil collectively induce a significant variation in magnetic flux, thereby enhancing voltage output. Furthermore, the continued axial load induces elastic deformation of the soft magnetoelastic block, further modulating the magnetic flux. The maximum voltage density and current density that SMEC can achieve are 9.87 mV/cm2 and 0.75 mA/cm2, respectively. Both indicators are higher than those of previous soft magnetoelectric composites. Additionally, the SMEC can output three voltage signals with different peak values as the direction of the applied pressure is different. Leveraging this characteristic, the SMEC is integrated into two HMI systems, successfully enabling precise controls such as light switching, PPT page turning, virtual button switching, and playing video games. This study proposes a novel strategy to induce magnetic field rotation via mechanical loads, providing a new pathway for breaking the performance limitations of soft magnetoelectric composites.
软磁电复合材料在能量收集、柔性传感、人机交互等方面具有巨大的应用潜力。然而,它们的电输出能力是有限的,因为机械变形通常只引起磁通量的微小变化。本文提出了一种新型的软磁电复合材料(SMEC)来提高电压输出。SMEC集成了一个线圈、一个软支架和一个软磁弹性块。在轴向载荷作用下,软磁弹性块在接近线圈时旋转。磁场的旋转和磁弹性块与线圈之间距离的变化共同引起磁通量的显著变化,从而增强了电压输出。此外,持续的轴向载荷引起软磁弹性块的弹性变形,进一步调制磁通量。SMEC能达到的最大电压密度和电流密度分别为9.87 mV/cm2和0.75 mA/cm2。这两项指标均高于以往的软磁电复合材料。此外,随着施加压力的方向不同,SMEC可以输出三个峰值不同的电压信号。利用这一特性,SMEC集成到两个HMI系统中,成功地实现了精确的控制,如灯光开关、PPT翻页、虚拟按钮切换和玩视频游戏。本研究提出了一种通过机械载荷诱导磁场旋转的新策略,为突破软磁电复合材料的性能限制提供了新的途径。
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引用次数: 0
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Composites Part B: Engineering
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