Modern aerospace design demands lightweight materials capable of simultaneous energy absorption and vibration suppression. To address this demand, a grain-refined Zn–22Al (ZA22) alloy foam-filled carbon fiber-reinforced polymer (CFRP) tube composite (ZA22-CFRP FFTC) was developed, featuring a robust interface between the CFRP tube and ZA22 foam core. The foam pore walls consist of fine equiaxed α-phase and reticular η-phase, achieved via grain refinement with an (Al3Ni + Al3Ti)/Al inoculant. Quasi-static and dynamic compression tests indicate the FFTC exhibits superior and more stable load-bearing capacity and energy absorption compared to the theoretical superposition of its individual constituents, confirming a significant synergistic effect. Under quasi-static loading, the 1.0 mm wall-thickness FFTC achieves optimal performance, with a specific energy absorption (SEA) 50.25% higher than that of pure ZA22 foam. Under dynamic loading, the 0.5 mm wall-thickness FFTC shows an extended, stable compression plateau, leading to a 114.4% increase in SEA. The composites also display distinct strain-rate sensitivity, with mechanical properties following a non-monotonic“increase-then-decrease”trend. Furthermore, the FFTC demonstrates ultra-high damping capacity over wide ranges of strain amplitudes (10−5–10−3) and temperatures (30–100 °C), with room-temperature damping enhanced by up to 401.9% relative to the theoretical superposition with increasing CFRP volume fraction. These enhancements in compressive energy absorption and damping, exceeding the sum of individual components, are attributed to the coupling effect induced by synergistic component interactions. The underlying mechanisms are thoroughly elucidated through in-depth microstructural analysis and finite element analysis (FEA).
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