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Ion-quadrupole effects in thermal energy ion-molecule collision rate constants 热能离子-分子碰撞速率常数中的离子-四极效应
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017079900
A. Kosmas
A simplified version of the Averaged Quadrupole Orientation (AQO) theory is attempted, by taking into account the adiabatic invariance approximation, to investigate the effect of the ion-quadrupolar molecule interaction on thermal energy reaction rate constant. The theory is formulated in terms of an orientation averaged potential energy function and predicts a significant increase in the capture rate constant over the Langevin value for molecules with large quadrupole moments and small polarizabilities. The results of the theory are compared to various experimental data and predictions of other theories Developpement d'une version simplifiee de la theorie de l'orientation quadripolaire moyenne, en considerant la methode de l'invariant adiabatique, pour etudier l'effet du potentiel d'interaction d'un ion avec une molecule quadripolaire sur la constante de vitesse de la reaction aux energies thermiques
在考虑绝热不变性近似的基础上,建立了简化的平均四极取向理论,探讨了离子-四极分子相互作用对热能反应速率常数的影响。该理论是根据取向平均势能函数来表述的,并预测具有大四极矩和小极化率的分子的捕获速率常数比朗之万值显著增加。该理论的结果与各种实验数据和其他理论的预测进行了比较,发展了一个简化了定向四极流理论的版本,考虑了不变绝热性的方法,建立了势相互作用的效应,建立了一个分子四极流理论,确定了能量热反应的常数
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引用次数: 8
Large scale instability of nonlinear standing waves 非线性驻波的大尺度不稳定性
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017078700
P. Coullet, S. Fauve, E. Tirapegui
We present the nonlinear phase equations describing the stability of a time-periodic one-dimensional spatial pattern, that arises in a system which is invariant by space and time translations and space reflection symmetry. We show that a large scale oscillatory instability can occur, leading to a quasiperiodic temporal regime with two different spatial scales On etablit les equations aux derivees partielles non lineaires qui gouvernent la stabilite a grande echelle d'une structure cellulaire unidimensionnelle oscillante, apparaissant dans un systeme hors equilibre, invariant par translations d'espace et de temps, et par reflexion d'espace. Existence d'une instabilite oscillatoire, conduisant a un regime quasi periodique, possedant deux echelles spatiales distinctes
本文给出了描述一维时间周期空间模式稳定性的非线性相位方程,该模式是由时空平移和空间反射对称引起的。我们证明了一个大尺度的振荡不稳定性可以发生,导致一个具有两个不同空间尺度的准周期时间状态。在可建立的方程上,推导出粒子的非线性,如政府的稳定,一维的大梯次的d'une结构,系统的平衡,不变的平移,空间的温度,空间的反射。不稳定振荡的存在性,准周期的存在性,准周期的存在性,空间上不同的双梯队
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引用次数: 78
Mean-field theory for optimization problems 优化问题的平均场理论
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017076300
H. Orland
A mean-field theory for optimization problems of the Travelling Salesman type, or of the Matching type, is presented. It involves an infinite set of order parameters which measure the lack of self-averageness of the system and its degree of freezing. We further conjecture that NP-completeness is associated with replica symmetry breaking Theorie de champ moyen pour les problemes d'optimisation du type «Voyageur de Commerce» ou problemes d'«appariement», a l'aide d'un ensemble infini de parametres d'ordre, qui mesurent l'absence d'automoyennage du systeme et donc son degre de gel. On conjecture que la NP-complexite est associee a la brisure de symetrie des repliques
提出了一种求解旅行商型或匹配型优化问题的平均场理论。它涉及一组无穷多的有序参数,这些参数用来度量系统的自平均缺乏性及其冻结程度。我们进一步推测np完备性与复制对称性破缺有关,理论上的金钱问题与优化问题有关,理论上的商业问题与设备问题有关,理论上的参数问题与集合无穷大问题有关,理论上的参数问题与秩序有关,理论上的测量问题与系统的缺失问题与系统的自动破缺有关,理论上的对称性破缺与系统的对称性破缺有关。关于np复合体的猜想,并与对称复合体的构造相联系
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引用次数: 70
A new torsion pendulum technique to measure the twist elastic constant of liquid crystals 一种测量液晶扭弹性常数的扭摆新技术
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046018088100
S. Faetti, M. Gatti, V. Palleschi
A new experimental method to measure the twist elastic constant of nematic liquid crystals is proposed. The method is based on a direct measurement of the torque which the nematic liquid crystal exerts on the surfaces when a magnetic field is applied. The reliability of this technique is tested by measuring the twist elastic constant of the nematic liquid crystal 4-n-pentyl-4'-cyanobiphenyl (5CB). The experimental results are compared with previous measurements performed by other authors Technique basee sur une mesure directe du couple exerce par le directeur sur les surfaces quand le nematique est soumis a un champ magnetique. Application a la mesure de K 22 du pentyl-4 cyano-4' biphenyle
提出了一种测量向列液晶扭弹性常数的新实验方法。该方法是基于直接测量向列液晶在施加磁场时对表面施加的扭矩。通过测定向列液晶4-正戊基-4′-氰联苯(5CB)的扭弹性常数,验证了该方法的可靠性。将实验结果与前人的测量结果进行了比较,技术基础为:定向定向测量耦合实验、定向定向表面实验和向列式测试。k22杜戊基-4 -氰基-4′联苯测定的应用
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引用次数: 17
On the coloration properties of CaF2 : Na CaF2: Na的着色性能研究
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046018086100
J. Tijero, J. Casas-González
We have investigated the dichroic properties and the existence of metastable excited states of several colour centres created by X-irradiation in CaF 2 :Na. According to our results absorption bands peaking at 600, 385 and 322 nm are associated to the same centre which behaves optically as orthorhombic. The lack of observation of a metastable state is in favour of the F 2A + model for this centre. On the other hand the band at 500 nm and another absorption at 322 nm are proved to belong to the same centre which behaves optically as tetragonal. A metastable excited state of this centre with lifetime of 0,83 s at 77 K has been detected. Two possible models are discussed for this centre Etude des proprietes dichroiques et de l'existence d'etats excites metastables de plusieurs centres colores crees par irradiation X
我们研究了在caf2:Na中x射线辐照产生的几个色心的二色性和亚稳态激发态的存在。根据我们的研究结果,在600、385和322 nm处的吸收峰与相同的中心相关联,在光学上表现为正交。缺少亚稳态的观测有利于该中心的f2a +模型。另一方面,证明了500 nm处的吸收带和322 nm处的吸收带属于同一中心,在光学上表现为四方。在77 K时,该中心的亚稳态激发态寿命为0.83 s。讨论了这一中心的两种可能的模型:在X射线辐照下,双色散中心和色散中心激发亚稳态
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引用次数: 8
Fractal structure of the equilibrium crystal shape. II. Fractal dimensions 平衡晶体形状的分形结构。2分形维
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017080500
S. Burkov
A crystal shape at T=0 is studied in the framework of the model of «bricks» attracting each other according to 1/rγ. It is shown that fractal dimensions of the Cantor sets of solitary edges and corners are γ/(γ−2) and 6/(γ−1), respectively Etude de la forme d'un cristal a T=0 dans un modele de briques s'attirant selon une loi en 1/rγ
在根据1/rγ相互吸引的“砖块”模型框架下,研究了T=0时的晶体形状。结果表明,孤边和孤角的Cantor集的分形维数分别为γ/(γ−2)和6/(γ−1),分别为T=0时de la forme d'un晶体的分形维数和1/rγ时的分形维数
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引用次数: 1
Phase diagram of quasi-one-dimensional conductors in strong magnetic field 强磁场下准一维导体的相图
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017083100
M. Héritier, G. Montambaux, P. Lederer
The phase diagram of quasi-1D conductors in magnetic field is derived. We perform a microscopic calculation of the Ginzburg-Landau free energy coefficients. They exhibit a novel behaviour as a function of field. As a result, different regimes of SDW ordering appear with increasing field, corresponding to different types of quantized nesting. This description may account for nearly all the available experimental data in (TMTSF) 2 ClO 4 Calcul microscopique des coefficients de Ginzburg-Landau pour l'energie libre, qui presentent un comportement original en fonction du champ magnetique: en champ croissant, apparition de differents regimes d'ordre d'onde de densite de spin correspondant a differents types de «nesting» quantifie. Explication de presque toutes les donnees experimentales sur (TMTSF) 2 ClO 4
导出了准一维导体在磁场中的相图。我们对金兹堡-朗道自由能系数进行了微观计算。它们表现出一种新的行为,作为场的函数。结果表明,随着场的增加,SDW排序出现了不同的制度,对应于不同类型的量化嵌套。这一描述可以解释(TMTSF) 2 ClO 4中几乎所有可用的实验数据,计算显微镜下的Ginzburg-Landau系数de de energy libre,相当不相容的原始的en函数du champ magnetique: en champ croissant,不同制度的显现,不同类型的嵌套量化对应的顺序,密度和自旋。解释的先决条件下的实验条件(TMTSF) 2 cl4
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引用次数: 28
THERMAL-CONDUCTIVITY AND THERMOELECTRIC-POWER OF UBE13 ube13的导热性和热电性能
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017081100
D. Jaccard, J. Flouquet, Z. Fisk, J. Smith, H. Ott
J. Physique Lett. ler L-811 - L-817 SEPTEMBRE L-811 Classification Physics Abstracts 72.15E - 72.15J - 74.30E Thermal D. conductivity and thermoelectric UBe13 Jaccard, J. Flouquet Centre de Recherches France Z. power of Fisk, sur les Tres Basses Temperatures, CNRS, BP 166 X, 38042 Grenoble Cedex, J. L. Smith Materials Science and NM 87545, U.S.A. Technology Division, Los Alamos National Laboratory, Los Alamos, and H. R. Ott Laboratorium fur Festkorperphysik, CH-8093 Zurich, Switzerland Eidgenossische Technische Hochschule, Honggerberg, (Refu le 8 avril 1985, accepte sous forme definitive le 8 juillet 1985) Des mesures de resistivite, pouvoir thermoelectrique et de conductivite thermique du compose a fermions lourds UBe13 ainsi que leurs relations avec le diagramme de phase temperature- champ critique sont presentees. A basse temperature (T 1 K), le pouvoir thermoelectrique de la phase normale est gigantesque. La conductivite thermique suit une loi en T2 dans la phase supra- conductrice sans contribution lineaire en T contrairement a ce qui est observe dans UPt3. Resume. Measurements of the resistivity, thermoelectric power and thermal conductivity of the heavy fermion compound UBe13 and their relations to the temperature-upper critical field phase diagram are reported. At low temperature (T 1 K), enormous thermoelectric powers are detected in the normal phase. The thermal conductivity obeys a T2 law in the superconducting phase with no supplementary T contribution which is not observed in the other heavy fermion compound UPt3. Abstract 1. Introduction. The discovery of superconductivity in UBe 13 at T~ ~ 0.9 K [1] has revived the debate on the origin of the superconductivity in heavy fermion compounds first found in CeCu2 Si2 [2]. The heavy fermion character of UBel3 is proved by the large value of the ratio of the specific heat C to the temperature T near Tc : Cl T - 1 J/mole/K2 [3]. One of the peculiarities of UBe 13 is that the elec- tron mean free path is extremely short near T~. At 1 K, the electrical resistivity ( p ~ 190 Jl!} cm) [ 1-4] is almost that estimated for the unitary limit; no sign of Fermi liquid behaviour ( p ~ T 2) is detected By contrast with liquid 3 He for which the superfluid transition ( T~ ~ 2 mK) is far below the Fermi temperature TF [5], the definition of TF is not obvious. Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyslet:019850046017081100
J.物理学Lett。L-811 1 - 9月L-817 L-811分类物理学文摘72.15E温泉- 72.15J 74.30E d .电导率与thermoelectric UBe13 j.m Flouquet能源政策研究中心在法国·z (power of Fisk,温度很低,中国科学院、BP、166×38042格勒诺布尔德克斯,j . l . Smith)材料科学与纳米87545,U.S.A.技术司、洛斯阿拉莫斯国家实验室、洛斯阿拉莫斯实验室,and h . r . Ott随着Festkorperphysik CH-8093苏黎世,音色Eidgenossische Technische Hochschule、Honggerberg(1985年4月8日,接受最终的形式本身,1985年7月8日)resistivite措施组成的热、conductivite thermoelectrique权力和关闭了重型UBe13以及他们与临界温度范围-相图是甲烷。在低温(t1 K)下,正相的热电功率是巨大的。与UPt3不同,上导电相的热导率在T2处遵循规律,在T处没有线性贡献。摘要。报告了重费米子化合物UBe13的电阻率、热电功率和导热性的测量及其与温度-上临界场相图的关系。在低温(t1k)下,在正常相中检测到巨大的热电功率。The温泉电导率obeys T2 with no law in The superconducting阶段补充了T贡献which is not in The other heavy观察复合UPt3费米子。文摘:1。引言。at The discovery of superconductivity in UBe 13 ~ 0.9 T K [1] has The debate revived in heavy on The origin of The superconductivity费米子化合物first Si2 CeCu2[2]中找到。UBel3的重费米子特性是由Tc附近的比热C与温度T之比的大值提供的:Cl T - 1 J/mol /K2[3]。= =地理= =根据美国人口普查,这个县的面积为,其中土地面积为。在1k时,电阻率(p ~ 190 Jl!= cm)[1-4]几乎是对单位极限的估计;与液体3 He相比,没有检测到费米液体行为(p ~ t2)的迹象,因为超流体跃迁(T~ ~ 2mk)远低于费米温度TF [5], TF的定义并不明显。这首歌在英国单曲排行榜上排名第二,在英国单曲榜上排名第三,在英国单曲榜上排名第四。
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引用次数: 23
First-order CIC transition induced by Coulomb forces 库仑力引起的一阶CIC跃迁
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017081900
S. Barǐsić, I. Barišić
It is shown that the long range Coulomb interaction between charged solitons is attractive. The transition from the commensurate to the incommensurate state occurs therefore at finite soliton density. Such transition is of the first order. The relevance of those results to real materials is briefly discussed Demonstration d'une interaction coulombienne attractive entre solitons charges, ce qui entraine une transformation commensurable→incommensurable du 1er ordre pour une densite de solitons finie
结果表明,带电孤子之间的远距离库仑相互作用是有吸引力的。因此,从相称态到不相称态的跃迁发生在有限孤子密度下。这种转变是一级的。简要地讨论了这些结果与实际材料的相关性,证明了d'une相互作用,库仑比吸引中心孤子电荷,即单变换可公度→不可公度,单密度孤子有限
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引用次数: 5
Parisi function q(x) for spin glasses near Tc Tc附近自旋玻璃的Parisi函数q(x)
Pub Date : 1985-09-01 DOI: 10.1051/JPHYSLET:019850046017077900
H. Sommers
We compute the orderparameter function q(x) for the Sherrington-Kirkpatrick spin-glass to high accuracy near T=T c in zero external field. The free energy is calculated to order (T c −T) 7 . The overlap function dx/dq is parabolic near q=0. We show generally that q(x) involves only odd powers of x below its plateau. Hence the overlap distribution in strictly zero fields is symmetric with continuous derivatives at q=0 Calcul de la fonction parametre d'ordre q(x) pour un verre de spin de Sherrington-Kirkpatrick en champ nul pres de T c , l'energie libre etant developpee jusqu'a l'ordre (T c -T 7 ): la fonction de recouvrement dx/dq est parabolique au voisinage de q=0, et q(x) ne contient que des puissances impaires de x au-dessous de la region du plateau
在零外场条件下,我们计算了Sherrington-Kirkpatrick自旋玻璃在T= t1附近的有序参数函数q(x),得到了高精度。自由能按(tc−T) 7阶计算。重叠函数dx/dq在q=0附近呈抛物线形。一般来说,我们证明q(x)只涉及x在平台以下的奇次幂。因此,严格零场的重叠分布是对称的,在q=0处有连续导数。计算函数参数d' orderre q(x) pour unverre de spin de Sherrington-Kirkpatrick en champ nupres de T c, l'能量自由事件发展' jusque ' l' orderre (T c -T 7):函数恢复dx/dq est抛物线在视场中q=0, et q(x) ne大陆,de puisances impaires de x -de desdesous de la region du plateau
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引用次数: 29
期刊
Journal De Physique Lettres
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