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Advancing high resolution photolithography with hybrid polymers for wafer-scale manufacture of micro-optics and patterned passivation layers 利用杂化聚合物推进高分辨率光刻技术,用于微光学和图案钝化层的晶圆级制造
Pub Date : 2023-05-01 DOI: 10.1117/12.2658408
M. Koch, M. Russew, Ludwig Scharfenberg, A. Benker, A. Schleunitz, G. Grützner
Hybrid Polymers are a material class established in the industry for manufacturing of high-performance optical components, mainly patterned by (nano)imprint processes. Recently, the application range of Hybrid Polymers has been extended into bonding and passivation. In this context, patterning by classical UV-lithography has come into focus as an alternative patterning method to (nano)imprinting. By applying a two-stage curing process with a high intensity, low dose patterning step and a high dose flood exposure after development, it is possible to realize previously unattainable resolutions limits for Hybrid Polymers of 6μm L/S and aspect ratios of more than 3.
杂化聚合物是一种用于制造高性能光学元件的材料,主要由(纳米)压印工艺制成。近年来,杂化聚合物的应用范围已扩展到粘接和钝化。在这种情况下,经典紫外光刻的图案化已经成为焦点,作为(纳米)压印的替代图案化方法。通过采用高强度、低剂量图像化步骤和显影后高剂量洪水暴露的两阶段固化工艺,可以实现以前无法实现的6μm L/S和大于3长宽比的杂化聚合物的分辨率限制。
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引用次数: 0
E-beam direct write lithography: the versatile ally of optical lithography 电子束直写光刻:光学光刻的通用技术
Pub Date : 2023-05-01 DOI: 10.1117/12.2658273
F. Laulagnet, Jacques-Alexandre Dallery, L. Pain, M. May, Béatrice Hémard, Franck Garlet, I. Servin, C. Sabbione
Electron Beam Direct Write (EBDW or E-Beam) Lithography is a worldwide reference technology used in laboratories, universities and pilot line facilities for Research and Developments. Due to its low writing speed, E-Beam direct write has never been recognized as an acceptable industrial solution, exception made for optical mask manufacturing. Nevertheless, its natural high-resolution capability allows low-cost patterning of advanced or innovative devices ahead of their high-volume manufacturing ramp-up. Thanks to its full versatility with almost all type of chemically amplified resists, EBDW is a perfect complementary solution to optical lithography. This paper demonstrates the compatibility of EBDW lithography with advanced Negative Tone Development (NTD) resist and the possibility to set-up an hybrid E-Beam/193i lithography process flow with high performances in terms of resolution and mix & match overlay. This high-end lithography strategy alliance offers flexibility and cost advantages for device development R&D but also powerful possibilities for specific applications such circuit encryption as discussed at the end of this work-study.
电子束直写(EBDW或电子束)光刻是世界范围内用于实验室,大学和试验线设施的研究和开发的参考技术。由于其低写入速度,E-Beam直接写入从未被认为是一种可接受的工业解决方案,光学掩模制造除外。尽管如此,其天然的高分辨率能力使得先进或创新设备的低成本模式在大批量生产之前得以实现。由于其具有几乎所有类型的化学放大抗蚀剂的通用性,EBDW是光学光刻的完美补充解决方案。本文演示了EBDW光刻与先进的负色调显影(NTD)抗蚀剂的兼容性,以及建立在分辨率和混合匹配覆盖方面具有高性能的电子束/193i混合光刻工艺流程的可能性。这种高端光刻战略联盟为设备开发研发提供了灵活性和成本优势,同时也为电路加密等特定应用提供了强大的可能性。
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引用次数: 0
A novel formulated developer for negative-tone imaging with EUV exposure to improve chemical stochastic 一种新型配方显影剂,用于EUV曝光的负色调成像,以改善化学随机性
Pub Date : 2023-05-01 DOI: 10.1117/12.2657421
Keiyu Ou, Naohiro Tango, Nishiki Fujimaki, Kazuhiro Marumo, Nobuhiro Hiura, Satomi Takahashi, Toru Fujimori
In 2019, finally, extreme ultraviolet (EUV) lithography has been applied to high volume manufacturing (HVM). However, the performance of EUV resist materials are still not enough for the expected HVM requirements, even by using the latest qualifying EUV resist materials. The critical issues are the stochastic issues, which will become ‘defectivity’. The analyzing summary of the stochastic factors in EUV lithography was reported, which described 2 (two) major stochastic issues, which are ‘Photon stochastic’ and ‘Chemical stochastic’. In the past, speaking of the stochastic issue was basically considered from low photon number from EUV light source, which means ‘photon shot noise’. It was still critical concerning point, even with recent progress on source power improvement. However, the stochastic issue is not only from them but also from EUV materials and processes, called ‘Chemical stochastic’. The ‘Chemical stochastic’ means caused from resist materials and processes for lithography, materials uniformity in the film, reactive uniformity in the film, and dissolving behavior with the developer. In this paper, we will focus on ‘Chemical stochastic’ improvement, especially, the dissolving behavior by using negative-tone imaging (NTI, using organic solvent-based developer) with EUV exposure (EUV-NTI). EUV-NTI had a potential for improving ‘Chemical stochastic’ because of their properties, which were low swelling and smooth dissolving behavior. However, the pattern collapse was easily observed for preparing fine patterns with the standard developer. Newly proposed novel formulated organic solvent-based developer will be expected to improve the patter collapse issue and ‘Chemical stochastic’. Lithographic performance will also be reported.
2019年,极紫外(EUV)光刻技术终于应用于大批量制造(HVM)。然而,即使使用最新的合格EUV抗材料,EUV抗材料的性能仍然不足以满足预期的HVM要求。关键问题是随机问题,这将成为“缺陷”。摘要对极紫外光刻中的随机因素进行了分析总结,描述了“光子随机”和“化学随机”两大随机问题。在过去,谈论随机问题基本上是从极紫外光源的低光子数出发,即“光子散粒噪声”。尽管最近在电源改进方面取得了进展,但这仍然是一个关键的问题。然而,随机问题不仅来自它们,还来自EUV材料和工艺,称为“化学随机”。“化学随机”是指光刻的抗蚀剂材料和工艺、胶片中的材料均匀性、胶片中的反应均匀性以及与显影剂的溶解行为造成的。在本文中,我们将重点关注“化学随机”改进,特别是通过使用EUV曝光(EUV-NTI)的负色调成像(NTI,使用有机溶剂基显影剂)的溶解行为。EUV-NTI具有低溶胀和平滑溶解的特性,具有改善“化学随机”的潜力。然而,在使用标准开发人员准备精细模式时,很容易观察到模式崩溃。新提出的新配方有机溶剂型显影剂有望改善模式崩溃问题和“化学随机”。光刻性能也将报告。
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引用次数: 1
Enabling process technologies for advanced logic devices beyond FinFET era 为超越FinFET时代的先进逻辑器件提供工艺技术
Pub Date : 2023-05-01 DOI: 10.1117/12.2660290
Tomonari Yamamoto
This invited talk describes the enabling process technologies for advanced logic devices beyond FinFET era. Gate-all-around (GAA) improves electrostatics over FinFET and enables continuous gate length scaling. Complementary FET (CFET), which is a structure of stacked transistors, is a next candidate architecture for the continuous cell height scaling enablement. Interconnect pitch scaling will also play crucial role for it and go with RC reduction knobs such as Cu damascene extension, post Cu and airgap. For better area usage and performance enhancement, backside power delivery network (PDN) is an attractive option. For these enablement, continuous process and tool advancement is necessary not only on film, etch, lithography and wet, but also on wafer bonding and thinning technologies. We will also review our recent progress in EUV related solutions including self-aligned patterning.
本次特邀演讲介绍了超越FinFET时代的先进逻辑器件的使能工艺技术。栅极全能(GAA)改善了FinFET的静电性能,并实现了连续栅极长度缩放。互补场效应管(互补场效应管)是一种堆叠晶体管结构,是实现连续单元高度缩放的下一个候选结构。互连间距缩放也将发挥至关重要的作用,并与RC减少旋钮,如Cu damascene扩展,后Cu和气隙。为了更好的区域使用和性能增强,后端电力输送网络(PDN)是一个有吸引力的选择。为了实现这些目标,不仅在薄膜、蚀刻、光刻和湿法上,而且在晶圆键合和减薄技术上,都需要持续的工艺和工具进步。我们还将回顾我们在EUV相关解决方案方面的最新进展,包括自对准模式。
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引用次数: 1
Ultra-thick positive photoresist layers for maskless grayscale lithography 用于无掩模灰度光刻的超厚正光刻胶层
Pub Date : 2023-05-01 DOI: 10.1117/12.2658355
Dominique Collé, G. Ekindorf
Maskless grayscale lithography is a key technology to create structured surfaces in photoresist, especially for micro-optic applications. It uses spatially modulated light intensity to expose a layer of low-contrast positive resist. A digital design that contains gray values or height information, corresponding to a certain target depth in the photoresist, can conveniently be exposed with a DWL 66+ from Heidelberg Instruments. Processes are well known for thicknesses up to 60 μm. The possibility to fabricate taller structures, are of great interest in the micro-fabrication world. Two experimental and one commercial resists have been compared to reach and exceed the 100 μm symbolic height. After a validating experiment in a single coated layer of an experimental DNQ-based photoresist, we doubled and tripled the coating cycles at relatively low velocity and quickly obtained promising results. The triple-coated film while enabling the possibility to fabricate structures 100 μm high showed some sort of delamination in the deepest region of the layer, close to the substrate’s surface. The delamination indicates the formation of N2 bubbles, a disadvantage of DNQ-based photoresists that release nitrogen when exposed to light. Experiments with a commercially available resist seems to show similar behavior for thicknesses above 80 μm. Recent experiments using a second experimental resist, from a different supplier, showed some promising results: structures slightly higher than 100 μm without visible defect caused by nitrogen have been fabricated. Another advantage is that overall dose required to reach this depth was significantly lower than in the previous test.
无掩模灰度光刻技术是在光刻胶中创建结构表面的关键技术,特别是在微光学应用中。它使用空间调制光强度来暴露一层低对比度的正抗蚀剂。包含灰度值或高度信息的数字设计,对应于光刻胶中的某个目标深度,可以方便地使用海德堡仪器的DWL 66+进行曝光。众所周知,厚度可达60 μm。制造更高结构的可能性,在微加工领域引起了极大的兴趣。对比了两种实验电阻和一种商用电阻达到和超过100 μm的符号高度。在实验用dnq基光刻胶的单层涂层上进行验证实验后,我们以相对较低的速度将涂层周期增加了一倍和三倍,并迅速获得了有希望的结果。三层涂层薄膜虽然可以制造100 μm高的结构,但在靠近衬底表面的层的最深处出现了某种分层。分层表明N2气泡的形成,这是dnq基光阻剂暴露在光线下释放氮气的缺点。用市售抗蚀剂进行的实验表明,对于厚度大于80 μm的抗蚀剂,也表现出类似的性能。最近使用来自不同供应商的第二种实验抗蚀剂进行的实验显示了一些有希望的结果:已经制造出略高于100 μm的结构,并且没有由氮引起的明显缺陷。另一个优点是达到这个深度所需的总剂量明显低于以前的试验。
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引用次数: 0
Profile control in conductor metal wet etch with advanced photoresists 先进光刻胶在导体金属湿式蚀刻中的轮廓控制
Pub Date : 2023-05-01 DOI: 10.1117/12.2657687
Ashley Moore, Julia Modl, Zhong Li, Hung-Yang Chen, Chunwei Chen, A. Behrendt, Katharina Schmoelzer
Despite their long history in the electronics industry, copper metal layers remain important components as interconnection layers in IC fabrication due to their higher thermal and electrical conductivity as well as their higher electromigration resistance. Structuring the copper metal layer via wet chemical etching places demands on the photoresist mask, requiring resistance to harsh etch chemistry and good adhesion to the substrate to prevent delamination and defects. The photoresist formulation AZ® TD-2010 is a positive-tone, DNQ-based i-line photoresist that incorporates an additional surface-grafting component to deliver improved etch performance via enhanced photoresist adhesion on metal substrates. The in-situ priming of the photoresist formulation during the patterning process leads to a greater interfacial adhesion, resulting in steep sidewalls, with a greater than 20° increase in etch angle over formulations without adhesion promoter, while maintaining undercut depth and Cu CD. The AZ®TD-2010 photoresist can also be used at high thickness to cover topography steps formed from underlying layers, while also exhibiting high enough photospeed to maintain production throughput standards for IC manufacturing.
尽管铜金属层在电子工业中有着悠久的历史,但由于其更高的导热性和导电性以及更高的电迁移电阻,它仍然是集成电路制造中作为互连层的重要组成部分。通过湿式化学蚀刻构造铜金属层对光刻胶掩膜提出了要求,要求耐苛刻的蚀刻化学反应,并与衬底具有良好的附着力,以防止分层和缺陷。光刻胶配方AZ®TD-2010是一种正色调,基于dnq的i线光刻胶,包含额外的表面接枝组件,通过增强光刻胶在金属基板上的附着力来改善蚀刻性能。在图画化过程中,光阻剂配方的现场注入导致更大的界面附着力,导致陡峭的边壁,与没有附着力促进剂的配方相比,蚀刻角度增加了20°以上,同时保持了凹痕深度和Cu CD。AZ®TD-2010光阻剂也可以在高厚度下使用,以覆盖由底层形成的地形台阶。同时也表现出足够高的光电速度,以保持集成电路制造的生产吞吐量标准。
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引用次数: 0
Realization of high-Q Lamb wave resonator with smooth vertical etching profile for thin film lithium niobate 铌酸锂薄膜光滑垂直刻蚀轮廓的高q Lamb波谐振器的实现
Pub Date : 2023-05-01 DOI: 10.1117/12.2665860
A. Aryal, Ravi Kiran Chityala, I. Stricklin, Sidhant Tiwari, A. Siddiqui, T. Busani
In this work, Lamb Wave Resonators (LWRs) based on 2 μm thin Y-cut LiNbO3 films have been fabricated using integrated fabrication process that defines IDTs (Inter Digital Transducers) on top surface and a partial Si cavity for a sacrificial layer on the bottom surface. We discuss the etch quality and its effects on the device's performance. For the first time, we present an optimized high-quality etched MEMS (Micro-electromechanical Systems) Resonator with smooth and vertical sidewalls on this material system, reporting the maximum Q-factor of 2500 at 846 MHz frequency. We observed that the resonator system has a Q-factor of 480 over the same frequency range when the etched surface has significant roughness and non-verticality. Q values of the device are greatly diminished by the presence of surface roughness and non-verticality of the etched edges. This truly highlights how important it is to have a high-quality etch profile for a piezoelectric material system like this so that the designed resonators can perform at their best.
在这项工作中,基于2 μm薄y型切割LiNbO3薄膜的Lamb波谐振器(LWRs)已经使用集成制造工艺制造,该工艺在表面上定义了IDTs(数字间换能器),并在底部表面定义了用于牺牲层的部分Si腔。讨论了蚀刻质量及其对器件性能的影响。我们首次在这种材料系统上提出了一种优化的高质量蚀刻MEMS(微机电系统)谐振器,具有光滑和垂直的侧壁,在846 MHz频率下的最大q因子为2500。我们观察到,当蚀刻表面具有显著的粗糙度和非垂直性时,谐振器系统在相同频率范围内的q因子为480。由于存在表面粗糙度和蚀刻边缘的非垂直性,器件的Q值大大降低。这确实突出了为这样的压电材料系统提供高质量的蚀刻轮廓是多么重要,这样设计的谐振器才能发挥其最佳性能。
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引用次数: 1
Middle-of-line plasma dry etch challenges for CFET integration 中线等离子体干蚀刻对CFET集成的挑战
Pub Date : 2023-05-01 DOI: 10.1117/12.2659095
D. Radisic, M. Hosseini, H. Mertens, D. Zhou, V. Vega Gonzalez, S. Wang, B. Chan, D. Batuk, E. Dupuy, Z. Tao, E. Dentoni Litta, N. Horiguchi
In this paper, middle-of-line (MOL) plasma etch development results for the monolithic CFET integration with nanosheet devices using scaling-relevant test vehicle (CPP48nm) are presented. Several critical MOL patterning steps are addressed, with the focus on the patterning of the trenches (M0) for contacting to the bottom and top devices. The patterning of M0A consists of SiO2 dielectric and thin SiN liner etch landing on epitaxial source drain (S/D). The critical M0 etch requirement is preserving the SiN gate spacer to avoid shorting between S/D and gate. Due to no-gate plug implementation in the process flow, the etch development must rely on very challenging, patterning the small critical dimension (CD) contacts to create enough dielectric barrier between the metal contact and the gate, and preferably, also very challenging, self-alignment to the thin gate spacer. The dependance of the M0 CD and the etch depth is accessed by using the range of the EUV lithography conditions and evaluating the maximum etch depth of the trench as a function of the printed CD. The minimum trench CD achieved on the bottom of the trench is ~ 13nm, and the minimum top CD in the range of ~ 16nm, with the evident etch non-uniformity observed in the etch depth. The trend of larger contact CD resulting in the deeper etch and process uniformity improvement is observed. Etch depth larger than 100nm is achieved when top M0 CD is >20nm. The option with the SiN liner deposition followed by SiN liner etch (spacer formation) post- M0 SiO2 is developed. This patterning sequence consists of SiO2 etch stopping on the thin SiN (over S/D) followed by additional SiN deposition and finally etching of the deposited SiN liner as well as SiN liner covering S/D. The option with SiN spacer formation minimizes the risk of short to the gate, due to extra SiN dielectric film protecting the gate. In addition, we present the results for another critical MOL patterning step, i.e., HAR metal recess post M0 metallization (AR~11)
本文介绍了采用与缩放相关的测试载体(CPP48nm)进行单片cefet与纳米片器件集成的中线等离子体刻蚀的开发结果。解决了几个关键的MOL图像化步骤,重点是与底部和顶部器件接触的沟槽(M0)的图像化。在外延源漏极(S/D)上,M0A的图形由SiO2介电层和薄薄的SiN衬里蚀刻层组成。关键的M0蚀刻要求是保留SiN栅极间隔,以避免S/D和栅极之间的短路。由于在工艺流程中实现了无栅塞,因此蚀刻开发必须依赖于非常具有挑战性的小临界尺寸(CD)触点图案,以在金属触点和栅极之间创建足够的介电屏障,并且最好也是非常具有挑战性的是,自对准薄栅极垫片。利用EUV光刻条件的范围,对刻蚀深度的最大刻蚀深度作为刻蚀深度的函数进行了评估,得到了M0刻蚀深度与刻蚀深度的依赖关系。在刻蚀深度范围内,刻蚀深度在~ 13nm和~ 16nm范围内达到了最小刻蚀深度。观察到接触面CD增大的趋势导致更深的蚀刻和工艺均匀性的改善。当最上层M0 CD为bb0 ~ 20nm时,可实现大于100nm的刻蚀深度。开发了在M0 SiO2后进行SiN衬垫沉积,然后进行SiN衬垫蚀刻(间隔层形成)的选择。这个图案序列包括SiO2蚀刻停止在薄SiN上(超过S/D),然后是额外的SiN沉积,最后蚀刻沉积的SiN衬里以及覆盖S/D的SiN衬里。由于额外的SiN介电膜保护栅极,带有SiN间隔层形成的选项最大限度地降低了栅极短路的风险。此外,我们还介绍了另一个关键的MOL图图化步骤,即M0金属化后HAR金属凹槽(AR~11)的结果。
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引用次数: 0
Overlay performances of wafer scale nanoimprint lithography 晶片级纳米压印光刻的覆盖性能
Pub Date : 2023-05-01 DOI: 10.1117/12.2655105
J. Reche, Api Warsono, Anaïs De Lehelle D'Affroux, Jonas Khan, S. Haumann, A. Kneidinger
Since its beginning in the 90’s NanoImprint Lithography (NIL) has been continuously improved to target the different industry requirements. Using an intermediate soft stamp media was one of the main improvements and has now become a standard technology. Based on that technology, EVG introduces a full wafer imprinting solution, whereas the size of the stamp corresponds to the size of the wafer to imprint. Results obtained at CEA-Leti using this solution, with respect to uniformity, sub-50nm resolution, repeatability, and high aspect ratio patterns, are today state of the art and allow NIL to be considered as an HVM technology. Nevertheless, further development is carried out on different aspects such as overlay (OVL) which is the scope of this work. Different contributors of OVL as translation, rotation but also distortion are dissociated and analyzed. Alignment repeatability is studied. Additionally, imprint to imprint OVL correction terms are applied. A dedicated methodology has been established and allows to obtain global OVL signature. According to the above, main process contributors are highlighted and studied in the paper to separate influence of each of them. Finally, different ways to improve overlay are discussed and some of them - which could be linked to hardware, process or both - are evaluated. Overall, the OVL status obtained and first improvements bring NIL technology closer to the alignment requirements of the industry.
自90年代开始,纳米压印光刻(NIL)一直在不断改进,以满足不同行业的需求。使用中间软压印介质是主要的改进之一,现在已经成为一种标准技术。基于该技术,EVG引入了一个完整的晶圆压印解决方案,而印章的尺寸对应于要压印的晶圆的尺寸。在CEA-Leti使用该解决方案获得的结果,在均匀性、低于50nm的分辨率、可重复性和高纵横比模式方面,是当今最先进的技术,允许NIL被认为是一种HVM技术。然而,在不同方面进行了进一步的开发,例如覆盖(OVL),这是本工作的范围。分析了OVL的不同影响因素,如平移、旋转和畸变。研究了对准的可重复性。此外,还应用了印对印OVL校正项。一个专门的方法已经建立,并允许获得全局OVL签名。据此,本文对主要的工艺因素进行了突出和研究,分离出各自的影响。最后,讨论了改善覆盖的不同方法,并对其中一些方法进行了评估,这些方法可以与硬件、工艺或两者相关联。总体而言,获得的OVL状态和首次改进使NIL技术更接近行业的对准要求。
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引用次数: 0
Understanding etch properties of advanced chemically amplified EUV resist 了解先进化学放大EUV抗蚀剂的蚀刻性能
Pub Date : 2023-05-01 DOI: 10.1117/12.2659178
J. Park, E. Aqad, Yinjie Cen, S. Coley, Li Cui, Conner A. Hoelzel, Benjamin Naab, Choong-Bong Lee, Rochelle Rena, Philjae Kang, Y. Shin, David Limberg, Lei Zhang
Extreme ultraviolet (EUV) lithography technology empowers integrated circuit industry to mass produce chips with smaller pitches and higher density. Along with EUV tool advancement, significant progress has also been made in the development and advancement of EUV chemically amplified resist (CAR) materials, which allows for the improvement of resolution, line edge roughness, and sensitivity (RLS) trade-off. The scarce number of EUV photons has triggered the development of resist material with high absorption at 13.5 nm. However, a review of open literature reveals very limited reports on the effect of high EUV absorption elements on etch properties of advanced EUV resist. To ensure Moore’s Law continues to move forward, further resist performance improvement is required. In this regard, stochastic defects originating from photon shot noise, materials, and processing variabilities present a unique challenge for the extension of CAR platform for the patterning of smaller nodes. Notably, less attention has been paid to defects formed during the etching process used for pattern transfer. In this paper, we report on the relationship between resist make-up and etch properties. In particular, the effect of incorporation of EUV high absorbing elements are examined. New resist material design strategies for continuous improvement of EUV CAR lithographic performance will be discussed.
极紫外(EUV)光刻技术使集成电路工业能够批量生产具有更小间距和更高密度的芯片。随着EUV工具的进步,EUV化学放大抗蚀剂(CAR)材料的开发和进步也取得了重大进展,这使得分辨率、线边缘粗糙度和灵敏度(RLS)的权衡得到了改善。由于极紫外光光子的稀少,在13.5 nm处具有高吸收率的抗蚀剂材料得到了发展。然而,对公开文献的回顾显示,关于高EUV吸收元素对高级EUV抗蚀剂腐蚀性能影响的报道非常有限。为了确保摩尔定律继续向前发展,需要进一步改进抗蚀性能。在这方面,由光子噪声、材料和加工变化引起的随机缺陷对CAR平台的扩展提出了独特的挑战,以实现较小节点的图案化。值得注意的是,很少注意到在蚀刻过程中形成的缺陷用于图案转移。本文报道了抗蚀剂补色与蚀刻性能之间的关系。特别考察了加入EUV高吸收元素的影响。本文将讨论持续改善EUV CAR光刻性能的新型抗蚀剂设计策略。
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引用次数: 0
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Advanced Lithography
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