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Effect of TiO2 nanostructure's shape on the DSSCs performance TiO2纳米结构形状对DSSCs性能的影响
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706576
Siti Khatijah Md Saad, A. Umar, S. Nafisah, M. Salleh, B. Majlis
The effect of morphology of anatase TiO2 nanoparticles as photoanode in dye sensitized solar cells (DSSCs) has been investigated. Two types of TiO2 nanostructures, namely nanograss and nanospherical particles, used in this study have been prepared via liquid phase deposition (LPD) method. Electrochemical impedance spectroscopy (EIS) analysis of DSSCs device with a sandwich structure of ITO/TiO2/dye/electrolyte/ Pt film indicated that the device utilizing TiO2 nanograss exhibited the lower in charge transfer resistance (Rct), of 49.1 Ω. This might be due to the high-porous characteristic of TiO2 nanograss compared to the nanospherical particles that provides facile charge transport and ion diffusion. Power conversion efficiency as high as 0.97% has been recorded from the device utilizing nanograss of TiO2, which was 3 times higher compared to TiO2 nanospherical particles of which its conversion efficiency was only 0.33%.
研究了锐钛矿型TiO2纳米颗粒形态对染料敏化太阳能电池(DSSCs)光阳极性能的影响。本研究采用液相沉积(LPD)法制备了两种类型的TiO2纳米结构,即纳米草和纳米球形颗粒。电化学阻抗谱(EIS)分析表明,ITO/TiO2/染料/电解质/ Pt薄膜夹层结构的DSSCs器件具有较低的电荷转移电阻(Rct),为49.1 Ω。这可能是由于与纳米球形粒子相比,TiO2纳米草的高多孔性提供了方便的电荷传输和离子扩散。利用TiO2纳米草的器件的功率转换效率高达0.97%,是TiO2纳米球形颗粒的3倍,其转换效率仅为0.33%。
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引用次数: 8
Centered-gap and aligned-gap multiple split ring resonator for bio-sensing application 用于生物传感的中心间隙和对准间隙多裂环谐振器
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706473
I. M. Rusni, A. Ismail, A. Alhawari, M. Hamidon, N. Yusof, M. Isa
In general, a classical Split Ring Resonator (SRR) structure exhibits high Q-factor based on deeper and sharper transmission dips at resonance as well as produce high electric field density at the gaps. It is believed, by introducing more gaps, a strong and localized E-field will be obtained in the area between the split gaps. Based on these features, three types of rectangular multiple Split Ring Resonators (SRRs) were proposed to resonate in the frequency range of 3-7 GHz and simulated using Computer Simulation Technology (CST) Microwave Studio to determine the transmission characteristics and the resonance frequency. A Nicolson-Ross-Weir (NRW) technique is used to retrieve the effective parameters from the resultant S-parameter. It is shown that the resonance frequency of investigated structures falls in a frequency region in which the real part of permeability is negative. Later, the simulated results were investigated and the performances as well as the size of each unit cell itself were compared. Simulation for three different type of dielectric samples were also presented to demonstrate that the proposed structure may be well suited for bio-sensing.
一般来说,经典的劈裂环谐振器(SRR)结构在共振时具有更高的q因子,并且在间隙处产生高的电场密度。相信通过引入更多的间隙,在分裂的间隙之间的区域会得到一个强的局域电场。基于这些特点,提出了三种矩形多裂环谐振器(SRRs),在3-7 GHz频率范围内谐振,并利用CST微波工作室对其进行了仿真,确定了其传输特性和谐振频率。采用Nicolson-Ross-Weir (NRW)技术从生成的s参数中检索有效参数。结果表明,所研究结构的共振频率落在磁导率实部为负的频率区域内。随后,对模拟结果进行了研究,并对各单元胞本身的大小和性能进行了比较。对三种不同类型的电介质样品进行了模拟,以证明所提出的结构可能非常适合生物传感。
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引用次数: 4
Humidity sensor based on SnO2 nanoparticle thin film synthesized by thermal chemical vapor deposition (CVD) 基于热化学气相沉积(CVD)合成SnO2纳米颗粒薄膜的湿度传感器
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706530
N. D. Md Sin, A. Shafura, M. H. Mamat, A. Mohamad, M. Rusop
SnO2 nanoparticle thin film has been synthesized by using thermal chemical vapor deposition (CVD). The SnO2 nanoparticle were growth on Au catalyst at different substrate temperature (400~550oC). The surface morphology of were characterized using field emission scanning electron microscopy (FESEM). The sensing properties of SnO2 nanoparticle thin film were examined using two point probe current-voltage (I-V) measurement (Keithley 2400). Heavily distribution of SnO2 nanoparticle thin film at 450°C that reveal from the FESEM image. The higher sensitivity of SnO2 nanoparticle thin film was performed good at 450°C compare to others samples with 45 ratio. The response and recovery of SnO2 nanoparticle thin film were 485 s and 24s respectively.
采用热化学气相沉积(CVD)法制备了SnO2纳米颗粒薄膜。在不同的衬底温度(400~550℃)下,在Au催化剂上生长SnO2纳米颗粒。采用场发射扫描电镜(FESEM)对其表面形貌进行了表征。采用两点探头电流-电压(I-V)测量仪(Keithley 2400)检测了SnO2纳米颗粒薄膜的传感性能。从FESEM图像可以看出,在450°C时,SnO2纳米颗粒薄膜大量分布。纳米SnO2薄膜在450°C温度下的灵敏度比其他样品高45倍。SnO2纳米颗粒薄膜的响应时间和回收率分别为485 s和24s。
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引用次数: 1
Design and analysis of a low-voltage electrostatic actuated RF CMOS-MEMS switch 低压静电驱动射频CMOS-MEMS开关的设计与分析
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706468
M. Ya, A. Nordin, N. Soin
This paper presents the design and analysis of a radio frequency (RF) micro-electromechanical system (MEMS) switch with low actuation voltage using MIMOS 0.35μm complementary metal oxide semiconductor (CMOS) process. The advantage of this RF MEMS switch is very low actuation voltage design which is compatible with other CMOS circuit without employing a separate on-chip voltage source or charge pump unit. Moreover, using CMOS technology to design can highly simplify the fabrication process, reduce the cost and improve the device performance. The RF MEMS switch is a capacitive shunt-connection type device which uses four folded beams to support a big membrane above the signal transmission line. The pull-in voltage, von Mises stress distribution and vertical displacement of the membrane, up-state and down-state capacitances, as well as the switch impedance is calculated and analyzed by finite element modelling (FEM) simulation.
介绍了一种基于0.35μm互补金属氧化物半导体(CMOS)工艺的低驱动电压射频(RF)微机电系统(MEMS)开关的设计与分析。这种射频MEMS开关的优点是非常低的驱动电压设计,与其他CMOS电路兼容,而无需使用单独的片上电压源或电荷泵单元。此外,利用CMOS技术进行设计,可以大大简化制造工艺,降低成本,提高器件性能。RF MEMS开关是一种电容式并联连接装置,它使用四个折叠梁来支撑信号传输线上方的大膜。通过有限元模拟计算和分析了膜的拉入电压、von Mises应力分布和垂直位移、上、下状态电容以及开关阻抗。
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引用次数: 13
Single and dual strained channel analysis of vertical strained — SiGe impact ionization MOSFET (VESIMOS) 垂直应变- SiGe冲击电离MOSFET (VESIMOS)的单、双应变通道分析
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706540
I. Saad, C. B. Seng, H. M. Zuhir, B. Nurmin, A. M. Khairul, B. Ghosh, R. Ismail, U. Hashim
Single Channel (SC) and Dual Channel (DC) Vertical Strained-SiGe Impact Ionization MOSFET (VESIMOS) has been successfully simulated and analyzed in this paper. Found out that SC VESIMOS operate in conventional MOSFET mode at VDS = 1.75V, with 10% to 30% Ge mole fraction. However for Ge=50%, it's operated in Impact Ionization (II) mode with fast switching speed of subthreshold value, S=9.8 mV/dec. A better performance in threshold voltage, VTH, S value and ION/IOFF ratio were found in DC VESIMOS as compared to SC VESIMOS. The VTH=0.6V, S=10.98 mV/dec and ION/IOFF = 1×1013 were measured in DC VESIMOS with Ge=30% that clarify the advantage of DC utilization on VESIMOS device. These improvements were mainly due to the enhancement of electron mobility from 600 m2/V-s (first channel) to 1400 m2/V-s (second channel). The electron mobility was increased due to the splitting of conduction band valley into six fold where the electron mass are reduced in out of plane direction and thus enhanced the mobility of electron.
本文对单通道(SC)和双通道(DC)垂直应变sige冲击电离MOSFET (VESIMOS)进行了成功的仿真和分析。发现SC VESIMOS在VDS = 1.75V时工作在传统MOSFET模式下,Ge摩尔分数为10% ~ 30%。而当Ge=50%时,则工作在冲击电离(II)模式,开关速度快,亚阈值S=9.8 mV/dec。与SC VESIMOS相比,DC VESIMOS在阈值电压、VTH、S值和ION/IOFF比方面具有更好的性能。在Ge=30%的直流VESIMOS中,VTH=0.6V, S=10.98 mV/dec, ION/IOFF = 1×1013,说明了在VESIMOS器件上利用直流的优势。这些改进主要是由于电子迁移率从600 m2/V-s(第一通道)提高到1400 m2/V-s(第二通道)。由于导带谷分裂为6倍,电子的质量在非平面方向上减少,从而提高了电子的迁移率。
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引用次数: 6
Frequency dependence of quality factor in vibration energy harvesting 振动能量收集中质量因子的频率依赖性
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706495
K. Ashraf, M. H. M. Md Khir, J. Dennis, Z. Baharudin
With the fast development in the ubiquitous computing and wireless sensing technologies, a new era of smart cities is evolving. Future smart cities will gather sensory data, needed for effective management of the city, using wireless sensor networks. Exhaustive power sources such as batteries need periodic replacement and hence increase the cost of ownership of wireless sensor network. On the other hand, renewable vibration energy is found in abundance in many target environments of wireless sensor network, which can be harvested to power up the sensor node. The average power of a vibration energy harvester strongly depends on the frequency of vibration and quality factor of the harvester. Unfortunately, most of the environmental vibrations occur in a low frequency range of few tens of Hz. This paper analytically investigates the challenges in designing a low frequency energy harvester with a high quality factor.
随着普适计算和无线传感技术的快速发展,智慧城市的新时代正在到来。未来的智慧城市将利用无线传感器网络收集有效管理城市所需的传感数据。电池等耗尽电源需要定期更换,因此增加了无线传感器网络的拥有成本。另一方面,在无线传感器网络的许多目标环境中存在着丰富的可再生振动能量,这些能量可以被收集起来为传感器节点供电。振动能量采集器的平均功率很大程度上取决于采集器的振动频率和质量因数。不幸的是,大多数环境振动发生在几十赫兹的低频范围内。本文分析了设计高品质因数的低频能量采集器所面临的挑战。
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引用次数: 2
Effect of channel width-to-length ratio on isothermal point of MOSFET-ISFET structure 沟道宽度与长度比对MOSFET-ISFET结构等温点的影响
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706490
Nurul Izzati Mohammad Noh, K. A. Yusof, M. Zolkapli, A. Abdullah, W. Abdullah, S. H. Herman
The effect of channel width-to-length (W/L) ratio on MOSFET-ISFET structures was investigated from simulation and experimental approach. A metal-oxide-semiconductor field-effect-transistor (MOSFET) has been adopted to investigate the isothermal point of an ion-sensitive FET (ISFET), which is needed to suit the readout interfacing circuit of an ISFET sensor. The MOSFET structure with different W/L ratio has been characterized in order to see the effect of W/L ratio to the isothermal point. The Keithley 236 Parameter Analyzer and Semi-auto prober micromanipulator system were used to measure the drain-source current (IDS) versus gate to source voltage (VGS) curves at various temperatures from 30 °C to 60 °C. The simulation result showed that the reduction of W/L ratio can decrease the isothermal point and this was proven by the actual measurement.
从仿真和实验两方面研究了沟道宽长比对MOSFET-ISFET结构的影响。采用金属氧化物半导体场效应晶体管(MOSFET)对离子敏感场效应管(ISFET)的等温点进行了研究,以适应离子敏感场效应管传感器读出接口电路的需要。为了观察W/L比对等温点的影响,对不同W/L比的MOSFET结构进行了表征。采用Keithley 236参数分析仪和半自动探针微操作系统测量了30 ~ 60℃不同温度下的漏源电流(IDS)与栅源电压(VGS)曲线。仿真结果表明,降低W/L比可以降低等温点,并通过实际测量得到了验证。
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引用次数: 1
Ni80Fe20 V-shaped magnetic core for high performance MEMS sensors and actuators 用于高性能MEMS传感器和执行器的Ni80Fe20 v形磁芯
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706474
U. Abidin, B. Majlis, J. Yunas
Development of integrated ferromagnetic materials structure as magnetic core is crucial for high performance MEMS sensors and actuators. A core structure is able to improve the magnetic flux linkage and concentrate the magnetic flux density in the magnetic device resulting high magnetic field generation. Previous research has utilized various ferromagnetic materials of different structures embedded into the silicon substrate as MEMS magnetic core. This paper presents fabrication of V-shaped magnetic core by anisotropic wet etching of 30 percent potassium hydroxide (KOH) at 75 °C to produce V-shaped silicon cavity structure. Filling process of Permalloy (Ni80Fe20) into the cavity is done by DC electroplating technique. Low current density of 10 mA/cm2 is used to electrodeposit Ni80Fe20 magnetic film in this study. Saccharin addition into the electrolyte composition produced a bright and crack free structure as internal stress in the electrodeposited film is reduced. This effect is essential to have good magnetic properties of the magnetic core. Thicker structure of electroplated Ni80Fe20 is observed at the sharp edges of the V-shaped cavity tip. The reason of this effect to happen is because high current flux density occurrence at those edges. From this work, fabrication of V-shaped Ni80Fe20 magnetic core has been successfully demonstrated. This magnetic core is expected to give superior magnetic performance for on chip MEMS device applications.
开发集成铁磁材料结构作为磁芯是高性能MEMS传感器和执行器的关键。磁芯结构能够改善磁通连接并使磁通密度在磁装置中集中,从而产生高磁场。以往的研究将不同结构的铁磁材料嵌入到硅衬底中作为MEMS磁芯。在75℃条件下,采用30%氢氧化钾(KOH)的各向异性湿法刻蚀制备v型磁芯,制备v型硅腔结构。采用直流电镀技术对坡莫合金(Ni80Fe20)进行填充。本研究采用10 mA/cm2的低电流密度电沉积Ni80Fe20磁膜。在电解液组合物中加入糖精,由于电沉积膜的内应力降低,产生了明亮且无裂纹的结构。这种效应对于具有良好磁性能的磁芯是必不可少的。镀镍Ni80Fe20在v型空腔尖端的锋利边缘处有较厚的组织。产生这种效应的原因是在这些边缘处产生了高电流通量密度。在此基础上,成功地证明了v型Ni80Fe20磁芯的制备。该磁芯有望为片上MEMS器件应用提供优越的磁性能。
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引用次数: 2
Silicon photonics for microelectronic op-chip optical interconnects 用于微电子运算芯片光学互连的硅光子学
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706566
H. Wong
The on-chip interconnects technology has faced a number of challenges in recent years. With the significant advancement in silicon integrated photonics, possibility of introducing on-chip optical interconnects for future gigascale circuits has been explored intensely in the last decade. The successful development of on-chip optical interconnects will be one of the major moves for the next technology revolution for the integrated circuits. Over the years, technology for making optical micro-waveguides based on CMOS processes has been developed and there are several proposals for making Si-based light sources. This talk highlights some attempts reported recently for making waveguide and light emitting devices based on the conventional CMOS processes. These technologies look promising for the on-chip optical interconnects in future gigascale CMOS technology.
近年来,片上互连技术面临着诸多挑战。随着硅集成光子学的显著进步,在过去的十年中,为未来的千兆级电路引入片上光学互连的可能性得到了热烈的探讨。片上光互连的成功开发将是集成电路下一次技术革命的主要举措之一。多年来,基于CMOS工艺制作光微波导的技术得到了发展,并提出了几种制作硅基光源的建议。本次演讲重点介绍了最近报道的基于传统CMOS工艺制造波导和发光器件的一些尝试。这些技术在未来千兆级CMOS技术的片上光互连中具有广阔的应用前景。
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引用次数: 0
Photoresist microbridge pattern optimization at 1μm using conventional photolithography technique 利用传统光刻技术优化1μm光刻胶微桥图案
Pub Date : 2013-09-01 DOI: 10.1109/RSM.2013.6706462
B. S. Rao, M. Nurfaiz, U. Hashim
One of the delicate processes in semiconductor microfabrication is the photolithography. It is the process that sets the design dimensions on various parts of the device. In order to complete this process, two requirements need to be satisfied. First is to create, the exact dimensions and pattern as established in design phase, which in other word can be referred as the resolution of the images on the wafer. The second is the correct placement of the device pattern on the wafer relative to the crystal orientation of the wafer substrate. This is called alignment or registration of patterns in correct position. This registration requirement is similar to the correct alignment of the different floors of a building. It is easy to visualize that misalignment of elevator shafts and stair wells would render the building useless. In a circuit, the effects of misaligned mask layers can cause the entire circuit to fail. In this paper we have reported a couple of results that leads to photoresist development and optimization technique as a standard manufacturing process to form 1μm microbridge for later process of size reduction to form nanogap. Therefore, at the final stage of fabrication, a nano-diagnostic biochip device is developed to use it as a biomolecule detection biosensor. The development of biosensors is still an open field and much remains to be done before many of these bioelectronic devices become commercialized. In this research, the key factors such as resist thickness, post-exposure bake (PEB) time and developer concentration are taken into account to study the optimum measurements and process. The thickness of resist will affect the resolution of image transferred and developing time. Both PEB and developer concentration also has the tendency to affect the device pattern and developing time. As the result, the photoresist thickness is optimized at 1500nm, the developer RD6 concentration diluted at 10:25 (DI water: RD6) and PEB time optimized at 65s.
在半导体微细制造中,光刻技术是一种精细的工艺。它是在设备的各个部件上设置设计尺寸的过程。为了完成这个过程,需要满足两个要求。首先是创建在设计阶段确定的精确尺寸和图案,换句话说,可以称为晶圆上图像的分辨率。第二是器件图案相对于晶圆衬底的晶体取向在晶圆上的正确放置。这称为模式在正确位置的对齐或注册。这一注册要求类似于建筑物不同楼层的正确对齐。很容易想象,电梯井和楼梯井的错位会使建筑毫无用处。在电路中,不对齐的掩模层的影响可能导致整个电路失效。在本文中,我们报告了一些结果,这些结果导致光刻胶的开发和优化技术成为形成1μm微桥的标准制造工艺,并在随后的尺寸减小过程中形成纳米间隙。因此,在制造的最后阶段,开发了一种纳米诊断生物芯片装置,将其用作生物分子检测生物传感器。生物传感器的发展仍然是一个开放的领域,在许多这些生物电子设备商业化之前还有很多工作要做。在本研究中,考虑了抗蚀剂厚度、曝光后烘烤(PEB)时间和显影剂浓度等关键因素,研究了最佳的测量和工艺。抗蚀剂的厚度会影响转印图像的分辨率和显影时间。PEB和显影剂浓度也有影响器件模式和显影时间的趋势。结果表明,光刻胶厚度优化为1500nm,显影剂RD6的稀释浓度为10:25 (DI水:RD6), PEB时间优化为65s。
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引用次数: 1
期刊
RSM 2013 IEEE Regional Symposium on Micro and Nanoelectronics
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