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2011 International Symposium on Advanced Packaging Materials (APM)最新文献

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20 Gigahertz noise suppressor based on ferromagnetic nanowire arrays 基于铁磁纳米线阵列的20ghz噪声抑制器
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105679
Yanqiu Li, Zheng Chen, Liangliang Li, J. Cai
The noise suppressors based on ferromagnetic nanowire arrays were fabricated on the anodic aluminum oxide templates (AAO), and the effects of the width and length of the device and the type of the ferromagnetic nanowire array on the microwave properties of the noise suppressor were investigated. The Co and Co-Ni magnetic nanowires with an average diameter of 200 nm and a length of 10 or 30 μm were electrodeposited in the AAO templates, and the ultrasonic vibration was utilized to promote ionic diffusion and to allow hydrogen to escape easily from the cathode. Scanning electron microscope images showed uniform ferromagnetic nanowires and the hysteresis loops demonstrated that these nanowire arrays had a strong magnetic anisotropy. The resonance frequency of S21 of the noise suppressors reached 25 GHz, indicating that the working frequency of the devices was beyond 20 GHz. The synthetic method of the ferromagnetic nanowires and the fabrication processes of the devices in this work could be applied to other microwave devices such as isolators and circulators. Key words: noise suppressor, S-parameter, ferromagnetic nanowires
在阳极氧化铝模板(AAO)上制备了基于铁磁纳米线阵列的噪声抑制器,研究了器件宽度、长度以及铁磁纳米线阵列类型对噪声抑制器微波性能的影响。在AAO模板中电沉积了平均直径为200 nm、长度为10 μm或30 μm的Co和Co- ni磁性纳米线,并利用超声振动促进离子扩散,使氢容易从阴极中逸出。扫描电镜图像显示均匀的铁磁纳米线,磁滞回线表明这些纳米线阵列具有很强的磁各向异性。噪声抑制器的S21谐振频率达到25 GHz,说明器件的工作频率超过了20 GHz。本文所研究的铁磁纳米线的合成方法和器件的制作工艺可应用于其它微波器件,如隔离器和环行器。关键词:噪声抑制器,s参数,铁磁纳米线
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引用次数: 8
Isocyanate-terminated polydimethylsiloxane-modified epoxy resin: Preparation and curing, characterization and mechanical properties 端部异氰酸酯聚二甲基硅氧烷改性环氧树脂:制备、固化、表征及力学性能
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105745
D. Gui, D. Si, B. Chen, J. Li, X. Yu
Isocyanate-terminated polydimethylsiloxane (ITPDMS) was synthesized by the reaction of Hydroxyl-terminated polydimethylsiloxane (HTPDMS) with Toluene diisocyanate (TDI) and was used to modify epoxy resin (Diglycidyl ether of bisphenol A epoxy resin (DGEBA)). The chemical structure of ITPDMS and ITPDMS/ER was characterized by FTIR. The morphology of fracture surfaces of the ITPDMS/ER cured samples were studied by SEM and the thermal analysis was carried out via TGA. The modified epoxy resin shows biphasic toughness fracture morphology and 5∼6 °C improvement in thermal stability over unmodified epoxy resin with brittle fracture morphology. The mechanical properties were investigated by universal testing machine and DMA. The results show that the modified epoxy resin has better mechanical properties with tensile strength, bending strength and elongation increased by 6.76%, 5.05% and 11.84% respectively than unmodified epoxy resin.
以端羟基聚二甲基硅氧烷(HTPDMS)与甲苯二异氰酸酯(TDI)反应合成端异氰酸酯聚二甲基硅氧烷(ITPDMS),并将其用于环氧树脂(双酚A环氧树脂二甘油酯醚(DGEBA))的改性。用FTIR表征了ITPDMS和ITPDMS/ER的化学结构。利用扫描电镜(SEM)研究了ITPDMS/ER固化试样的断口形貌,并通过热重分析仪(TGA)进行了热分析。与未改性的脆性断裂环氧树脂相比,改性后的环氧树脂表现出双相韧性断裂形貌,热稳定性提高了5 ~ 6℃。采用万能试验机和DMA对其力学性能进行了研究。结果表明,改性后的环氧树脂具有较好的力学性能,抗拉强度、抗弯强度和伸长率分别比未改性的环氧树脂提高6.76%、5.05%和11.84%。
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引用次数: 1
Photoluminescence properties of BaxSryLizSiO4:Ce3+, Mn2+ phosphors for NUV-LED lighting 紫外光led照明用BaxSryLizSiO4:Ce3+, Mn2+荧光粉的光致发光性能
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105689
Yisen Lin, Z. Xiong, L. Hong, H. Xue, Laura Chen
A series of Ce3+, Mn2+ codoped BaxSryLizSiO4:Ce3+, Mn2+ phosphors were synthesized by partially liquid-phase method. The effects of Ba/Sr ratio, Ce/Mn ratio and lithium content on the emission spectra of the BaxSryLizSiO4:Ce3+, Mn2+ (BSLS:Ce, Mn) phosphors were investigated in details, which showed blue emission around 410nm wavelength and red emission at about 620nm wavelength, respectively. With the increasing of Sr/Ba ratio, the color of BSLS:Ce, Mn was changed from orange to red. However, the intensity of blue emission was reduced and red emission was enhanced with an incensement of Mn/Ce ratio. The strongest intensity of emission for the phosphor was obtained at Li content of 15 mol%.
采用部分液相法合成了一系列Ce3+, Mn2+共掺杂BaxSryLizSiO4:Ce3+, Mn2+荧光粉。详细研究了Ba/Sr比、Ce/Mn比和锂含量对BaxSryLizSiO4:Ce3+, Mn2+ (BSLS:Ce, Mn)荧光粉发射光谱的影响。结果表明,BaxSryLizSiO4:Ce3+, Mn2+ (BSLS:Ce, Mn)荧光粉分别在410nm波长附近和620nm波长附近发射蓝光和红光。随着Sr/Ba比的增加,BSLS:Ce, Mn的颜色由橙色变为红色。随着Mn/Ce比的增加,蓝色发射强度降低,红色发射强度增强。当锂含量为15 mol%时,荧光体的发射强度最强。
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引用次数: 0
The research of relationship between the void of DBC and the temperature distribution DBC空穴与温度分布关系的研究
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105692
Xiaofei Lv, Libing Zheng, Xiangdong Kong, Pengyun Jin, Han Li
DBC (Direct bonding Copper) is the most common substrate of IGBT power module in recent years. The existence of voids between the copper and the ceramic is the main process defect. The temperature distribution is multiple because of the differences in the ratio and location of the voids. In this paper, the integration of the test and numerical simulation is used to research the temperature distribution of DBC with different ratios of voids and loads. The results show that the location of the voids between the copper and the ceramic influence the temperature distribution of DBC clearly.
DBC (Direct bonding Copper)是近年来最常用的IGBT功率模块衬底。铜与陶瓷之间存在空隙是主要的工艺缺陷。由于空洞的比例和位置的不同,温度分布是多重的。本文采用试验与数值模拟相结合的方法,研究了不同空隙比和载荷下DBC的温度分布。结果表明,铜与陶瓷之间空隙的位置对DBC的温度分布有明显的影响。
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引用次数: 2
Progress on thermally conductive adhesive for electronic packaging 电子封装用导热胶的研究进展
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105736
Xibing Zhan, T. Jin, Junying Zhang, Jue Cheng
In recent years, with the rapid development of large scale integrated circuit and micro-packaging technology, the electronic components and devices tend to be high miniaturization and intensity. The heat dissipation of electronic components has become more crucial to the overall system because it affects the lifetime, performance and reliability of electronic device[1]. According to survey, the reliability of electronic components decrease by10% with the temperature increase by 2°C[2]. Heat dissipation from microelectronics is most commonly performed by thermal conduction. For this purpose, most of metal materials are used due to their good thermal conductivity, but they have some disadvantages, such as high density, complicated processing technology and poor resistance to corrosion[3]. So many researchers direct their interest to the study of thermal conductive adhesives (TCAs). As we all know, polymer matrix have low heat conductivity, so how to improve the thermal conductivity of TCAs has aroused more and more researcher's attention. In this paper, the thermal conducting mechanism and heat transfer model were introduced. In addition, it's demonstrated in detail that the recent research advances in heat conductive adhesive in the field of fixation and packaging of electronic devices. And then the factors affecting thermal conductivity and methods of enhancing thermal conducting were presented, such as exploiting new filler, modifying the surface of filler and optimizing the technological conditions. Meanwhile, the direction of further development of thermal conductive adhesive in the field of electronics was pointed out.
近年来,随着大规模集成电路和微封装技术的迅速发展,电子元器件和器件趋向于高小型化和高强度化。电子元器件的散热对整个系统的影响越来越重要,因为它影响着电子器件的寿命、性能和可靠性[1]。据调查,温度每升高2℃,电子元件的可靠性就会下降10%[2]。微电子的散热最常用的方式是热传导。为此,大多数金属材料因其导热性好而被采用,但其存在密度大、加工工艺复杂、耐腐蚀性差等缺点[3]。因此,热导胶粘剂(TCAs)的研究引起了许多研究者的兴趣。众所周知,聚合物基体导热系数低,如何提高TCAs的导热系数已引起越来越多研究者的关注。本文介绍了热传导机理和传热模型。此外,还详细阐述了导热胶在电子器件固定和封装领域的最新研究进展。然后提出了影响导热系数的因素和提高导热系数的方法,如开发新型填料、改性填料表面和优化工艺条件等。同时指出了导热胶在电子领域的进一步发展方向。
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引用次数: 0
Investigation on cracked inductors based on finite element analysis 基于有限元分析的裂纹电感器研究
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105713
M. Cai, Daoguo Yang, Y. Tao, Cassie Su, Boyi Wu, Zaifu Cui
I-type ferrite inductors are prone to cracking easily after undergoing cooling and heating cycles. It is necessary to work out a method to improve reliability of the device, even if the cracking does not damage the device directly. In this paper, one failure case on product line is investigated deeply by combining finite element analysis, environmental tests and failure analysis methods. Analysis results show the internal fillet radius R of the inductor affects the stress distribution directly. When the radius size gets smaller, the stress is more concentrated, and the cracking occurs easily. The key stress will decrease by 60–90Mpa when R increases from 0.02mm to 0.7mm, which will greatly improve the reliability of the device. Moreover, the results also show the filler material of the inductor is one of key factors of improving cracking phenomenon. So it can improve the stress distribution to select the optimal filler material. To optimize the entire device, it is necessary to use the existing optimization design method of multivariate nonlinear to synthetically optimize parameters of various materials and size parameters of the device and to find out the best materials and sizes that are suitable for the current process.
i型铁氧体电感在经过冷却和加热循环后容易开裂。有必要研究出一种方法来提高设备的可靠性,即使开裂不会直接损坏设备。本文结合有限元分析、环境试验和失效分析等方法,对某生产线的一个失效案例进行了深入的研究。分析结果表明,电感器内部圆角半径R直接影响应力分布。半径越小,应力越集中,越容易发生开裂。当R从0.02mm增加到0.7mm时,关键应力降低60-90Mpa,大大提高了器件的可靠性。此外,研究结果还表明,电感的填充材料是改善裂纹现象的关键因素之一。因此,选择合适的填充材料可以改善应力分布。为了对整个器件进行优化,需要利用现有的多元非线性优化设计方法,对器件的各种材料参数和尺寸参数进行综合优化,找出适合当前工艺的最佳材料和尺寸。
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引用次数: 1
Comparative study on interfacial reactions between Sn-3.5Ag, Sn-3.0Ag-0.5Cu solder balls and ENEPIG pad after multiple reflows 多次回流后Sn-3.5Ag、Sn-3.0Ag-0.5Cu焊球与ENEPIG焊盘界面反应对比研究
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105717
F. Yang, L. Liu, M. Huang
Nowadays, with electronic products tending to become shorter, smaller, lighter, and thinner, solder balls used to join chips and substrates are also downsizing. This may have an adverse effect on the reliability of electronic products. The focus of this study is on the effect of solder volume on the interfacial reactions between Sn-3.5Ag, Sn-3.0Ag-0.5Cu lead-free solder balls and electroless nickel electroless palladium immersion gold (ENEPIG) pads on printed circuit board (PCB) after various reflows. The diameters of solder balls were 200, 300, 400 and 500 μm, respectively. In the interfacial reaction between Sn-3.5Ag solder balls and ENEPIG pads, as the diameters of the solder balls changed, obvious changes in Ni3Sn4 intermetallic compound (IMC) morphologies and thickness were not found. We attribute this phenomenon to the limited Ni concentration in the solder. When a small amount of Cu was added into Sn-Ag lead-free solder, changes in type, morphology and growth kinetics of interfacial IMCs occurred. In the case of Sn-3.0Ag-0.5Cu/ENEPIG reaction, volume effect in the form of IMC type transition occurred. Only (Ni, Cu)3Sn4 IMCs with morphologies of needle and chunk shape were observed at the interface of 200 μm solder ball. Interestingly, chunk type (Ni, Cu)3Sn4 IMCs co-existed with the octahedron-type (Cu, Ni)6Sn5 IMCs at the interface between Ni-P layer and 300 μm solder ball. And in the case of 400 μm and 500 μm solder balls, only (Cu, Ni)6Sn5 IMCs in the needle-type shape were formed at the interface. This phenomenon was related to the absolute Cu content in the solder which was changed with solder volume.
如今,随着电子产品趋向于变得更短、更小、更轻、更薄,用于连接芯片和衬底的焊料球也在小型化。这可能会对电子产品的可靠性产生不利影响。本研究的重点是研究焊料体积对Sn-3.5Ag、Sn-3.0Ag-0.5Cu无铅焊料球与印刷电路板(PCB)上化学镀镍-化学镀钯浸金(ENEPIG)焊盘在各种回流后界面反应的影响。焊球直径分别为200、300、400和500 μm。在Sn-3.5Ag钎料球与ENEPIG焊盘的界面反应中,随着钎料球直径的变化,Ni3Sn4金属间化合物(IMC)的形貌和厚度没有明显变化。我们将这种现象归因于焊料中镍的浓度有限。在Sn-Ag无铅钎料中加入少量Cu后,界面IMCs的类型、形貌和生长动力学发生了变化。在Sn-3.0Ag-0.5Cu/ENEPIG反应中,出现了IMC型转变形式的体积效应。在200 μm钎料球界面上只观察到针状和块状的(Ni, Cu)3Sn4 IMCs。有趣的是,块状(Ni, Cu)3Sn4 IMCs与八面体(Cu, Ni)6Sn5 IMCs在Ni- p层与300 μm钎料球界面共存。而在400 μm和500 μm的钎料球中,界面处只形成针状的(Cu, Ni)6Sn5 imc。这种现象与焊料中Cu的绝对含量随焊料体积的变化有关。
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引用次数: 4
Annealing effect and crystallization characteristics of copper wire bonding on pre-plated leadframe 预镀引线框架上铜线键合的退火效果及结晶特性
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105727
B. An, L. Ding, Techun Wang, T. Lu, Yiping Wu
Copper wire bonding on pre-plated leadframe (PPF) is an ever-increasing mode of interconnection in electronic packaging to substitute the gold wire bonding in the volume production in the forthcoming years. Reliability from copper wire bonding should however be well known before putting the process into manufacturing. In this letter, the 4N copper wire with 50 μm diameter bonded on PPF substrate was investigated. It was found for some samples that due to the work hardening effect of the copper, low bonding strength in the heel of the 2nd bond between the copper wire and the PPF surface was noticeable. An anneal process was introduced to recover the microstructural weakness, and wire pull tests revealed that it remarkably enhanced the bond strength of the 2nd joint. Interfacial crystallization characteristics have shown the difference between the 1st and the 2nd bonds which were attributed to hot forming and cold forming respectively.
预镀引线框架(PPF)上的铜线键合是电子封装中一种日益增长的互连方式,在未来几年将取代金线键合在量产中。然而,在将该工艺投入生产之前,应该了解铜线粘合的可靠性。本文研究了直径为50 μm的4N铜线在PPF衬底上的键合。在部分试样中,由于铜的加工硬化效应,铜丝与PPF表面的第2键后跟处的结合强度较低。采用退火工艺修复微观组织缺陷,拉丝试验结果表明,退火工艺显著提高了第二接头的结合强度。界面结晶特征表明,第一键和第二键在热成型和冷成型过程中存在差异。
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引用次数: 2
Finite element simulation of thermal properties of 40Si-Al alloys for electronics packaging 电子封装用40Si-Al合金热性能的有限元模拟
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105729
Shen Wei, Pu Yu-ping, Zhao Peng, Zhu Li-ran
Due to lighter, stiffer and offer superior heat-sinking than traditional packaging materials, Si-Al alloys have been proved as novel materials used for packaging microwave hybrid circuitry. In the current paper, finite element geometric models based on the real microstructural images of 40Si-Al are generated. Furthermore, based on Fourier's law for heat conduction and thermal expansion equation, thermal properties including the thermal conductivity and the coefficient of thermal expansion (CTE) of 40Si-Al are quantified by finite element method (FEM). By means of statistical method in conjunction with FEM results, the thermal conductivity and CTE at room temperature are calculated, respectively. The numerical simulation result agrees with the corresponding experimental result, which shows that the methodology developed in this paper is efficient in calculating thermal properties of Si-Al alloys.
由于硅铝合金比传统的封装材料更轻、更硬、具有更好的散热性能,已被证明是用于封装微波混合电路的新型材料。本文基于40Si-Al的真实显微结构图像生成了有限元几何模型。基于傅里叶热传导和热膨胀方程,采用有限元法对40Si-Al的导热系数和热膨胀系数进行了量化。采用统计方法,结合有限元计算结果,分别计算了室温下的导热系数和CTE。数值模拟结果与实验结果吻合,表明本文所建立的方法是计算硅铝合金热性能的有效方法。
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引用次数: 2
Characterization of Al/Cu/W bond pad micro-corrosion Al/Cu/W焊盘微腐蚀的表征
Pub Date : 2011-12-19 DOI: 10.1109/ISAPM.2011.6105706
G. Gong, Li Li, Wei Liu, M. Song, Xue-Song Xu, D.H. Ye, J. Yao
In this paper, micro-corrosion of Al/Cu/W bond pad was studied. During DI water cleaning process, theta phase Al2Cu and surrounding Al performed well as typical galvanic cell, resulting in pad metal micro-corrosion. DI water with Pb2+ is thought to be outside electrical path of the galvanic cell. It is firmly believed that Pb-contained particles on top of Al2Cu and surrounding Al oxide and/or hydroxide were the cathodic and anodic reaction product respectively.
本文对Al/Cu/W焊盘的微腐蚀进行了研究。在DI水清洗过程中,θ相Al2Cu和周围Al表现良好,与典型原电池一样,导致焊盘金属微腐蚀。含Pb2+的去离子水被认为在原电池的电路外。结果表明,Al2Cu表面的含pb颗粒和周围的氧化铝和/或氢氧化物分别是阴极反应产物和阳极反应产物。
{"title":"Characterization of Al/Cu/W bond pad micro-corrosion","authors":"G. Gong, Li Li, Wei Liu, M. Song, Xue-Song Xu, D.H. Ye, J. Yao","doi":"10.1109/ISAPM.2011.6105706","DOIUrl":"https://doi.org/10.1109/ISAPM.2011.6105706","url":null,"abstract":"In this paper, micro-corrosion of Al/Cu/W bond pad was studied. During DI water cleaning process, theta phase Al2Cu and surrounding Al performed well as typical galvanic cell, resulting in pad metal micro-corrosion. DI water with Pb2+ is thought to be outside electrical path of the galvanic cell. It is firmly believed that Pb-contained particles on top of Al2Cu and surrounding Al oxide and/or hydroxide were the cathodic and anodic reaction product respectively.","PeriodicalId":6440,"journal":{"name":"2011 International Symposium on Advanced Packaging Materials (APM)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73067040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
2011 International Symposium on Advanced Packaging Materials (APM)
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